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The purpose of this paper is to improve the strength and adhesion properties of modified acrylic polyol resin using epoxy polyol resin (DEGBA).

The hybrid systems were prepared by blending acrylic resin with epoxy polyol resin (Diglycidyl Ether of Bisphenol‐A, DGEBA) and polyisocyanate resin as hardener in various weight ratios with xylene as a solvent. The samples were applied on the pre‐treated cold rolled mild steel panels. The mechanical property of the blend has been evaluated using rapid impact tester (Sheen 806/40) and adhesion tester (Sheen Cross‐Hatch 750). Intended panels were checked for cracks using Dino‐Lite and Pinhole detectors (Elcometer 270/4). Crossed panels were observed for damages using digital polarized microscope (Dino‐Lite, AM413ZT). The thermal properties were studied using thermal analysis system (TGA TA‐Q500, DSC TA‐Q200).

The modification of acrylic polyol resins using DGEBA showed significant improvement of toughness compared to pure acrylic polyol resins. The blending systems with 10 wt percent of DGEBA and 90 wt percent of acrylic resin showed good adhesion and impact resistance properties on mild steel substrate.

The hybrid coating system has contributed to the basic conceptual understanding of the corrosion protection property, focusing mainly on recent research available.

The blending method provided a simple and practical solution to improve the toughness of acrylic polyol resins.

The method for enhanced toughness of cured acrylic was novel and functionality of coating critically depends on adhesion between the coatings and underlying metal substrate.

UV‐curable systems based on the copolymerisation of a typical acrylic resin with low amount of fluorinated monomers (less than 1 per cent w/w) were prepared. The bulk properties of the films were unchanged, while a strong modification of the surface was obtained, depending on the monomer structure, on its concentration and on the type of substrate.

Acryclic copolymers from methacrylic acid‐ethyl acrylate or butylacrylate were prepared and incorporated into the castor oil alkyd structure. The neutralised product was water soluble. Water soluble hexamethoxy methyl melamine resin was prepared and used as curing agent. Several proportions of water soluble acrylic modified alkyds and hexamethoxy methyl melamine resin were examined at various baking schedules. It was established that 30% of the curing agent gave most satisfactory properties after baking at 150°C for 30 minutes. It was found that ethyl acrylate modified compositions had better scratch hardness and acid resistance than those of the butyl acrylate modified composition. However, the latter had better alkali resistance. These surface coating compositions have been recommended as industrial primers.

Although the original finish market is quite large, the automotive refinish market is substantially larger in dollar volume, comprising a wide variety of products for automotive refinishing needs. Some of the major products for the refinish market include: 1. primer‐surfacers, 2. synthetic primers, 3. acrylic lacquers, 4. cellulose nitrate lacquers, 5. alkyd enamels, 6. acrylic enamels, 7. sealers, 8. urethane enamels, and 9. speciality products.

This paper aims to improve some properties of poly (methyl methacrylate) by copolymerization with butyl acrylate (BA) monomer along with the incorporation of the stable and economical synthesized silicone-containing monomer hexamethyldisilazanomethacryloxyphenyl ketone (HDMK) into the copolymer matrix.

For this target solution copolymerization of methyl methacrylate (MMA), BA and HDMK were carried out using a 250 mL four-necked round-bottom flask. Before solution polymerization start-up, the reaction vessel was first charged with 34.8 mL toluene and heated to 170 °C with stirring and reflux cooling. A monomer mixture of 25.86 g (260 mmol) MMA, 26.40 g (200 mmol) BA, 3.00 g (8.60 mmol) HDMK and 0.45 g (2.00 mmol) dibenzoyl peroxide was added continuously from the dropping funnel over a period of 4 h.

The HDMK was successfully synthesized and the water resistance of acrylic resins was improved because of the existence of HDMK.

The materials that were used in this research paper had a reasonably low cost. Also, the procedures for synthesis of monomers and polymers were extremely easy because there was no need for high pressure or temperature and no dangerous solvents were used.

The acrylic resin that contained HDMK was used to synthesis a white architectural paint for exterior coating. Examining the paint characteristics has shown acceptable washing and abrasion resistance, good brushing, excellent storage stability and great surface coating.

HDMK was synthesized for the first time.

This study aims to use hexanediol, pentaerythritol and keratin as crosslinking agents on the acrylic fabric used as garments.

Plain 1/1 acrylic fabric was produced with 14 and 11 weft yarn/cm using yarn count 28/2 Ne, then it was modified with different agents, and the effect of crosslinking on some of the inherent properties was determined. The color strength as well as washing fastness was evaluated. The Fourier transform infrared spectroscopy determined the changes that acted in the structure of the treated acrylic fabrics. Several physical and functional utility characteristics were studied such as stiffness, crease recovery, tensile strength and elongation, pilling, air permeability, absorbency and static electricity.

Polyacrylonitrile is one of the man-made materials used in the textile field; despite novel characteristics, it has some negative properties, especially in absorbency and pilling, which are improved after treatment.

The results presented that the different conditions that were used with cross-linkers enhanced the acrylic fabrics properties. Where analysis of variance test at P-value 0.05 and radar chart area offered that the treated acrylic fabric with 5% (w/v) keratin accomplished the highest preferable properties for end use.

Fluorine materials have received the keen attention of many researchers because of their water repellency and low surface free energy. The purpose of this paper is to prepare fluorine-containing soap-free acrylic emulsion, which sodium allyoxypropyl hydroxypropyl sulfonate (COPS-1) and anionic emulsifier sodium a-alkenyl sulfonate (a-AOS) were combined as polymerizable emulsifier, and undecylenic acid (UA) and dodecafluoroheptyl methacrylate(DFMA) were introduced as functional monomer.

The fluorinated polyacrylate emulsion was successfully prepared by semi-continuous seed emulsion polymerization, wherein the main monomers were methyl methacrylate (MMA) and butyl methacrylate (BA), and the initiator was potassium persulfate (KPS). Sodium alloxypropyl sulfonate (COPS-1) and an anionic emulsifier sodium a-alkenyl sulfonate (a-AOS) were compounded as a polymerizable emulsifier. Besides, undecylenic acid (UA) and dodecafluoroheptyl methacrylate (DFMA) were introduced as the functional monomers.

The optimum recipe of preparing the modified latex is as follows: the amount of emulsifier was 4%, the ratio of emulsifier (COPS-1: AOS) was 3: 1, and the content of initiator was 0.6%. In this case, the conversion rate of acrylic polymer emulsion was high and the polymerization stability was good. When the amount of monomer UA was 2% and the amount of DFMA was 4%, the overall performance of the emulsion was the best.

The fluorine-containing soap-free acrylic emulsion is prepared via semi-continuous seeded emulsion polymerisation, which sodium allyoxypropyl hydroxypropyl sulfonate (COPS-1) and anionic emulsifier sodium a-alkenyl sulfonate (a-AOS) were combined as polymerizable emulsifier, and undecylenic acid (UA) and dodecafluoroheptyl methacrylate (DFMA) were introduced as functional monomer. There are two main innovations. One is that the fluorine-containing soap-free acrylic emulsion is prepared successfully. The other is that the undecylenic acid is introduced as functional monomer.

Polymeric fibres that have a unique capability to change their structure in response to small environmental changes such as pH, electrolyte and electric field are an attractive alternative for artificial muscles. Stimuli sensitive fibres were prepared by the modification of commercial polyacrylonitrile (PAN) fibres. The modification was carried out in two steps: thermo-oxidation and hydrolysis. During the thermo-oxidation step, the crosslinks imparted through the pendant nitrile groups provided a stable structure. While in the subsequent saponification step, the uncrosslinked nitrile groups were converted to responsive carboxylic acid groups. The effect of stabilization parameters and saponification conditions on the structure, properties and swelling behaviour of these fibres was investigated. The fibres showed muscle like expanding and contracting behaviour stimulated by changes in pH of the environment.

The purpose of this paper is to develop the efficiency of styrene-acrylate (SA) emulsions for polymer cement waterproof coatings with improved bacteria resistance and mechanical properties.

For effective bacteria resistance and excellent mechanical properties, various concentrations of methacryloxyethylhexadecyl dimethylammonium bromide (MHDB) were synthesised and incorporated into SA emulsions. The properties of SA emulsions modified with MHDB were characterised and compared with those of unmodified ones according to the formulations of polymer cement waterproof coatings.

The SA emulsions modified with MHDB exhibited significant enhancement of bacteria resistance and mechanical properties over the unmodified ones. The positive quaternary nitrogen and long-chain alkyl groups of MHDB in SA emulsions could attract phospholipid head groups of bacterial and insert them into the cell wall, which results in biomass leak and bactericidal effect. Moreover, MHDB as a softened monomer was beneficial to the synthesis of SA copolymer with low glass-transition temperature (T_g), then the copolymer and cement would form a more compact film which was the main reason for the enhancement of mechanical properties.

The modifier MHDB was synthesised from diethylaminoethyl methacrylate (DEAM) and 1-bromohexadecane. Besides, the congeners of MHDB could be synthesised from DEAM and 1-bromododecane, 1-tetradecyl dromide, 1-octadecyl bromide, etc. In addition, the efficiency of other modifications into SA emulsions for antibacterial polymer cement waterproof coatings could be studied as well.

The method provided a practical solution for the improvement of water-based antibacterial acrylate polymer cement waterproof coatings.

The method for enhancing bacteria resistance and mechanical properties of the waterproof coating was novel and valuable.

This paper details the use of isophthalic acid and trimellitic anhydride for the design and production of water reducible alkyd coatings. The performance of these systems is equal to or better than conventional solvent based systems. The use of special processing, compounding or application equipment is not required for the production of these coatings, however, the raw materials must be carefully selected to ensure optimum performance. Both water reducible alkyds and water reducible acrylated alkyds for air drying and force cured applications will be discussed. Coatings manufacturers in the United States have commercialized these systems for applications varying from air dry implement enamels to interior can coatings.