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This study aims to explore the synergistic effect of oxide nanoparticles (ZnO, Fe₂O₃, SiO₂) and cerium nitrate inhibitor on anti-corrosion performance of epoxy coating. First, cerium nitrate inhibitors are absorbed on the surface of various oxide nanoparticles. Thereafter, epoxy nanocomposite coatings have been fabricated on carbon steel substrate using these oxide@Ce nanoparticles as both nano-fillers and nano-inhibitors.

To evaluate the impact of oxides@Ce nanoparticles on mechanical properties of epoxy coating, the abrasion resistance and impact resistance of epoxy coatings have been examined. To study the impact of oxides@Ce nanoparticles on anti-corrosion performance of epoxy coating for steel, the electrochemical impedance spectroscopy has been carried out in 3% NaCl solution.

ZnO@Ce3+ and SiO2@Ce3+ nanoparticles provide more enhancement in the epoxy pore network than modification of the epoxy/steel interface. Whereas, Fe2O3@Ce3+ nanoparticles have more to do with modification of the epoxy/steel interface than to change the epoxy pore network.

Incorporation of both oxide nanoparticles and inorganic inhibitor into the epoxy resin is a promising approach for enhancing the anti-corrosion performance of carbon steel.

This study aims to examine the reuse of plastic and fly ash (FA) to improve the soil and achieve sustainable development goals.

Sand from the Anzali port was reinforced with Geopet (GP) and stabilized with FA plus 3% sodium hydroxide. The GP was placed in FA-stabilized soil and the California bearing ratio (CBR), and unconfined compressive strength (UCS) tests were performed on samples at the optimum moisture content.

The results showed that the improvement in the optimum CBR was 174.9%. The UCS increased 15.25% and 48.65% in soil reinforced with three layers of GP plus 15% FA over those containing 10% and 5% FA, respectively. Additionally, the current analysis used response surface methodology (RSM) to investigate the impact of FA percentage, GP layers and their interaction on CBR. The results highlight the efficacy of the used RSM model, as evidenced by the significantly low p-value (<0.0001).

This demonstrates the suitability and effectiveness of RSM for evaluating CBR in this scientific study.

The color painting of ancient buildings has high historical and artistic value but is prone to aging due to long-term outdoor exposure. The purpose of this study is to develop a new type of sealing coating to mitigate the impact of ultraviolet (UV) light on color painting.

The new coating was subjected to a 500-h UV-aging test. Compared with the existing acrylic resin Primal AC33, the UV aging behavior of the new coating, such as color difference and gloss, was studied with aging time. The Fourier infrared spectra of the coatings were analyzed after the UV-aging test.

Compared with AC33, the antiaging performance of SF8 was substantially improved. SF8 has a lower color difference value and better light retention and hydrophobicity. The Fourier transform infrared spectroscopy results showed that the C-F bond and Si-O bonds in the resin of the optimized sealing coating protected the main chain C-C structure from degradation during the aging process; thus, the resin maintained good stability. The hindered amine light stabilizer TN292 added to the coating inhibited the antiaging process by trapping active free radicals.

To address the problem of UV aging of oil-decorated colored paintings, a new type of sealing coating with excellent antiaging properties was developed, laying the foundation for its demonstration application on the surface of ancient buildings.

This study aims to investigate the behavior of the green biomass-derived copper (lignin/silica/fatty acids) complex, copper lignin/silica/fatty acids (Cu-LSF) complex, when incorporated into the nonpolar ethylene propylene diene (EPDFM) rubber matrix, focusing on its reinforcing and antioxidant effect on the resulting EPDM composites.

The structure of the prepared EPDM composites was confirmed by Fourier-transform infrared spectroscopy, and the dispersion of the additive fillers and antioxidants in the EPDM matrix was investigated using scanning electron microscopy. Also, the rheometric characteristics, mechanical properties, swelling behavior and thermal gravimetric analysis of all the prepared EPDM composites were explored as well.

Results revealed that the Cu-LSF complex dispersed well in the nonpolar EPDM rubber matrix, in thepresence of coupling system, with enhanced Cu-LSF-rubber interactions and increased cross-linking density, which reflected on the improved rheological and mechanical properties of the resulting EPDM composites. From the various investigations performed in the current study, the authors can suggest 7–11 phr is the optimal effective concentration of Cu-LSF complex loading. Interestingly, EPDM composites containing Cu-LSF complex showed better antiaging performance, thermal stability and fluid resistance, when compared with those containing the commercial antioxidants (2,2,4-trimethyl-1,2-dihydroquinoline and N-isopropyl-N’-phenyl-p-phenylenediamine). These findings are in good agreement with our previous study on polar nitrile butadiene rubber.

The current study suggests the green biomass-derived Cu-LSF complex to be a promising low-cost and environmentally safe alternative filler and antioxidant to the hazardous commercial ones.

For the sake of sustainable development and environmental preservation, it is crucial to develop UV-curable coatings composed of renewable resources. Castor oil, being both bio-based and economical, serves as the focal point of this research paper. The purpose of this research paper is to synthesize, formulate and apply a UV-curable biobased oligomer ECOSAGMA as a wood coating, with a focus on sustainable development and environmental preservation. Castor oil, being both bio-based and economical, serves as the focal point of this research paper.

ECOSAGMA was prepared by reacting epoxidized castor oil with sebacic acid, followed by reaction with glycidyl methacrylate through ring opening reaction. The chemical structure of ECOSAGMA was confirmed by Fourier-Transform infrared spectroscopy, 13C-NMR and 1H-NMR spectroscopy. The synthesized oligomer was used for UV-curable coating formulations by combining it with varying amounts of TMPTA from 10 to 40 wt.% and studied for their rheological properties. The UV curable formulations were co-photopolymerized into thin coatings and were thoroughly examined based on thermal, chemical and mechanical properties.

The UV-cured coating containing ECOSAGMA and TMPTA exhibits exceptional mechanical, chemical and thermal properties, underscoring their potential for deployment in real-world application. It is observed that an increase in the concentration of TMPTA is associated with a notable enhancement in the properties of the UV-cured coatings. The UV-cured wood coating, composed of 40 wt.% TMPTA, demonstrates remarkable stain resistance properties.

In conclusion, by embracing eco-friendly and economically conscious principles., it is evident that this synthesized novel castor oil-based oligomer offers a range of valuable properties to the coating such as stain resistance and thermal stability as well as characteristics such as gloss, hardness, adhesion and chemical resistance.

The silicone modifications of two-component epoxy resin coatings are commonly built on epoxy resins rather than on epoxy curing agents. The silicone-modified epoxy curing agent system is rarely reported yet. This study aims to prepare the polysiloxane (PS)-modified waterborne epoxy coatings based on aqueous curing agents technology.

Waterborne epoxy curing agents with different contents of terminal epoxy PS were synthesized by reacting with triethylenetetramine, followed by incorporating of epoxy resin (NPEL-128) and polyethylene glycol diglycidyl ether. The waterborne epoxy coatings were prepared with the above curing agents, and their performance was investigated through thermogravimetric analysis, scanning electron microscopy, mechanical characterization, gloss measurement, chemical resistance test and ultraviolet (UV) aging experiment.

The results showed that the epoxy coating prepared by silicon-modified curing agent has higher gloss, better chemical resistance and UV resistance than the coating from unmodified curing agent with terminal epoxy PS and commercially available waterborne epoxy curing agent (Aradur 3986), as well as the competitive mechanical properties and heat resistance. Reduced water absorption on fibrous paper was also obtained with the help of silicon-modified curing agent.

These findings will be valuable for resin researchers in addressing the modification issues about waterborne epoxy resin and curing agent.

This paper aims to investigate the effects on coatings performance in the epoxy silicone resin system owing to the existence of the different chain length of open-chain epoxy monomer. In this paper, [4-Methylphenyl-(4–(2-methylpropyl) phenyl)]iodonium as photoinitiator was added into epoxy silicone resin by ultraviolet (UV)-cured polymerization to investigate the effects on coatings performance owing to the existence of the different chain length of open-chain epoxy monomer.

A simple hydrosilylation reaction was used to synthesize epoxy-based silicone prepolymers by using hydrogen-terminated polydimethylsiloxane, 1,2-epoxy-5-hexene, 1,2-epoxy-7-octene and 1,2-epoxy-9-decene as precursors.

The results revealed that the glass transition temperatures (Tg) and hydrophobicity increased with the chain length of open-chain epoxy monomer in the UV curable epoxy-based silicone coatings, and these films had excellent heat resistance, hydrophobicity, antigraffiti and ink removal properties.

The cationic photocuring systems are not susceptible to the effect of oxygen inhibition. However, the limitation of cationic light curing process is that it requires a long curing time.

The coatings prepared via the UV curing approach can provide superior antismudge effects, and thus they are promising candidates for use in various industries, especially in fields such as antismudge coatings and antigraffiti coatings.

This paper aims to investigate the bond strength of metakaolin-based geopolymer mortar with cement mortar.

The mortar-mortar bond strength is assessed by slant shear and split tensile tests; pure shear strength is evaluated by Mohr’s criterion for result validation. Metakaolin-based geopolymer mortar is cast over the cured cement mortar specimen with two levels of surface roughness: smooth or grooved interface. The influence of the alkaline solution to metakaolin ratio on geopolymer bond strength is studied. Compressive strength, ultrasonic pulse velocity, permeability and flow table tests are also performed.

The paper’s findings are highlighted as follows: (1) strong mortar-mortar bond properties achieved for geopolymer mortar in all tests and conditions and validated by Mohr’s criterion and pure shear, (2) a lower alkaline solution to metakaolin ratio achieves higher bond strength to Portland cement mortar and (3) geopolymer mortar has higher compressive strength and ultrasonic pulse velocity than cement mortar at all curing ages; additionally, it is more flowable and less permeable.

The full replacement of Portland cement with metakaolin, a more sustainable cementitious material, will contribute to the decarbonization of the construction industry.

Limited research has been carried out on the bond strength of metakaolin-based geopolymer mortar to Portland cement mortar. Also, computing the pure shear using Mohr’s circle criterion of metakaolin-based geopolymer to validate the results can be considered original.

Low-carbon concrete represents a new direction in mitigating the global warming effects caused by clinker manufacturing. Utilizing Saudi agro-industrial by-products as an alternative to cement is a key support in reducing clinker production and promoting innovation in infrastructure and circular economy concepts, toward decarbonization in the construction industry. The use of fly ash (FA) as a cement alternative has been researched and proven effective in enhancing the durability of FA-based concrete, especially at lower replacement levels. However, at higher replacement levels, a noticeable impediment in mechanical strength indicators limits the use of this material.

In this study, low-carbon concrete mixes were designed by replacing 50% of the cement with FA. Varying ratios of nano-sized glass powder (4 and 6% of cement weight) were used as nanomaterial additives to enhance the mechanical properties and durability of the designed concrete. In addition, a 10% of the mixing water was replaced with EMs dosage.

The results obtained showed a significant positive impact on resistance and durability properties when replacing 10% of the mixing water with effective microorganisms (EMs) broth and incorporating nanomaterial additives. The optimal mix ratios were those designed with 10% EMs and 4–6% nano-sized glass powder additives. However, it can be concluded that advancements in eco-friendly concrete additive technologies have made significant contributions to the development of sophisticated concrete varieties.

This study focused at developing nanomaterial additives from Saudi industrial wastes and at presenting a cost-effective and feasible solution for enhancing the properties of FA-based concrete. It has also been found that the inclusion of EMs contributes effectively to enhancing the concrete's resistance properties.

One of the often-employed building constituents in the construction sector is concrete, which involves hydration of cement, leading to the generation of carbon footprints during its production. Also, massive amount of natural aggregate is illegally mined, which poses serious environmental issues along with ecological misbalance. Researchers are in continuous search of appropriate substitutes to mitigate those challenges and develop innovative concrete mix. Consequently, depletion of natural resources, the disturbances to the environmental and ecological imbalance will reduce. The purpose of this study is to develop a Portland Slag Cement based novel sustainable concrete incorporating Alccofine and Recycled Refractory Brick as fractional replacement of cement and fine aggregate, respectively and evaluate its destructive, non-destructive and microstructural properties.

M25 grade of concrete adopting 0.45 water-binder proportion, with diverse percentage of Alccofine as fractional substitution of cement and 20% of recycled refractory brick (RRB) as fine aggregate, has been cast and evaluated for diverse mechanical strength following a curing of 7, 14 and 28 days. Scanning electron microscopic analysis has been carried out to study the microstructural changes in the specimens.

Supplementary use of Alccofine enhanced normal compressive strength of sustainable concrete mix blended with Portland Slag Cement by a large amount at all levels of 7, 14 and 28 days of curing. Test results indicated development of a favourable high-strength sustainable concrete mix by substituting cement with Alccofine.

This manuscript has demonstrated the possibility of developing sustainable concrete blends by incorporating Alccofine 1203 and RRB as partial replacement of Portland Slag Cement and natural fine aggregate, respectively. The strength and potential of concrete incorporating RRB for wider and special application in adverse environmental conditions having higher thermal gradient, as RRB is a valuable waste from high temperature kiln and furnaces. Alccofine 1203 has been included in the concrete mix as an alternative to Portland Slag Cement to improve the mechanical strength properties and durability of concrete intended for adverse environmental application.