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1 – 10 of 855Shanhua Qian, Hongyue Wang, Chuanhui Huang and Yongwu Zhao
This paper aims to modify carbon nanotubes with oleic acid, and to study the tribological properties of castor oil with modified carbon nanotubes additives. The proper additives…
Abstract
Purpose
This paper aims to modify carbon nanotubes with oleic acid, and to study the tribological properties of castor oil with modified carbon nanotubes additives. The proper additives are sought for the future engineering application of castor oil.
Design/methodology/approach
Tribological properties of the castor oils mixed with the modified carbon nanotubes of four mass percentages were investigated using a four-ball testing rig. Coefficient of friction and wear scar diameter were obtained in each test, and the mechanism of modified carbon nanotubes and castor oil was discussed.
Findings
The results indicated that modified carbon nanotubes had better dispersion in castor oil. Coefficient of friction first increased, then decreased and finally grew stable with the time, and wear scar diameter of steel surface functioned as a first reduced then increased change with the additive mass percentage of modified carbon nanotubes. The minimum of average coefficient of friction and wear scar diameter occurred at 0.02 Wt.% modified carbon nanotubes.
Originality/value
A small amount of modified carbon nanotubes could improve properties of the castor oil, and the mixed castor oil with 0.02 Wt.% modified carbon nanotubes would be most possibly used in engineering applications.
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M.R. Noor El-Din, Marwa R. Mishrif, Satish V. Kailas, Suvin P.S. and Jagadeesh K. Mannekote
This paper aims to formulate a new metal working fluid (MWF) composition including some eco-friendly emulsifiers, corrosion inhibitor, biocide, and non- edible vegetable oil …
Abstract
Purpose
This paper aims to formulate a new metal working fluid (MWF) composition including some eco-friendly emulsifiers, corrosion inhibitor, biocide, and non- edible vegetable oil (castor oil) as the base oil. To achieve this aim, five MWFs with different hydrophilic–lipophilic balance (HLB) value as 10, 9.5, 9, 8.5 and 8 were prepared to identify the optimum HLB value that gives a highly stable oil-in-water emulsion. The performance of castor oil based MWF was evaluated using tool chip tribometer and drill dynamometer. The surface morphology of steel disc and friction pin was performed using scanning electron microscope (SEM) and 3D profilometer. The results revealed that the use of the prepared cutting fluid (E1) caused the cutting force to decrease from 500 N for dry high-speed steel sample to 280N, while the same value for a commercial cutting fluid (COM) was recorded as 340 N at drilling speed and cutting feed force as 1120 rpm and 4 mm/min., respectively.
Design/methodology/approach
A castor oil-based metalworking fluid was prepared using nonionic surfactants. The composition of the metalworking fluid was further optimized by adding performance-enhancing additives. The performance of castor oil based MWF was analyzed using Tool chip tribometer and Drill dynamometer. The surface morphology of steel ball and a disc was done using 3D profilometer and SEM.
Findings
Studies revealed that castor oil-based MWF having Monoethanolamine (MEA) as corrosion inhibitor was found to be highly stable. The drilling dynamometer and tool chip tribometer studies showed that castor oil-based MWF performance was comparable to that of commercial MWF.
Research limitations/implications
This study aims to explore the performance of the castor oil based metalworking fluid (MWF) using tool chip tribometer and drill dynamometer.
Practical implications
The conventional MWFs are petroleum derives and are unsustainable. Use of non-edible plant-based oils for preparing the MWF will not only be conserved environment but also add value addition to agricultural crops.
Social implications
The social Implications is aiming to decrease the environmental impact that results from the using of mineral cutting fluids.
Originality/value
The originality of this work is to replace the mineral oil and synthetic oil based cutting fluids with more eco-friendly alternatives one. In addition, the investigation will focus on developing functional additives required for cutting fluids which are environmentally benign.
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Stanley Ifeanyi Anyanwu-Azuka, Gabriel Sunday Aloh, Winner Oyidiya Kalu and Chinedum Eleazu
This study aims to report the phytochemical screening and anti-diarrhoea properties of methanol extract of Diodia sarmentosa Swartz (DSS) leave (at 200, 400 and 600 mg/kg) in…
Abstract
Purpose
This study aims to report the phytochemical screening and anti-diarrhoea properties of methanol extract of Diodia sarmentosa Swartz (DSS) leave (at 200, 400 and 600 mg/kg) in albino rats.
Design/methodology/approach
Three types of diarrhoea models (castor oil-induced diarrhoea, castor oil-induced gastrointestinal motility and castor oil-induced enteropooling), as well as an assay for serum and faecal electrolyte concentrations, were used. Acute toxicity study and phytochemical screening of the extract were carried out using standard techniques.
Findings
The percentage inhibition of diarrhoea by DSS 200, 400 and 600 mg/kg was obtained as 25.7%, 55% and 84.6%, respectively, compared with loperamide that had 87.6% inhibition. DSS dose dependently modulated the number and frequency of defecation, the weight of the faeces of the diarrhoea rats, the distance that was travelled by charcoal meal, mean differences in the full lengths of the intestines and the distance travelled by charcoal meal, weight and volume of intestinal contents, serum and faecal concentrations of potassium, sodium, chloride, magnesium, bicarbonate, iron and zinc relative to the negative control and in a manner akin to loperamide (for the extract at 600 mg/kg). DSS or loperamide attenuated the loss of calcium in the faeces of the rats. DSS possesses anti-diarrhoea properties, which may be attributed to the phytochemicals in it. Finally, the study showed the safety in the usage of DSS.
Originality/value
DSS exerted its anti-diarrhoea action in castor oil-induced diarrhoea rats, by modulating their intestinal secretory and motile activity in a manner akin to loperamide (for DSS at 600 mg/kg).
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J.K. Vinaik, S. Chandra and A.K. Vasishtha
Polycarbonate was incorporated in castor oil and nigerseed oil alkyds of various oil lengths. Compatibility of polycarbonate with these alkyds was investigated. It was found that…
Abstract
Polycarbonate was incorporated in castor oil and nigerseed oil alkyds of various oil lengths. Compatibility of polycarbonate with these alkyds was investigated. It was found that only a small amount (4 to 10%) of polycarbonate could successfully be blended with these alkyds. Film properties of these blends were examined and compared with those of amino alkyd blends, in order to determine the usefulness of the polycarbonate alkyd blends. It was observed that polycarbonate modified alkyds, even with a small amount of polycarbonate were superior in film properties as compared to amino modified alkyds, especially with respect to chemicals and physical properties.
Emad S. Shafik, Azza A. Ward and Adel Farid Younan
This study aims to develop a biodegradable linear low-density polyethylene (LLDPE)/starch blends with improved mechanical and flow characteristics and evaluate the probability of…
Abstract
Purpose
This study aims to develop a biodegradable linear low-density polyethylene (LLDPE)/starch blends with improved mechanical and flow characteristics and evaluate the probability of using essential oils such as Moringa oleifira and castor oils as green plasticizers and compatibilizers to avoid using harmful chemicals.
Design/methodology/approach
Corn starch was blended with LLDPE through the melt blending technique. The corn starch content was varied from 5 to 40 phr in LLDPE. To enhance poor mechanical characteristic of the LLDPE/starch, essential oils such as M. oleifira and castor oils were incorporated into the composites with different concentrations starting from 1 to 7 phr. The essential oils’ effect on mechanical, flow character, thermal stability and electrical properties of the LLDPE/starch was also investigated. The morphology of LLDPE/starch containing essential oils was also investigated by scanning electron microscope (SEM).
Findings
The results revealed that increasing the corn starch content had an adverse effect on mechanical and flow characteristics of the composites, whereas incorporation of essential oils had increased the flow and mechanical characteristics of the composites. Also, dielectric measurements revealed that permittivity and dielectric loss increased by increasing oil content. Moreover, the values of the blends containing castor oil are higher compared to that containing M. oleifira. The SEM micrographs illustrated that the presence of essential oils in LLDPE/starch enhanced the distribution and the homogeneity of the composites, and the particle size of starch granules became smaller in LLDPE matrix.
Originality/value
This study aims to introduce green plasticizer and compatibilizer to avoid using harmful chemicals in packaging industry.
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Pradeep G. Shende, Abhijit B. Jadhav and Shrikant B. Dabhade
Attempt has been made in this study, to utilize castor oil in the preparation of polyesteramide resins. Castor oil was first converted into dehydrated castor oils (DCO) to improve…
Abstract
Attempt has been made in this study, to utilize castor oil in the preparation of polyesteramide resins. Castor oil was first converted into dehydrated castor oils (DCO) to improve drying characteristics. DCO was then converted into diethanolamide {(N, N‐ bis hydroxethyl) castor oil amide} of mixed fatty acids using 0.5 per cent sodium methoxide as a catalyst and converted to polyesteramide resins after reacting with various dibasic acids such as phthalic anhydride, sebacic, succinic and adipic acids in presence of xylene as azeotropic solvent. The resins obtained were then analysed for its physico‐chemical, film performance properties and resistance to various chemicals.
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Chinwuba Victor Ossia, Hung Gu Han and Hosung Kong
The purpose of this paper is to evaluate local biodegradable oils with long chain fatty acids namely: castor (Ricinus communis L.), jojoba (Simmondsia chinensis L.), olive (Oleo…
Abstract
Purpose
The purpose of this paper is to evaluate local biodegradable oils with long chain fatty acids namely: castor (Ricinus communis L.), jojoba (Simmondsia chinensis L.), olive (Oleo europaea L.), and sunflower (Helianthus annuus L.) oils for lubrication candidacy as a substitute to petroleum mineral oils.
Design/methodology/approach
Evaluation criteria includes antiwear, lubricity, and extreme pressure (load carrying capacity) using the four‐ball configuration, oxidation induction by pressure differential scanning calorimetry, thermal stability by thermo‐gravimetric analyses, and viscometry using relevant American Society of Testing and Materials (ASTM) standards.
Findings
The results show that the lubrication films at the interface failed by the decomposition of the metallic soaps formed by the chemical reaction of the constituent fatty acid molecules and the rubbing surfaces. The biodegradable oils show superior lubricant performance compared to the paraffin‐based mineral oil, despite their poor oxidation stability. Oxidation induction and thermo‐gravimetric characteristics of the biodegradable oils are closely related to their polyunsaturated and monounsaturated fatty acid composition.
Originality/value
The paper shows how these biodegradable oils could be used as good substitute for petroleum mineral oils in as‐received state or little antioxidant additives.
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The animal and vegetable oils, fats, and waxes provide vital raw materials for a large number of industries. Soap, paint, foodstuffs, textiles, leather, and linoleum are but a few…
Abstract
The animal and vegetable oils, fats, and waxes provide vital raw materials for a large number of industries. Soap, paint, foodstuffs, textiles, leather, and linoleum are but a few of the diversity of products which employ one or more of this large class of natural bodies.
Suman Pasari and Sushil Chandra
Polystyrene glycol was prepared and incorporated into nigerseed oil and castor oil alkyds representing semi‐drying and non‐drying type alkyds respectively. Compatibility of…
Abstract
Polystyrene glycol was prepared and incorporated into nigerseed oil and castor oil alkyds representing semi‐drying and non‐drying type alkyds respectively. Compatibility of polystyrene glycol with these alkyds was investigated. It was found that 11 to 12 per cent polystyrene glycol could successfully be blended with these alkyds. In order to determine usefulness of these polyblends, film properties were examined and compared with those of plain alkyds. It was observed that polystyrene glycol modified alkyd blends were superior in film properties as compared to plain alkyds.
O. Thornycroft and C.H. Barton
THE function and behaviour of a lubricant on certain parts of an internal‐combustion engine is so complex that the knowledge on this subject is still very incomplete. After…
Abstract
THE function and behaviour of a lubricant on certain parts of an internal‐combustion engine is so complex that the knowledge on this subject is still very incomplete. After several years of experimentation both with specially designed apparatus and with actual engines, the authors of these notes have reached certain conclusions which they will here endeavour to record. Some of the conclusions must, nevertheless, be regarded as opinions only, since lubrication in all its forms is not yet an exact science. For instance, the exact means by which oil lubricates a piston‐ring reciprocating within a cylinder remains very obscure. The action of the lubricant at the rings and in some bearings, such as at the gudgeon‐pin, does not lend itself to mathematical treatment because the conditions are not constant. The alternate sliding and stopping is not a strictly continuous process, and neither the “fluid” nor the “boundary” theories of lubrication can be satisfactorily applied.