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1 – 10 of 68Bassem Assfour, Bassam Abdallah, Hour Krajian, Mahmoud Kakhia, Karam Masloub and Walaa Zetoune
The purpose of this study is to investigate the structural, surface roughness and corrosion properties of the zirconium oxide thin films deposited onto SS304 substrates using the…
Abstract
Purpose
The purpose of this study is to investigate the structural, surface roughness and corrosion properties of the zirconium oxide thin films deposited onto SS304 substrates using the direct current (DC) magnetron sputtering technique.
Design/methodology/approach
DC sputtering at different powers – 80, 100 and 120 W – was used to deposit ZrO2 thin films onto different substrates (Si/SS304) without annealing of the substrate. Atomic force microscope (AFM), energy-dispersive X-ray spectroscopy (EDS), Tafel extrapolation and contact angle techniques were applied to investigate the surface roughness, chemical compositions, corrosion behavior and hydrophobicity of these films.
Findings
Results showed that the thickness of the deposited film increased with power increase, while the corrosion current decreased with power increase. AFM images indicated that the surface roughness decreased with an increase in DC power. EDS analysis showed that the thin film has a stoichiometric ZrO2 (Zr:O 1:2) composition with basic uniformity. Water contact angle measurements indicated that the hydrophobicity of the synthesized films decreased with an increase in surface roughness.
Originality/value
DC magnetron sputtering technique is infrequently used to deposition thin films. The obtained thin films showed good hydrophobic and anticorrosion properties. Finally, results are compared with other deposition techniques.
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Qiang Sun, Quantong Jiang, Siwei Wu, Chang Liu, Heng Tang, L. Song, Hao Shi, Jizhou Duan and BaoRong Hou
The purpose of this paper is to explore the effect of ZnO on the structure and properties of micro-arc oxidation (MAO) coating on rare earth magnesium alloy under large…
Abstract
Purpose
The purpose of this paper is to explore the effect of ZnO on the structure and properties of micro-arc oxidation (MAO) coating on rare earth magnesium alloy under large concentration gradient.
Design/methodology/approach
The macroscopic and microscopic morphology, thickness, surface roughness, chemical composition and structure of the coating were characterized by different characterization methods. The corrosion resistance of the film was studied by electrochemical and scanning Kelvin probe force microscopy. The results show that the addition of ZnO can significantly improve the compactness and corrosion resistance of the MAO coating, but the high concentration of ZnO will cause microcracks, which will reduce the corrosion resistance to a certain extent.
Findings
When the concentration of zinc oxide is 8 g/L, the compactness and corrosion resistance of the coating are the best, and the thickness of the coating is positively correlated with the concentration of ZnO.
Research limitations/implications
Too high concentration of ZnO reduces the performance of MAO coating.
Practical implications
The MAO coating prepared by adding ZnO has good corrosion resistance. Combined with organic coatings, it can be applied in corrosive marine environments, such as ship parts and hulls. To a certain extent, it can reduce the economic loss caused by corrosion.
Originality/value
The effect of ZnO on the corrosion resistance of MAO coating in electrolyte solution was studied systematically, and the conclusion was new to the common knowledge.
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Ayad Alameeri, Gholamreza Abdollahzadeh and Seyedkomeil Hashemiheidari
This study aims to determine the effect of replacing a portion of the cement in the concrete mixture with silica fume (SF) on the corrosion resistance of reinforcing bars, the…
Abstract
Purpose
This study aims to determine the effect of replacing a portion of the cement in the concrete mixture with silica fume (SF) on the corrosion resistance of reinforcing bars, the compressive strength of concrete and the tensile strength of hook bars in both corroded and non-corroded external joints of structures. The external beam-column connection was studied because of its critical role in maintaining structural continuity in all three directions and providing resistance to rotation.
Design/methodology/approach
In external concrete joints, the bars at the end of the beams are often bent at 90° to form hooks that embed in columns. Owing to the importance of embedding distance and the need to understand its susceptibility to corrosion damage from chloride attack, a series of experiments were conducted on 12 specimens that accurately simulate real-site conditions in terms of dimensions, reinforcement and hook bars. SF was replaced with 10% and 15% of the weight of cement in the concrete mixture. To simulate corrosion, the specimens were subjected to accelerated corrosion in the laboratory by applying a low continuous current of 0.35 mA for 58 days.
Findings
The results revealed the effect of SF in improving the compressive strength of concrete, the pullout resistance of the hook bars and the corrosion resistance. In addition, it showed an apparent effect of the corrosion of reinforcing bars in reducing the bonding strength of hook bars with concrete and the effect of SF in improving this strength.
Originality/value
It was noted that the improvement of the results, achieved by replacing 10% of the weight of cement with SF, was significantly close to the results obtained by replacing 15% of the SF. It is recommended that an SF ratio of 10% be adopted to achieve the greatest economic savings.
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Yan Gao, Qiubo Li, Wei Wu, Qiwei Wang, Yizhe Su, Junxi Zhang, Deyuan Lin and Xiaojian Xia
The purpose of this paper is to study the effect of current-carrying condition on the electrochemical process and atmospheric corrosion behavior of the commercial aluminum alloys.
Abstract
Purpose
The purpose of this paper is to study the effect of current-carrying condition on the electrochemical process and atmospheric corrosion behavior of the commercial aluminum alloys.
Design/methodology/approach
Potentiodynamic polarization tests were performed to study the electrochemical process of the aluminum alloys. Salt spray tests and weight loss tests were carried out to study the atmospheric corrosion behavior. The corrosion morphology of the alloys was observed, and the products were analyzed.
Findings
The corrosion process of four aluminum alloys was accelerated in the current-carrying condition. Moreover, the acceleration effect on A2024 and A7075 was much stronger than that on A1050 and A5052. The main factors would be the differences in microstructure and corrosion resistance between these alloys. As the carried current increased, the corrosion rate and corrosion current density of the aluminum alloys gradually increased, with the protection of the corrosion product film decreasing linearly.
Originality/value
This is a recent study on the corrosion behavior of conductors under current-carrying condition, which truly understands the corrosion status of power grid materials. Relevant results provide support for the corrosion protection and safe service of aluminum alloy in power systems.
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This paper aims to achieve phosphating via optimal features of Mg metal as a suitable base coating, which is considered for other properties such as barrier properties against the…
Abstract
Purpose
This paper aims to achieve phosphating via optimal features of Mg metal as a suitable base coating, which is considered for other properties such as barrier properties against the passage of several factors.
Design/methodology/approach
In this research, in the phosphate bath, immersion time, temperature and the content of sodium nitrite as an accelerator were changed.
Findings
As a result, increasing the immersion time of AZ31 Mg alloy samples in the phosphating bath as well as increasing the ratio of sodium dodecyl sulfate (SDS) concentration to sodium nitrite concentration in the phosphating bath formulation increase the mass of phosphating formed per unit area of the Mg alloy. The results of the scanning electron microscope test showed phosphating is not completely formed in short immersion times, which is a thin and uneven layer.
Research limitations/implications
Mg and its alloys are sensitive to galvanic corrosion, which would lead to generating several holes in the metal. As such, it causes a decrease in mechanical stability as well as an unfavorable appearance.
Practical implications
Mg is used in several industries such as automobile and computer parts, mobile phones, astronaut compounds, sports goods and home appliances.
Social implications
Nevertheless, Mg has high chemical reactivity, so an oxide-hydroxide layer is formed on its surface, which has a harmful effect on the adhesion and uniformity of the coating applied on Mg.
Originality/value
By increasing the ratio of SDS concentration to sodium nitrite concentration in the phosphating bath, the corrosion resistance of the phosphating increases.
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Vahid Ahmadi, Seyed Mohammad Ali Hosseini, Effat Jamalizadeh and Razie Naghizade
This paper aims to investigate the corrosion resistance of two types of coatings – one is ceria sol coating and the other is ceria sol coating modified by ZnO nanoparticles on…
Abstract
Purpose
This paper aims to investigate the corrosion resistance of two types of coatings – one is ceria sol coating and the other is ceria sol coating modified by ZnO nanoparticles on 7075 aluminum alloy in 3.5% NaCl solution.
Design/methodology/approach
Aluminum alloys were dipped into ceria sol and ceria sol modified by ZnO nanoparticles separately and removed after 10 min from the solutions and dried at 110°C for 30 min and heated at 500 °C for 30 min to form the coatings. The coatings have been characterized by using field emission scanning electron microscopy (FE-SEM), electrochemical impedance spectroscopy (EIS), X-ray diffraction (XRD) and energy dispersive spectroscopy (EDS). The EIS tests were performed in a corrosive solution of 3.5% NaCl.
Findings
The results showed that the coating of ceria sol modified by ZnO nanoparticles has higher corrosion resistance than the ceria sol coating and the bare sample. Also, the best efficiency is related to aluminum sample immersion after 1 h in NaCl corrosive solution for coating modified by ZnO nanoparticles.
Originality/value
In this research, the modification of ceria sol coating by ZnO nanoparticles had an effect on improving the corrosion behavior of aluminum alloy. It is also understood that modification of coatings is an effective parameter on corrosion resistance.
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Shuliu Wang, Qianqian Liu, Jin Wang, Nana Chen, JunHang Chen, Jialiang Song, Xin Zhang and Kui Xiao
This study aims to investigate the role of aluminium (Al) in marine environment and the corrosion mechanism of galvalume coatings by conducting accelerated experiments and data…
Abstract
Purpose
This study aims to investigate the role of aluminium (Al) in marine environment and the corrosion mechanism of galvalume coatings by conducting accelerated experiments and data analysis.
Design/methodology/approach
Samples were subjected to accelerated corrosion for 136 days via salt spray tests to simulate the natural conditions of marine environment and consequently accelerate the experiments. Subsequently, the samples were examined using various test methods, such as EDS, scanning electron microscopy (SEM), X-ray diffraction (XRD) and electrochemical impedance spectroscopy (EIS), and the obtained data were analysed.
Findings
Galvalume coatings comprised interdigitated zinc (Zn)-rich and dendritic Al-rich phases. Corrosion was observed to begin with a Zn-rich phase. The primary components of the corrosion product film were Al2O3 and Zn5(OH)8Cl2·H2O. It was confirmed that the role of Al was to form a dense protective film, thereby successfully blocking the entry of corrosive media and protecting the iron substrate.
Originality/value
This study provides a clearer understanding of the corrosion mechanism and kinetics of galvalume coatings in a simulated marine environment. In addition, the role of Al, which is rarely mentioned in the literature, was investigated.
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Suyun Liu, Hu Liu, Ningning Shao, Zhijun Dong, Rui Liu, Li Liu and Fuhui Wang
Polyaniline (PANI) has garnered attention for its potential applications in anticorrosion fields because of its unique properties. Satisfactory outcomes have been achieved when…
Abstract
Purpose
Polyaniline (PANI) has garnered attention for its potential applications in anticorrosion fields because of its unique properties. Satisfactory outcomes have been achieved when using PANI as a functional filler in organic coatings. More recently, research has extensively explored PANI-based organic coatings with self-healing properties. The purpose of this paper is to provide a summary of the active agents, methods and mechanisms involved in the self-healing of organic coatings.
Design/methodology/approach
This study uses specific doped acids and metal corrosion inhibitors as active and self-healing agents to modify PANI using the methods of oxidation polymerization, template synthesis, nanosheet carrier and nanocontainer loading methods. The anticorrosion performance of the coatings is evaluated using EIS, LEIS and salt spray tests.
Findings
Specific doped acids and metal corrosion inhibitors are used as active agents to modify PANI and confer self-healing properties to the coatings. The coatings’ active protection mechanism encompasses PANI’s own passivation ability, the adsorption of active agents and the creation of insoluble compounds or complexes.
Originality/value
This paper summarizes the active agents used to modify PANI, the procedures used for modification and the self-healing mechanism of the composite coatings. It also proposes future directions for developing PANI organic coatings with self-healing capabilities. The summaries and proposals presented may facilitate large-scale production of the PANI organic coatings, which exhibit outstanding anticorrosion competence and self-healing properties.
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Liang Ma, Qiang Wang, Haini Yang, Da Quan Zhang and Wei Wu
The aim of this paper is to solve the toxic and harmful problems caused by traditional volatile corrosion inhibitor (VCI) and to analyze the effect of the layered structure on the…
Abstract
Purpose
The aim of this paper is to solve the toxic and harmful problems caused by traditional volatile corrosion inhibitor (VCI) and to analyze the effect of the layered structure on the enhancement of the volatile corrosion inhibition prevention performance of amino acids.
Design/methodology/approach
The carbon dots-montmorillonite (DMT) hybrid material is prepared via hydrothermal process. The effect of the DMT-modified alanine as VCI for mild steel is investigated by volatile inhibition sieve test, volatile corrosion inhibition ability test, electrochemical measurement and surface analysis technology. It demonstrates that the DMT hybrid materials can improve the ability of alanine to protect mild steel against atmospheric corrosion effectively. The presence of carbon dots enlarges the interlamellar spacing of montmorillonite and allows better dispersion of alanine. The DMT-modified alanine has higher volatilization ability and an excellent corrosion inhibition of 85.3% for mild steel.
Findings
The DMT hybrid material provides a good template for the distribution of VCI, which can effectively improve the vapor-phase antirust property of VCI.
Research limitations/implications
The increased volatilization rate also means increased VCI consumption and higher costs.
Practical implications
Provides a new way of thinking to replace the traditional toxic and harmful VCI.
Originality/value
For the first time, amino acids are combined with nano laminar structures, which are used to solve the problem of difficult volatilization of amino acids.
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Dexin Chen, Hongyuan He, Zhixin Kang and Wei Li
This study aims to review the current one-step electrodeposition of superhydrophobic coatings on metal surfaces.
Abstract
Purpose
This study aims to review the current one-step electrodeposition of superhydrophobic coatings on metal surfaces.
Design/methodology/approach
One-step electrodeposition is a versatile and simple technology to prepare superhydrophobic coatings on metal surfaces.
Findings
Preparing superhydrophobic coatings by one-step electrodeposition is an efficient method to protect metal surfaces.
Originality/value
Even though there are several technologies, one-step electrodeposition still plays a significant role in producing superhydrophobic coatings.
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