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This paper aims to analyze the effect of cerium addition on the microstructure and the mechanical properties of Tin-Silver-Copper (SAC) alloy. The mechanical properties and refined microstructure of a solder joint are vital for the reliability and performance of electronics. SAC305 alloys are potential choices to use as lead-free solders because of their good properties as compared to the conventional Tin-Lead solder alloys. However, the presence of bulk intermetallic compounds (IMCs) in the microstructure of SAC305 alloys affects their overall performance. Therefore, addition of cerium restrains the growth of IMCs and refines the microstructure, hence improving the mechanical performance.

SAC305 alloy is doped with various composition of xCerium (x = 0.15, 0.35, 0.55, 0.75, 0.95) % by weight. Pure elements in powdered form were melted in the presence of argon with periodic stirring to ensure a uniform melted alloy. The molten alloy is then poured into a pre-heated die to obtain a tensile specimen. The yield strength and universal tensile strength were determined using a fixed strain rate of 10 mm per minute or 0.1667 mm s^(−1). The IMCs are identified using X-ray diffraction, whereas the elemental phase composition and microstructure evolution are, respectively, examined by using electron dispersive spectroscopy and scanning electron microscopy.

Improvement in the microstructure and mechanical properties is observed with 0.15% of cerium additions. The tensile test also showed that SAC305-0.15% cerium exhibits more stress-bearing capacity than other compositions. The 0.75% cerium doped alloy indicated some improvement because of a decrease in fracture dislocation regions, but microstructure refinement and the arrangement of IMCs are not those of 0.15% Ce. Different phases of Cu_6 Sn_5, Ag_3 Sn and CeSn_3 and ß-Sn are identified. Therefore, the addition of cerium in lower concentrations and presence of Ce-Sn IMCs improved the grain boundary structure and resulted refinement in the microstructure of the alloy, as well as an enhancement in the mechanical properties.

Characterization of microstructure and evaluation of mechanical properties are carried out to investigate the different composition of SAC305-xCerium alloys. Finally, an optimized cerium composition is selected for solder joint in electronics.

The purpose of this paper is the microstructural and mechanical characterization of a biomedical Ti‐6Al‐4V alloy produced by electron beam melting, and the study of the stability of the as‐built microstructure upon heat treatment.

Ti‐6Al‐4V alloy produced by electron beam melting has been mechanically characterized through tensile and fatigue testing. Its microstructure has been investigated by optical observation after etching and by X‐ray diffractometry analysis. The stability of the microstructure of the as‐built material has been deepened carrying out suitable heat treatments, after an analysis by dilatometry test.

The microstructure of a Ti‐6Al‐4V alloy produced by electron beam melting has a very fine and acicular morphology, because of the intrinsically high‐solidification rate of the process. This microstructure is very stable, and the traditional thermal treatments cannot modify it; the microstructure changes significantly only when an amount of strain is introduced in the material. However, the mechanical properties of the alloy produced by electron beam melting are good.

The paper provides evidence of the microstructural stability of the material produced by electron beam melting. Even if the microstructure of the as‐built material is not recommended by the specific ISO standard, the related mechanical properties are fully satisfactory. This is a significant indication from the point of view of the production of Ti‐6Al‐4V orthopaedic and dental prostheses by electron beam melting.

This paper aims to introduce a novel concept of a double-wire feed (DWF) to alleviate heat accumulation and improve the cooling rate of the molten pool in gas tungsten arc (GTA)-based additive manufacturing (AM), in which the former wire is fed into the arc and the latter wire is melt by the molten pool.

The microstructure, phase composition and mechanical properties of 308 L stainless steel components built by single-wire feed (SWF) AM and DWF-AM are compared, and the differences are analyzed in detail.

The microstructures for both wire feeding modes include δ and γ phases. Compared with the SWF-AM, the sample fabricated in the DWF-AM exhibits finer microstructure, and the microstructure in the middle region is transformed from columnar grains to cellular grains. Microhardness of the sample produced in the DWF-AM is higher than the SWF-AM. In comparison to the SWF-AM, the tensile strength of the specimen fabricated using the DWF-AM reaches 571 MPa and increases by 16.14%.

This study proposes a novel concept of the DWF-AM to reduce heat accumulation as well as enhance the cooling rate of the molten pool, and improved mechanical properties of the 308 L stainless steel component are obtained.

This paper aims to develop a numerical, micromechanical model to predict the evolution of autogenous shrinkage of hydrating cement paste at early age (up to 7 days). Autogeneous shrinkage can be important in high-performance concrete characterized by low water to cement (w/c) ratios. The occurrence of this phenomenon during the first few days of hardening may result in early-age cracking in concrete structures. A good prediction of autogeneous shrinkage is necessary to achieve better understanding of the mechanisms and the deployment of effective measures to prevent early-age cracking.

Three-dimensional digital microstructures from the hydration modelling platform μic of cement paste were used to simulate macroscopic autogenous shrinkage based on the mechanism of capillary tension. Elastic and creep properties of the digital microstructures were calculated by means of finite element (FE) method homogenization. Autogenous shrinkage was then estimated as the average hydrostatic strain resulting from the capillary stress that was globally applied on the simulated digital microstructures. For this estimation, two approaches of homogenization technique, i.e. analytical poro-elasticity and numerical creep-superposition were used.

The comparisons of between the simulated and experimentally measured deformations indicate that the creep-superposition approach is more reasonable to estimate shrinkage at different water to cement ratios. It was found that better estimations could be obtained at low degrees of hydration, by assuming a loosely packed calcium silicate hydrates (C-S-H) growing in the microstructures. The simulation results show how numerical models can be used to upscale from microscopic characteristics of phases to macroscopic composite properties such as elasticity, creep and shrinkage.

While the good predictions of some cement paste properties from the microstructure at early age were obtained, the current models have several limitations that are needed to overcome in the future. Firstly, the limitation of pore-structure representation is not only from lack understanding of C-S-H structure but also from the computational complexity. Secondly, the models do not consider early-age expansion that usually happens in practice and appears to be superimposed on an underlying shrinkage as observed in experiments. Thirdly, the simplified assumptions for mechanical simulation do not accurately reflect the solid–liquid interactions in the real partially saturated system, for example, the globally applying capillary stress on the boundary of the microstructure to find the effective deformation, neglecting water flow and the pore pressure. Last but not least, the models, due to the computational complexities, use many simplifications such as FE approximation, mechanical phase properties and creep statistical data.

This study holistically tackles the phenomenon of autogeneous shrinkage through microstructural modelling. In a first such attempt, the authors have used the same microstructural model to simulate the microstructural development, elastic properties, creep and autogeneous shrinkage. The task of putting these models together was not simple. The authors have successfully handled several problems at each step in an elegant manner. For example, although several earlier studies have pointed out that discrete models are unable to capture the late setting times of cements due to mesh effects, this study offers the most effective solution yet on the problem. It is also the first time that creep and shrinkage have been modelled on a young evolving microstructure that is subjected to a time variable load.

The purpose of this paper is to investigate the density, surface quality, microstructure and mechanical properties of the components of the selective laser melting (SLM) parts made at different building orientations. SLM is an additive manufacturing technique for three-dimensional parts. The process parameters are known to affect the properties of the eventual part. In this study, process parameters were investigated in the building of 316L structures at a variety of building orientations and for which the fracture toughness was measured.

Hardness and tensile tests were carried out to evaluate the effect of consolidation on the mechanical performance of specimens. Optical and electron microscopy were used to characterise the microstructure of the SLM specimens and their effects on properties relating to fracture and the mechanics. It was found that the density of built samples is 96 per cent, and the hardness is similar in comparison to conventional material.

The highest fracture toughness value was found to be 176 MPa m^(1/2) in the oz. building direction, and the lowest value was 145 MPa m^(1/2) in the z building direction. This was due to pores and some cracks at the edge, which are slightly lower in comparison to a conventional product. The build direction does have an effect on the microstructure of parts, which subsequently has an effect upon their mechanical properties and surface quality. Dendritic grain structures were found in oz. samples due to the high temperature gradient, fast cooling rate and reduced porosity. The tensile properties of such parts were found to be better than those made from conventional material.

The relationship between the process parameters, microstructure, surface quality and toughness has not previously been reported.

This paper aims to investigate the possibilities and determination of hot and warm forging of ultrahigh-strength steel 300M and subsequent quenching with accelerated air. Analysis of microstructure and mechanical properties of forged steel 300M focused on investigation of the effect of processing conditions on final properties, such as strength, impact strength and hardness, taking into consideration temperature gradients and within-part strain nonuniformity occurring in forging and direct cooling of aircraft landing gear.

The research involved semi-industrial physical modeling of hot deformation and direct cooling, aided with numerical analysis of both deformation and kinetics of phase transformations on cooling, with process conditions determined on the basis of numerical simulation of industrial process. Examination of forged and quench-tempered samples involved testing mechanical properties (tensile properties, hardness and impact strength) and microstructure.

Three major findings were arrived at: first, assessment of the effects of energy-saving method of cooling conducted directly after forging. Second, tensile properties, hardness and impact strength, were analyzed on the background of microstructure evolution during hot-forging and direct cooling; hence, applied temperature and cooling rates refer to actual condition of the material including varied deformation history. Third, the accelerated air cooling tests were carried out directly after forging with accurately measured and described cooling efficiency, which enabled the acquisition of data for heat treatment simulation with use of untypical cooling media.

The conclusions formulated on the strenght of studies carried out in semi-industrial conditions with the use of model samples, despite strain and strain rate similarity, wait for full-scale verification in industrial conditions. The direct cooling tests carried out in semi-industrial conveyor Quenchtube are of cognitive value. Industrial realization of the process for the analyzed part calls for special construction of the cooling line and provision of higher cooling rate for heavy sections.

The results present microstructure properties’ relations for good-hardenability grade of steel, which is representative of several similar grades used in aircraft industry, which can support design of heat treatment (HT) cycles for similar parts, regardless of whether direct or conventional quenching is used. As they illustrate as-forged and direct-cooled microstructure and resultant mechanical properties, the studies concerning processing the steel of areas of lower temperature are transferable to warm forging processes of medium-carbon alloy steels. The geometry of the part analyzed in the case study is typical of landing gear of many aircrafts; hence, there is the high utility of the results and conclusions.

The direct heat treatment technologies based on utilization of the heat attained in the part after forging allow significant energy savings, which besides cost-effectiveness go along with ecological considerations, especially in the light of CO₂ emission reduction, improving economical balance and competitiveness. The presented results may encourage forgers to use direct cooling, making use of the heat attained in metal after hot forging, for applications to promote environmentally friendly heat treatment-related technologies.

Direct heat treatment typically seems to be reserved for micro alloyed steel grades and sections small enough for sufficient cooling rates. In this light, taking advantage of the heat attained in forged part for energy-saving method of cooling based on direct quenching as an alternative to traditional Q&T treatment used with application to relatively heavy sections is not common. Moreover, in case the warm-work range is reached in any portion of the forged part, effect of direct cooling on warm-forged material is addressed, which is a unique issue to be found in the related studies, whereas in addition to warm forging processes, the results can be transferable to coining, sizing or shot peening operations, where gradient of properties is expected.

The purpose of this paper is to investigate effects of layer thickness on densification, surface morphology, microstructure and mechanical and corrosion properties of 420 stainless steel fabricated by laser-powder bed fusion (L-PBF).

Standard specimens were printed at layer thickness of 10, 20 and 30 µm to characterize Archimedes density, surface roughness, tensile strength, elongation, hardness, microstructural phases and corrosion performance in the as-printed and heat-treated condition.

Archimedes density slightly increased from 7.67 ± 0.02 to 7.70 ± 0.02g/cm³ and notably decreased to 7.35 ± 0.05 g/cm³ as the layer thickness was changed from 20 µm to 10 and 30 µm, respectively. The sensitivity to layer thickness variation was also evident in properties, the ultimate tensile strength of as-printed parts increased from 1050 ± 25 MPa to 1130 ± 35 MPa and decreased to 760 ± 35 MPa, elongation increased from 2.5 ± 0.2% to 2.8 ± 0.3% and decreased to 1.5 ± 0.2, and hardness increased from 55 ± 1 HRC to 57 ± 1 HRC and decreased to 51 ± 1 HRC, respectively. Following heat treatment, the ultimate tensile strength and elongation improved but the general trends of effects of layer thickness remained the same.

Properties obtained by L-PBF are superior to reported properties of 420 stainless steel fabricated by metal injection molding and comparable to wrought properties.

This study successfully the sensitivity of mechanical and corrosion properties of the as-printed and heat-treated parts to not only physical density but also microstructure (martensite content and tempering), as a result of changing the layer thickness. This manuscript also demonstrates porosity evolution as a combination of reduced energy flux and lower packing density for parts processed at an increasing layer thickness.

The research on lead-free solder alloys has increased in past decades due to awareness of the environmental impact of lead contents in soldering alloys. This has led to the introduction and development of different grades of lead-free solder alloys in the global market. Tin-silver-copper is a lead-free alloy which has been acknowledged by different consortia as a good alternative to conventional tin-lead alloy. The purpose of this paper is to provide comprehensive knowledge about the tin-silver-copper series.

The approach of this study reviews the microstructure and some other properties of tin-silver-copper series after the addition of indium, titanium, iron, zinc, zirconium, bismuth, nickel, antimony, gallium, aluminium, cerium, lanthanum, yttrium, erbium, praseodymium, neodymium, ytterbium, nanoparticles of nickel, cobalt, silicon carbide, aluminium oxide, zinc oxide, titanium dioxide, cerium oxide, zirconium oxide and titanium diboride, as well as carbon nanotubes, nickel-coated carbon nanotubes, single-walled carbon nanotubes and graphene-nano-sheets.

The current paper presents a comprehensive review of the tin-silver-copper solder series with possible solutions for improving their microstructure, melting point, mechanical properties and wettability through the addition of different elements/nanoparticles and other materials.

This paper summarises the useful findings of the tin-silver-copper series comprehensively. This information will assist in future work for the design and development of novel lead-free solder alloys.

The purpose of this paper is to develop an automated phase segmentation model from complex microstructure. The mechanical and physical properties of metals and alloys are influenced by their microstructure, and therefore the investigation of microstructure is essential. Coexistence of random or sometimes patterned distribution of different microstructural features such as phase, grains and defects makes microstructure highly complex, and accordingly identification or recognition of individual phase, grains and defects within a microstructure is difficult.

In this perspective, computer vision and image processing techniques are effective to help in understanding and proper interpretation of microscopic image. Microstructure-based image processing mainly focuses on image segmentation, boundary detection and grain size approximation. In this paper, a new approach is presented for automated phase segmentation from 2D microstructure images. The benefit of the proposed work is to identify dominated phase from complex microstructure images. The proposed model is trained and tested with 373 different ultra-high carbon steel (UHCS) microscopic images.

In this paper, Sobel and Watershed transformation algorithms are used for identification of dominating phases, and deep learning model has been used for identification of phase class from microstructural images.

For the first time, the authors have implemented edge detection followed by watershed segmentation and deep learning (convolutional neural network) to identify phases of UHCS microstructure.

The paper presents a wide range of post processing heat treatment cycles performed to Electron Beam Melted (EBM) Ti6Al4V alloy and establishes correlations of heat treat process to microstructure and mechanical property (microhardness). The research also identifies the optimal heat treatment to obtain the best microstructure and mechanical properties (hardness and tensile).

Rectangular bars fabricated using EBM was used to study the different heat treatment cycles. A variety of heat treatments from sub ß-transus, super ß-transus, near ß-transus and solution aircool plus ageing were designed. After the heat treatment process, the samples were analysed for, α lath width, prior ß grain size, microhardness and nanohardness. Tensile tests were done for the heat treated samples showing most refined α lath structure with uniform globular grains.

A clear correlation was observed between α lath width and the microhardness values. The solution aircooled plus aged samples exhibited the best refinement in α-ß morphology with uniform equiaxed grains. The tensile properties of the solution aircooled plus aged samples were comparable to that of the EBM printed samples and better than ASTMF1472 specifications.

There is hardly any prior work related to post processing heat treatment of EBM built Ti6Al4V other than HIP treatments. The variety of heat treatment cycles and its influence in microstructure and properties, studied in this research, gives a clear understanding on how to tailor final microstructures and select the optimal heat treatment process.