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The conflicting results on the corrosion characteristics of aluminium matrix composites reinforced with agrarian waste have stimulated an investigation on the hardness and corrosion rate of sugar palm fibre ash (SPFA) reinforced LM26 Al/alloy composite by varying the SPFA from 0 to 10 wt% in an interval of 2 wt%. This paper aims to discuss the aforementioned issue.

The composites were produced via stir-casting and the hardness was determined using a Vickers hardness testing machine, corrosion rate was examined through the weight loss method by immersion in 0.5, 1.0 and 1.5 M hydrochloric acid (HCl) at temperatures of 303, 318, and 333 K for the maximum duration of 120 h. The morphological study was conducted using a scanning electron microscope (SEM) on the samples before and after immersion in HCl.

The incorporation of SPFA improved the hardness of the alloy from 58.22 to 93.62 VH after 10 wt% addition. The corrosion rate increases with increased content of SPFA, the concentration of HCl and temperature. The least corrosion rate of 0.0272 mpy was observed for the LM26 Al alloy in 0.5 M after 24 h while the highest corrosion rate of 0.8511 mpy was recorded for LM26 Al/10 wt% SPFA in 1.5 M HCl acid after 120 h. The SEM image of corroded samples revealed an increased number of pits with increased SPFA content.

The work is limited to SPFA up to 10 wt% as reinforcement in LM26 Al alloy, the use of HCl as corrosion medium, temperatures in the range of 303–333 K, and a weight loss method were used to evaluate the corrosion rate.

The corrosion rate was determined for LM26 Al/SPFA composites with various amounts of SPFA in 0.5, 1.0 and 1.5 M HCl at 303, 318 and 333 K and compared with the matrix alloy.

One of the sources for the increase in the carbon footprint on the earth is the manufacturing of cement, which causes a severer environmental impact. Abundant research is going on to diminish CO₂ content in the atmosphere by appropriate utilization of waste by-products of industries. Alkali-activated slag concrete (AASC) is an innovative green new concrete made by complete replacement of cement various supplementary cementitious raw materials. Concrete is a versatile material used in different fields of structures, so it is very important to study the durability in different exposures along with the strength. The purpose of this paper is to study the performance of AASC by incorporating quartz sand as fine aggregate under different exposure conditions.

The materials for this innovative AASC are selected based on preliminary studies and literature surveys. Based on numerous trials a better performance mix proportion of AASC with quartz sand is developed with 1:2:4 mix proportion, 0.8 alkali Binder ratio, 19 M of NaOH and 50% concentration of Na₂SiO₃. Subsequently, AASC cubes are prepared and exposed for 3, 7, 14, 28, 56, 90, 112, 180, 252 and 365 days in ambient, acid, alkaline, sulfate, chloride and seawater and tested for compressive strength. In addition, to study the microstructural characteristics, scanning electron microscope (SEM), energy dispersive X-ray analysis and X-ray diffraction analysis was also performed.

Long-term performance of AASC developed with quartz sand is very good in the ambient, alkaline environment of 5% NaOH and seawater with the highest compressive strength values of 51.8, 50.83 and 64.46, respectively. A decrease in compressive strengths was observed after the age of 14, 56 and 112 days for acid, chloride and sulfate exposure conditions, respectively. SEM image shows a denser microstructure of AASC matrix for ambient, alkaline of 5% NaOH and seawater.

The proposed AASC is prepared with a mix proportion of 1:2:4, so the other proportions of AASC need to verify. In general plain, AASC is not used in practice except in few applications, in this work the effect of reinforced AASC is not checked. The real environmental exposure in fields may not create for AASC, as it was tested in different exposure conditions in the laboratory.

The developed AASC is recommended in practical applications where early strength is required, where the climate is hot, where water is scarce for curing, offshore and onshore constructions exposed to the marine environment and alkaline environment industries like breweries, distilleries and sewage treatment plants. As AASC is recommended for ambient air and in other exposures, its implementation as a construction material will reduce the carbon footprint.

The developed AASC mix proportion 1:2:4 is an economical mix, because of low binder content, but it exhibits a higher early age compressive strength value of 45.6 MPa at the age of 3 days. The compressive strength increases linearly with age from 3 to 365 days when exposed to seawater and ambient air. The performance of AASC is very good in the ambient, alkaline environment and seawater compared to other exposure conditions.

The main purpose of the present work is to introduce two new Schiff bases as corrosion inhibitors (CIs) for carbon steel (CS). The anti-corrosion performance of these Schiff bases having N and S heteroatoms in their structures was investigated and compared in 2 M HCl electrolyte. The inhibitory activity of these Schiff bases was also assessed.

Common electrochemical assays like potentiodynamic polarization and electrochemical impedance measurements were used to evaluate the ability of compounds in reduction of the rate of corrosion. Quantum chemical calculations (QCCs) were also used to examine the corrosion inhibitive and the process related to the electrical and structural characteristics of the molecules acting as CIs.

The electrochemical measurements indicate that both Schiff bases acted as the efficient CIs of CS in 2 M HCl electrolyte. The adsorption of the Schiff base on the surface of the CS caused the corrosion to be inhibited. The change of Gibbs energies indicated that both physical and chemical interactions are involved in the adsorption of NNS and SNS on CS surfaces. The predicted QCCs of the CIs neutral and positively charged versions were well-aligned with those obtained by electrochemical experiments.

Using electrochemical experiments and quantum chemical modelings, two new Schiff bases, N-2-((2-nitrophenyl)thio)phenyl)-1-(pyrrole-2-yl)methanimine (NNS) and N-2-((2-nitrophenyl)thio)phenyl)-1-(thiophen-2-yl)methanimine (SNS), were evaluated as anti-corrosion agents for CS in 2 M HCl electrolyte. The DFT calculations were considered to compute the quantum chemical parameters of the inhibitors.

This study aimed to review various existing methods for improving the quality of recycled concrete aggregates (RCAs) as a possible substitution for natural aggregates (NAs) in concrete. It is vital as the old paste attached to the RCA weakens its structure. It is due to the porous structure of the RCA with cracks, weakening the interfacial transition zone (ITZ) between the RCA and binding material, negatively impacting the concrete's properties. To this end, various methods for reinforcement of the RCA, cleaning the RCA's old paste and enhancing the quality of the RCA-based concrete without RCA modification are studied in terms of environmental effects, cost and technical matters. Furthermore, this research sought to identify gaps in knowledge and future research directions.

The review of the relevant journal papers revealed that various methods exist for improving the properties of RCAs and RCA-based concrete. A decision matrix was developed and implemented for ranking these techniques based on environmental, economic and technical criteria.

The identified methods for reinforcement of the RCA include accelerated carbonation, bio deposition, soaking in polymer emulsions, soaking in waterproofing admixture, soaking in sodium silicate, soaking in nanoparticles and coating with geopolymer slurry. Moreover, cleaning the RCA's old paste is possible using acid, water, heating, thermal and mechanical treatment, thermo-mechanical and electro-dynamic treatment. Added to these treatment techniques, using RCA in saturated surface dry (SSD) mixing approaches and adding fibres or pozzolana enhance the quality of the RCA-based concrete without RCA modification. The study ranked these techniques based on environmental, economic and technical criteria. Ultimately, adding fibres, pozzolana and coating RCA with geopolymer slurry were introduced as the best techniques based on the nominated criteria.

The study supported the need for better knowledge regarding the existing treatment techniques for RCA improvement. The outcomes of this research offer an understanding of each RCA enrichment technique's importance in environmental, economic and technical criteria.

The practicality of the RCA treatment techniques is based on economic, environmental and technical specifications for rating the existing treatment techniques.

This research aims to study the materials that compose older reinforced concrete bridges which are damaged and degrading to explain the mechanisms and origins of various disorders. Therefore, this work will contribute to providing answers on the capacity of nondestructive evaluation method during the diagnosis. In addition to the characterization of affected structures, it will aim to provide effective solutions for different serious pathologies.

In this context, two bridges located on NH16 and NH21, respectively, were studied in Annaba city (north-east Algeria), specifically in El-Hadjar municipality located in the central industrial zone of Pont-Bouchet. This study makes it possible to make conclusions from the in-depth diagnosis based on disorders exposition causes and mechanical characteristics evolution by non-destructive testing (NDT) tools. Furthermore, solutions are proposed, including conservation maintenance of these degraded structures.

All degradations can be the result of several factors: either human (poor design) or chemical (surface water, wastewater and groundwater quality (acidic or basic)). In addition to other natural causes (geological formations, flood phenomena or climate), NDT tools play a major role in the evaluating mechanical performance of degraded structures (resistance and hardness).

The NDT techniques can be transmitted to civil engineering experts because their training is limited regarding mechanical and structural construction.

NDT tools are the most suitable for in-situ assessing, and the concrete constructions health state, so far from financial problems.

Degraded bridge diagnosis by NDT testing is necessary for a thorough safety evaluation (mechanical performance, strength and deformability), to protect human lives and design durability.

This is an original paper which contains new information at different scales and from special fields, based on an evaluation using NDT tools on real degraded structures. It can be used to improve the knowledge of materials employed in a bridge without performing expensive direct tests or the need for destroying it.

With increased populations and movement of people worldwide, traffic emissions will lead to an increase in carbon dioxide emissions, which is one of the greenhouse gases. This will increase outdoor air pollution and other environmental risks that will impact people's health and livelihood, crops, as well as the built environment such as architecture, buildings and other structures. Few studies have been devoted to addressing the effect of air pollution on historic buildings. However, there is no specific study on the impact of traffic-related emissions.

A thorough analysis has been conducted in selecting eight historic districts (HDs) among all of 31 located within the city of San Antonio. Motor Vehicle Emission Simulator (MOVES) software has been utilized to process the data collected from the average annual daily traffic (AADT) and vehicle operational speeds and evaluate the amounts of emissions for each HD.

MOVES outcomes showed that HDs are under the threat of deterioration caused by traffic emissions. Therefore, transportation and environmental planners need to implement sustainable solutions to reduce the impact of CO₂ emissions on HDs and, ultimately, historic buildings.

This study will help policymakers plan a better course of action for the future conditions associated with the increased traffic volumes. It is also beneficial for the developers, preservationists, architects and all other stakeholders willing to preserve the history of a country.

This paper aims to investigate the corrosion inhibition ability of 4–(4-nitrophenyl) thiazol-2-amine (NPT) on the copper in 1 M HCl.

The corrosion inhibitory ability of NPT on the copper in 1 M HCl was studied by electrochemical impedance spectroscopy, scanning electron microscopy and atomic force microscopy. Theoretical calculations (molecular dynamics simulation, density functional theory and the nucleus independent chemical shift [NICS] as aromaticity indicator of the molecule) were also performed.

The corrosion inhibition efficacy of this compound was about 80%. Nyquist plots display a small arc contributed to the film or oxide layer resistance and a large loop associated with charge transfer resistance. The inhibitor adsorption was under Langmuir’s adsorption model. ΔG⁰_ads values point to the presence of physical and chemical adsorption. Results of quantum chemical calculations showed that NPT has better interaction with copper than NPTH⁺. NICS of NPT in benzene or thiazole rings was less negative compared to NICS of NPTH⁺. Thus NPT shows less aromaticity compared with NPTH⁺, showing NPT can have better interaction with copper than NPTH⁺. NPT had more negative E_int value and more interactions with the Cu relative to NPTH⁺, this result was in agreement with the results of quantum chemical calculations.

NPT is an efficient corrosion inhibitor for copper in HCl. Theoretical calculations showed that NPT can have better interaction with copper than NPTH⁺. The results of the theoretical studies were in good agreement with the experimental studies.

In the last 10 years, India has amended its laws dealing with sexual offences against women with the changes ranging from increasing terms of imprisonment for the offence of rape to state-funded compensation schemes for women and child victims. In this regard, challenges persist for the agencies of the criminal justice system in India especially the courts to realise the vision of restorative justice as these forums have to navigate the relevant statutory provisions and binding precedents. This chapter seeks to analyse the challenges faced by courts in proper reintegration of victims and offenders of sexual offences, the institutional responses of the courts and suggests reforms to the criminal justice system in India in consonance with the principles of restorative justice acknowledged in the restorative justice movement in the international discourse.

This paper presents the outcomes of the international project “Protecting Landscape Heritage: a requalification project as an instrument for the re-birth of Quang Tri Old Citadel in Vietnam”, achieved with scientific cooperation between the Università Politecnica delle Marche (Italy) and Hue University of Sciences (Vietnam) funded by the Italian Ministry of Foreign Affairs and International Cooperation and Ministry of Science and Technology of Vietnam. The research focuses on the Quang Tri Citadel, founded in 1809 and now in an advanced state of degradation.

For the purpose of rehabilitation, the wide multidisciplinary project first examined the historical context of the military model, the architectural aspects of the structure, the characterization of the existing materials, the degradation levels of different parts, and, finally, a proposal of the suggested interventions.

The original structure and geometry were extrapolated and studied. Building materials were produced with nearby raw materials. Firing temperatures of bricks ranged from 800 to 1,000 °C, hydraulic lime was supposed the binder of the mortar with a calcination temperature lower than 1,000 °C. Damage assessment was provided and after these analyses a requalification project was proposed so the cultural heritage can play a role for the future in the dialog between different cultures.

The requalification project achieved by an integrated analytical approach defines aspects in relation to the restoration of the structures, enabling compliance with the geometry, techniques, building materials used in the original construction and allowing its guardianship and management to align with the historical context of the architectural heritage.

The COVID-19 outbreak has significant psychological effects because of reduced support system and social quarantine, making women the worst-hit population of shadow pandemic, i.e. domestic violence. While food shortages, unemployment and increased domestic-work burdens are the immediate effects of the lockdown, women at home have to bear its far-reaching impacts in the long term in the form of domestic abuse, making the study of the psychological impact of domestic violence against women imperative. This paper aims to identify the factors and causes responsible for domestic violence and its psychological impacts on women in different aspects. This paper further focuses on the reasons behind an escalation in psychological violence against women.

This paper is based on extrapolating data from various journal articles, Indian Government reports, newspaper articles and other printed materials that are recent, relevant and discuss domestic violence and mental stress during the COVID-19 pandemic. Researchers use Indian National Commission for Women’s (NCW) data on complaints received regarding violence against women and domestic abuse in the year 2020 and 15 journal articles that discuss domestic violence against women during the COVID-19 period in different countries to discuss social inequalities and power relations impact on women’ mental health.

The findings suggest that economic instability during the pandemic and social and cultural norms of India ignited psychological abuse against women during the pandemic. The number of monthly complaints of dowry death, dowry harassment and protection of women against domestic violence reflect on increased registered complaints in the postlockdown period in the year 2020. The number of monthly complaints received by the NCW from January 2020 to December 2020 in India represents that WhatsApp chat is a powerful tool for reporting domestic violence.

The pandemic lockdown has an adverse psychological impact on women, making them suffer from posttraumatic symptoms, substance abuse, panic attacks, depressions, hallucinations, eating disorders, self-harm, etc. This paper strives to reflect upon mitigation strategies to curb domestic violence in India.