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A series of polyurethane/bishydroxyl-terminated polydimethylsiloxane composites (PU/BTPDMS) were prepared. The effect of BTPDMS content on the tribological properties of the PU/BTPDMS composites was studied. The paper aims to discuss these issues.

The composites were prepared by a pre-polymer method. The properties were measured with Fourier transform infrared spectroscopy (FTIR), thermogravimetry analysis (TGA). The friction and wear characteristic of the composites were examined with MRH-3 friction-abrasion testing machine. The worn surfaces of the composites were investigated by scanning electron microscopy (SEM).

Experimental results indicated that the polyurethane modified with 7 percent BTPDMS had better tribological property than pure PU and other PU/BTPDMS composites in the present study. It exhibits lower coefficient of friction (COF) and lower wear rate value, especially under water lubrication.

The polyurethane was synthesized by a pre-polymer method combination with chemical modification.

The purpose of this paper is the production of mechanical meta-material samples by rapid prototyping (RP) and replica technique for patient-specific skin graft or cranial implant applications in tissue engineering.

Positive moulds (patterns) were produced by stereolithography-based RP. Impression moulding method was used for the production of silicone products (skin grafts). Alginate was used as a moulding material (negative mould). Room temperature vulcanising silicone was poured into the cavity of alginate mould and then products were produced. TiO₂ powder and carbon fibres were used as reinforcement. Meta-material structured polyurethane reinforced silicone composites were also produced. Liquid components (diisocyanate and polyol) were poured into the mould and then polyurethane was produced. Then, polyurethane was immersed in the liquid silicone.

It is found that non-destructive ultrasonic test is a fast and reliable method. Meta-material-based composites show dome-shaped tensile/synclastic surface properties which are important for the skin graft and cranial implants. Increasing the amounts of cross-linking agent and TiO₂ particles increased the hardness and elastic modulus. Carbon fibre addition enhanced the elastic modulus.

Although there are studies on the meta-materials, there is limited study on the RP of the meta-materials for patient-specific implants (skin grafts). Auxetic surface shows perfect fit to curved surface of the skull. Although there are studies on the silicone and polyurethane composites, there is limited study on the characterisation of mechanical properties by ultrasonic tests and strain gauge analysis.

This paper aims to design a composite, aiming to improve the static puncture resistance through polyurethane impregnated treatment with five concentration gradients.

The relationship between polyurethane concentration, the number of polyester nonwovens, component fiber type (filament or staple) and the static puncture resistance is explored respectively and elaborately.

This study provides a new perspective to design flexible composites with better static puncture resistance, feasible preparation process as well as low cost.

The results show that the static puncture resistance of nonwovens impregnated by polyurethane is improved obviously. Meanwhile the puncture strength-T of nonwovens increases first and then decreases with the increase of the number of layers, and the maximum puncture strength-T is found at 20 layers. Moreover, the composite with filaments illustrates better mechanical resistance.

As the service time of bridges increases, the degradation of bending capacity, the lack of safety reserves and the decrease in bridge reliability are common in early built bridges. Due to the defective lateral hinge joints, hollow slab bridges are prone to cracking of hinge joint between plates, transverse connection failure and stress of single plates under the action of long-term overload and repeated load. These phenomena seriously affect the bending capacity of the hollow slab bridge. This paper aims to describe a new method of simply supported hollow slab bridge reinforcement called polyurethane–cement (PUC) composite flexural reinforcement.

This paper first studies the preparation and tensile and compressive properties of PUC composite materials. Then, relying on the actual bridge strengthening project, the 5 × 20 m prestressed concrete simply supported hollow slab was reinforced with PUC composites with a thickness of 3 cm within 18 m of the beam bottom. Finally, the load test was used to compare the performance of the bridge before and after the strengthening.

Results showed that PUC has high compressive and tensile strengths of 72 and 46 MPa. The static test revealed that the measured values and verification coefficients of the measured points were reduced compared with those before strengthening, the deflection and strain were reduced by more than 15%, the measured section stiffness was improved by approximately 20%. After the strengthening, the lateral connection of the bridge, the strength and rigidity of the structure and the structural integrity and safety reserves were all significantly improved. The application of PUC to the flexural strengthening of the bridge structure has a significant effect.

As a new type of material, PUC composite is light, remarkable and has good performance. When used in the bending strengthening of bridge structures, this material can improve the strength, rigidity, safety reserve and bending capacity of bridges, thus demonstrating its good engineering application prospect.

The purpose of this paper is to investigate the effects of carbon nanotubes (CNTs) on the mechanical, thermal and colour properties of solvent-containing two-component polyurethane (PU) coating.

Fourier transform infrared spectroscopy and observation of dispersion stability were used to assess the effects of acid treatment on CNTs. The CNTs and PU composite coating was synthesised by in situ polymerisation and bending polymerisation, and the mechanical, thermal and colour appearance properties of coating were characterised.

It was found that desirable modifications to CNTs occurred after acid treatment; thus, mainly carboxylic acid groups were introduced onto the surface of CNTs. And the acid-treated CNTs could improve the mechanical and thermal properties of PU coating, and the properties of composite coating was improved more successfully by in situ polymerisation than by blending polymerisation.

The investigation established a method to synthesise CNTs and PU composite coating. The mechanical and thermal properties of PU coating could be improved by the inclusion of CNTs.

This study established a method to synthesise CNTs and PU composite coating by in situ polymerisation and blending polymerisation; the effects of CNTs on modifying mechanical, thermal and colour properties of PU coating were investigated and compared in detail.

The purpose of this paper is to investigate the effects of alkali treatment on adhesion of industrial thermoplastic polyurethane elastomer (TPU)/polyester woven fabric inter-ply hybrid composites.

Inter-ply hybrid composites were exposed to varying concentration of sodium hydroxide at different temperature and time and their mechanical properties including differential scanning calorimetry, scanning electron microscope, tensile and peeling strength evaluated to determine optimal treatment parameters.

Modified polyester fabrics treated with alkali had higher tensile and peeling strengths. Accordingly, alkali treatment roughened the surface of polyester fabric, decreasing warp and weft densities, thus increasing fiber surface energy. The fabric had the highest peeling strength of 3.23 N/mm at treatment of 25% concentration of sodium hydroxide (NaOH). Short-term exposure to ultraviolet had little effect on interfacial adhesion of alkali-treated conveyor belt.

Polyester fabric, applied in reinforcing industrial conveyor belts, is never degreased, roughened, sensitized or activated. In this paper, one-step treatment of polyester fabric was performed to increase its adhesion with polyester inter-ply hybrid composites, providing a reference for practical industrial application.

The method developed in this research is simple and provides a solution to improving the interfacial adhesion of TPU/polyester conveyor belt.

The novel alkali treatment technology has many applications in the interfacial performance of composite materials.

The purpose of this paper is to introduce an innovative transversal tubular braid texture and to study the elastic behavior of its 3 D printed structure comparatively to 3 D printed longitudinal tubular braid texture (maypole) to be used as reinforcement.

Regarding the lack of proper machines for the production of the proposed texture, the structure of samples was produced as a tubular lattice braid texture using a 3 D printer with the fused deposition modeling method subsequent to simulation by Rhinoceros software. The produced specimens were composited by polyurethane resin. The composite samples were evaluated by the split disk mechanical test to obtain their hoop stress. The structures of the reinforced composites were theoretically analyzed by ANSYS software.

The results of the mechanical test and theoretical analysis showed that the composites reinforced with transversal tubular lattice braid have higher strength compared to the composites reinforced with longitudinal ones. This assured that the composite reinforced by transversal tubular lattice braid is reliable to be used as high-performance tube for different applications.

Further work is carried out to produce the innovated complex structure continuously by a specially designed machine and fibrous materials to reinforce tubular composites in an industrial continual process to be applied for high-pressure fluids flows.

The purpose of this study is to review and summarise the existing available literature on lightweight cladding systems to provide detailed information on fire behaviour (ignitibility, heat release rate and smoke toxicity) and various test method protocols. Additionally, the paper discusses the challenges and provides updated knowledge and recommendation on selective-fire mechanisms such as rapid-fire spread, air cavity and fire re-entry behaviours due to dripping and melting of lightweight composite claddings.

A comprehensive literature review on fire behaviour, fire hazard and testing methods of lightweight composite claddings has been conducted in this research. In summarising all possible fire hazards, particular attention is given to the potential impact of toxicity of lightweight cladding fires. In addition, various criteria for fire performance evaluation of lightweight composite claddings are also highlighted. These evaluations are generally categorised as small-, intermediate- and large-scale test methods.

The major challenges of lightweight claddings are rapid fire spread, smoke production and toxicity and inconsistency in fire testing.

The review highlights the current challenges in cladding fire, smoke toxicity, testing system and regulation to provide some research recommendations to address the identified challenges.

With the rapid development of transportation and the continuous increase of traffic volume and load level, some bridges cannot meet the use requirements, and the demand for bridge strengthening is growing. Furthermore, bridges are affected by factors such as structure and external environment. With the increase of service time, the deterioration of bridges is also increasing. In order to avoid the waste caused by demolition and reconstruction, it is necessary to strengthen the bridge accurately and effectively to improve the bearing capacity and durability, eliminate the hidden dangers, and ensure the normal operation of the bridge. It is of great significance to study the strengthening methods. Compared with traditional strengthening methods, the advantages of using new materials and new technology to strengthen bridges are more obvious. This paper introduces a new method for bridge active strengthening, called modified polyurethane cement with prestressed steel wire rope (MPC-PSWR).

Relying on the actual bridge strengthening project, five T-beams of the superstructure of the bridge are taken as the research object, and the T-beams before and after strengthening are evaluated, calculated, and analyzed by finite element simulation and field load test. By comparing the numerical simulation and load test data, the strengthening effect of modified polyurethane cement with prestressed steel wire rope on stiffness, strength, and bearing capacity is verified, which proves that the strengthening effect of MPC-PSWR is effective for strengthening.

MPC-PSWR can effectively reduce deflection, cracks, and strain, thereby significantly improving the flexural capacity of existing bridges. Under the design load, the deflection, crack width, and stress of the strengthened beams decrease in varying degrees. The overall performance of the beams strengthened by MPC-PSWR has been improved, and the flexural performance meets the requirements of the code.

MPC-PSWR is an innovative bridge-strengthening method. Through the analysis of its MPC-PSWR effect, the MPC-PSWR method with reference to significance for the design and construction of similar bridges is put forward.

The aim of this paper is to synthesise polyester/silica hybrid resins and their hybrid polyurethanes via in situ (IS) and blending (BL) methods and to evaluate the effect of preparation method, interaction type and silica content on the physico‐chemical and thermal properties of polyurethane/silica (PU/Silica) hybrid coatings.

Silica particle‐containing silica sol was prepared according to Stöber method using tetraethylorthosilicate as the precursor and then introduced into polyester matrix by in situ and direct blending method. The modified polyester/silica resin was further crosslinked with TMP‐TDI adduct to synthesise PU/Silica hybrid coatings and studied for thermo‐mechanical, physico‐chemical properties.

It was found IS polymerisation caused more polyester segments to chemically bond onto the surface of silica particles than BL process. Results also reveal that due to stronger interaction between silica particles and PU matrix, hybrid resins prepared by IS method confers better properties than BL method and exhibit optimal properties at the critical concentration of 8 wt% silica.

In the present study, silica particles are used to modify properties of polyurethane resins. Many other countless combinations in terms of inorganic filler or organic matrices can be explored to obtain a wide range of interesting properties and applications.

The results obtained in this study will be extremely useful to enhance the understanding of this class of hybrid materials.

Hybrid organic‐inorganic networks offer a new area of material science that has extraordinary implications for developing novel materials that exhibit a diverse range of multi‐functional properties.