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The purpose of this study is to reduce the cracks, pores and unfused defects in arc welding, improve the crystalline structure of the weld, refine its grains and improve the mechanical properties.

Taking E690 marine steel as the research object, the experiment adopts a new process method of laser forging coupled arc welding. Welding for comparative experiments. Experiments show that the “V”-shaped groove arc welding process has a larger fusion area, but has pores, the arc current is 168 A, the arc voltage is 28 V and the welding speed is 600 mm/min.

It can be seen from tensile tests that the coupling welding process has the highest tensile strength and yield strength, 872 MPa and 692 MPa, respectively, and the fracture elongation is 29.29%. The single-beam laser forging coupled arc welding process has a distance of laser and wire of 6–8 mm, a laser wavelength of 1,064 nm and the highest weld fusion ratio. The microhardness test shows that the average hardness of single-beam laser forging in the weld zone is 487.54 HV, which is 10.30% higher than that of arc welding. The average hardness in the fusion zone is 788.08 HV, which is 14.52% higher than that of the arc welding process.

The originality of the experiment: proposed a new process method of coupling arc repair for offshore steel forging; adopted a new process method of simultaneous coupling of single-beam short-pulse laser, double-beam short-pulse laser and arc welding; and obtained effect of pulsed laser and arc composite repair on porosity and fusion of E690 marine steel welds.

This paper aims to reveal the corrosion mechanism and corrosion development regulation of marine engineering structural steel in the marine environment and provide constructive suggestions for marine immersed tunnel engineering.

In this study, marine engineering structural steel’s behavior and corrosion prediction were carried out under the conditions of no cathodic protection and under-protection by artificially adding dissolved oxygen in a simulated seawater solution as a depolarizing agent.

Marine resources are rich in China. With the development of the economy and the improvement of engineering technology, marine engineering structural steel is used more and more widely. Engineering structural steel has a great risk of corrosion failure for long-term service in seawater, as seawater is a kind of corrosive medium containing various salts. At present, there are few projects and research studies available on the corrosion in the seawater environment of Q390C engineering structural steel, which is used in the Shenzhen–Zhongshan Link immersed tunnel steel shell at home and abroad. It cannot guide the corrosion of immersed tunnel steel shells in the ocean.

In this paper, the corrosion mechanism and corrosion development regulation of marine engineering structural steel in the marine environment are studied by accelerated corrosion test in the laboratory, which is of great significance to ensure the long-life durability of the immersed tunnel in marine engineering.

The purpose of this study is to analysis the pitting corrosion on the mechanical behavior of E690 high-strength steel sandwich panel. The pitting corrosion depth and degree of pitting (DOP) damage were used to evaluate the mechanical behaviors such as peak load and specific energy absorption of E690 panel.

The mechanical behavior of quasi-static compression, low-speed impact and three-point bending of E690 panel after pitting corrosion was simulated by ABAQUS nonlinear finite element method.

The quasi-static compression and low-speed impact mechanical properties can be greatly reduced by the pitting corrosion of the panel core, the pitting corrosion of the outer panel shows no obvious effect. The mechanical properties decrease with the increase of the pitting corrosion depth and DOP, and the influence of DOP is greater than that of pitting corrosion depth. The DOP of outer panel has less effect on mechanical properties of three-point bending compared with that of the core. Therefore, the pitting corrosion in the core of panel should be strictly controlled to prevent adverse effects on the mechanical properties of the structure.

To make up for the deficiency of the research on the corrosion behavior of high-strength steel sandwich panel structure, this paper chose E690 high-strength steel panel as the research object, and nonlinear finite element method was adopted to simulate the influence of pitting corrosion coverage area and pitting depth on its mechanical property degradation. The quasi-static compression, low-speed impact and three-point bending mechanical properties of panel with various DOPs and pitting depths were systematic studied.

This paper aims to make clear the sensitive zone of subsea pipeline to stress corrosion cracking (SCC) under a disbonded coating.

The change of microenvironment under a disbonded coating in artificial seawater was analyzed by using a rectangular crevice cell. The SCC behavior of subsea pipeline was studied by slow strain rate tensile tests.

The microenvironment at the crevice bottom exhibits obvious acidification, Cl- aggregation and cathodic protection potential (CP) rise. Accordingly, the susceptibility of X70 steels to SCC is high due to the intensive anodic dissolution effect. At the opening, hydrogen atom can access into the steel and induce hydrogen embrittlement effect on account of the applied over-protected CP potential, resulting in a relatively high susceptibility to SCC. The corrosiveness of the microenvironment at crevice middle, however, is mild with proper CP potential; thus, the susceptibility of X70 steel to SCC here is lower than that obtained at the opening and the crevice bottom.

A rectangular crevice cell is built to survey the microenvironment evolution under a disbonded coating in situ. The sensitive zone of subsea pipeline to SCC under a disbonded coating is clarified.

The purpose of this paper is to investigate the influence of the potential of hydrogen (pH) and dissolved oxygen in artificial seawater on the passivation behavior of 316L stainless steel.

The corrosion behavior was studied by using electrochemical measurements such as electrochemical impedance spectroscopy and polarization curve. The passive films were characterized with X-ray photoelectron spectroscopy.

The polarization resistance of the passive film decreases as the pH value drops ascribed to the formation of much more point defects. The donor carrier concentration (ND) in the passive film formed in the deaerated condition is lower than that in aerated conditions. Nevertheless, this phenomenon is the opposite when the pH value is 1 due to the significant decrease of Fe oxides/hydroxides coupled with the stable content of Cr oxides/hydroxides species. In addition, the compositional variation of the passive film also leads to the changes of its semiconductor properties from N-type to bipolar type.

This paper shows the variation of polarization resistance, corrosion potential, passive film composition and semiconductor properties with the pH value and dissolved oxygen. The results can serve as references to the further study on crevice corrosion of 316L in seawater.

This study aims to develops a new-type low-alloy corrosion resistant steel containing Sb and investigate the corrosion mechanism of this new-type low-alloy steel.

Energy dispersive spectrometer, X-ray photoelectron spectroscopy, X-Ray diffraction and scanning electron microscopy were used to evaluate the corrosion resistance of the rust layers formed on these samples. Laser confocal microscopy was used to observe the corroded surfaces of the steels.

Results showed that Sb added can consume H⁺ in the solution, thereby preventing the oxygen reaction to slow down the corrosion rate. Meanwhile, a stable and insoluble substance (Sb₂O₃) in the acidic solution would be produced when the reaction of the product of Sb and H⁺ with the enough dissolved oxygen in the solution. Due to the precipitation of Sb₂O₃ and iron oxyhydroxides, the rust layer of Sb-containing steel became more uniform and compact, which resulted in better corrosion resistance in acid environment.

In this study, a new-type acid resistant low-alloy steel containing Sb was developed. Compared with the results, the corrosion mechanism of the new-type low-alloy steel in acid environment was discussed.

The purpose of this paper is to determine the corrosion fatigue behavior and mechanism of 6005A aluminum alloy and welded joint.

Electron back-scattered diffraction (EBSD) were adopted to characterize the microstructure of 6005A aluminum alloy and welded joint. Through potentiodynamic polarization, electrochemical impedance spectroscopy (EIS) and corrosion fatigue experiments, the corrosion fatigue behavior and mechanism of 6005A aluminum alloy base metal and welded joint were studied.

The results show that the corrosion fatigue crack initiation of 6005A aluminum alloy base metal and welded joint is mainly caused by the preferential anodic dissolution and hydrogen concentration in the areas with inclusions and welding defects.

The research is an originality study on the corrosion fatigue behavior and mechanism of 6005A aluminum alloy and welded joint.

An electrochemical method based on the open circuit potential (OCP) fluctuations was put forward. It can be used to optimize the alloy compositions for improving the corrosion resistance of rust layer.

The potential trends and potential fluctuations of carbon steels in seawater were separated by Hodrick–Prescott filter. The Spearman correlation coefficient and max information coefficient were used to explore the correlation of alloy compositions and potential fluctuations.

After long-term immersion, potential fluctuation resistance (PFR) can be used to characterize the corrosion resistance of metals and its rust layers. In the 1,500 to 2,500 h exposure period, Fe, C and S compositions have strong negative correlations, whereas PFR and P composition have weak negative correlations. Mn, Cu and Ti alloy compositions help the rust layer of carbon steels have higher PFRs. These elements that exhibit higher PFRs in this period have been confirmed to have the effect on improving the corrosion resistance of rust layer.

A new computing method for alloy composition optimization of carbon steels based on the OCP fluctuations was put forward. This method combines electrochemical monitoring with the long-term actual seawater environmental tests of various carbon steels.

This paper aims to investigate the evolution law of surface characteristic of corroded cold-formed thin-walled steel in industrial environments.

Five test specimens sourced from cold-formed thin-walled C-shaped steel that have been in service for three years in actual industrial environments were subjected to surface characteristic test. The surface characteristic of corroded hot-rolled steel and cold-formed steel were compared and analyzed. The relationship between the surface morphology parameters and the average corrosion depth was established.

The evolution law of the surface morphology of corroded cold-formed thin-walled steel and corroded hot-rolled steel was similar. The frequency histogram of corrosion depth was mainly single peak with high values on the middle and low values on both sides. The corrosion depth conformed to the normal distribution. The roughness average height and the root mean square of surface height gradually increased linearly with increasing the average corrosion depth.

The reduction in the standard deviation of corrosion depth, the maximum corrosion depth, the roughness average height and the root mean square of surface height of the cold-formed thin-walled steel was smaller than those of the hot-rolled steel.

To study the corrosion behavior of pipeline steel in coastal areas, a tidal seawater macro-cell corrosion device was built using a cycle soaking tank and a macro-cell corrosion facility to simulate the corrosion behavior of pipeline steel in a simulated coastal environment (dry and wet alternations during seawater-soil corrosion macro-cell processes).

The corrosion behaviors were studied via the weight loss method, electrochemical methods and morphological observations on corrosion.

The results show that during the initial stage of tidal seawater/soil macro-cell corrosion process of the X65 steel, the working electrode on the seawater side is the anode of the macro-battery. As corrosion progresses, the anode and the cathode of the macro-battery become inverted. As the area ratio and the dry – wet ratio increase, the time of anode and cathode inversion shortens. Galvanic current density decreases as the dry – wet ratio increases and increases as the area ratio increases. The corrosion process of macro-cell is affected by the reversal of anode and cathode. After the reversal of anode and cathode, the corrosion rate is mainly controlled by dry – wet alternating corrosion.

The corrosion behavior of a pipeline steel in a coastal environment was studied using a tidal seawater macro-cell corrosion device. The synergism effect between the tidal seawater and seawater-soil macro-cell on corrosion behavior was clarified.