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1 – 5 of 5Piotr Walter, Andrzej Pepłowski, Łukasz Górski, Daniel Janczak and Małgorzata Jakubowska
Because of the bioaccumulation effect, organophosphorus pesticides cause long-term damage to mammals, even at small concentrations. The ability to perturb the phospholipid bilayer…
Abstract
Purpose
Because of the bioaccumulation effect, organophosphorus pesticides cause long-term damage to mammals, even at small concentrations. The ability to perturb the phospholipid bilayer structure as well as the overstimulation of cholinergic receptors makes them hazardous to humans. Therefore, there is a need for a quick and inexpensive detection of organophosphorus pesticides for agricultural and household use. As organophosphorus pesticides are acetylcholinesterase (AChE) inhibitors, biosensors using this mechanism hold a great promise to meet these requirements with a fraction of reagents and time used for measurement comparing to laboratory methods. This study aims to manufacture AChE-coated, screen-printed carbon electrodes applicable in such amperometric biosensors.
Design/methodology/approach
AChE enzyme, known for catalytic activity for the hydrolysis of acetylthiocholine (ATCh), could be used to obtain electrochemically active thiocholine from acetylthiocholine chloride in aqueous solutions. Using Malathion’s inhibitory effect towards AChE, pesticides’ presence can be detected by reduction of anodic oxidation peaks of thiocholine in cyclic voltammetry.
Findings
The conducted research proved that it is possible to detect pesticides using low-cost, simple-to-manufacture screen-printed graphite (GR) electrodes with an enzymatic (AChE) coating. Investigated electrodes displayed significant catalytic activity to the hydrolysis of ATCh. Owing to inhibition effect of the enzyme, amperometric response of the samples decreased in pesticide-spiked solution, allowing determination of organophosphorus pesticides.
Originality/value
Printed electronics has grown significantly in recent years as well as research focused on carbon-based nanocomposites. Yet, the utilization of carbon nanocomposites in screen-printed electronics is still considered a novelty in the market. Biosensors have proved useful not only in laboratory conditions but also in home applications, as glucometers are a superior solution for glucose determination for personal use. Although pesticides could be detected accurately using chromatography, spectroscopy, spectrometry or spectrophotometry, the market lacks low-cost, disposable solutions for pesticide detection applicable for household use. With biosensing techniques and electric paths screen-printed with GR or graphene nanocomposites, this preliminary research focuses on meeting these needs.
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Lucja Dybowska-Sarapuk, Daniel Janczak, Bartlomiej Podsiadly, Malgorzata Jakubowska and Marcin Sloma
A comparison of electric and viscosity percolation threshold is crucial from the scientific and technical points of view to understand the features and capabilities of…
Abstract
Purpose
A comparison of electric and viscosity percolation threshold is crucial from the scientific and technical points of view to understand the features and capabilities of heterogeneous graphene composite materials and properly select the functional phase volume. Therefore, the purpose of this paper is to present the analysis of the electrical and rheological percolation thresholds in the polymer–graphene screen printing pastes and the analysis of the relation between these two parameters.
Design/methodology/approach
In the paper, the properties of polymer-based pastes with graphene nanoplatelets were tested: paste viscosity and printed layers conductivity. The tests of pastes with different filler content allowed to determine both the electrical and rheological percolation thresholds using power law, according to Kirkpatrick’s percolation model.
Findings
The electrical percolation threshold for graphene nanoplatelets (GNPs) in the composite was 0.74 Vol.% when the rheological percolation threshold is observed to be at 1.00 Vol.% of nanoplatelets. The percolation threshold values calculated using the Kirkpatrick’s percolation model were 0.87 and 0.5 Vol.% of GNPs in the paste for electrical and rheological percolation thresholds, respectively.
Originality/value
Recently, GNPs are becoming more popular as the material of the functional phase in screen printing heterophase materials, because of their unique mechanical and electrical properties. However, till date no research presented in the literature is related to the direct comparison of both the electrical and rheological percolation thresholds. Such analysis is important for the optimization of the printing process toward the highest quality of printed conductive paths, and finally the best electrical properties.
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Grzegorz Wroblewski, Marcin Słoma, Daniel Janczak and Malgorzata Jakubowska
The aims of this paper are to investigate the influence of direct current (DC) electric field on separation and orientation of carbon nanotubes (CNTs) in spray-coated layers and…
Abstract
Purpose
The aims of this paper are to investigate the influence of direct current (DC) electric field on separation and orientation of carbon nanotubes (CNTs) in spray-coated layers and apply this method to the fabrication of elastic and transparent electrodes. The orientation of CNTs in the form of paths in the direction of electrical conduction should increase the electrode conductivity without decreasing its optical transmission.
Design/methodology/approach
Materials are deposited using vacuum-free, ultra-fine nozzle spray coating technique, easily applicable for large-scale production. After the deposition of carbon nanomaterials, nanoparticles are oriented in the electric field and initially cured with infrared halogen lamp to evaporate solvents and preserve orientation of the nanoparticles in the deposited layer. Afterwards, layers are cured in a chamber dryer to obtain desired properties. Nanoparticles orientation and carbon nanomaterials separation via DC electric field are analysed, and the optical and electrical properties of prepared electrodes are measured.
Findings
Experiments described in this paper showed that DC electric field can be applied provide separation and orientation of CNTs and combined with spray coating technique, can be used as additional tool for tuning the conductivity of flexible and transparent electrodes by decreasing the sheet resistance about five times.
Originality/value
The results showed that spray coating combined with electric field orientation is a promising solution of obtaining elastic and transparent electrodes with oriented carbon particles. According to the authors’ knowledge, none of the experiments was directed to obtain DC electric field-oriented transparent layers produced with the use of spray coating technique.
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Andrzej Peplowski, Daniel Janczak, Grzegorz Wróblewski, Marcin Słoma, Łukasz Górski, Elżbieta Malinowska, Tadeusz Pałko and Małgorzata Jakubowska
– The aim of this paper was to verify applicability of graphene-based sensors for voltammetric and amperometric measurements of low-concentration compounds in biological fluids.
Abstract
Purpose
The aim of this paper was to verify applicability of graphene-based sensors for voltammetric and amperometric measurements of low-concentration compounds in biological fluids.
Design/methodology/approach
Using the screen printing method, electrochemical sensors were manufactured on polymethylmetacrylate foil using a paste consisting of organic solvents and graphene nanopetals. As the model of a biological fluid tear film was chosen, the compound chosen as the analyte was H2O2, which is produced in oxidation of biological compounds. Tear film analog was prepared, in which, the measurements were carried out in a wide range of concentrations to determine the oxidation potential of H2O2 through square-wave voltammetry. The second series of amperometric measurements was carried out for concentrations between 0 and 30 μM/L, which is the lower range of physiological glucose concentration in tear films.
Findings
The sensors presented linearity for concentrations from 0 to 3.5 per cent. Mean linear correlation coefficient between the peak current and the concentration for the examined sensors was 0.9764. Mean sensitivity was 434.4 mA·M−1·L−1.
Research limitations/implications
Results indicate a need for optimization of the sensors ' performance. Main parameters to be improved are surface area of electrodes and purity of the graphene layer, as well as uniformity of the manufacturing process to improve accuracy and repeatability of measurements.
Practical implications
Technology and materials used present an opportunity for creating low-cost, miniaturized and biocompatible sensors to be used in medical monitoring.
Originality/value
Printed electronics technology described was not investigated previously in the field of biological sensors and could contribute to the solving of vital medicine problems.
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Marcin Sloma, Daniel Janczak, Grzegorz Wroblewski, Anna Mlozniak and Malgorzata Jakubowska
New types of substrates were used for fabrication of printed electroluminescent structures. Polymer foils mainly used as substrates for such optoelectronic elements were replaced…
Abstract
Purpose
New types of substrates were used for fabrication of printed electroluminescent structures. Polymer foils mainly used as substrates for such optoelectronic elements were replaced with paper and textiles. Printing on non-transparent substrate requires elaboration of printed transparent electrode, while usually polyester foils with sputtered ITO transparent electrodes are used. The paper aims to discuss these issues.
Design/methodology/approach
Electroluminescent structures were fabricated with elaborated polymer compositions filled with nanomaterials, such as carbon nanotubes and graphene platelets, dielectric and luminophore nanopowders. Structures were printed as “reverse stack”, where transparent electrode is printed on top of the last luminophore layer. For that carbon nanotubes and graphene platelets filled composition was used, deposited with spray-coating technique.
Findings
Main issue with new substrates is proper wetting with the use of screen-printing pastes, and much higher roughness especially for textiles.
Originality/value
Fully functional structures were obtained, but several disadvantages were observed that needs to be eliminated in further studies.
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