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To study the corrosion behavior of pipeline steel in coastal areas, a tidal seawater macro-cell corrosion device was built using a cycle soaking tank and a macro-cell corrosion facility to simulate the corrosion behavior of pipeline steel in a simulated coastal environment (dry and wet alternations during seawater-soil corrosion macro-cell processes).

The corrosion behaviors were studied via the weight loss method, electrochemical methods and morphological observations on corrosion.

The results show that during the initial stage of tidal seawater/soil macro-cell corrosion process of the X65 steel, the working electrode on the seawater side is the anode of the macro-battery. As corrosion progresses, the anode and the cathode of the macro-battery become inverted. As the area ratio and the dry – wet ratio increase, the time of anode and cathode inversion shortens. Galvanic current density decreases as the dry – wet ratio increases and increases as the area ratio increases. The corrosion process of macro-cell is affected by the reversal of anode and cathode. After the reversal of anode and cathode, the corrosion rate is mainly controlled by dry – wet alternating corrosion.

The corrosion behavior of a pipeline steel in a coastal environment was studied using a tidal seawater macro-cell corrosion device. The synergism effect between the tidal seawater and seawater-soil macro-cell on corrosion behavior was clarified.

This study aims to investigate the effect of post-treatment on anti-corrosion performance of Al coating on the surface of Ti-6Al-4V (TC4) fastener.

The Al coatings with different layer structures were prepared on TC4 by middle-frequency and direct-current combined magnetron sputtering. The cross-sectional morphology and surface roughness of coatings were characterized by scanning electron microscope and atomic force microscope. The corrosion resistance was evaluated by electrochemical method. The monolayer coating was post-treated by Alodine chemical conversion, Ar⁺ bombardment and a combination of two methods above.

The results show that the interfaces in bilayer and trilayer coatings reduce the defects. Ar⁺ bombardment reduces the corrosion current density, and Alodine chemical conversion leads to a higher pitting corrosion potential. The combined post-treatment has the highest polarization resistance.

The corrosion resistance of the Al coating is enhanced as the layer quantity increases. The combination of two post-treatments, Ar⁺ bombardment and Alodine chemical conversion, could achieve an overall improvement in corrosion resistance of Al coating.

To provide a summary of research work carried out mainly in the authors' group for evaluating various protective coatings including rustproofing oils, and also for studying corrosion inhibitors using the wire beam electrode (WBE) method.

A range of published papers published during the past 15 years was summarised and reviewed. Recent research work in the authors' group was also included, which involved the combined use of the WBE with electrochemical noise analysis and the scanning reference electrode technique.

The WBE method has been developed into a very useful tool of evaluating the performance of coatings and inhibitors. In particular, The WBE is uniquely applicable for determining the performance of coatings and inhibitors to control localised corrosion.

Focusing mainly on recent research.

A useful source of information for researchers and graduate students working in the areas of organic coating and inhibitor research.

The first summary or review on this research topic.

This study aims to reveal the differential concentration corrosion (DCC) mechanism, which has been ignored by researchers for a long time.

The ionic conductive layer near the pipe wall was extracted and discretized. In the case of DCC, the equations of corrosion potential after polarization in units are derived according to Kirchhoff’s Law. By solving these equations, the corrosion potential and current on situation of DCC are calculated.

DCC can change origin distribution of (nature) potential and current greatly; it will cause polarization. The positions with original lower corrosion potential will produce anodic polarization; meanwhile, the speed of corrosion also increases; the position with original higher corrosion potential will produce cathodic polarization, and the corrosion current is also decreased. Generally speaking, the potential will be homogenized by DCC mechanism.

This model makes an in-depth analysis of the traditional FAC theory, greatly supplements it and enriches the theory.

The safety of reinforced concrete structures is generally related to the expected service life of their individual materials. Corrosion damage manifesting on steel reinforcement is usually underestimated, although it greatly affects both load bearing capacity and plastic deformation limits of steel reinforcement. Corrosion damage degree has a great impact on the life expectancy of structures. This paper aims to discuss these issues.

In the present study, an effort has been made to examine and present critical parameters, which are significantly responsible for the differentiation of the corrosion damage level, as far as mass loss is concerned. Consequently, the size effect of the exposed – to the aggressive conditions – area of the specimen, as well as the volume of the protected (against corrosion) area, was examined in detail.

Differential aeration greatly affects the results of corrosion on the material, given that under both high and low oxygen concentration corrosion process is still ongoing.

Findings proceeded are worth mentioning, as they may contribute to a more pertinent evaluation of the corrosion damage (as far as mass loss is concerned), restricting the risk of erroneous predictions concerning the mechanical behavior of steel reinforcement.

The purpose of this paper is to verify the influence of superplasticizer and air entrainment admixtures (AEs) in the electrical resistivity of concrete.

Ten different types of concrete have been studied. Three levels of superplasticizer and air AEs have been used (0.20, 0.35 and 0.50 per cent). Concrete samples were cast and the electrical resistivity was monitored at the ages of 28, 63 and 91 days. Compressive strength and density tests have also been executed.

The superplasticizer admixture presented an optimal level of 0.35 per cent that significantly increased the electrical resistivity. The air AEs at the same dosage caused a considerable decrease in the electrical resistivity. The concrete with air AEs showed highest resistivity/MPa ratio.

The results should be carefully extrapolated for other materials and admixtures.

The usage of chemicals admixture in concrete is extremely common nowadays. However, only a few authors have studied the impact of such materials on the concrete’s electrical resistivity. Since many other researchers have already correlated electrical resistivity with other concrete’s properties, such as strength, setting time and corrosion probability, it is important to better understand how superplasticizers and air-entraining agents, for instance, impact the resistivity.

The vast majority of studies only tested the resistivity of cement paste or mortar and usually for short period of time (up to 28 days), which seems not to be adequate since the cement reaction continues after that period. This paper fills this gap and studied the impact of admixture on concrete and for a period of 91 days.

The purpose of this paper is to present the results of a two-year long study carried out in order to evaluate the corrosion performance of mild steel bare bars (BB) and epoxy-coated rebar (ECR) in concrete under a simulated harsh environment of chlorides.

The blocks are subjected to Southern Exposure testing. The electrochemical impedance spectroscopy (EIS), linear polarization resistance (LPR) and Tafel plot are performed to measure the polarization resistance and corrosion current densities of these rebars. Knife-peel test was performed to assess the adhesion between epoxy and underlying steel after two years of exposure.

Mild steel BB showed a high corrosion current density of 1.24 µA/ cm² in Tafel plots and a very low polarization resistance of 4.5 kΩ cm² in LPR technique, whereas very high charge transfer resistance of 1672 and 1675 kΩ cm² is observed on ECR and ECR with controlled damage (ECRCD), through EIS technique, respectively. EIS is observed to be a suitable tool to detect the defects in epoxy coatings. After two years of immersion in 3.89 percent NaCl⁻ solution, the mild steel BB were severely corroded and a considerable weight loss was observed, whereas under heavy chloride attack, ECR showed no deterioration of epoxy coating and neither any corrosion of underlying steel. Results of this study show that the durability of reinforced concrete (RC) structures with respect to corrosion could be enhanced by using ECR, especially in harsh climatic conditions.

The corrosion performance of mild steel and ECR in concrete under a simulating splash zone environment is evaluated. EIS was used to evaluate the health of epoxy and corrosion state of underneath steel rebars. EIS was able to detect the defects in epoxy. The durability of RC structures could be enhanced in harsh climate regions by using ECR.