Synthesis of waterborne hydroxyl acrylate resins and its application in VOC-free waterborne coatings

Abstract

Purpose

A kind of the Z-6020/E-44 modified waterborne hydroxyl acrylate resin (Z-WEA) and its application in volatile organic compound-free waterborne coatings were prepared.

Design/methodology/approach

The Z-6020/E-44 modified waterborne hydroxyl acrylate resin (Z-WEA) was obtained dropwise by adding a mixed solution of methyl methacrylate, n-butyl acrylate, hydroxyethyl methacrylate, acrylic acid and an initiator into a pre-prepared solution of isopropyl alcohol and E-44 and by semi-continuous solution polymerization, and this chain was further extended with organosiloxane (Z-6020) through graft copolymer, which was then neutralized with organic base and dispersed with water, with waterborne amino resin curing agent to form a film, and the properties were tested.

Findings

The results showed that when the dosage of initiator was 2.5% accounts for the total acrylic monomer, the hydroxyl content was 10%; the dosage of E-44 was 16%; the dosage of Z-6020 was 6%; the mass ratio of hard and soft monomer was 2.0:1; the neutralization was 100%; Z-6020/E-44 modified waterborne hydroxyl acrylate resin (Z-WEA) had excellent dispersion performance in water and storage stability; water absorption of cured film was 7.8%; pencil hardness reached 5H; adhesive force was 1 level; and the film was uniform and endowed with remarkable heat resistance, high gloss and good fullness.

Practical implications

This paper established a method to synthesize Z-6020/E-44 modified waterborne hydroxyl acrylate resin (Z-WEA) with green surfactants that can be used in the coatings, adhesives, finishing agents and so on.

Originality/value

This paper provides a method of preparing Z-6020/E-44 modified waterborne hydroxyl acrylate resin (Z-WEA) and with waterborne amino resin curing agent to form a film, and the film is uniform and endowed with remarkable heat resistance, high gloss and good fullness and meets the requirements of high-grade paint.

Citation

Wang, Y., Zhang, Z., Wang, J., Sang, R. and Zhang, W. (2021), "Synthesis of waterborne hydroxyl acrylate resins and its application in VOC-free waterborne coatings", Pigment & Resin Technology, Vol. 50 No. 5, pp. 468-474. https://doi.org/10.1108/PRT-05-2020-0043