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Glucose-lignin-based phenolic resin: an environmentally friendly low-formaldehyde wood adhesive

Kaiyan Yang (School of Chemistry and Chemical Engineering/State Key Laboratory Incubation Base for Green Processing of Chemical Engineering, Shihezi University, Shihezi, China)
Xiaowu Gong (School of Chemistry and Chemical Engineering/State Key Laboratory Incubation Base for Green Processing of Chemical Engineering, Shihezi University, Shihezi, China)
Lanli Bai (School of Chemistry and Chemical Engineering/State Key Laboratory Incubation Base for Green Processing of Chemical Engineering, Shihezi University, Shihezi, China)
Yun Zhang (School of Chemistry and Chemical Engineering/State Key Laboratory Incubation Base for Green Processing of Chemical Engineering, Shihezi University, Shihezi, China)
Na Zhou (School of Chemistry and Chemical Engineering/State Key Laboratory Incubation Base for Green Processing of Chemical Engineering, Shihezi University, Shihezi, China)

Pigment & Resin Technology

ISSN: 0369-9420

Article publication date: 13 April 2023

63

Abstract

Purpose

This study aims to prepare a low-formaldehyde and environmentally friendly glucose-lignin-based phenolic resin.

Design/methodology/approach

The authors directly used lignin to substitute formaldehyde to prepare lignin-based phenolic resin (LPF) with urea as formaldehyde absorbent. To improve the performance of the adhesive, the biobased glucose was introduced and the modified glucose-LPF (GLPF) was obtained.

Findings

The results showed that when the replacing amount of lignin to formaldehyde reached 15 Wt.%, the physical properties of the prepared LPF met the Chinese national standard, and the bonding strength increased by 21.9%, from 0.75 to 0.96 MPa, compared with PF. The addition of glucose boost the performance of wood adhesive, for example, the free phenol content of the obtained GLPF was significantly reduced by 79.11%, from 5.60% to 1.17%, the bonding strength (1.19 MPa) of GLPF increased by 19.3% in comparison to LPF and the curing temperature of GLPF decreased by 13.08%.

Practical implications

The low-formaldehyde and environmentally friendly GLPF has higher bonding strength and lower curing temperature, which is profitable to industrial application.

Social implications

The prepared GLPF has lower free formaldehyde and formaldehyde emission, which is cost-effective and beneficial to human health.

Originality/value

The joint work of lignin and glucose provides the wood adhesive with increased bonding strength, decreased free phenol content and reduced curing temperature.

Keywords

Acknowledgements

This work was supported by National Natural Science Foundation of China (Grant No. 21464011), the Scientific Research Program of Shihezi University (RCZK2021B09) and Science and Technology Project of Xinjiang Bingtuan (2022ZD070).

Declaration of interest statement: The authors declare no competing financial interest.

Citation

Yang, K., Gong, X., Bai, L., Zhang, Y. and Zhou, N. (2023), "Glucose-lignin-based phenolic resin: an environmentally friendly low-formaldehyde wood adhesive", Pigment & Resin Technology, Vol. ahead-of-print No. ahead-of-print. https://doi.org/10.1108/PRT-12-2022-0150

Publisher

:

Emerald Publishing Limited

Copyright © 2023, Emerald Publishing Limited

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