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The purpose of this paper is to use alternative polymerisation methods, i.e. UV irradiation to synthesise poly(acrylamide)/montmorillonite nanocomposite and characterise the composite.

Polymer/montmorillonite nanocomposite was synthesised by the polymerisation, induced by UV radiation and the structure of the composite was studied by means of FTIR, NMR(¹³ C, ²⁷Al and ²⁹Si) and X‐ray diffraction.

The poly(acrylamide)/montmorillonite nanocomposite was synthesised by UV irradiation, and its structures showed that the acrylamide was intercalated in the lamina of montmorillonite in bimolecular layers. FTIR and NMR analyses showed that there was no major chemical change of the polymer chain associated with the intercalation. The interaction between montmorillonite and polymer was mainly related with the van der Waals forces and hydrogen bonding, not with the bonding involved with the carbon atoms.

There are few reports on the synthesis and characterisation of polymer/montmorillonite composite prepared with UV radiation.

The alternative synthesis method using UV irradiation can provide a new way for the preparation of montmorillonite/acrylamide nanocomposite for the application in moisture and organic solvent vapour sensors, etc.

This provides a way for the synthesis of polymer/montmorillonite nanocomposite using polymerisation induced by UV radiation, which can be used in the thin membrane preparation for sensor and special application. Characterisation of the material revealed the structure of the nanocomposite, which would be helpful for the study of structure design and property improvement.

Bismaleimide (BMI) is a kind of thermosetting resin and its application is usually limited by low toughness. In this paper, two kinds of reinforcement intercalator amino-terminated polyoxypropylene (POP) and octadecyl trimethyl ammonium chloride (OTAC) were designed and synthesized to toughen BMI resin and the toughening effect was compared and analyzed. The purpose of this paper is to toughen BMI resin and analyze the toughening effect of two reinforcements intercalator amino-terminated polyoxypropylene (POP) and octadecyl trimethyl ammonium chloride (OTAC).

Sodium-based montmorillonite (Na-MMT) was modified by POP and OTAC, and the ion-exchange reaction obtained organic montmorillonite (POP-MMT and OTAC-MMT). The polymer matrix (MBAE) was synthesized, in which 4,4’-diamino diphenyl methane BMI was used as the monomer and 3,3’-diallyl bisphenol A and bisphenol A diallyl ether were used as active diluents. And then, POP-MMT/MBAE and OTAC-MMT/MBAE composites were prepared using MBAE as matrix and POP-MMT or OTAC-MMT as reinforcement. The Fourier-transform infrared, X-ray diffraction and scanning electron microscope (SEM) of the filler and microstructure and mechanical properties of the composite were characterized to the better reinforcement.

POP-MMT and OTAC-MMT enhanced BMI-cured products’ toughness by generating microcracks in the polymer to absorb more fracture energy. Meanwhile, POP-MMT and OTAC-MMT were the main stress components and the enhancement of the interface interaction was beneficial to transfer the external force from the matrix to the reinforcement and improved the mechanical properties of the composite. Furthermore, with the intercalation rate increasing, the compatibility of the two phases was increased and the performance of MBAE was also elevated.

BMI is generally used as aerospace structural materials, functional materials, impregnating paint and other fields. However, high crosslinking density leads to moulding material’s brittleness and limits a wider range of applications. Therefore, it has become an urgent priority to explore and improve the mechanical properties of BMI resin.

POP and OTAC have successfully intercalated Na-MMT layers to get POP-MMT and OTAC-MMT, and the interplanar crystal spacing and the intercalation rate were calculated, respectively. The results were corresponding with the SEM images of POP-MMT and OTAC-MMT. After that, the morphology of composites illustrated the compatibility was related to the intercalation rate. According to the mechanism of modified MMT toughening epoxy resin, when they were dispersed uniformly in the matrix, the composite’s mechanical properties had been significantly improved. Additionally, OTAC-MMT with a higher intercalation rate had better compatibility and interfacial force with the matrix, so that the mechanical properties of OTAC-MMT/MBAE were the best.

Materials commonly involve microstructure. Clay is a microinhomogeneous material with nanoscale microstructure. Key issues to understand the behavior of such a finely microinhomogeneous material are as follows: the microstructure is characterized in detail, the local distribution of material properties is identified by experiment or simulation, and the microscale characteristics are related to the macroscale behavior by a seamless manner. For characterizing a microstructure of bentonite, we introduce a conforcal laser scanning microscope (CLSM) together with SEM. By CLSM we can specify a 3D configuration under atmospheric condition. Properties of water‐saturated bentonite are mainly controlled by hydrated montmorillonite, which is the major clay mineral of bentonite. Smectite minerals including montmorillonite are extremely fine and poorly crystallized, so it is difficult to determine the properties by experiment. We inquire into the physicochemical properties by a molecular dynamics simulation method. Then, we develop a multiscale homogenization method to extend the microscopic characteristics to the macroscopic behavior. We show numerical examples of a diffusion problem.

Organophilic Sylodex Bentonites are organically treated forms of the clay mineral montmorillonite. The latter is present in the form of microscopically small platelets. The platelets are characteristic of the crystalline structure of the montmorillonite. The chemical composition is that of an aluminium hydrosilicate in which the silicon, aluminium and oxygen atoms are arranged in 3 layers (see Fig. 1). The outer layers consist of SiO2‐tetrahedra and the inner layers of (AlO4(OH)2) octahedra. An idealized initial structure of the precursor of montmorillonite exhibits the following neutral formula:

The aim of this paper is to solve the toxic and harmful problems caused by traditional volatile corrosion inhibitor (VCI) and to analyze the effect of the layered structure on the enhancement of the volatile corrosion inhibition prevention performance of amino acids.

The carbon dots-montmorillonite (DMT) hybrid material is prepared via hydrothermal process. The effect of the DMT-modified alanine as VCI for mild steel is investigated by volatile inhibition sieve test, volatile corrosion inhibition ability test, electrochemical measurement and surface analysis technology. It demonstrates that the DMT hybrid materials can improve the ability of alanine to protect mild steel against atmospheric corrosion effectively. The presence of carbon dots enlarges the interlamellar spacing of montmorillonite and allows better dispersion of alanine. The DMT-modified alanine has higher volatilization ability and an excellent corrosion inhibition of 85.3% for mild steel.

The DMT hybrid material provides a good template for the distribution of VCI, which can effectively improve the vapor-phase antirust property of VCI.

The increased volatilization rate also means increased VCI consumption and higher costs.

Provides a new way of thinking to replace the traditional toxic and harmful VCI.

For the first time, amino acids are combined with nano laminar structures, which are used to solve the problem of difficult volatilization of amino acids.

The purpose of this paper was to research the influence of polyaniline/montmorillonite (PANI/OMMT) composite powder content on the corrosion protection of epoxy (EP) coating.

The polyaniline/montmorillonite/epoxy (PANI/OMMT/EP) coatings containing different contents of PANI/OMMT composite powder were prepared on steel. The corrosion protection performances of PANI/OMMT/EP coatings in 3.5 per cent NaCl solutions were investigated by electrochemical impedance spectroscopy. The barrier property of coatings was examined using water absorption analysis. The structure and crosslink density of coatings were examined using scanning electron microscopy and differential scanning calorimetry, respectively.

The PANI/OMMT composite powder could enhance the barrier properties of the EP coating and reduce the corrosion rate of the steel beneath the coating. The coating showed the best corrosion protection performance when 3 per cent PANI/OMMT powder was added to the coating.

The research clarified the influence of PANI/OMMT content on the corrosion protection of coating from two aspects: one is the barrier performance of the coating; the other is the corrosion inhibitors for metal substrate.

This paper aims to achieve an anti-corrosive coating via uniform dispersion of nanoclay particles (montmorillonite) and polypyrrole (PPy) as a conductive polymer as well as their effects on the anti-corrosion features in the presence of the eco-friendly ionic liquids (ILs).

In this research, PPy with different forms of nanoclay were used. Moreover, ILs additive is used to enhance the better dispersion process of clay and PPy nanoparticles in the resin.

As a result, the IL additive in the formulation of nano-composite coatings greatly improves the dispersion process of clay and PPy nanoparticles in the resin. Due to its high compatibility with polyurethane resin and clay and PPy nanoparticles, this additive contains a high dispersing power to disperse the investigated nanoparticles in the resin matrix.

High polarity of ILs as well as abilities to dissolve both mineral and organic materials, they can provide the better chemical processes compared to common solvents.

IL abilities have not been discovered to a large extent such as catalysts and detectors.

ILs have been emerging as promising green solvents to replace conventional solvents in recent years. They possess unique properties such as nonvolatility, low toxicity, ease of handling, nonflammability and high ionic conductivity. Thus, they have received much attention as green media for various chemistry processes.

The simultaneous existence of clay, PPy and IL additive in the nano-composite coating formulation is responsible for the high corrosion resistance of the coating.

This study aims to offer an effective nanocomposite for potential use to consolidate and protect deteriorated archaeological pottery.

Three nanocomposites were used in the experimental study. This study used nano Primal AC33, silicon dioxide (SiO₂) and montmorillonite (MMT) nanoparticles to protect and consolidate pottery specimens. Pottery specimens were made at 800°C for this investigation. Consolidation materials were applied with a brush. The properties of the treated pottery specimens were assessed using several methods such as digital and scanning electron microscopes, static water contact angle, color alteration, physical properties and compressive strength.

Microscopic examination indicated the ability of the nano Primal AC33/MMT nanocomposites to cover the outer surface well and bind the inner granules. Concerning specimens with code F treated with nano Primal AC33 5%/MMT 3% nanocomposites, it achieved an increase in contact angle (120°), density (1.23 g/cm³) and compressive strength (561 kg/cm²), as well as a decrease in color change (ΔE = 2.62), water absorption (4.45%) and porosity (5.46%). The novelty of the results is due to the characteristics of nano Primal AC33 5%/MMT 3% nanocomposites used in the current study.

This study describes the significant results of the analytical methods used for evaluating consolidation materials used in this study. The findings offer useful information for the protection of archaeological pottery. The investigation indicated that nano Primal AC33 5%/MMT 3% nanocomposites gave the best results. Therefore, it is recommended to use this nanocomposite to consolidate archaeological pottery. As a result, the current work provides a promising first step in conserving archaeological pottery for future studies.

This study aims to reduce the harm of industrial lubricants to consumers. Composite aluminum-based grease (CAG) was prepared, and medical-grade montmorillonite (M-MMT) was used to improve the antiwear performance of the prepared grease.

The influence of the additive (M-MMT) on the tribological performance is mainly investigated using a ball-disc wear tester, and the wear scar surface about the disc was characterized by white light interferometer and electrochemical workstation. Moreover, the cell viability test was used to evaluate the safety of the grease.

The results indicated that for the grease containing 1.5% M-MMT, the average coefficient of friction was reduced by about 46% compared with the CAG, the wear volume of the disc reduced by about 74%. Moreover, CAG and 1.5% M-MMT-containing CAG were proved safety by means of the cell viability test.

The integral properties of CAG can be improved with the medical-grade materials as the additives, while ensuring the safety.

A wide range of clays are presently available in Egypt. These clays are potentially economic substances as they contain minerals such as montmorillonite, kaolinite and illite. The x‐ray flourescence and the thermal gravimetric analysis (TGA) were calculated for the clay sample under consideration. The modification of the clay surface was achieved by using two different organic substances such as stearic acid and poly (methacrylic acid) solutions. It was found that the modification process improved the pigmentary properties of this clay.