Search results

The traditional VeoVa10-VAc copolymer latex, which prepared via the emulsion polymerization of the mixed monomers of VAc and VeoVa10, has the poor water resistance and thermal stability because of the migration of the conventional emulsifier molecules and the low bond energy of C-C bond. The purpose of this work is that the fluorinated monomer is used to modify the latex. The film of the resultant latex has the C-F bond with high bond energy and low surface energy, which can effectively improve the heat resistance and water resistance of the resultant film. In addition, the reactive emulsifier is used to replace the conventional emulsifier. The drawbacks of the conventional emulsifier molecules migrate and desorb can be avoided when the polymer latex is stored, thereby also improving the water resistance.

The modified VAc-VeoVa10 latex has been successfully synthesized via the semi-continuous seeded emulsion polymerization, which VAc and VeoVa10 is used as the main monomers and HFMA was used as the functional monomer. KPS and reactive surfactants of SE-10 were used as the initiator and emulsifier, respectively. The structure of resultant latex film was characterized by Fourier transform infrared spectroscopy (FTIR). The latex films were tested by thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) and contact angle (CA). The particle size and its distribution of the latex were measured by the nano particle size analyzer.

The factors that had an influence on the properties of the latex and the film were investigated in detail. The stability of the resultant latex is good. The average particles of the latex and its distribution are small and uniform, respectively. In comparison with the conventional latex film, the thermal stability and hydrophobicity of the resultant latex film are improved obviously.

The resultant latex can be used in both the waterborne interior and exterior wall coatings, pickering stabilized waterborne polymer dispersions, polymer powders, environmentally friendly polymer-modified waterproof mortar and other fields, which can be satisfied with the high demand of thermal stability and hydrophobicity.

The modification of poly (VAc-VeoVa10) by reactive surfactant and fluorinated monomer is seldom reported. In this study, the fluorinated poly (VAC-VeoVa) latex is prepared via the reactive surfactants, which VAc and VeoVa10 is used as the main monomers and hexafluorobutyl methacrylate is used as the functional monomer. Potassium persulfate (KPS) and allyl nonyl phenoxy propyl alcohol polyoxyethylene ether ammonium sulfate are used as the initiator and emulsifier, respectively.

This paper aims to assess the efficiency of emulsified essential oils in glycerol as eco-friendly antimicrobial and plasticized agents added to the biopolymer of gelatin for lining historical oil paintings on canvases.

Cedar oil, cinnamon oil and their mixtures were emulsified in glycerol and incorporated into gelatin adhesive as green biocides and plasticizers. Physical, biological, chemical and mechanical tests were conducted on experimental mock-ups to assess the gelatin-based adhesive formulations for the reinforcement of canvas supports. Scanning electron microscope, colorimetric measurements, antimicrobial activity test, attenuated total reflection-Fourier transform infrared spectroscopy, tensile strength and elongation tests were carried out on the mock-ups before and after the artificial aging.

The formulations of gelatin-based adhesive with cinnamon and cinnamon-cedar mixture emulsified in glycerol proved their efficiency on the antimicrobial activity test, chemically delaying the decomposition of gelatin and accordingly providing compatible mechanical properties. Gelatin-based adhesive with emulsified cinnamon oil showed a slight yellowing that was quite improved with the mixture of the cinnamon-cedar-based adhesive formulation.

This study promotes a green approach to lining historical oil paintings by developing green formulations from bio-based origins that minimize the shrinkage and microbial infection of gelatin for lining paintings.

This study aims to propose a method for monitoring bearing health in the time–frequency domain, termed the Lock-in spectrum, to track the evolution of bearing faults over time and frequency.

The Lock-in spectrum uses vibration signals captured by vibration sensors and uses a lock-in process to analyze specified frequency bands. It calculates the distribution of signal amplitudes around fault characteristic frequencies over short time intervals.

Experimental results demonstrate that the Lock-in spectrum effectively captures the degradation process of bearings from fault inception to complete failure. It provides time-varying information on fault frequencies and amplitudes, enabling early detection of fault growth, even in the initial stages when fault signals are weak. Compared to the benchmark short-time Fourier transform method, the Lock-in spectrum exhibits superior expressive ability, allowing for higher-resolution, long-term monitoring of bearing condition.

The proposed Lock-in spectrum offers a novel approach to bearing health monitoring by capturing the dynamic evolution of fault frequencies over time. It surpasses traditional methods by providing enhanced frequency resolution and early fault detection capabilities.

The purpose of this study is to systematically analyze the wear of cylindrical needle bearings in rotary vector reducers under temperature rise and identify the influencing factors.

Based on the dynamic characteristics of the RV-20E reducer, the time-varying contact force of the cylindrical needle bearing and the entrainment speed of the inner and outer raceways were calculated. A mixed elastohydrodynamic lubrication model of the needle bearing, considering friction and temperature rise, was established using a dynamic rough tooth surface model. The model solved for the oil film thickness, contact stress and wear conditions of the bearing raceway contact area. The effects of the number of rolling needles, the diameter of rolling needles and surface strength on the wear characteristics were analyzed.

The results of this study show that the oil film thickness, oil film pressure and surface scratches of cylindrical needle bearings exhibit an uneven, patchy distribution under the combined effects of friction and temperature rise. When the radius of the rolling needle is less than 1.44 mm, inner ring wear is less than outer ring wear. Conversely, when the radius exceeds 1.44 mm, inner ring wear is greater. The optimal rolling needle radius is 1.6 mm. Increasing the number of rolling needles and enhancing the yield strength of the contact surface significantly extend bearing life.

This study provides valuable recommendations for optimizing bearing structural parameters and material characteristics in the design of rotary vector reducers.

The peer review history for this article is available at: https://publons.com/publon/10.1108/ILT-07-2024-0242/

The aim was not to perform a systematic review but firstly to search in PubMed, Science Direct, Scopus and Web of Science databases on the papers published in the last five years using tools for reviewing the statement of preferred information item for systematic reviews without focusing on a randomized analysis and secondly to perform a bibliometric analysis on the properties of films and coatings added of tocopherol for food packaging.

On January 24, 2022, information was sought on the properties of films and coatings added of tocopherol for use as food packaging published in PubMed, Science Direct, Scopus and Web of Science databases. Further analysis was performed using bibliometric indicators with the VOSviewer tool.

The searches returned 33 studies concerning the properties of films and coatings added of tocopherol for food packaging, which were analyzed together for a better understanding of the results. Data analysis using the VOSviewer tool allowed a better visualization and exploration of these words and the development of maps that showed the main links between the publications.

In the area of food science and technology, the development of polymers capable of promoting the extension of the shelf life of food products is sought, so the knowledge of the properties is vital for this research area since combining a biodegradable polymeric material with a natural antioxidant active is of great interest for modern society since they associate environmental preservation with food preservation.

This study aims to introduce a predictive homogenization model incorporating electrical percolation considerations to forecast the electrical characteristics of unidirectional carbon-epoxy laminate composites.

This study presents a method for calculating the electrical conductivity tensor for various ply arrangement patterns to elucidate phenomena occurring around the interfaces between plies. These interface models are then integrated into a three-dimensional (3D) magneto-thermal model using the finite element method. A comparative study is conducted between different approaches, emphasizing the advantages of the new model through experimental measurements.

This research facilitates the innovative integration of electrical percolation considerations, resulting in substantial improvement in the prediction of electrical properties of composites. The validity of this improvement is established through comprehensive validation against existing approaches and experimentation.

The study primarily focuses on unidirectional carbon-epoxy laminate composites. Further research is needed to extend the model's applicability to other composite materials and configurations.

The proposed model offers a significant improvement in predicting the electrical properties of composite materials by incorporating electrical percolation considerations at inter-ply interfaces, which have not been addressed in previous studies. This research provides valuable information to improve the accuracy of predictions of the electrical properties of composites and offers a methodology for accounting for these properties in 3D magneto-thermal simulations.

This study aims to provide empirical evidence on the return and volatility spillover structures between Bitcoin, Fintech stocks and Asian-Pacific equity markets over time and during different market conditions, and their implications for portfolio management.

We use Time-varying parameter vector autoregressive and quantile frequency connectedness approach models for the connectedness framework, in conjunction with Diebold and Yilmaz’s connectivity approach. Additionally, we use the minimum connectedness portfolio model to highlight implications for portfolio management.

Regarding the uncertainty of the whole system, we show a small contribution from Bitcoin and Fintech, with a higher contribution from the four Asian Tigers (Taiwan, Singapore, Hong Kong and Thailand). The quantile and frequency analyses also demonstrate that the link among assets is symmetric, with short-term spillovers having the largest influence. Finally, Bitcoins and Fintech stocks are excellent diversification and hedging instruments for Asian equity investors.

There is an instantaneous, symmetric and dynamic return and volatility spillover between Asian stock markets, Fintech and Bitcoin. This conclusion should be considered by investors and portfolio managers when creating risk diversification strategies, as well as by policymakers when implementing their financial stability policies.

The study’s major contribution is to analyze the volatility spillover between Bitcoin, Fintech and Asian stock markets, which is dynamic, symmetric and immediate.

This study aims to enhance merging of additive manufacturing (AM) techniques with powder injection molding (PIM). In this way, the prototypes could be 3D-printed and mass production implemented using PIM. Thus, the surface properties and mechanical performance of parts produced using powder/polymer binder feedstocks [material extrusion (MEX) and PIM] were investigated and compared with powder manufacturing based on direct metal laser sintering (DMLS).

PIM parts were manufactured from 17-4PH stainless steel PIM-quality powder and powder intended for powder bed fusion compounded with a recently developed environmentally benign binder. Rheological data obtained at the relevant temperatures were used to set up the process parameters of injection molding. The tensile and yield strengths as well as the strain at break were determined for PIM sintered parts and compared to those produced using MEX and DMLS. Surface properties were evaluated through a 3D scanner and analyzed with advanced statistical tools.

Advanced statistical analyses of the surface properties showed the proximity between the surfaces created via PIM and MEX. The tensile and yield strengths, as well as the strain at break, suggested that DMLS provides sintered samples with the highest strength and ductility; however, PIM parts made from environmentally benign feedstock may successfully compete with this manufacturing route.

This study addresses the issues connected to the merging of two environmentally efficient processing routes. The literature survey included has shown that there is so far no study comparing AM and PIM techniques systematically on the fixed part shape and dimensions using advanced statistical tools to derive the proximity of the investigated processing routes.

This paper aims to numerically examine the impact of gyrotactic microorganisms and radiation on heat transport features of magnetic nanoliquid within a closed cavity. Thermophoresis, chemical reaction and Brownian motion are also considered in flow geometry for the moment of nanoparticles.

Finite element method (FEM) was depleted to numerically approximate the temperature, momentum, concentration and microorganisms concentration of the nanoliquid. The present simulation was unsteady state, and the resulting transformed equations are simulated by FEM-based Mathematica algorithm.

It has been found that isotherm patterns get larger with increasing values of the magnetic field parameter. Additionally, numerical codes for rate of heat transport impedance inside the cavity with an increasing Brownian motion parameter values.

To the best of the authors’ knowledge, the research work carried out in this paper is new, and no part is copied from others’ works.

Despite the huge financial resources associated with oil, Nigeria has consistently recorded poor growth performance. Therefore, this study aims to examine how corruption and oil rent influence Nigeria’s economic performance during the 1996–2021 period.

Various estimation techniques were used. These include the bootstrap autoregressive distributed lag (ARDL) bounds-testing, dynamic ordinary least squares (DOLS), the fully modified OLS (FMOLS) and the canonical cointegration regression (CCR) estimators and the Toda–Yamamoto causality.

The bounds testing results provide evidence of a cointegrating relationship between the variables. In addition, the results of the ARDL, DOLS, CCR and FMOLS estimators demonstrate that oil rent and corruption have a significant positive impact on growth. Further, the results indicate that human capital and financial development enhance economic growth, whereas domestic investment and unemployment rates slow down long-term growth. Additionally, the causality test results illustrate the presence of a one-way causality from oil rent to economic growth and a bi-directional causal relationship between corruption and economic growth.

Existing studies focused on the effects of either oil rent or corruption on growth in Nigeria. Little attention has been paid to the exploration of how the rent from oil and the pervasiveness of corruption contribute to the performance of the Nigerian economy. Based on the outcome of this study, strategies and policies geared towards reducing oil dependence and the pervasiveness of corruption, enhancing human capital and financial development and reducing unemployment are recommended.