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The aim of this work is to investigate the decomposition behaviour of the activator species commonly used in the wave solder no-clean flux systems and to estimate the residue amount left after subjecting the samples to simulated wave soldering conditions.

Changes in the chemical structure of the activators were studied using Fourier transform infrared spectroscopy technique and were correlated to the exposure temperatures within the range of wave soldering process. The amount of residue left on the surface was estimated using standardized acid-base titration method as a function of temperature, time of exposure and the substrate material used.

The study shows that there is a possibility of anhydride-like species formation during the thermal treatment of fluxes containing weak organic acids (WOAs) as activators (succinic and DL-malic). The decomposition patterns of solder flux activators depend on their chemical nature, time of heat exposure and substrate materials. Evaporation of the residue from the surface of different materials (laminate with solder mask, copper surface or glass surface) was found to be more pronounced for succinic-based solutions at highest test temperatures than for adipic acid. Less left residue was found on the laminate surface with solder mask (∼5-20 per cent of initial amount at 350°C) and poorest acid evaporation was noted for glass substrates (∼15-90 per cent).

The findings are attributed to the chemistry of WOAs typically used as solder flux activators. The results show the importance WOA type in relation to its melting/boiling points and the impact on the residual amount of contamination left after soldering process.

The results show that the evaporation of the flux residues takes place only at significantly high temperatures and longer exposure times are needed compared to the temperature range used for the wave soldering process. The extended time of thermal treatment and careful choice of fluxing technology would ensure obtaining more climatically reliable product.

Self-healing concrete is a revolutionary building material that will generally reduce the maintenance cost of concrete constructions. Self-healing of cracks in concrete structure would contribute to a longer service life of the concrete and would make the material more durable and more sustainable. The cementitious mortar with/without incorporating encapsulates at different percentages of slag replacement with the cement mix improves autogenous healing at different ages. Therefore, this study’s aim is to develop a self-healing cementitious matrix for repair and retrofitting of concrete structures.

In the present work, waste straw pipes are used as a capsule, filled with the solution of sodium hydroxide (NaOH), sodium silicate (Na₂SiO₃) and colloidal nano-silica as self-healing activators. An artificial micro-crack on the control and blended mortar specimens at different percentages of slag replacement with cement (with/without encapsulation) is developed by applying a compressive load of 50% of its ultimate load-carrying capacity. The mechanical strength and ultrasonic pulse velocity, water absorption and chloride ion penetration test are conducted on the concrete specimen before and after the healing period. Finally, the self-healing activity of mortar mixes with/without encapsulation is analysed at different ages.

The encapsulated mortar mix with 10% of slag content has better self-healing potential than all other mixes considering mechanical strength and durability. The enhancement of the self-healing potential of such mortar mix is mainly due to hydration of anhydrous slag on the crack surface and transformation of amorphous slag to the crystalline phase in presence of encapsulated fluid.

The self-healing activities of the slag-based cementitious composite are studied for a healing period of 90 days only. The strength and durability performance of the cracked specimen may be increased after a long healing period.

The outcome of the work will help repair the cracks in the concrete structure and enhances the service life.

This study identifies the addition encapsulates with a self-healing activator fluid that can recover its strength after minor damage.

The coal-based synthetic natural gas slag (CSNGS) is a solid waste remaining from the incomplete combustion of raw coal to produce gas. With the continuous promotion of efficient and clean utilization of coal in recent years, the stockpiling of CSNGS would increase gradually, and it would have significant social and environmental benefits with reasonable utilization of CSNGS. This study prepared a new geopolymer by mixing CSNGS with PC42.5 cement in a certain mass ratio as the precursor, with sodium hydroxide and sodium silicate solution as the alkali activators.

The formulation of coal-based synthetic natural gas slag geopolymer (CSNGSG) was determined by an orthogonal test, and then the strength mechanism and microstructure of CSNGSG were characterized by multi-scale tests.

The results show that the optimum ratio of CSNGSG was a sodium silicate modulus of 1.3, an alkali dosage of 21% and a water cement ratio of 0.36 and the maximum unconfined compressive strength of CSNGSG at 7 d was 26.88 MPa. The increase of curing temperature could significantly improve the compressive strength of CSNGSG, and the curing humidity had little effect on the compressive strength of CSNGSG. The development of the internal strength of CSNSG at high temperatures consumed SiO₂, Al₂O₃ and CaO and the intensity of corresponding crystalline peaks decreased.

Moreover, the vibration of chemical bonds in different wavenumbers also revealed the reaction mechanism of CSNSG from another perspective. Finally, the relevant test results indicated that CSNGS had practical application value as a raw material for the preparation of geopolymer cementing materials.

This paper aims to investigate the effect of delayed water curing on the mechanical and microstructural properties of fly ash-based geopolymer paste-blended with Ground Granulated Blast Furnace Slag (GGBS) with different rest periods.

The blended geopolymer paste was composed of GGBS (15 per cent of the total weight) and the base material, Fly Ash (FA). The blended mix was activated by activator solution (Sodium hydroxide and Sodium silicate) containing 6 per cent Na₂O of total base material. The effect of delayed water curing has been studied by gradually increasing the aging period (Rest Period) from 2 hours to 24 hours in the formation of activated outcome along with Calcium Silicate Hydrate (CSH). To analyze the mechanical and microstructural properties of the resultant blended geopolymer paste, compressive strength test, FESEM and XRD have been carried out. Moreover, a long-term durability test subjected to sulphate exposure has been performed to evaluate the durability of the designed sustainable geopolymer paste.

The present paper shows that the delayed water curing incorporates secondary heat input enhancing the partial polymer formation along with CSH. Slag-blended AAFA-based geopolymer paste is seen to exhibit quick setting property. Also, AAFA-based geopolymer paste samples subjected to longer rest period show early strength gain at a high rate under water curing as compared to those subjected to the shorter rest period.

To the best of authors’ knowledge, the effect of delayed water curing on the mechanical and microstructural properties of slag-blended AAFA-based geopolymer paste has not been studied before.

The purpose of this study is to investigate the effect of various heat conditions on the durability of eggshell powder (ESP)–flyash (FA) geopolymer subjected to wetting–drying cycles.

In this study, two waste materials, ESP and FA, which are destined for landfills, were used as precursors to produce geopolymers in a sustainable manner. The mixture of Na₂SiO₃ and NaOH was used as a liquid alkaline activator in geopolymerization. The ESP and FA content were varied as 30, 50 and 70% and Na₂SiO₃/NaOH ratios were varied as 0.5, 1 and 2. Geopolymer samples were cured at three heat conditions: 25°C (ambient temperature), 50°C and 80°C for seven days prior to durability tests.

The results of this study revealed that the strength loss of the geopolymer decreases with an increase in curing temperature up to 50°C and then increases for higher temperature up to 80°C. Further, the strength loss of the geopolymer decreases with an increase in FA replacement and Na₂SiO₃/NaOH ratio. Geopolymer composites exhibited early strength development because of the inclusion of calcium-rich ESP. The weight loss of the ESP–FA geopolymer follows a similar pattern of strength loss. Geopolymer samples previously cured at optimum heat condition of 50°C for seven days exhibited higher durability.

The inclusion of calcium-rich ESP in FA-based geopolymer is novel research. As ESP–FA geopolymer composites show higher mechanical strength and higher durability compared to Indian standards, the potential use of this geopolymer can be in road subbases/subgrades.

Particles bed binding by selective cement activation (SCA) method is a computer-aided manufacturing (CAM) technique used to produce cementitious elements. A computer-aided design file is sliced to generate G-codes before printing. This paper aims to study the effect of key input parameters for slicer software on the final properties of printed products.

The one factor at a time (OFAT) methodology is used to investigate the impact of selected parameters on the final properties of printed specimens, and the causes for the variations in outcomes of each variable are discussed.

Finer aggregates can generate a more compact layer, resulting in a denser product with higher strength. Fluid pressure is directly determined by voxel rate (r_V); however, high pressures enable better fluid penetration control for fortified products; for extreme r_Vs, residual voids in the interfaces between successive layers and single-line primitives impair mechanical strength. It was understood that printhead movement along the orientation of the parts in the powder bed improved the mechanical properties.

The design of experiment (DOE) method assesses the influence of process parameters on various input printing variables at the same time. As the resources are limited, a fractional factorial plan is carried out on a subset of a full factorial design; hence, providing physical interpretation behind changes in each factor is difficult. OFAT aids in analyzing the effect of a change in one factor on output while all other parameters are kept constant. The results assist engineers in properly considering the influence of variable variations for future DOE designs.

This paper outlines the current position of water based no‐clean liquid fluxes for wave soldering. The primary differences between these and “traditional” alcohol based liquid fluxes are explored using wetting balance methods. Reduced wetting capability (of the flux onto the PCB) can be addressed by using various surfactant additives; improved solderability is due to enhanced acid activator dissociation resulting from increased solvent polarity. Regarding implementation in a production environment, there is only minor impact. A slightly increased preheat capability is required, and foam application demands tight control of the feed gas flow rate. More generally, in addition to the “headline” environmental benefit of reduced VOC emissions, water based liquid fluxes confer significant handling advantages, for example zero flammability and low odour/evaporation at room temperature. Against this background, it is suggested that water based liquid fluxes will become ever more popular.

Permanganate desmear technology has been widely accepted in the US as a quality and cost improvement over the traditional desmear methods. Based on two years intensive research and development efforts the paper describes a technological breakthrough resulting in a new application of permanganate technology: genuine etchback without the use of chrome, sulphuric or plasma.

Concrete is a building material widely used for the infrastructural development. Cement is the binding material used for the development of concrete. It is the primary cause of CO₂ emission globally. The purpose of this study is to develop sustainable concrete material to satisfy the present need of construction sector. Geopolymer concrete (GPC) is a sustainable concrete developed without the use of cement. Therefore, investigations are being conducted to replace the cement by 100% with high calcium fly ash (FA) as binding material.

High calcium FA is used as cementitious binder, sodium hydroxide (NaOH) and sodium silicates (Na₂SiO₃) are used as alkaline liquids for developing the GPC. Mix proportions with different NaOH molarities of 4, 6, 8 and 10 M are considered to attain the appropriate mix. The method of curing adopted is ambient and oven curing. Workability, compressive strength and microstructure characteristics of GPC are analysed and presented.

An increase of NaOH in the mix decreases the workability. Compressive strength of 29 MPa is obtained for Mix-I with 8 M under ambient curing. A polynomial relationship is obtained to predict the compressive strength of GPC. Scanning electron microscope analysis is used to confirm the geo-polymerisation process in the microstructure of concrete.

This research work focuses on finding some alternative cementitious material for concrete that can replace ordinary portland cement (OPC) to overcome the CO₂ emission owing to the utilisation of cement in the construction industry. An attempt has been made to use the waste material (high calcium FA) from thermal power plant for the production of GPC. GPC concrete is the novel building material and alternative to conventional concrete. It is the ecofriendly product contributing towards the improvement of the circular economy in the construction industry. There are several factors that affect the property of GPC such as type of binder material, molarity of activator solution and curing condition. The novelty of this work lies in the approach of using locally available high calcium FA along with manufactured sand for the development of GPC. As this approach is rarely investigated, to prove the attainment of compressive strength of GPC with high calcium FA, an attempt has been made during the present investigation. Other influencing parameter which affects the strength gain has also been analysed in this paper.

In the preceding three parts of this series, the authors have extensively reviewed and quantified the special processing sequences required for the ‘additive’ and ‘semi‐additive’ process strategies of PWB manufacture. In this, the fourth part of the series of five, they wish to present a series of full build processes which meet all the interconnect requirements of the 1990s while eliminating the drawbacks traditionally associated with additive processes.