Search results

The flammability of epoxy resin is a major disadvantage in applications that require flame resistance. Epoxy monomers and hardeners containing flame-retardant elements are molecularly incorporated in the resin network are expected to exhibit better flame resistance than those borne on an additive approach. In recent years, because of health and environmental regulation, the use of waterborne coatings has received many attentions. However, waterborne epoxy resin curing agent with excellent flame retardancy has been seldom reported. The paper aims to study the preparation of waterborne P-N-containing epoxy resin curing agent and its performances (P-N – phosphorous and nitrogen).

Waterborne P-N-containing epoxy curing agent was prepared in this study using reactive flame retardant 10-(2,5-dihydroxyphenyl)-9,10-dihydro-9-xa-10-phosphaphenanthrene-10-oxide, liquid epoxy resin, triethylenetetramine and butyl glycidyl ether at the mole ratio of 1.0:2.0:2.0:2.0.

The results show that the epoxy thermoset from the prepared P-N-containing curing agent presents good flame retardancy and can pass the V-1 rating, and the cured epoxy thermoset film presents excellent performances such as water resistance, adhesion, impact resistance and pencil hardness. This study provides useful suggestions for the application of the water-borne flame retardancy epoxy resins in coating industry.

Each step of products during the preparation of waterborne P-N-containing epoxy curing agent cannot be accurately tested.

This method for synthesis of waterborne P-N-containing epoxy curing agent is novel and could be used for various applications in epoxy coating industry.

The silicone modifications of two-component epoxy resin coatings are commonly built on epoxy resins rather than on epoxy curing agents. The silicone-modified epoxy curing agent system is rarely reported yet. This study aims to prepare the polysiloxane (PS)-modified waterborne epoxy coatings based on aqueous curing agents technology.

Waterborne epoxy curing agents with different contents of terminal epoxy PS were synthesized by reacting with triethylenetetramine, followed by incorporating of epoxy resin (NPEL-128) and polyethylene glycol diglycidyl ether. The waterborne epoxy coatings were prepared with the above curing agents, and their performance was investigated through thermogravimetric analysis, scanning electron microscopy, mechanical characterization, gloss measurement, chemical resistance test and ultraviolet (UV) aging experiment.

The results showed that the epoxy coating prepared by silicon-modified curing agent has higher gloss, better chemical resistance and UV resistance than the coating from unmodified curing agent with terminal epoxy PS and commercially available waterborne epoxy curing agent (Aradur 3986), as well as the competitive mechanical properties and heat resistance. Reduced water absorption on fibrous paper was also obtained with the help of silicon-modified curing agent.

These findings will be valuable for resin researchers in addressing the modification issues about waterborne epoxy resin and curing agent.

This study aims to construct a double layer heat insulation coating based on hollow glass microspheres (HGMs) and to investigate the effect of particle size on barrier property and heat insulation performance.

The waterborne double layer coating was composed of an anticorrosive epoxy ester primer and an HGM-containing silicone acrylic topcoat. With varied HGM sizes (20 μm, 40 μm, 60 μm and a 1:3 w/w mixture of 20 and 60 μm particles), the coating was immersed in 3.5 wt% NaCl solution for 28 days and was then subjected to a salt spray test for 450 h. The barrier properties of the coating were evaluated through electrochemical impedance spectroscopy. Heat insulation performance was examined using a self-made device.

The addition of HGMs decreased the barrier properties of the coating by creating particle/resin interfaces for water penetration. In the HGMs-containing coatings, the use of larger HGMs showed relatively good barrier properties because of the lower particle density. The coating with smaller particles yielded a higher heat insulating capacity as indicated by lower equilibrium temperatures.

Future work will be focused on improving the barrier properties of the coating. Field exposure tests should also be performed to assess the long-term performance of the coating.

The mechanical properties of the coatings in this study also implied that HGMs can be used to develop scratch-resistant and impact-resistant coatings. Other potential applications for further studies include the uses of HGMs for coatings with improved fire retardancy and electromagnetic interference shielding.

A double layer coating was developed to provide balanced performance on both anticorrosion and heat insulation. The effects of HGM size were particularly highlighted.

In this work, the authors used reversible addition-fragmentation transfer (RAFT) polymerization to develop a new cationic acrylate modified epoxy resin emulsion for water-borne inkjet which have the advantages of both polyacrylate and epoxy resin. The emulsion was successfully used in the canvas coating for inkjet printing. This paper aims to contribute to the development of novel cationic emulsions for inkjet printing industry.

In this work, the epoxy acrylate was synthesized from RAFT agent and epoxy resin firstly. Cationic macromolecular emulsifier was prepared by RAFT polymerization, using 2,2’-Azobisisobutyronitrile as initiator, 2-(dimethylamino)ethyl methacrylate and styrene as monomer, which was directly used to prepare the emulsion. The influences of the amount of 2-(dimethylamino)ethyl methacrylate on particle size, zeta potential and water contact angle were studied. Finally, the cationic emulsion was used to print images by inkjet printing.

The emulsion has the smallest particle size, the highest potential and the highest water contact angle when the DM content is 13 Wt.%. The transmission electron microscopy analysis reveals the latex particles is core-shell sphere with the diameters in the range 120–200 nm. The emulsion was successfully used in the canvas coating for inkjet printing. This work will contribute to the development of novel cationic emulsions for inkjet printing industry.

The emulsion was successfully used in the canvas coating for inkjet printing. This work will contribute to the development of novel cationic emulsions for inkjet printing industry.

The purpose of this study is to prepare a new self-emulsified waterborne epoxy hardener which can emulsify the liquid epoxy resin in aqueous media without addition of acid neutralizers.

Two synthetic steps were adopted to prepare novel self-emulsified amine-epoxy adduct type hardener composition based on the reaction of a commercially available polyetheramine, bisphenol A epoxy resin and triethylene tetramine. The different factors affecting the synthesis of the waterborne epoxy hardener were explored by emulsifying and curing properties. The process and products were analyzed and confirmed by FIRT.

Compared to an introduction of polyether as a hydrophilic segment in previous literature, whose reaction required Lewis acid catalysts and strict control of the presence of water, the introduction of polyetheramine to obtain a novel self-emulsified waterborne epoxy hardener were concise and convenient by mere two amine-epoxy addition steps in this research. Moreover, the final product offered good film formation with a practical value of mechanical properties, glass transition temperature and water-resistant property.

The self-emulsified waterborne epoxy hardener can be used to prepare water-resistant waterborne coatings from liquid epoxy resins while also providing the option of zero VOC formulations.

Introduction of hydrophilic polyether amine to prepare self-emulsified waterborne epoxy hardener without acid neutralizers has not been systematically studied previously.

A kind of the Z-6020/E-44 modified waterborne hydroxyl acrylate resin (Z-WEA) and its application in volatile organic compound-free waterborne coatings were prepared.

The Z-6020/E-44 modified waterborne hydroxyl acrylate resin (Z-WEA) was obtained dropwise by adding a mixed solution of methyl methacrylate, n-butyl acrylate, hydroxyethyl methacrylate, acrylic acid and an initiator into a pre-prepared solution of isopropyl alcohol and E-44 and by semi-continuous solution polymerization, and this chain was further extended with organosiloxane (Z-6020) through graft copolymer, which was then neutralized with organic base and dispersed with water, with waterborne amino resin curing agent to form a film, and the properties were tested.

The results showed that when the dosage of initiator was 2.5% accounts for the total acrylic monomer, the hydroxyl content was 10%; the dosage of E-44 was 16%; the dosage of Z-6020 was 6%; the mass ratio of hard and soft monomer was 2.0:1; the neutralization was 100%; Z-6020/E-44 modified waterborne hydroxyl acrylate resin (Z-WEA) had excellent dispersion performance in water and storage stability; water absorption of cured film was 7.8%; pencil hardness reached 5H; adhesive force was 1 level; and the film was uniform and endowed with remarkable heat resistance, high gloss and good fullness.

This paper established a method to synthesize Z-6020/E-44 modified waterborne hydroxyl acrylate resin (Z-WEA) with green surfactants that can be used in the coatings, adhesives, finishing agents and so on.

This paper provides a method of preparing Z-6020/E-44 modified waterborne hydroxyl acrylate resin (Z-WEA) and with waterborne amino resin curing agent to form a film, and the film is uniform and endowed with remarkable heat resistance, high gloss and good fullness and meets the requirements of high-grade paint.

The effects of ultrasonication on the epoxy resin and its emulsion were investigated to find out the changes in the M_η and molecular structure of epoxy, as well as its room temperature storage stability, centrifugal stability, particle size and its distribution and particle morphology more importantly with the influence of different ultrasonic irradiation time, power and temperature.

The emulsion was prepared using an emulsifier with epoxy resin and by using phase inversion after subjecting to ultrasound irradiation with a power of 200 W at 50°C for 60 min. The changes in the epoxy resin and its emulsion induced by ultrasound were characterized by Ubbelohde viscometer, FT-IR, ¹³C-NMR, high-speed desktop centrifuge, laser particle size analyzer and transmission electron microscope.

The molecular weight of the epoxy resin was initially decreased and then stabilized by the increasing of ultrasonic irradiation time. The mole rate of the epoxy groups in epoxy molecular were decreased by about 14 per cent, resulting from ultrasonic irradiation. The particle size of the emulsion was decreased, while the particle size distribution became uniform in a certain time. The narrow distribution, stable and uniform of waterborne epoxy resin emulsion with more than 60 days room temperature storage period, 80 per cent of the supernatant volume, about 220 nm average particle size was gained with a power of 200 W at 50°C for 60 min.

To overcome the problems commonly encountered with an epoxy emulsion, for example, short storage period and wider particle size, which limit its practical application, the effects of ultrasonic irradiation on the epoxy resin and its emulsion, were investigated. As the stability of emulsion was improved with the introduction of ultrasonic irradiation, the application of epoxy emulsion was improved.

The room temperature storage stability and centrifugal stability of the emulsion were decreased by the mechanical method, and thus, the benefit of an in-depth understanding of the influence of ultrasonic treatment on epoxy resin and its emulsion could further promote the development of water-based coatings.

This study aims to discuss the effect of carbon fiber on the electric-respone of shape memory epoxy property. Epoxy (EP) is a typical excellent thermosetting shape memory polymer (SMP). To enrich the shape memory epoxy (SMEP) responsive mode, the carbon fiber fabric-reinforced SMEP composites were prepared, and the mechanical properties and the electric- and light-responsive shape memory effect of the composites were investigated and confirmed.

The carbon fiber fabric/SMEP composites were prepared via a dipping method. The carbon fiber fabric was dipped into the waterborne epoxy emulsion and dried at room temperature and then post-cured in the oven at 120 °C for 2 h. The mechanical properties and the multi-responsive shape memory properties of the composites were tested and confirmed via tensile test instrument, DC electrical source and near-infrared (NIR) laser source control system.

The carbon fiber fabric/SMEP composites showed excellent electric- and light-responsive shape memory effect.

High performance and multi-responsive shape memory materials have always been the goal of the scientists. Carbon fiber fabric and SMEP both consist of a good reputation in the field of composites, and the combination of both would set a solid foundation for getting a high performance and multi-responsive shape memory effect materials, which will enrich the responsive mode and broaden the application of SMEP.

Multi-responsive SMEP composites were prepared from waterborne epoxy and carbon fiber fabric.