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This study aims to investigate the effect of the material thickness and build orientation on the mass transfer of low molecular weight substances through polyamide 12 (PA12) structures produced by laser sintering (LS).

Disc-shaped PA12 sheets having a nominal thickness ranging from 700 to 2,000 µm were built in horizontal, vertical and diagonal orientations and their permeation properties to oxygen and water vapor were measured. The structural properties of the sheets were examined by X-ray micro-computed tomography, differential scanning calorimetry and polarized light microscopy.

All the LS sheets that were investigated had water vapor and oxygen permeation coefficients that are in the range of those of PA12 produced by traditional manufacturing technologies. Despite significant differences in the porosity characteristics, the permeation properties of sheets built in different orientations were similar. The pores seem to have no measurable effect on the mass transfer rates in the sheets, and the transport processes seem to predominantly follow the rules of a regular solution-diffusion mechanism. The results showed a non-significant trend toward thickness-dependent permeation coefficients, which agrees with the observed differences in the crystal structures of the sheets.

The results are an important basis for the qualification of LS technology for direct manufacturing in applications requiring special barrier performance.

This study provides new information on mechanisms of mass transport through LS PA12 and the effect of the material thickness and build orientation. Furthermore, the results enhance understanding of the structural properties of thin polymeric sheets produced by LS.

The purpose of this paper is to evaluate the effect of different amounts of sodium hydroxide (NaOH) introduced during the resin synthesis on the properties of bark‐phenol‐formaldehyde (BPF) adhesives aims at achieving a balance between storage life and other properties of BPF adhesives.

Based on the best synthetic technologies for the production of BPF adhesives obtained in a previous study, a new synthetic technology is developed for the production of BPF adhesives that involve a three‐step addition of NaOH using different amounts of NaOH in the third charge. Gel permeation chromatography is used to evaluate properties of the phenol‐formaldehyde (PF) and BPF adhesives.

The amount of NaOH in the third charge has an important influence on many BPF adhesive properties. The paper determines that the synthetic technology involving three‐step NaOH additions with only water introduced in the third charge of NaOH produces a BPF adhesive with the longest storage life and best bonding strength.

BPF adhesives are very complex systems with many unknown variables.

The improved storage life of the BPF adhesive prepared with the new synthetic technology is comparable to that of a commercial PF adhesive, which indicates that this new technology shows greater potential for commercial applications.

A new synthetic technology is developed to produce a BPF adhesive that is more comparable to commercial PF adhesives than other BPF adhesives in terms of storage life and other resin properties.

This study aims to optimize the preparation conditions and modify the nanofiltration (NF) membranes to prepare high-performance polysulfone/sulfonated polysulfone composite nanofiltration (PSF/SPSF-NF) membranes through interfacial polymerization.

Investigating the impacts of anhydrous piperazine (PIP) concentration, trimesoyl chloride (TMC) concentration and basement membrane type on NF membrane performance, the optimal membrane was prepared. In addition, nano-SiO₂ was added to the active separation layer to modify the NF membranes.

The comprehensive performance of PSF/SPSF-NF membranes was optimized when the concentration of PIP was 0.75 Wt.% and the concentration of TMC was 0.15 Wt.%, at which time the water flux was 66.1 L·m⁻²·h⁻¹ and the retention rate of Na₂SO₄ was 98.1%. The comprehensive performance of polysulfone/sulfonated polysulfone-SiO₂ nanofiltration (PSF/SPSF-SiO₂-NF) membranes was optimized when the blending ratio of nano-SiO₂ to PIP was 2:3, with a pure water flux of 81.9 L·m⁻²·h⁻¹ and a Na₂SO₄ retention rate of 95.9%. Compared to polysulfone nanofiltration (PSF-NF) membranes and PSF/SPSF-NF membranes, NF membranes with nano-SiO₂ increased the flux recovery rate by 22.9% and 8.7%.

PSF/SPSF-SiO2-NF membrane exhibits excellent antifouling properties.

There is currently no literature available on the preparation of NF membranes using polysulfone/sulfonated polysulfone (PSF/SPFS) as a substrate. This provides a method for modifying NF membranes, starting with the modification of the basement membrane and then modifying the active separation layer.

Twenty five litre plastic drums are widely used throughout industry and find application in the printed circuit board (PCB) and metal finishing sectors for the supply of process chemistry to manufacturers. These drums represent an important source of recyclable high density polyethylene since the containers are made of single polymer and constitute an easily recognisable waste stream that provides a homogeneous recyclate. This paper summarises some of the obstacles that have to date inhibited the recycling of the containers used in the PCB and related sectors. It also details work to identify a viable recycling pathway and describes a number of real applications in which the recyclate can be put to use. The issues of contamination that have prevented recycling of these containers are also discussed and plans to establish a proposed industrial cross‐sectoral recycling scheme are also outlined.

Since the film and its formation is basic to the performance of a coating there are, as might be expected, many studies published yearly on film formation and film properties. Following are typical reports.

This paper presents the effects of replacing fine aggregate (FA) with waste foundry sand (WFS) in natural aggregate and construction waste aggregate concrete specimens without and with superplasticizer (SP), silica fume (SF) and fiber (F) to solve the disposal problems of various wastes along with saving the environment. This study aims to investigate the effect of construction waste, WFS along with additives on the stress-strain behavior and development of compressive strength with age.

The various concrete specimen were prepared in mix proportion of 1: 2: 4 (cement (C): sand: coarse aggregate). The water-cement ratio of 0.5 (decreased by 10% for samples containing SP) to grading 1: 2: 4 under air-dry condition was adopted in the preparation of concrete specimens. The compressive strength of various concrete specimen were noticed for 3, 7 and 28 days by applying load through universal testing machine.

Upon adding construction and demolition waste aggregates, the compressive strength of concrete after 28 days was comparable to that of the control concrete specimen. An enhancement in the value of compressive strength is perceived when FA is replaced with WFS to the extent of 10%, 20% and 30%. If both construction and demolition waste aggregate and WFS replacing FA are used, the compressive strength increases. When FA is interchanged with WFS in natural aggregate or construction demolition waste aggregate concrete including usage of SF or F, the compressive strength improves significantly. Further, when construction and demolition waste aggregate and WFS replacing FA including SP are used, the compressive strength improves marginally compared to that of control specimen. The rate of strength development with age is observed to follow similar trend as in control concrete specimen. Therefore, construction and demolition waste and or WFS can be used effectively in concrete confirming an improvement in strength.

The utilization of these wastes in concrete will resolve the problem of their disposal and save the environment.

The purpose of this paper is to check the feasibility of using biomaterial such as of Phragmites-Australis (PA) in cement paste to achieve sustainable building materials.

In this study, cement pastes were prepared by adding locally produced PA fibers in four different volumes: 0%, 0.5%, 1% and 2% for a duration of 180 days. Bottles and prisms were subjected to chemical shrinkage (CS), drying shrinkage (DS), autogenous shrinkage (AS) and expansion tests. Besides, prism specimens were tested for flexural strength and compressive strength. Furthermore, a mathematical model was proposed to determine the variation length change as function of time.

The experimental findings showed that the mechanical properties of cement paste were significantly improved by the addition of 1% PA fiber compared to other PA mixes. The effect of increasing the % of PA fibers reduces the CS, AS, DS and expansion of cement paste. For example, the addition of 2% PA fibers reduces the CS, expansion, AS and DS at 180 days by 36%, 20%, 13% and 10%, respectively compared to the control mix. The proposed nonlinear model fit to the experimental data is appropriate with R2 values above 0.92. There seems to be a strong positive linear correlation between CS and AS/DS with R2 above 0.95. However, there exists a negative linear correlation between CS and expansion.

The PA used in this study was obtained from one specific location. This can exhibit a limitation as soil type may affect PA properties. Also, one method was used to treat the PA fibers.

The utilization of PA fibers in paste may well reduce the formation of cracks and limit its propagation, thus using a biomaterial such as PA in cementitious systems can be an environmentally friendly option as it will make good use of the waste generated and enhance local employment, thereby contributing toward sustainable development.

To the authors best knowledge, there is hardly any research on the effect of PA on the volume stability of cement paste. Therefore, the research outputs are considered to be original.

The purpose of this work is to study the in-situ performance of ternary geopolymer concrete in road repair work. Geopolymer cement concrete is an attractive alternative to Portland cement concrete owing to environmental, economic and performance benefits. Industrial wastes, such as fly ash (FA) and ground granular blast furnace slag (GGBS), have been extensively used to manufacture unitary and binary geopolymer concrete with heat activation (at different temperature); however, it has indicated a limitation for its application in precast industry only.

In the present study, efforts have been made to produce a ternary geopolymer concrete mix, using GGBS, FA and Silica fumes (SF) in varied proportion mixed with 8 M sodium hydroxide (NaOH) as alkali activator and cured at ambient temperature. Total ten geopolymer concrete mixes have been prepared and tested for strength and durability properties and compared with control mix of ordinary Portland cement (OPC). Based on the mechanical properties of various mixes, an optimum geopolymer concrete mix has been identified. The control mix and optimum geopolymer have been studied for microstructural properties through scanning electron microscopy.

The in situ performance of the optimum mix has been assessed when used as a road repair material on a stretch of road. The ternary geopolymer concrete mixes (a) 65% GGBS + 25% FA + 10% SF, (b) 70% GGBS + 20% FA + 10% SF, and (c) 75% GGBS + 15% FA + 10% SF have resulted in good strength at ambient temperature and the mix 75% GGBS + 15% FA + 10% SF have shown good in situ performance when tested for road repair work.

Geopolymer concrete is gaining interest in many fields as an alternative to conventional concrete, as it not only reduces carbon footprint due to huge cement production but also provides a sustainable disposal method for many industrial wastes. This paper focuses on finding some alternative of OPC concrete to reduce dependency on the OPC.

A series of polyurethane/bishydroxyl-terminated polydimethylsiloxane composites (PU/BTPDMS) were prepared. The effect of BTPDMS content on the tribological properties of the PU/BTPDMS composites was studied. The paper aims to discuss these issues.

The composites were prepared by a pre-polymer method. The properties were measured with Fourier transform infrared spectroscopy (FTIR), thermogravimetry analysis (TGA). The friction and wear characteristic of the composites were examined with MRH-3 friction-abrasion testing machine. The worn surfaces of the composites were investigated by scanning electron microscopy (SEM).

Experimental results indicated that the polyurethane modified with 7 percent BTPDMS had better tribological property than pure PU and other PU/BTPDMS composites in the present study. It exhibits lower coefficient of friction (COF) and lower wear rate value, especially under water lubrication.

The polyurethane was synthesized by a pre-polymer method combination with chemical modification.

Recent laboratory research has shown that small additions of monofilament polypropylene fibres in concrete, in diameter range of 22 to 35 micron by 19mm long, reduce the flow of water through the concrete matrix by preventing the transmission of water through the normal modes of ingress, e.g. capillaries, pore structure, covercrete, etc. The implications of these qualities in concrete with polypropylene fibre additions is that cement hydration will be improved, separation of aggregate will be reduced and the flow of water through concrete that causes deterioration from freeze/thaw action and rebar corrosion will be reduced, creating an environment in which enhanced durability may take place. As a consequence, lower life cycle costs and best value will be achieved for concrete use, with an ultimate reduction in the cost of maintaining the aging infrastructure. A unique aspect of this work is that heart and covercrete are analysed and compared with corroborative results.