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The purpose of this paper is to report on a method of synthesis of TiO₂‐SiO₂ oxide composites characterised by spherically shaped particles with sizes in the micrometric ranges, which can be applied as a new generation of textile/TiO₂‐SiO₂ composites with barrier properties against UV radiation. Synthesis and characterisation of TiO2‐SiO2 oxide composites with a high degree of dispersion were performed, and their influence on the barrier properties of textile fabrics was investigated.

The precipitation was performed with the use of solutions of titanium sulphate and sodium silicate as the precipitating agent, which are cheap alternatives to organic precursors of Ti and Si. The reaction was conducted in an emulsion system, where cyclohexane was used as the organic phase and non‐ionic surfactants NP3 and NP6 as emulsifiers were applied.

The direction of substrate supply, concentration of the reagents and their ratio and other conditions of precipitation process were found to significantly affect the physicochemical parameters of the pigments obtained. A possibility is provided of manufacturing a new generation of textile/TiO2‐SiO2 composites with barrier properties against UV radiation.

Titanium sulphate, sodium silicate, cyclohexane as the organic phase, and non‐ionic surfactants NP3 and NP6 as emulsifiers, were used.

Synthesis of a new generation of textile/TiO2‐SiO2 composites with barrier properties against UV radiation has been performed. Textile fabrics modified with hybrid composites demonstrated high absorption of UV radiation over the full wavelength range.

Determination of optimum conditions of TiO2‐SiO2 oxide composites precipitation to obtain products with desired physicochemical, dispersive and structural properties. Development of nano‐structural textile composites with barrier properties, protecting against UV radiation.

The purpose of this paper is to help reduce power consumption by using platinum‐based microhotplate with different dielectric membranes SiO2 and Si3N4 for gas sensing applications, and to develop platinum lift‐off process using DC sputtering method for fabrication of platinum resistor.

Semiconductor gas sensors normally require high power consumption because of their elevated operating temperature 300‐600°C. Considering the thermal resistant and sensitive characteristics of metal platinum as well as heat and electricity insulating characteristics of SiO2, Si3N4 and combination of both, a kind of the Si‐substrate microhotplate was designed and simulated using ANSYS 10.0 tool. Thermal oxidation of Si wafer was carried out to get a 1.0 μm thick SiO2 layer. Pt deposition on oxidized silicon substrate by lift‐off was carried out using DC sputtering technique.

The platinum‐based microhotplate requires 31.3‐70.5 mW power to create the temperature 348‐752°C for gas sensing applications. The SiO2 membrane can operate the gas sensitive film at higher temperature than the Si3N4 and combination of both the membranes at same power consumption. The paper also presents the FEM simulation of different heating elements like nichrome and tantalum and its comparison to platinum for microhotplate applications.

Both the simulation and experimental work provides the low cost, high yield and repeatability in realization of microhotplate. The design and simulation work provides the better selection of heating elements and dielectric membranes. The developed experimental process provides the easy fabrication of platinum resistors using DC sputtering technique.

Presents the outcome of intensive research into highly dispersed sodium‐aluminium silicate. Optimal conditions of the precipitation process of sodium‐aluminium silicates of high dispersion degrees from the solution of sodium metasilicate were given. In the precipitation process water soluble aluminium salts were used. A physicochemical analysis and microscopic structure of the obtained silicates were performed. The products obtained are characterized by parameters comparable to those of the sodium‐aluminium silicate P‐820 (Degussa).

We have developed a computer oxidation modeling program, named NOVEL, which has been integrated into our process simulator FINDPRO. It combines the modified Deal‐Grove growth rate model with a nonlinear viscoclastic deformation model to predict both the oxide shape and stress. Modeling the thermal oxidation of silicon presents several numerical challenges. First, the oxide region expands and deforms extensively during the process which has to be modeled as a moving boundary, large deformation problem. Second, the SiO2 mechanical property changes from clastic to viscoclastic to viscous as the processing temperature is changed from a value below the the glass transition temperature (960°C) to one above it. The viscoclastic deformation model which is adequate over the entire temperature range of interest has an intrinsic numerical singularity when the oxide viscosity (divided by time) becomes relatively lower than the elastic modulus at high temperatures. These must be handled appropriately to ensure that the modeled results are correct. In this paper, we present details of how NOVEL solves the above mentioned problems. We show examples of low temperature/high pressure oxidation of a LOCOS structure, trench isolation structure, and the technique by which the finite element program NOVEL interfaces with the finite difference process simulator FINDPRO.

This contribution aims to introduce an effective low cost polymer-nanocomposite for possible application to achieve a super protection for highly damaged ancient Egyptian wall paintings.

SiO2 and Al2O3 nanoparticles were synthesized by the sol-gel method. Then, the polymer-nanocomposite was prepared by simple mixing and dispersing the nanoparticles into the tetraethoxysilane polymer solution, with the aid of an ultrasonic dismembrator. The application of the polymer-nanocomposite and other polymeric nanodispersions, on laboratory models, was performed by the brushing technique. Next, the materials stability was evaluated by means of digital optical microscope, colorimetry, FE-scanning electron microscope, measuring the static contact angle and water absorption rates.

The results were promising in creating a superhydrophobicity and the static contact angle (?S) measured for the polymer-nanocomposite reached 135o. An average of three measurements of the water absorption rate after polymer-nanocomposite treatment was 0.66 g/m2 s, compared to 2.60 g/m2 s for the control model (untreated). Further, an average of color difference (?E*) for the treated surface was 2.78, and after the accelerated thermal aging was 3.6. Observing the surface morphology, the polymer-nanocomposite enhanced the roughness of the treated surface and showed a high resistance to laboratory salt weathering.

Preparation of a polymer-nanocomposite by adding SiO2 and Al2O3 NPs to tetraethoxysilane polymer has been proposed. As a promising conservation material, the produced polymer-nanocomposite helped to form an efficient protective film.

This paper attains to develop an economic polymer-nanocomposite to maintain a high protection to damaged ancient Egyptian wall paintings and similar objects.

Reviews some of the more important technologies used for fabricating microcomponents and systems – bulk silicon micromachining, surface micromachining and LIGA, a process for forming deep microstructures by lithography, electroforming and moulding. Discusses the relative merits of using synchroton, electron beam and excimer laser irradiation. Gives a comb actuator and an electrostatic motor as examples of micromachined components.

The purpose of this paper is to enhance the anticorrosion property of aluminium pigments and to improve their compatibility with polymers in coating.

Aluminium pigments encapsulated by organic‐inorganic layer were prepared by hydrolysis and condensation of organic silane acrylate resin and tetraethoxy silane (TEOS) on the surface of pigments via sol‐gel method. TEOS and poly (methyl methacryalte‐n‐butyl acrylate‐vinyl triethoxysilane) (PMBV) formed in advance by co‐polymerisation of methyl methacrylate (MMA), n‐butyl acrylate (BA) and vinyl triethoxysilane (VTES) were used as precursors. The adhesion property of the aluminium pigments was measured by peel test, and the loss of silvery appearance after encapsulation and acid soaking were both evaluated by colour lightness difference (ΔL) measurement. The encapsulated aluminium pigments were further characterised by means of FTIR, SEM, TG and XPS.

It was found that PMBV‐SiO2 thin films could be formed on the surface of aluminium pigments smoothly and uniformly, and the adhesion and anticorrosion performances of encapsulated aluminium pigments were improved significantly.

The organic silane acrylate resin used as a precursor in the sol‐gel process could be synthesised from other aclyate monomers. In addition, the hydrolysis and condensation mechanism of organic silane acrylate resin on the surface of aluminium pigments need further studies.

The method developed provided a good solution to the two problems of aluminium pigments and increased their application values.

The method of improving adhesion and anticorrosion properties of aluminium pigments was novel and could find numerous applications in surface coatings and adhesives.

An efficient method for the calculation of 3‐D stress distributions at embedded structures in silicon caused by different thermal expansion coefficients between silicon and inclusion is presented. The method is based on the analytical solution for the stress field outside a rectangular parallelepipedic trench. This solution is adapted for the calculation of arbitrarily shaped inclusions and for the stress calculation inside the inclusion, too.

The purpose of this paper is to numerically study the phenomenon of separation and subsequent reattachment that happens due to a sudden contraction or expansion in flow geometry, in addition, to investigating the effect of nanoparticles suspended in water on heat transfer enhancement and fluid flow characteristics.

Turbulent forced convection flow over triple forward facing step (FFS) in a duct is numerically studied by using different types of nanofluids. Finite volume method is employed to carry out the numerical investigations. with nanoparticles volume fraction in the range of 1-4 per cent and nanoparticles diameter in the range 30-75 nm, suspended in water. Several parameters were studied, such as the geometrical specification (different step heights), boundary conditions (different Reynolds [Re] numbers), types of fluids (base fluid with different types of nanoparticles), nanoparticle concentration (different volume fractions) and nanoparticle size.

The numerical results indicate that the Nusselt number increases as the volume fraction increases, but it decreases as the diameter of the nanoparticles of nanofluids increases. The turbulent kinetic energy and its dissipation rate increase as Re number increases. The velocity magnitude increases as the density of nanofluids decreases. No significant effect of increasing the three steps heights on Nusselt along the heated wall, except in front of first step where increasing the first step height leads to an increase in the recirculation zone size adjacent to it.

The phenomenon of separation and subsequent reattachment happened due to a sudden contraction or expansion in flow geometry, such as forward facing and backward facing steps, respectively, can be recognized in many engineering applications where heat transfer enhancement is required. Some examples include cooling systems for electronic equipment, heat exchanger, diffusers and chemical process. Understanding the concept of these devices is very important from the engineering point of view.

Convective heat transfer can be enhanced passively by changing flow geometry, boundary conditions, the traditional fluids or by enhancing thermal conductivity of the fluid. Great attention has been paid to increase the thermal conductivity of base fluid by suspending nano-, micro- or larger-sized particles in fluid. The products from suspending these particles in the base fluid are called nanofluids. Many studies have been conducted to investigate the heat transfer and fluid flow characteristics over FFS. This study is the first where nanofluids are employed as working fluids for flow over triple FFS.

In this paper the boundary conditions for point defect distributions in monocrystalline silicon are investigated. These boundary conditions are established by simple thermodynamic considerations. A circle process is used including vacancy, interstitial and Frenkel pair generation which yields a simple relationship between the vacancy and interstitial equilibrium concentrations at the surface. A new OED model is also presented which explains the t−1/4 behaviour of the interstitial supersaturation. This model is used to simulate experiments of Mizuo and Higuchi. In this way values for the equilibrium concentrations and the diffusion coefficients of vacancies and interstitials are obtained.