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The purpose of this paper is to study and analyze the effects of fly ash (FA) as a mineral admixture on compressive strength (CS), carbonation resistance and corrosion resistance of reinforced concrete (RC). In addition, the utilization of inexpensive and abundantly available FA as a cement replacement in concrete has several benefits including reduced OPC usage and elimination of the FA disposal problem.

Reinforcement corrosion and carbonation significantly affect the strength and durability of the RC structures. Also, the utilization of FA as green corrosion inhibitors, which are nontoxic and environmentally friendly alternatives. This review discusses the effects of FA on the mechanical characteristics of concrete. Also, this review analyzes the impact of FA as a partial replacement of cement in concrete and its effect on the depth of carbonation in concrete elements and the corrosion rate of embedded steel as well as the chemical composition and microstructure (X-ray diffraction analysis and scanning electron microscopy) of FA concrete were also reviewed.

This review provides a clear analysis of the available study, providing a thorough overview of the current state of knowledge on this topic. Regarding concrete CS, the findings indicate that the incorporation of FA often leads to a loss in early-age strength. However, as the curing period increased, the strength of fly ash concrete (FAC) increased with or even surpassed that of conventional concrete. Analysis of the accelerated carbonation test revealed that incorporating FA into the concrete mix led to a shallower carbonation depth and slower diffusion of carbon dioxide (CO₂) into the concrete. Furthermore, the half-cell potential test shows that the inclusion of FA increases the durability of RC by slowing the rate of steel-reinforcement corrosion.

This systematic review analyzes a wide range of existing studies on the topic, providing a comprehensive overview of the research conducted so far. This review intends to critically assess the enhancements in mechanical and durability attributes (such as CS, carbonation and corrosion resistance) of FAC and FA-RC. This systematic review has practical implications for the construction and engineering industries. This can support engineers and designers in making informed decisions regarding the use of FA in concrete mixtures, considering both its benefits and potential drawbacks.

The silicone modifications of two-component epoxy resin coatings are commonly built on epoxy resins rather than on epoxy curing agents. The silicone-modified epoxy curing agent system is rarely reported yet. This study aims to prepare the polysiloxane (PS)-modified waterborne epoxy coatings based on aqueous curing agents technology.

Waterborne epoxy curing agents with different contents of terminal epoxy PS were synthesized by reacting with triethylenetetramine, followed by incorporating of epoxy resin (NPEL-128) and polyethylene glycol diglycidyl ether. The waterborne epoxy coatings were prepared with the above curing agents, and their performance was investigated through thermogravimetric analysis, scanning electron microscopy, mechanical characterization, gloss measurement, chemical resistance test and ultraviolet (UV) aging experiment.

The results showed that the epoxy coating prepared by silicon-modified curing agent has higher gloss, better chemical resistance and UV resistance than the coating from unmodified curing agent with terminal epoxy PS and commercially available waterborne epoxy curing agent (Aradur 3986), as well as the competitive mechanical properties and heat resistance. Reduced water absorption on fibrous paper was also obtained with the help of silicon-modified curing agent.

These findings will be valuable for resin researchers in addressing the modification issues about waterborne epoxy resin and curing agent.

The aim of this paper is to investigate the potential impact of Industry 4.0 (I4.0) digital technologies on promoting sustainability in small and medium-sized enterprises (SMEs) within developing economies such as Brazil. Additionally, we present a comprehensive framework that consolidates this correlation.

Qualitative research was conducted through semi-structured interviews with leaders of SMEs to identify the specific challenges in achieving sustainability. Additionally, interviews were conducted with technology provider firms to evaluate the existing solutions available to SMEs. The interview results were analyzed, and technological solutions were proposed through a focus group session involving four experts in I4.0. These proposed solutions were then compared with the offerings provided by the technology providers. Based on this, a second round of meetings was conducted to gather feedback from the SMEs.

The findings of this study confirm the feasibility of implementing I4.0 and sustainable practices in SMEs. However, it is crucial to tailor the technologies to the specific circumstances of SMEs. The study presents propositions on how specific applications of technology can address the economic, environmental and social demands of SMEs. Furthermore, a framework is proposed, emphasizing the integration of smart technologies as essential components across sustainability dimensions.

This study makes a significant contribution to the current body of literature as it pioneers the examination of the relationship between I4.0 technologies and sustainability, focusing specifically on SMEs in a developing country context.

El objetivo de este estudio es investigar el potential impacto de las tecnologías digitales de la Industria 4.0 en la promoción de la sostenibilidad en las pequeñas y medianas empresas (PYMES) en economías en desarrollo, como Brasil.

Realizamos una investigación cualitativa mediante entrevistas semiestructuradas a líderes de PYMES para identificar los desafíos que enfrentan en la búsqueda de la sostenibilidad. También llevamos a cabo entrevistas con empresas proveedoras de tecnología para evaluar las soluciones existentes. Los resultados de las entrevistas se analizaron y se propusieron soluciones tecnológicas a través de una sesión de grupo focal con cuatro expertos en la Industria 4.0. Estas soluciones se compararon con las ofertas proporcionadas por los proveedores de tecnología. Posteriormente, se realizaron una segunda reunión para recopilar comentarios de las PYMES.

Los hallazgos de este estudio confirman la viabilidad de implementar la Industria 4.0 y prácticas sostenibles en las PYMES. Sin embargo, es crucial adaptar las tecnologías a las circunstancias de las PYMES. Presentamos propuestas sobre cómo las aplicaciones de la tecnología pueden abordar las demandas económicas, ambientales y sociales de las PYMES. Además, proponemos un marco que destaca la integración de tecnologías como componentes esenciales de la sostenibilidad.

Este estudio es pionero en examinar la relación entre las tecnologías de la Industria 4.0 y la sostenibilidad, centrándose específicamente en las PYMES en un contexto de país en desarrollo.

Multinational business deliver value via multiple sites with similar operational capacities. The age of the Fourth Industrial Revolution (4IR) delivers significant opportunities for the deployment of digital tools for business optimization. Therefore, this study aims to study the Industry 4.0 implementation for multinationals.

The key objective of this research is multi-site systems integration using a reproducible, modular and standardized “Cyber Physical System (CPS) as-a-Service”.

A best practice reference architecture is adopted to guide the design and delivery of a pioneering CPS multi-site deployment. The CPS deployed is a cloud-based platform adopted to enable all manufacturing areas within a multinational energy and petrochemical company. A methodology is developed to quantify the system environmental and sustainability benefits focusing on reduced carbon dioxide (CO₂) emissions and energy consumption. These results demonstrate the benefits of standardization, replication and digital enablement for multinational businesses.

The research illustrates the ability to design a single system, reproducible for multiple sites. This research also illustrates the beneficial impact of system reuse due to reduced environmental impact from lower CO₂ emissions and energy consumption. The paper assists organizations in deploying complex systems while addressing multinational systems implementation constraints and standardization.

This paper aims to conduct a detailed analysis of the industrial practices currently being used in the geothermal energy industry and to determine whether they are contributing to any limitations. A HAZOP-based upgradation model for improvement in existing industrial practices is proposed to ensure the removal of inefficient conventional practices. The HAZOP-based upgradation model examines the setbacks, identifies its causes and consequences and suggests improvement methods comprising of modern-day technology.

This paper proposed a HAZOP-based upgradation model for improvement in existing industrial practices. The proposed HAZOP model identifies the drawbacks brought on by conventional practices and suggests improvements.

The study reviewed the challenges geothermal power plants currently face due to conventional practices and suggested a total of 22 upgradation recommendations. From those, a total of 11 upgradation modules comprising modern digital technology and Industry 4.0 elements were proposed to improve the existing practices in the geothermal energy industry. Autonomous robots, augmented reality, machine learning and Internet of Things were identified as useful methods for the upgradation of the existing geothermal energy system.

If proposed recommendations are incorporated, the efficiency of geothermal energy generation will increase as cumulating setbacks will no longer degrade the work output.

The proposed recommendation by the study will make way for Industry 4.0 integration with the geothermal energy sector.

The paper uses a proposed HAZOP-based upgradation model to review issues in existing industrial practices of the geothermal energy sector and recommends solutions to overcome operability issues using Industry 4.0 technologies.

This paper aims to critically review the isolation and chemistry of plant pigments.

A literature survey from 1974 to 2022 was carried out and studied thoroughly. The authors reviewed literature in various areas such as isolation methods and catalytic properties of pigments.

With vast growing research in the field of catalytic activities of various pigments like chlorophyll, anthocyanin and flavonoids, there is still scope for further research for the pigments such as Lycopene, carotenoids and xanthophyll as there has not been any significant work in this area.

Plant pigments may be used as an ecofriendly catalyst for chemical reactions.

One can get the direction of pigment research.

Plant pigments are natural and ecofriendly catalyst which can reduce the pollution.

This is an original work. This paper precisely depicts the advantages as well as disadvantages of the isolation techniques of pigments. This study also presents the chemistry of plant pigments.

The aim of this paper is to determine the thermal conductivity of a protective layer of alkali-activated cement and the possibility of performing fire protection with fireclay sand and Lightweight mortar. Unprotected steel structures have generally low fire resistance and require surface protection. The design of passive protection of a steel element must consider the service life of the structure and the possible need to replace the fire protection layer. Currently, conventional passive protection options include intumescent coatings, which are subject to frequent inspection and renewal, gypsum and cement-based fire coatings and gypsum and cement board fire protection.

Alkali-activated cements provide an alternative to traditional Portland clinker-based materials for specific areas. This paper presents the properties of hybrid cement, its manufacturability for conventional mortars and the development of passive fire protection. Fire experiments were conducted with mortar with alkali-activated and fireclay sand and lightweight mortar with alkali-activated cement and expanded perlite. Fire experiment FE modelling.

The temperatures of the protected steel and the formation of cracks in the protective layer were investigated. Based on the experiments, the thermal conductivities of the two protective layers were determined. Conclusions are presented on the applicability of alkaline-activated cement mortars and the possibilities of applicability for the protection of steel structures. The functionality of the passive fire layer was confirmed and the strengths of the mortar used were determined. The use of alkali-activated cements was shown to be a suitable option for sustainable passive fire protection of steel structures.

Eco-friendly fire protection based on hybrid alkali-activated cement of steel members.

This paper aims to identify modern construction techniques for affordable housing, such as prefabrication and interlocking systems, that can save time and cost while also providing long-term sustainable benefits that are desperately needed in today's construction industry.

The need for housing is growing worldwide, but traditional construction cannot cater to the demand due to insufficient time. There should be some paradigm shift in the construction industry to supply housing to society. This paper presented a state-of-the-art review of modern construction techniques practiced worldwide and their advantages in affordable housing construction by conducting a systematic literature review and applying the backward snowball technique. The paper reviews modern prefabrication techniques and interlocking systems such as modular construction, formwork systems, light gauge steel/cold form steel construction and sandwich panel construction, which have been globally well practiced. It was understood from the overview that modular construction, including modular steel construction and precast concrete construction, could reduce time and costs efficiently. Further enhancement in the quality was also noticed. Besides, it was observed that light gauge steel construction is a modern phase of steel that eases construction execution efficiently. Modern formwork systems such as Mivan (Aluminium Formwork) have been reported for their minimum construction time, which leads to faster construction than traditional formwork. However, the cost is subjected to the repetitions of the formwork. An interlocking system is an innovative approach to construction that uses bricks made of sustainable materials such as earth that conserve time and cost.

The study finds that the prefabrication techniques and interlocking system have a lot of unique attributes that can enable the modern construction sector to flourish. The study summarizes modern construction techniques that can save time and cost, enhancing the sustainability of construction practices, which is the need of the Indian construction industry in particular.

This study is limited to identifying specific modern construction techniques for time and cost savings, lean concepts and sustainability which are being practiced worldwide.

Modern formwork systems such as Mivan (Aluminium Formwork) have been reported for their minimum construction time which leads to faster construction than traditional formwork.

The need for housing is growing rapidly all over the world, but traditional construction cannot cater to the need due to insufficient time. There should be some paradigm shift in the construction industry to supply housing to society.

This study is unique in identifying specific modern construction techniques for time and cost savings, lean concepts and sustainability which are being practiced worldwide.