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Article
Publication date: 3 January 2017

Thanapackiam P., Kumaravel Mallaiya, Rameshkumar S. and Subramanian S.S.

This paper aims to evaluate the inhibition efficiency of norfloxacin on the corrosion of copper in 1.0 M nitric acid and 0.5 M sulfuric acid solutions.

Abstract

Purpose

This paper aims to evaluate the inhibition efficiency of norfloxacin on the corrosion of copper in 1.0 M nitric acid and 0.5 M sulfuric acid solutions.

Design/methodology/approach

Evaluation was carried out by electrochemical techniques such as electrochemical impedance spectroscopy and potentiodynamic polarization studies. Scanning electron microscopy was used, and it finally confirmed the existence of the adsorbed film.

Findings

The electrochemical measurements showed that norfloxacin has good inhibition efficiency on the corrosion of copper in 1.0 M nitric acid and 0.5 M sulfuric acid solutions. The inhibition action of norfloxacin in both of the corrosive media was observed to be of mixed type but with more of cathodic nature. The temperature dependence of the corrosion rate was studied in the temperature range from 35 to 55°C and the activation energy (Ea) was calculated. The adsorption of norfloxacin molecules on copper surface obeyed Langmuir adsorption isotherm. Studies on the potential of zero charge have been carried out to establish the mechanism of adsorption of the inhibitor onto the metal surface. The thermodynamic parameters such as the adsorption equilibrium constant (Kads) and the free energy of adsorption (ΔGads) were calculated. The value of free energy of adsorption very close to −40 kJmol−1 indicates that the adsorption is through electrostatic coulombic attraction and chemisorption. The decrease in value of Ea with the addition of inhibitor also shows the chemisorption of the inhibitor on the metal surface.

Originality/value

This paper indicates that norfloxacin can act as a good inhibitor for the corrosion of copper in both the acid media.

Details

Anti-Corrosion Methods and Materials, vol. 64 no. 1
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 29 August 2023

Chigoziri N. Njoku, Temple Uzoma Maduoma, Wilfred Emori, Rita Emmanuel Odey, Beshel M. Unimke, Emmanuel Yakubu, Cyril C. Anorondu, Daniel I. Udunwa, Onyinyechi C. Njoku and Kechinyere B. Oyoh

Corrosion is a major concern for many industries that use metals as structural or functional materials, and the use of corrosion inhibitors is a widely accepted strategy to…

Abstract

Purpose

Corrosion is a major concern for many industries that use metals as structural or functional materials, and the use of corrosion inhibitors is a widely accepted strategy to protect metals from deterioration in corrosive environments. Moreover, the toxic nature, non-biodegradability and price of most conventional corrosion inhibitors have encouraged the application of greener and more sustainable options, with natural and synthetic drugs being major actors. Hence, this paper aims to stress the capability of natural and synthetic drugs as manageable and sustainable, environmentally friendly solutions to the problem of metal corrosion.

Design/methodology/approach

In this review, the recent developments in the use of natural and synthetic drugs as corrosion inhibitors are explored in detail to highlight the key advancements and drawbacks towards the advantageous utilization of drugs as corrosion inhibitors.

Findings

Corrosion is a critical issue in numerous modern applications, and conventional strategies of corrosion inhibition include the use of toxic and environmentally harmful chemicals. As greener alternatives, natural compounds like plant extracts, essential oils and biopolymers, as well as synthetic drugs, are highlighted in this review. In addition, the advantages and disadvantages of these compounds, as well as their effectiveness in preventing corrosion, are discussed in the review.

Originality/value

This survey stresses on the most recent abilities of natural and synthetic drugs as viable and sustainable, environmentally friendly solutions to the problem of metal corrosion, thus expanding the general knowledge of green corrosion inhibitors.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Content available
Article
Publication date: 31 October 2008

46

Abstract

Details

Nutrition & Food Science, vol. 38 no. 6
Type: Research Article
ISSN: 0034-6659

Content available
Article
Publication date: 6 February 2009

100

Abstract

Details

Nutrition & Food Science, vol. 39 no. 1
Type: Research Article
ISSN: 0034-6659

Article
Publication date: 29 April 2024

Yaqi Diao, Jihui Wang, Renhong Song, Xue Fei, Zhichang Xue and Wenbin Hu

The purpose of this paper is to prepare a multifunctional nanocomposite that is slow-release and resistant to seawater corrosion and biofouling corrosion and to explore the…

Abstract

Purpose

The purpose of this paper is to prepare a multifunctional nanocomposite that is slow-release and resistant to seawater corrosion and biofouling corrosion and to explore the synergistic effect between the two corrosion inhibitors.

Design/methodology/approach

The morphology, structure and release properties of CAP@HNTs, BTA@HNTs and CAP/BTA@HNTs were investigated by scanning electron microscopy, transmission electron microscopy, Fourier transform infrared spectroscopy, specific surface area analysis and UV spectrophotometry. The corrosion resistance and antimicrobial properties were investigated by electrochemical measurements and bioinhibition rate tests, and the synergistic effect between the two corrosion inhibitors was explored by X-ray photoelectron spectroscopy.

Findings

The CAP/BTA@HNTs are responsive to acidic environments and have significantly improved antibacterial and corrosion resistance compared with CAP@HNTs and BTA@HNTs. CAP and BTA have a positive synergistic effect on anticorrosion and antifouling.

Originality/value

Two types of inhibitors, anticorrosion and antifouling, were loaded into the same nanocontainer to prepare a slow-releasable and multifunctional nanocomposite with higher resistance to seawater corrosion and biocorrosion and to explore the synergistic effect of CAP and BTA on corrosion resistance.

Details

Anti-Corrosion Methods and Materials, vol. 71 no. 4
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 10 February 2012

Praufulla Kumar Das

Drugs and pharmaceuticals assume importance in the healthcare system today for their capacity to replace costly treatments like surgery. The pharmaceutical industry is considered…

430

Abstract

Purpose

Drugs and pharmaceuticals assume importance in the healthcare system today for their capacity to replace costly treatments like surgery. The pharmaceutical industry is considered capital intensive and building a new product costs as much as $900 million. Though the cost of developing a new product is significantly low in a country like India, it is substantial. Therefore, perhaps, companies try to go for incremental innovation. This apart, finding new symptoms to promote products, hiding major side effects, publishing data mixing the outcomes of different studies, publishing major outcomes in reputed journals and poor outcome studies in less important journals are some of the strategies being adopted by pharmaceutical companies. The purpose of this paper is to analyze these issues and their impacts on the Indian economy. As most of the Indian pharmaceutical companies are in private hands, this paper focuses on the possible plight of Indian poor in the changing world order.

Design/methodology/approach

This paper draws upon earlier research undertaken by the author. His experience from the pharmaceutical industry as well as the published works of other researchers also helped complete the work.

Findings

The analysis of this paper indicates that in order to avoid the loss of revenue and to keep their businesses floating, drug and pharmaceutical companies resort to information manipulation.

Research limitations/implications

The research is limited to the author's ability to review literatures in the field of marketing and corporate ethics related to drugs and pharmaceuticals. As competition and economic liberalization would have a significant impact on pharmaceutical brand‐success, therefore, perhaps, drug companies would resort to manipulations for survival. This paper is an attempt to alert the society to these sorts of information laundering.

Practical implications

This paper would perhaps provide consumers with necessary information to understand the unethical practices being adopted by drug companies and help them consider what exactly to look for and would press for their right to good health.

Originality/value

This paper is the record of original work done by the author. It would probably fulfil an identified need and would perhaps help the society fight unethical practices being adopted by pharmaceutical companies.

Article
Publication date: 12 February 2018

Fei Li, Jin Chen and Yu-Shan Su

Collaboration with universities is an important innovation strategy for enterprises. However, currently very little research has focused on how such university-industry…

Abstract

Purpose

Collaboration with universities is an important innovation strategy for enterprises. However, currently very little research has focused on how such university-industry collaborative innovation activities should be managed. The paper aims to discuss this issue.

Design/methodology/approach

This paper introduces the university-industry collaborative innovation practices of Zhejiang NHU Company in China. By using a case study as the method, this paper aims to illustrate the mechanism of university-industry collaborative innovation and how to manage the collaborative innovation activities efficiently.

Findings

Zhejiang NHU Company established a university-industry collaborative innovation link through three innovation platforms: the technology R&D center, the ZJU-NHU joint-research center, and the national engineer center. Zhejiang NHU Company manages its collaborative relationships with universities through this innovation network.

Originality/value

NHU Company managed the collaborative relationship efficiently with the institutions, representing an effective degree of university-industry collaborative innovation management.

Details

Journal of Organizational Change Management, vol. 31 no. 1
Type: Research Article
ISSN: 0953-4814

Keywords

Article
Publication date: 4 October 2011

Justin Paul and Pragya Bhawsar

The purpose of this paper is to examine the rationale and synergies of a Japanese firm's acquisition of India's leading pharmaceutical firm, Ranbaxy, and to answer the following…

Abstract

Purpose

The purpose of this paper is to examine the rationale and synergies of a Japanese firm's acquisition of India's leading pharmaceutical firm, Ranbaxy, and to answer the following pertinent questions: could Ranbaxy have been able to survive and succeed, had the firm not gone for this strategic sale to a foreign firm? What is the rationale for this strategic sale immediately after undertaking many major acquisitions during the previous two‐year period? For what strategic reasons did a Japanese firm pay a premium price for this international acquisition?

Design/methodology/approach

An exploratory method was used in this study to analyze the rationale and synergies of the acquisition. The method of case writing has been followed as a design (case situation first, then goes back to the past, then comes back to the current situation).

Findings

The findings confirm that Ranbaxy got a premium price for agreeing to be acquired for their share (much higher price than the market price). Japanese firm Dai‐Ichi got greater market access and control of Ranbaxy, which were driving factors for them to pay a higher share price for Ranbaxy.

Originality/value

This original study gives insight into the points to be taken into consideration while thinking about international acquisitions.

Details

Competitiveness Review: An International Business Journal, vol. 21 no. 5
Type: Research Article
ISSN: 1059-5422

Keywords

Article
Publication date: 28 June 2021

Meimei Zhao, Dalong Li, Yaqin Xu, Xueying Bu, Chen Shen, Libo Wang, Yu Yang and Jingwen Bai

This paper aims to explore the adsorption kinetics of syringin from Syringa oblata Lindl. leaves on macroporous resin and develop an efficient, simple and recyclable technology…

Abstract

Purpose

This paper aims to explore the adsorption kinetics of syringin from Syringa oblata Lindl. leaves on macroporous resin and develop an efficient, simple and recyclable technology for the separation and purification of syringin.

Design/methodology/approach

Static adsorption and desorption properties of six resins were tested to select a suitable resin for the purification of syringin. Langmuir and Freundlich isotherm models were used to estimate the adsorption behavior of syringin on AB-8 resin. Breakthrough point and eluent volume were determined by dynamic adsorption and desorption tests. High-performance liquid chromatography-electrospray ionization-mass spectrometry was applied to identify the syringin in the purified product [syringin product (SP)]. Antioxidant and antibacterial activities of SP in vitro were evaluated by free radical scavenging ability and biofilm formation inhibitory tests.

Findings

AB-8 exhibited the most suitable adsorption and desorption capacity. Adsorption isotherm parameters indicated favorable adsorption between AB-8 and syringin. The optimal results were as follows: for adsorption, the sample concentration was 1.85 mg/mL, the sample volume was 3.5 bed volume (BV), the flow rate was 0.5 mL/min; for desorption, the ethanol concentration was 70%, the elution volume was 2.5 BV, the elution velocity was 1.0 mL/min. SP with 80.28% syringin displayed the potent antioxidant activities and inhibitory effects on biofilm formation of Streptococcus suis.

Originality/value

To the best of authors’ knowledge, there are no reports on purifying syringin from Syringa oblata Lindl. leaves using macroporous resins. This paper may also provide a theoretical reference for the purification of other phenylpropanoid glucosides.

Details

Pigment & Resin Technology, vol. 51 no. 2
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 10 December 2019

Akbar Eslami, Zahra Goodarzvand Chegini, Maryam Khashij, Mohammad Mehralian and Marjan Hashemi

A nanosilica adsorbent was prepared and characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD) and BET.

Abstract

Purpose

A nanosilica adsorbent was prepared and characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD) and BET.

Design/methodology/approach

The optimum conditions for the highest adsorption performance were determined by kinetic modeling. The adsorbent was used for the adsorption of acetaminophen (ACT), and the parameters affecting the adsorption were discussed like pH, initial concentration, contact time and adsorbent dosage. The adsorbent have been characterized by SEM, XRD and BET analysis. The kinetic models including pseudo-first-order and pseudo-second-order with Langmuir and Freundlich isotherm models were applied to investigate the kinetic and isotherms parameters.

Findings

The adsorption of ACT increased to around 95% with the increase of nanosilica concentration to 30 g/L. Moreover, the adsorption process of ACT follows the pseudo-second-order kinetics and the Langmuir isotherm with the maximum adsorption capacity of 609 mg/g.

Practical implications

This study provided a simple and effective way to prepare of nanoadsorbents. This way was conductive to protect environmental and subsequent application for removal of emerging pollutants from aqueous solutions.

Originality/value

The novelty of the study is synthesizing the morphological and structural properties of nanosilica-based adsorbent (specific surface area, pore volume and size, shape and capability) and improving its removal rate through optimizing the synthesis method; and studying the capability of synthesis of nanosilica-based adsorbent for removal of ACT as a main emerging pharmaceutical water contaminant.

Details

Pigment & Resin Technology, vol. 49 no. 1
Type: Research Article
ISSN: 0369-9420

Keywords

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