Search results
1 – 10 of 34Ümran Burcu Alkan, Nilgün Kızılcan and Başak Bengü
The purpose of this study is the development of sustainable and low-formaldehyde emission wood adhesive formulations.
Abstract
Purpose
The purpose of this study is the development of sustainable and low-formaldehyde emission wood adhesive formulations.
Design/methodology/approach
Three-step urea formaldehyde (UF) resin has been in situ modified with calcium lignosulfonate (LS) and/or 1,4 butanediol diglycidyl ether (GE). The structural, chemical, thermal and morphological characterizations were carried out on resin samples. These resins have been applied for particleboard pressing, and UF, UF-LS and UF-GE were evaluated as P2 classes according to EN 312.
Findings
The results show that the improved LS- or diglycidyl ether-modified UF wood adhesives were successful in their adhesive capacity, and the formaldehyde content of the final product was obtained as low as 8 mg/100 g. This paper highlights that the presented adhesive formulations could be a potential eco-friendly and cost-effective alternative to formaldehyde-based wood adhesives for interior particleboard production.
Research limitations/implications
Combination of LS and GE resulted in weaker mechanical properties and fulfilled P1 class particleboards due to temperature and duration conditions. Therefore, in situ usage of LS or GE in UF resins is highly recommended for particleboard pressing. Formaldehyde content of particleboards was determined with the perforator method according to EN 12460-5 and all of the particleboards exhibited E1 class. LS was more efficient in decreasing formaldehyde content than GE.
Practical implications
This study provides the application of particleboards with low formaldehyde emission.
Social implications
The developed LS- and diglycidyl ether-modified UF resins made it possible to obtain boards with significantly low formaldehyde content compared with commercial resins.
Originality/value
The developed formaldehyde-based resin formulation made it possible to produce laboratory-scale board prototypes using LS or GE without sacrificing of press factors and panel quality.
Details
Keywords
Kaiyan Yang, Xiaowu Gong, Lanli Bai, Yun Zhang and Na Zhou
This study aims to prepare a low-formaldehyde and environmentally friendly glucose-lignin-based phenolic resin.
Abstract
Purpose
This study aims to prepare a low-formaldehyde and environmentally friendly glucose-lignin-based phenolic resin.
Design/methodology/approach
The authors directly used lignin to substitute formaldehyde to prepare lignin-based phenolic resin (LPF) with urea as formaldehyde absorbent. To improve the performance of the adhesive, the biobased glucose was introduced and the modified glucose-LPF (GLPF) was obtained.
Findings
The results showed that when the replacing amount of lignin to formaldehyde reached 15 Wt.%, the physical properties of the prepared LPF met the Chinese national standard, and the bonding strength increased by 21.9%, from 0.75 to 0.96 MPa, compared with PF. The addition of glucose boost the performance of wood adhesive, for example, the free phenol content of the obtained GLPF was significantly reduced by 79.11%, from 5.60% to 1.17%, the bonding strength (1.19 MPa) of GLPF increased by 19.3% in comparison to LPF and the curing temperature of GLPF decreased by 13.08%.
Practical implications
The low-formaldehyde and environmentally friendly GLPF has higher bonding strength and lower curing temperature, which is profitable to industrial application.
Social implications
The prepared GLPF has lower free formaldehyde and formaldehyde emission, which is cost-effective and beneficial to human health.
Originality/value
The joint work of lignin and glucose provides the wood adhesive with increased bonding strength, decreased free phenol content and reduced curing temperature.
Details
Keywords
Salise Oktay, Nilgün Kızılcan and Başak Bengü
In industrial applications, formaldehyde-based wood adhesives have been used extensively because of their low costs and high reactivity. However, their real-world applications are…
Abstract
Purpose
In industrial applications, formaldehyde-based wood adhesives have been used extensively because of their low costs and high reactivity. However, their real-world applications are hindered by some main bottlenecks, especially the formaldehyde emission and usage of nonrenewable raw materials. The purpose of this study is the development of sustainable and formaldehyde-free wood adhesive formulation.
Design/methodology/approach
In this study, starch and tannin-based wood adhesive were synthesized. Chemical structures and thermal properties of the prepared bio-based resin formulations were elucidated by using Fourier transform infrared and differential scanning calorimetry analysis, respectively. Laboratory scale particleboard production was carried out to determine the performance of the developed resin formulations. Obtained results were evaluated in dry medium (P2) according to European norms EN 312 (2010). Furthermore, the board formaldehyde content was determined by using the perforator method according to the European Norm EN 12460-5.
Findings
The results show that the improved starch and tannin-based wood adhesives were successful in their adhesive capacity, and the formaldehyde content of the final product was obtained as low as 0.75 mg/100 g. This paper highlights that the presented adhesive formulations could be a potential eco-friendly and cost-effective alternative to the formaldehyde-based wood adhesives for interior particleboard production.
Research limitations/implications
Starch-based resins in the liquid form needed to be continuously mixed throughout their shelf life to prevent the starch from settling because it was not possible to dissolve the precipitated starch again after a while. For this reason, starch was given to the chips in powder form while preparing the particleboard.
Practical implications
In conclusion, this study shows that the developed bio-based resin formulations have a high potential to be used for producing interior-grade particleboards instead of commercial formaldehyde-based wood adhesives because the obtained results generally satisfied the interior grade particleboard requirements according to European norms EN 312, P2 class (2010). In addition, it was determined that the produced boards had significantly low formaldehyde content. The low formaldehyde content of the final boards was not because of the resin but because of the natural structure of the wood raw material, press parameters and environmental factors.
Social implications
The developed bio-based resin system made it possible to obtain boards with significantly low formaldehyde content compared to commercial resins.
Originality/value
The developed bio-based resin formulation made it possible to produce laboratory-scale board prototypes at lower press factors and board densities compared to their counterparts.
Details
Keywords
Bo Wang, Yanhua Zhang, Haiyan Tan and Jiyou Gu
The purpose of the study was to prepare melamine-urea-formaldehyde (MUF) resin that would be resistant to boiling water and high temperature and exhibit low formaldehyde emission.
Abstract
Purpose
The purpose of the study was to prepare melamine-urea-formaldehyde (MUF) resin that would be resistant to boiling water and high temperature and exhibit low formaldehyde emission.
Design/methodology/approach
The authors prepared MUF resin with different F/(M + U) and changed the amount of melamine added, through the analysis of MUF resin properties to get the best reaction parameters, and used different amino acid cure systems including NH4Cl cured the resin.
Findings
Resin’s heat resistance and water resistance are mainly determined by the amount of melamine added, and formaldehyde emission of the plywood can be changed by adjusting F/(M + U). The peak temperature of the curing agent-cured resin increases as compared with the self-curing resin. Stronger the acidity of curing agent, faster the viscosity increased in probation period and lower the bonding strength and heat resistance of the resin.
Research limitations/implications
Melamine improves the heat resistance and water resistance of the resin. When the amount of melamine is more than a certain value, water resistance of the resin decreased.
Practical implications
MUF resin that is resistant to boiling water and exhibits low formaldehyde emission can be used in high temperature, high humidity and strict formaldehyde emission environment and can also be combined with other materials.
Social implications
It was helpful to reduce the effect of formaldehyde emission on people’s health and environmental pollution and is also beneficial for the expansion of the application range of aldehyde resin.
Originality/value
The originality is twofold: the influence of the acid strength of curing agent on the bonding strength of the resin adhesive and the method for preparing high performance MUF resin by following the traditional process.
Details
Keywords
Chuanjie Zhang, Li Cui, Ping Zhu and Yun Liu
Glutaraldehyde is chosen as a novel non-formaldehyde durable press finish for cotton fabrics in this investigation. The optimum technique conditions and influences of…
Abstract
Glutaraldehyde is chosen as a novel non-formaldehyde durable press finish for cotton fabrics in this investigation. The optimum technique conditions and influences of glutaraldehyde concentration and catalysts, pH value, and curing conditions for the properties of the finished fabric have been investigated in detail. The finished fabric achieves the best performance with a pH value in the range of 4 to 4.5 for the glutaraldehyde finishing bath, magnesium chloride as the catalyst, and curing conditions of 160oC for 3 minutes. In addition, in contrast to low formaldehyde resin and non-formaldehyde finishers sold in the market, the wrinkle recovery angle of the fabric finished with glutaraldehyde is better than that finished with FREEREZ NFR (DHDMI), but not as satisfactory as that finished with FREEREZ 880 (low formaldehyde 2D). However, its strength is greater than the fabric finished with FREEREZ 880, but less so than that finished with FREEREZ NFR.
Details
Keywords
Acid catalysed lacquers have earned a reputation as being the workhouse of the woodfinishing range. With their excellent durability, acid catalysed finishes are commonly used for…
Abstract
Acid catalysed lacquers have earned a reputation as being the workhouse of the woodfinishing range. With their excellent durability, acid catalysed finishes are commonly used for applications such as office, kitchen and contract furniture where a high quality finish with good resistance is required.
Sea‐Nine Biocide ‐ Rohm and Haas Company announced that Sea‐Nine 211 biocide has been registered for use in marine paints by the US Environmental Protection Agency. Sea‐Nine 211…
Abstract
Sea‐Nine Biocide ‐ Rohm and Haas Company announced that Sea‐Nine 211 biocide has been registered for use in marine paints by the US Environmental Protection Agency. Sea‐Nine 211 is the first new generation organic biocide to earn this registration.
An important technological innovation by Haverhill‐based Macpherson Woodfinishes, part of the Finnish multinational Kemira, significantly reduces the formaldehyde content of all…
Abstract
An important technological innovation by Haverhill‐based Macpherson Woodfinishes, part of the Finnish multinational Kemira, significantly reduces the formaldehyde content of all the company's acid catalysed lacquer finishes.
As from July 1st, the Wood Finishes Division of Becker Industrial Coatings, based at Cheslyn Hay, Walsall has been trading as Becker‐Acroma. Having spoken last month to Eddy…
Abstract
As from July 1st, the Wood Finishes Division of Becker Industrial Coatings, based at Cheslyn Hay, Walsall has been trading as Becker‐Acroma. Having spoken last month to Eddy Moules, business manager of Becker‐Acroma and Mike Beaumont, national sales manager it became clear that this change of name is not just a cosmetic operation.
A new non‐yellowing acid catalysed lacquer is available now from Haverhill‐based Macpherson Wood‐finishes, a major UK manufacturer of factory applied coatings for wood.