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This paper aims to explore how graphene can improve the mechanical and anti-corrosion properties of TiO₂-SiO₂ sol-gel coating. This sol-gel coating has been prepared on aluminum alloy substrate using graphene as both nano-filler and corrosion inhibitor.

To examine the effect of graphene on mechanical properties of sol-gel coating, the abrasion resistance, adhesion strength and scratch resistance of coating have been evaluated. To reveal the effect of graphene on the anti-corrosion property of coating for aluminum alloy, the electrochemical impedance spectroscopy (EIS) has been conducted in 3.5 Wt.% NaCl medium.

Scanning electron microscopy images indicate that graphene nanoplatelets (GNPs) have been homogeneously dispersed into the sol-gel coating matrices (at the contents from 0.1 to 0.5 Wt.%). Mechanical tests of coatings indicate that the graphene content of 0.5 Wt.% provides highest values of adhesion strength (1.48 MPa), scratch resistance (850 N) and abrasion strength (812 L./mil.) for the sol-gel coating. The EIS data show that the higher content of GNPs improve both R₁ (coating) and R₂ (coating/Al interface) resistances. In addition to enhancing the coating barrier performance (graphene acts as nanofiller/nano-reinforcer for coating matrix), other mechanism can be at work to account for the role of the graphene inhibitor in improving the anticorrosive performance at the coating/Al interface.

Application of graphene-based sol-gel coating for protection of aluminum and its alloy is very promising.

This study aims to investigate a chromium-free sealing treatment process to replace the chromate sealing process in response to the environmental hazards caused by chromate in the Phosphate chemical conversion (PCC) coating post-treatment sealing process.

In this paper, chromium-free sealing technology was used to post-treat PCC coatings. Scanning electron microscopy was used to investigate the structure of the surface of the PCC coatings after the sealing treatment, and the corrosion resistance, hydrophobicity and bonding were tested using an electrochemical workstation, a copper sulfate spot-drop test, a lacquer bonding test, a contact angle meter and a neutral salt spray test.

Chromium-free closure makes the grain distribution on the surface of the PCC coating more uniform and dense, and forms an organic film on the surface of the coating, which significantly improves the corrosion resistance and hydrophobicity of the PCC coating, does not affect the coating film bonding force and has similar performance with potassium dichromate solution.

The results show that the corrosion resistance of PCC coatings after chromium-free sealing treatment is improved, and chromium-free sealing has the potential to replace chromium sealing.

Natural extracts produced with Annona squamosa and Moringa oleifera leaves through the methanol-based solvent were coated on 100% cotton and 80%:20% polyester/cotton blends to improve the functional properties such as antimicrobial activity, wicking, stiffness and crease recovery of the fabric using an eco-friendly 1,2,3,4-butane tetracarboxylic acid (BTCA) crosslinking agent.

In this study, 100% cotton and 80:20% Polyester/Cotton fabrics with surface densities of 113.5 g/m2 and 101 g/m2 were treated BTCA. Eight different samples were produced by padding through the natural extracts. The FTIR investigation was performed on all the fabric samples. These coated fabrics were studied for their antimicrobial activity, wicking, stiffness and crease recovery properties.

It was found that the BTCA cross-linked fabrics showed higher antimicrobial activity against gram-positive and gram-negative bacteria. Similarly, the percentage crease recovery angle was higher for the Annona squamosa coated sample than for Moringa Oleifera leaf extract in both cotton and polyester cotton blend samples. Furthermore, no significant variation in stiffness values was discovered between the control samples of cotton and polyester cotton blend and its treatment one. It was interesting to note that treating the fabrics with cross-linker showed improved vertical wicking properties, which were closer to control fabric values. The study confirms that crosslinking the fabrics with BTCA has improved the functional properties of the fabrics. The zone of inhibition values of BTCA cross-linked moringa methanolic leaves extract coated cotton and polyester cotton blend were 6 to 6.5 cm, which was more than 50% higher than non-BTCA cross-linked fabric, and BTCA cross-linker has improved the vertical wicking properties.

The outcome of this study will help to gain a better understanding of BTCA cross-linkers for improving the functional coating on textile substrates.

This study was conducted to improve the natural extract coating on textile material with eco-friendly aspects, enhancing the commercial utility of these finished fabrics

To improve the corrosion resistance of magnesium alloys, the construction of protective coatings is necessary to extend the service life of Mg-based materials.

SiO₂ nanoparticles modified by dodecyltrimethoxysilane (DTMS) were added to the PP and a superhydrophobic Mg(OH)₂/PP-60mSiO₂ composite coating was fabricated on the surface of AZ31 magnesium alloy via the hydrothermal method and subsequently the immersion treatment.

Hydrophilic SiO₂ nanoparticles become hydrophobic after modified by DTMS, showing a higher dispersibility in xylene. By incorporating modified SiO₂ nanoparticles into the composite PP coating, the hydrophobicity of the layer was enhanced, resulting in a contact angle of 166.3° and a sliding angle of 3.4°. It also improved the water repellency and durability of the coating. Furthermore, the intermediate layer of Mg(OH)₂ significantly strengthened the bond between the PP layer and the substrate. The Mg(OH)₂/PP-60mSiO₂ composite coating significantly enhances the corrosion resistance of the magnesium alloy by effectively blocking the infiltration of the corrosion anions during corrosion. The corrosion current density of the Mg(OH)₂/PP-60mSiO₂ composite coating is approximately 8.23 × 10^–9 A·cm^-2, which can achieve a magnitude three times lower than its substrate, making it a promising surface modification for the Mg alloy.

The composite coating effectively and durably enhances the corrosion resistance of magnesium alloys.

The purpose of this paper is to investigate the effect of plasma electrolytic oxidation (PEO) coatings and sealed PEO coatings on the corrosion resistance and cytocompatibility of a novel Mg-1Zn-0.45Ca alloy in simulated body fluid (SBF).

The microstructure, corrosion resistance and cytocompatibility of PEO coatings and phosphate conversion-treated PEO coatings were investigated and was compared with the bare Mg alloy.

The hot-extruded Mg-Zn-Ca alloy exhibit inhomogeneous microstructure and suffered from localized corrosion in the SBF. The PEO coating after phosphate conversion treatment offers enhanced protectiveness to the Mg alloy within an immersion period of up to 60 days, which is significantly improved compared with the performance of the PEO-coated Mg alloy, but the cytocompatibility was slightly decreased.

This work offers new perspective in balancing the protectiveness and cytocompatibility of bio-materials.

The hybrid nanofluid flow due to a rotating disk has numerous applications, including centrifugal pumps, paper production, polymers dying, air filtration systems, automobile cooling and solar collectors. This study aims to investigate the convective heat transport and magnetohydrodynamics (MHD) hybrid nanofluid flow past a stretchable rotating surface using the Yamada-Ota and Xue models with the impacts of heat generation and thermal radiation.

The carbon nanotubes such as single-wall carbon nanotubes and multi-wall carbon nanotubes are suspended in a base fluid like water to make the hybrid nanofluid. The problem’s governing partial differential equations are transformed into a system of ordinary differential equations using similarity transformations. Then, the numerical solutions are found with a bvp4c function in MATLAB software. The impacts of pertinent parameters on the flow and temperature fields are depicted in tables and graphs.

Two solution branches are discovered in a certain range of unsteadiness parameters. The fluid temperature and the rate of heat transport are enhanced when the thermal radiation and heat generation effects are increased. The Yamada-Ota model has a higher temperature than the Xue model. Furthermore, it is observed that only the first solution remains stable when the stability analysis is implemented.

To the best of the authors’ knowledge, the results stated are original and new with the investigation of MHD hybrid nanofluid flow with convective heat transfer using the extended version of Yamada-Ota and Xue models. Moreover, the novelty of the present study is improved by taking the impacts of heat generation and thermal radiation.