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Article
Publication date: 4 September 2017

Leipeng Zhang, Binghan Zhang, Bo Fan, Zhenhua Gao and Junyou Shi

This paper aims to focus on the liquefaction of soybean protein to obtain a homogeneous protein solution with a high solid/protein content but low viscosity, which may improve the…

Abstract

Purpose

This paper aims to focus on the liquefaction of soybean protein to obtain a homogeneous protein solution with a high solid/protein content but low viscosity, which may improve the bond properties and technological applicability of soybean protein adhesive.

Design/methodology/approach

The liquefactions of soybean protein in the presence of various amounts of sodium sulphite, urea and sodium dodecyl sulphate (SDS) are investigated, and their effects on the main properties of liquefied soybean protein and soybean protein adhesives are characterized by Fourier transform infrared spectroscopy (FT-IR), gel permeation chromatography (GPC), viscosity tracing and plywood evaluation. Meanwhile, the applicability of soybean protein adhesive composed of liquefied protein for particleboard is also investigated.

Findings

Soybean protein can be effectively liquefied to form a homogeneous protein solution with a soybean protein content of 25 per cent and viscosity as low as 772 mPa.s; the addition of sodium sulphite, urea and SDS are beneficial for the liquefaction of soybean protein and have important effects on the technological applicability and water resistance of the obtained adhesive. The optimal liquefying technology of soybean protein is obtained in the presence of 1.5 Wt.% of sodium sulphite, 5 Wt.% of urea, 1.5 Wt.% of SDS and 3 Wt.% of sodium hydroxide. The optimal soybean protein adhesive has the desired water resistance in terms of the boiling-dry-boiling aged wet bond strength, which is up to 1.08 MPa higher than the required value (0.98 MPa) for structural use according to the commercial standard JIS K6806-2003. The optimal liquefied protein has the great potential to prepare particleboard.

Research limitations/implications

The protein content of liquefied soybean protein is expected to further increase from 25 to 40 Wt.% or even higher to further reduce the hot-pressing cycle or energy consumption of wood composites bonded by soybean protein adhesives.

Practical implications

The soybean protein adhesive composed of optimal liquefied protein has potential use in the manufacturing of structural-use plywood and has comparable applicability as a commercial urea-formaldehyde resin for the manufacturing of common particleboard.

Social implications

Soybean protein adhesive is an environmentally safe bio-adhesive that does not lead to the release of toxic formaldehyde, and the renewable and abundant soybean protein can be used with higher value added by the application as wood adhesive.

Originality/value

A novel liquefaction approach of soybean protein is proposed, and the soybean protein adhesive based on the liquefied protein is obtained with good technological applicability and desired bond properties that extend the applications of the soybean protein adhesive from interior plywood to particleboard and exterior or structural plywood.

Details

Pigment & Resin Technology, vol. 46 no. 5
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 18 October 2022

Reza Amini and Pooneh Kardar

This paper aims to achieve phosphating via optimal features of Mg metal as a suitable base coating, which is considered for other properties such as barrier properties against the…

Abstract

Purpose

This paper aims to achieve phosphating via optimal features of Mg metal as a suitable base coating, which is considered for other properties such as barrier properties against the passage of several factors.

Design/methodology/approach

In this research, in the phosphate bath, immersion time, temperature and the content of sodium nitrite as an accelerator were changed.

Findings

As a result, increasing the immersion time of AZ31 Mg alloy samples in the phosphating bath as well as increasing the ratio of sodium dodecyl sulfate (SDS) concentration to sodium nitrite concentration in the phosphating bath formulation increase the mass of phosphating formed per unit area of the Mg alloy. The results of the scanning electron microscope test showed phosphating is not completely formed in short immersion times, which is a thin and uneven layer.

Research limitations/implications

Mg and its alloys are sensitive to galvanic corrosion, which would lead to generating several holes in the metal. As such, it causes a decrease in mechanical stability as well as an unfavorable appearance.

Practical implications

Mg is used in several industries such as automobile and computer parts, mobile phones, astronaut compounds, sports goods and home appliances.

Social implications

Nevertheless, Mg has high chemical reactivity, so an oxide-hydroxide layer is formed on its surface, which has a harmful effect on the adhesion and uniformity of the coating applied on Mg.

Originality/value

By increasing the ratio of SDS concentration to sodium nitrite concentration in the phosphating bath, the corrosion resistance of the phosphating increases.

Details

Pigment & Resin Technology, vol. 53 no. 3
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 1 February 1998

J.I. Amalvy

The effects of amount of conventional surfactant sodium dodecyl sulfate in the synthesis of carboxylated acrylic latices prepared by semicontinuous emulsion polymerization method…

Abstract

The effects of amount of conventional surfactant sodium dodecyl sulfate in the synthesis of carboxylated acrylic latices prepared by semicontinuous emulsion polymerization method were investigated. The properties considered were particle size and colloidal stability by addition of sodium chloride solution, on the latex system and water sorption, tensile strength at break and elongation, on latex films. It was found that the surfactant concentration had an important effect on the above mentioned properties. The particle size decreases with increasing surfactant concentration and the colloidal stability has a maximum value. The critical coagulation concentration value found in this work, seems to indicate an additional stabilisation of latex particles, due to a steric factor. The water uptake and the mechanical behaviour of latex films are affected considerably when SDS concentration rises. In conclusion, depending on the final use of latex, there is an optimal surfactant concentration for which the properties are appropriate.

Details

Pigment & Resin Technology, vol. 27 no. 1
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 12 July 2024

Nadeem Afraz, Shaheen Sardar, Muhammad Mohsin, Mumtaz Hasan Malik, Khurram Shehzad Akhtar and Muhammad Ilyas Tariq

In the textile dyeing industry, the foam dyeing has been recognized as a significantly sustainable alternative for the cotton fabrics. However, this efficient technology undergoes…

Abstract

Purpose

In the textile dyeing industry, the foam dyeing has been recognized as a significantly sustainable alternative for the cotton fabrics. However, this efficient technology undergoes the many issues related to the foam generation, foam optimization and the required performance of the resultant fabrics. The purpose of this paper is to address these issues through the development and optimization of the novel reactive foam dyeing recipes for the cotton fabrics.

Design/methodology/approach

The foam dyeing recipes were generated and optimized using the different stabilizers, foaming agents and three primary colors of reactive dyes. The different recipes were applied onto the cotton fabric using laboratory scale foam coating machine. The performance of the foam coated and padded fabrics was evaluated using different criteria including the shade depth, rubbing fastness, air permeability, washing fastness, perspiration fastness, light fastness and tear strength. Then, a complex decision-making approach, namely, analytic hierarchy process (AHP), was applied for the ranking of the key recipes based on the main criteria.

Findings

The newly optimized foam dyeing recipes were found very competitive with the conventional pad dyeing process with respect to the shade-depth and the other performance properties. The optimization of foaming parameters and addition of stabilizers have advanced the foam dyeing process, which would accelerate the implementation of foam dyeing methods in the textile industry. Furthermore, significant water and energy savings would be achieved as compared to the conventional foam dyeing. AHP model offered a comprehensive and rational way to identify the most important recipes amongst the selected recipes.

Originality/value

In this research, novel foam dyeing recipes have been developed for the cotton fabrics through the optimization of the different stabilizers, foaming agents and the three primary colors of reactive dyes. Until now, the exiting literature has not reported the combination of these stabilizers with the different foaming agents and three primary reactive dyes for the improvement of sustainable foam cotton dyeing process.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 1 April 2005

S. Rajendran, S.P. Sridevi, N. Anthony, A. John Amalraj and M. Sundaravadivelu

To evaluate the inhibition efficiency (IE) of polyvinyl alcohol (PVA) in controlling the corrosion of carbon steel immersed in neutral aqueous solutions containing 60 ppm of Cl

1052

Abstract

Purpose

To evaluate the inhibition efficiency (IE) of polyvinyl alcohol (PVA) in controlling the corrosion of carbon steel immersed in neutral aqueous solutions containing 60 ppm of Cl, in the absence and presence of Zn2+. To investigate the influence of sodium sulphite (Na2SO3), sodium dodecyl sulphate (SDS), pH and duration of immersion on the IE of PVA‐Zn2+ system. To analyse the protective film formed on the metal surface.

Design/methodology/approach

The IE has been evaluated by weight loss method. The protective film was analysed by FTIR and fluorescence spectra.

Findings

A formulation consisting of 100 ppm of PVA and 75 ppm of Zn2+ offered 81 per cent IE to carbon steel immersed in a solution containing 60 ppm of Cl. A synergistic effect on inhibition of a combination of PVA and Zn2+ was observed during the tests. The protective film consisted of the Fe2+‐PVA complex and Zn(OH)2. It was found to be UV‐fluorescent. When SDS was added to the PVA‐Zn2+ system, the mixture showed maximum IE at the critical micelle concentration (200 ppm) of SDS (an anionic surfactant). The oxygen‐scavenging effect of Na2SO3 increased as the concentration of Na2SO3 was increased. At lower concentrations of Na2SO3, the transport of the inhibitors played a more major role than did the removal of dissolved oxygen. As the pH value was increased, the IE of the PVA‐Zn2+ system decreased. As the duration of immersion was increased, the IE was observed to decrease.

Research limitations/implications

Electrochemical studies such as polarization and AC impedance spectra will enlighten more on the mechanistic aspects of corrosion inhibition.

Practical implications

If this study is carried out at high temperature under simulated conditions, the findings may find applications in cooling water systems.

Originality/value

The role of transport of inhibitors towards the metal surface from the bulk of the solution, formation of micelles by surfactants, removal of dissolved oxygen by oxygen scavenger, competition between formation of insoluble iron‐inhibitor complex on metal surface and formation of soluble iron chloride in influencing the inhibitive property has been investigated. The protective film was analysed by FTIR spectra and fluorescence spectra.

Details

Anti-Corrosion Methods and Materials, vol. 52 no. 2
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 9 August 2019

Rouhollah Mousavi, Mohammad Ebrahim Bahrololoom and Flavio Deflorian

In this research, the microstructure and corrosion behavior of Ni-Mo alloy coatings obtained from a citrate bath solution containing sodium dodecyl sulfate (SDS) as an anionic…

Abstract

Purpose

In this research, the microstructure and corrosion behavior of Ni-Mo alloy coatings obtained from a citrate bath solution containing sodium dodecyl sulfate (SDS) as an anionic surfactant, and cetyltrimethylammonium bromide (CTAB) as a cationic surfactant, have been investigated.

Design/methodology/approach

For this purpose, the Cathodic polarization curves were plotted using a potentiostat/galvanostat set. Scanning electron microscopy and energy dispersive spectroscopy were, respectively, used to investigate the morphology and chemical composition of the coatings.

Findings

The results of the corrosion test showed that the corrosion resistance of the coatings obtained from electroplating bath only containing CTAB surfactant was deteriorated. On the other hand, SDS anionic surfactant positively affected on the corrosion resistance of the coatings when it was added to the electroplating bath.

Originality/value

For this purpose, the Cathodic polarization curves were plotted using a potentiostat/galvanostat set. Scanning electron microscopy and energy dispersive spectroscopy were respectively used to investigate the morphology and chemical composition of the coatings.

Details

Anti-Corrosion Methods and Materials, vol. 66 no. 5
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 18 March 2022

Yufu Xu, Kequn Sun, Quan Zheng, Lulu Yao, Yinghui Dong and Ruhong Song

This paper aims to offeri novel nano-additives polymer microgels to precisely improve the lubrication properties of titanium alloy under different temperatures.

Abstract

Purpose

This paper aims to offeri novel nano-additives polymer microgels to precisely improve the lubrication properties of titanium alloy under different temperatures.

Design/methodology/approach

The surfactant-free emulsion polymerization method was used to prepare Poly(N-isoprolylacrylamide) (PNIPAM) microgels. A ball-on-disk tribometer was applied to investigated the temperature-sensitive lubrication behavior of PNIPAM microgels.

Findings

The results show that the as-prepared microgels are ball-like nanoparticles with the size of 50–900 nm. In addition, potassium persulfate as initiator, complete mixing technic and high sodium dodecyl sulfate (SDS) concentration contribute to the formation of microgels with small size. The tribosystem shows a lower friction coefficient with the lubrication of PNIPAM microgels as aqueous solution additives when the temperature exceeding the critical temperature.

Originality/value

This work reports the temperature-sensitive lubrication of PNIPAM microgels. The critical temperature of PNIPAM microgels could be regulated by the addition of SDS in the solutions. This offers an effective and facile strategy for regulation of the critical temperature of smart microgels, which is helpful for the smart lubrication in the future.

Details

Industrial Lubrication and Tribology, vol. 74 no. 5
Type: Research Article
ISSN: 0036-8792

Keywords

Article
Publication date: 2 January 2018

Ali Yousefi, Saeed Amir Aslanzadeh and Jafar Akbari

The purpose of this paper is to investigate the surface properties, particle sizes and corrosion inhibition performance of sodium dodecyl sulfate (SDS) in the presence of…

Abstract

Purpose

The purpose of this paper is to investigate the surface properties, particle sizes and corrosion inhibition performance of sodium dodecyl sulfate (SDS) in the presence of imidazolium-based ionic liquid as an additive. Up to now, different properties of alone surfactants and ionic liquids have been studied. However, few studies have been devoted to mixed ionic liquid and surfactant. The significance and novelty of this research is the investigation of 1-methylimidazolium trinitrophenoxide ([MIm][TNP]) as ionic liquid effects on SDS corrosion behavior.

Design/methodology/approach

The inhibition effect of [MIm][TNP], SDS and their mixtures on mild steel surface in 2 M hydrochloric acid (HCl) solution was examined by electrochemical impedance spectroscopy, potentiodynamic polarization (PDP), scanning electron microscopy (SEM), atomic force microscopy and quantum chemical calculations as well as dynamic light scattering (DLS) and surface tension measurements to discuss surface properties of studied solutions.

Findings

Based on the results, ionic liquid/SDS mixtures significantly indicated better inhibition properties than pure surfactant solution. PDP curves indicated that the studied compounds act as mixed-type of inhibitors. The critical micelle concentration, surface properties and particle sizes were investigated from the surface tension measurements and DLS results.

Originality/value

Adsorption of the inhibitors on the steel surface obeyed the Villamil adsorption model. SEM was used for surface analysis and verified the inhibition efficiency of mixed IL/SDS system. Quantum chemical calculations were performed using density functional theory, and a good relationship between experimental and theoretical data has been obtained.

Details

Anti-Corrosion Methods and Materials, vol. 65 no. 1
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 17 July 2023

Zulfiqar Ali Raza, Aisha Rehman, Faiza Anwar and Naseer Ahmad

This study aims to investigate the effect of the copresence of ferrous (Fe2+) ions and sodium dodecyl sulfate (SDS) on the activity of an amylase enzyme during the desizing of…

44

Abstract

Purpose

This study aims to investigate the effect of the copresence of ferrous (Fe2+) ions and sodium dodecyl sulfate (SDS) on the activity of an amylase enzyme during the desizing of greige viscose fabric for potential industrial applications. The removal of starches is an essential step before processing the fabric for dyeing and finishing operations. The authors tend to accomplish it in eco-friendly and sustainable ways.

Design/methodology/approach

The experiments were designed under the Taguchi approach, and the results were analyzed using grey relational analysis to optimize the process. The textile properties of absorbency, reducing sugars, bending length, weight loss, Tegawa rating and tensile strength were assessed using the standard protocols. The control and optimized viscose specimens were investigated for certain surface chemical properties using advanced analytical techniques including scanning electron microscopy (SEM), X-ray diffraction (XRD) and thermal gravimetric analysis (TGA).

Findings

The results demonstrate that the Fe2+ concentration and process time were the main influencing factors in the amylolytic desizing of viscose fabric. The optimized process conditions were found to be 0.1 mm Fe2+ ions, 3 mm SDS, 80°C, 7 pH and 30 min process time. The copresence of Fe2+ ions and SDS promoted the biodesizing of viscose fabric. The SEM, Fourier transform infrared spectroscopy, XRD and TGA results demonstrated that the sizing agent has efficiently been removed from the fabric surface.

Practical implications

The amylase desizing of viscose fabric in the presence of certain metal ions and surfactants is a significant subject as the enzyme may face them due to their prevalence in the water systems. This could also support the biodesizing and bioscouring operations to be done in one bath, thus making the textile pretreatment process both economical and environmentally sustainable.

Originality/value

The authors found no report on the biodesizing of viscose fabric in the copresence of Fe2+ ions and the SDS surfactant under statistical multiresponse optimization. The biodesized viscose fabric has been investigated using both conventional and analytical approaches.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 21 February 2024

Bahareh Babaie, Mohsen Najafi and Maryam Ataeefard

Toner is a crucial dry colorant composite used in printing based on the electrophotographic process. The quality of printed images is greatly influenced by the toner production…

Abstract

Purpose

Toner is a crucial dry colorant composite used in printing based on the electrophotographic process. The quality of printed images is greatly influenced by the toner production method and material formulation. Chemically in situ polymerization methods are currently preferred. This paper aims to optimize the characteristics of a composite produced through emulsion polymerization using common raw materials for electrophotographic toner production.

Design/methodology/approach

Emulsion polymerization provides the possibility to optimize the physical and color properties of the final products. Response surface methodology (RSM) was used to optimize variables affecting particle size (PS), PS distribution (PSD), glass transition temperature (Tg°C), color properties (ΔE) and monomer conversion. Box–Behnken experimental design with three levels of styrene and butyl acrylate monomer ratios, carbon black pigment and sodium dodecyl sulfate surfactant was used for RSM optimization. Additionally, thermogravimetric analysis and surface morphology of composite particles were examined.

Findings

The results indicated that colorants with small PS, narrow PSDs, spherical shape morphology, acceptable thermal and color properties and a high percentage of conversion could be easily prepared by optimization of material parameters in this method. The anticipated outcome of the present inquiry holds promise as a guiding beacon toward the realization of electrographic toner of superior quality and exceptional efficacy, a vital factor for streamlined mass production.

Originality/value

To the best of the authors’ knowledge, for the first time, material parameters were evaluated to determine their impact on the characteristics of emulsion polymerized toner composites.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

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