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Thiadiazole compounds and their derivatives have carrying capacity and good lubricating properties. However, their poor oil-solubility limited their wide usage in lubricating oil. The study aims to develop thiadiazole lubricant additives with better oil-solubility. When the hindered phenol antioxidation functional group and alkyl-chain are introduced to thiadiazole, the resulting product could have better oil-solubility and excellent antioxidation resistance, anti-wear and corrosion resistance in the lubricating oil.

One kind of thiadiazole lubricant additive, for the first time, has been synthesized from 2,5-dimercapto-1,3,4-thiadiazole. Its tribological performance has also been evaluated by four-ball test. And, its oxidation resistance has been estimated by rotating pressure vessel oxidation test and pressurized differential scanning calorimetry. The anticorrosion performance of such an additive has been studied by GB/T 5096 standard method test.

The synthesized thiadiazole additive has excellent anti-oxidation capability, good anti-wear and extreme pressure properties and good anticorrosion performance, in comparison with zinc dialkyl dithiophosphate (ZDDP). In base oils, the comprehensive performance of thiadiazole additive is comparable to ZDDP. Mechanistic studies indicate that the S and N active elements were involved in the formation of a boundary film. This may account for the formation of a composite membrane on the metal surface and thus for the tribological performance of such thiadiazole additives.

The thiadiazole derivatives, which are ashless and have environmentally friendly features, are a potential alternative to ZDDP. Because of the film formed on the friction surface, thiadiazole compounds may serve as an excellent anti-wear additive and are expected to reduce friction and wear between metals.

LONG before man learnt to make fire by the friction of wood, he experienced the burden of friction in dragging home his kill. Perhaps it is not too fanciful to suppose that the torn sides of his beast gave the first solid lubricant. Blood and mutton fat were seriously recommended as lubricants for church bell trunnions as recently as the 17th century. Indoed we still reckon fatty acids the best of all boundary lubricants. The range of man's activities has increased enormously in the present century, and particularly in the last few decades. Men have circled the earth in space; a space ship is on its way to examine another planet; terrestrial man is boring to the bottom of the earth's crust; others have descended to the depths of the ocean, and oven established a home on the floor of the Mediterranean, Speeds have increased by factors of thousands, temperatures range from near absolute zero to thousands of degrees; and a new environment of high‐intensity nuclear radiation has been created. Still, objects must move over and along each other in these exotic conditions; and to a large extent solid lubricants can provide the answer to the frictional problems.

The purpose of this paper is to test two kinds of rare earth complexes of Lanthanum Dialkyldithiophosphate (LaDDP) and Lanthanum Dialkylphosphate (LaDP) as lubricant additives in liquid paraffin for the untreated 60Si2Mn steel and laser‐cladding Ni35A coating on 60Si2Mn steel sliding pairs which are a potential substitute for Zinc Dialkldithiophosphate (ZnDDP).

Tribological properties were evaluated by an Optimol‐SRV oscillating friction and wear test. The morphologies of the worn surfaces were observed by a scanning electron microscope (SEM), and the chemical states of several typical elements on the worn surfaces were examined by means of X‐ray photoelectron spectroscopy (XPS).

Treated laser cladding coatings of steel can improve its hardness and strength and the coated steel possess higher load‐carrying capacity than that of 60Si2Mn; The rare earth complexes of LaDDP and LaDP possess good oil‐solubility, friction‐reducing and wear resistance properties. Those rare earth complexes as additives in liquid paraffin during the friction process can form a protective film containing rare earth oxide, sulfate and sulfur‐containing compound during the friction process.

The paper presents two kinds of potentially useful, environmentally‐friendly and highly efficient substitutes for the ZnDDP additives in lubricants.

Owing to their good friction‐reducing and wear resistance properties, LaDDP and LaDP are two optimum and promising industry lubrication additives.

This work is a new application of rare earth complex as lubricant additive in liquid paraffin, which provides a new direction for designing friction pairs and lubricant additive. The tribology experiments have been carried out through the variation of experiment conditions.

A method extensively used in the production of optically flat and finely finished surfaces is that of lapping the surface upon a plate using a loose abrasive mixed into a slurry form with a carrying fluid. If the surfaces finished in this way are in continuous or intermittent sliding contact, it is the author's opinion that any abrasives retained in their surfaces will affect surface wear. This paper reported on some exploratory work to indicate the degree of embedment of abrasive in certain materials lapped by hand.

Nanoparticles are not well dispersed in non‐polar organic solvents due to their hydrophilic property which limits their applications in lubricant oils. To improve the oil‐solubility of nanoparticles, a novel technology was used to prepare a kind of lubricant containing calcium borate nanoparticles.

The microstructures of the prepared nanoparticles were characterized by transmission electron microscope (TEM) and infrared spectra (IR). Tribological properties of calcium borate nanoparticles used as additive in base oil were evaluated using four‐ball tribotester and SRV tribotester, and the worn surface of the steel ball was investigated by Polarized microscope (PM) and X‐ray photoelectron spectroscopy (XPS). In addition, the dispersing stability and antioxidation property of lubricant containing nanoparticles were also studied.

The results indicate that the average size of the prepared nanoparticles is in the range of 50‐100 nm, and the surface of the nanoparticles was altered from hydrophilicity to hydrophobicity. At the same time, the nanoparticles can be well dispersed in the base oil totally under novel process which has no significantly negative effect on the antioxidation property. The results of tribological tests show that calcium borate nanoparticles under the novel process (CBNN) show better antiwear property and friction‐reducing property in base oil compared to calcium borate nanoparticles under tradition process (CBNT). Based on the results of PM and XPS, it can be deduced that a continuous resistance film containing depositions and the tribochemical reaction products such as B₂O₃, FeB, Fe₂O₃ and CaO formed during the sliding process.

The main innovative thought of this work lies in dealing with the oil‐solubility problem through the combination effect of surface modification and special blend process of lubricating oil, and this method was first used to prepare lubricant containing calcium borate nanoparticles. It should be helpful for the borate nanoparticles used as additives in engine oil, gear oil and other industrial lubricants.

This study aims to compare the influence of different solid lubricants on the friction stability of a non-asbestos disc brake pad.

Three brake pads were developed using three lubricants, namely, non-asbestos brake pad with sulfide mix (NASM), non-asbestos brake pad with bismuth sulfide (NABS) and non-asbestos brake pad with molybdenum disulfide (NAMO). Sulfide mix was indigenously developed by physically mixing friction modifiers, alkaline earth chemicals and various metallic sulfides homogeneously dispersed in graphite medium. The physical, chemical, mechanical and thermal properties of brake pads were characterized as per industrial standards. The tribological performances were studied using the Chase testing machine as SAE-J661-2012. The worn surface of the pads was studied using scanning electron microscope to analyze the dominating wear mechanism.

NASM was excellent in fade as well as wear resistance. NABS was better from a wear point of view, but fade resistance was moderate despite its higher cost. NAMO fared average in fade and wear despite its excellent dry lubricating properties. NASM was excellent in terms of fade as well as wear resistance.

Among the selected metal sulfides, the indigenously developed sulfide mix was better than the other two sulfides, which indicates that the synergetic effect of metal sulfides was always preferable to the individual sulfides.

The purpose of this paper is to investigate the tribological properties of Si₃N₄ sliding against Dy−sialon ceramics lubricated by two novel phosphazenes bridged fluorophenoxycyclotriphosphazene (coded as L‐2P) and metal halide‐stabilized linear phosphazene derivatives (coded as LMZn‐3). The traditional phosphazene tetrakis (3‐trifluoromethylphenoxy)‐bis(4‐fluorophenoxy) – cyclotriphosphazene (X‐1P) was also tested as the reference.

The lubricity characteristics of phosphazene derivatives were evaluated on an Optimol SRV oscillating friction and wear tester. The morphology of the worn sialon surface was analyzed with a scanning electron microscope (SEM) and X‐ray photoelectron spectroscope (XPS).

The two novel phosphazenes are effective lubricants for Dy−sialon and show superior tribological properties to traditional phosphazene X‐1P and glycerol. Among all lubricants, linear phosphazene LMZn‐3 exhibits the lowest wear volume loss at 20°C or 100°C. Moreover, LMZn‐3 and L‐2P show much better antiwear ability than X‐1P under higher load than 60N. The decreased friction coefficient and wear volume of Dy−sialon ceramics under lubrication of the phosphazene lubricants are attributed to the tribochemical products mainly consisting of organic oxyfluoride or carbonfluoride species and silicon fluoride.

The paper deals with only limited compounds. The paper works on the subject progressively to explore more combinations for better tribological properties.

The phosphazene derivatives present better tribological performance used as base oils and additives.

There are few data about other phosphazene with different structures, such as bridged cyclotriphosphazene and metal halide‐stabilized linear phosphazene, used as lubricants for ceramics materials.

The purpose of this paper is to synthesize a novel kind of crown‐type phosphate ionic liquids with better tribological properties for steel/Al system. The anions of crown‐type phosphate ionic liquids contain no F element, which are non‐corrosive to metal.

To improve the tribological properties of ionic liquid lubricants for the extremely difficult system of the steel‐against‐aluminum metal couple, novel crown‐type phosphate ionic liquids were prepared. The tribological properties of the crown‐type phosphate ionic liquids were evaluated at different loads and frequencies on an Optical SRV oscillating friction and wear tester. The morphology and chemical compounds of the wear scars were investigated by scanning electron microscope (SEM) and X‐ray photoelectron spectroscopy (XPS).

Compared with conventional ionic liquids, the novel crown‐type phosphate ionic liquids prepared in the present work exhibit a more excellent anti‐wear ability for steel/Al2024 contact at different loads and frequencies. By the morphological analysis with SEM, less debris was observed in the worn surface lubricated with crown‐type phosphate ionic liquids, though more debris was observed when lubricated with LB106 and LP106. By the XPS analysis, boundary lubrication film composed of aluminum (III) oxide, organometallic compounds, and silicon aluminum phosphate were found in the worn surface. Namely, the tribological behaviors of the crown‐type phosphate ionic liquids could be attributed to their stronger adsorption and tribochemical interactions with the Al alloys.

Because of the higher mean friction coefficients of crown‐type phosphate ionic liquids in the research, researchers are encouraged to modify their structure for better tribological properties.

The crown‐type phosphate ionic liquid exhibited better anti‐wear performance for steel/aluminum contact than the conventional ionic liquids containing F element. This will expand the application of high strength aluminum alloys.

The phosphate ionic liquid is a non‐corrosive liquid and would not cause metal corrosion. Also, the tribological properties of crown‐type phosphate ionic liquid with steel/aluminum contact are better than that of conventional ionic liquids. By the designing of molecular structure, new phosphate ionic liquids will exhibit excellent tribological properties: lower wear volume and lower friction coefficient.

The purpose of this paper is to study the tribological properties of a thiazole derivatives (T561), overbased alkyl benzene calcium sulfonate (T106A) compounded with T561 and overbased alkyl benzene magnesium sulfonate (T107) compounded with T561 in rapeseed oil (RSO).

A four-ball machine was used to evaluate the tribological properties of each compound and their combinations with T561 in RSO. Scanning electron microscopy, EDX and X-ray photoelectron spectroscopy were applied to analyze the tribofilm formed on the worn surfaces.

Results of tribotesting demonstrated that synergistic effects exist between the overbased sulfonates, T106A and T107, and the thiazole derivative, T561. The texts of tribofilm indicated that iron sulfide and iron oxides exist in T561 single agent lubricant film and two composite additives lubricant film, and no sulfates were detected. It suggested that the addition of alkyl benzene sulfonate did not hinder the formation of iron sulfides and iron oxides. Meanwhile, CaSO₄ (MgSO₄) and CaCO₃ (MgCO₃) were detected on the worn surface of the composite additives, which were not detected on the single agent friction surface.

A tribofilm mainly contains CaSO₄ (MgSO₄) and CaCO₃ (MgCO₃) formed on the worn surfaces, which is responsible for excellent extreme pressure and anti-wear properties of the compound agents because of their high melting point and high shear stress.