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The purpose of this study is to investigate the effect of laser scanning speed (LSS) on the corrosive-tribological performance of Ni-60%WC coating in Wusu mine water, which was beneficial to improve the friction–wear performance of cylinder liner on water injection pump.

Ni-60%WC coatings were fabricated on 45 steel by laser cladding, and the microstructure and tribological performance was analyzed using a super depth of field microscope and ball-on-plate friction tester, and the wear mechanism was also discussed.

At room temperature (RT, 25 ± 2 °C), the average coefficients of friction of substrate and Ni-60%WC coatings fabricated at the LSS of 6, 10, 12 and 14 mm/s are 0.48 ± 0.08, 0.23 ± 0.01, 0.21 ± 0.05, 0.22 ± 0.02 and 0.25 ± 0.04, respectively, and the corresponding wear rates are 8.755 × 10⁴, 4.525 × 10³, 1.539 × 10³, 1.957 × 10³ and 2.743 × 10³ µm³·s^–1·N^–1, respectively, showing that the coating fabricated at the LSS of 10 mm/s has best friction reduction and wear resistance. The wear mechanism of Ni-60%WC coating is abrasive wear, fatigue wear and oxidative wear, which is resulted from the WC particles with the high-hardness.

Ni-60%WC coatings were first applied for cylinder liner, and the effect of laser scanning speed on its tribological performance was investigated.

This paper aims to investigate the effect of Ti₃SiC₂ on the high-temperature tribological behaviors of NiCr coating, which was beneficial to improve the friction-wear performance of hot work mold.

NiCr-Ti₃SiC₂ coatings were prepared on H13 steel substrate by laser cladding. The microstructure, phases and hardness of obtained coatings were analyzed using a super-depth of field microscope, X-ray diffraction and microhardness tester, respectively, and the tribological performance of obtained coatings at 500°C was investigated using a high-temperature tester.

The results show the NiCr-Ti₃SiC₂ coatings are comprised of γ-Ni solid, solution, Ti_xNi_y, TiC and Ti₃SiC₂ phases, and the coating hardness is increased with the increase of Ti₃SiC₂ mass fraction, which is contributed to the fine-grain and dispersion strengthening effect by the addition of Ti₃SiC₂. The NiCr-Ti₃SiC₂ coatings present excellent friction reduction and wear resistance by the synergetic action of Ti₃SiC₂ lubricant and hard phase, and the wear mechanism is predominated by abrasive wear and oxidation wear.

Ti₃SiC₂ phase was used to reinforce the tribological performance of H13 steel at high temperature, and the roles of friction reduction and wear resistance were discussed.

The peer review history for this article is available at: https://publons.com/publon/10.1108/ILT-01-2023-0004/

High-nitrogen steel is a common material for the manufacture of drilling equipment such as drill collars. However, its poor surface properties often limit its applications. The purpose of this paper is to find a way to enhance the surface performance of high-nitrogen steel, which is expected to improve the wear resistance of high-nitrogen steel.

The CoCrNi and CoCrFeNi medium-entropy alloy (MEA) coatings were prepared on high-nitrogen steel substrate by laser cladding technology. The microstructure, phase composition and element distribution of the fabricated coatings were investigated using scanning electronic microscopy, electron backscatter diffraction and X-ray diffraction. The phase structure, phase stability and structural stability of the CoCrNi and CoCrFeNi MEAs were investigated in combination with phase diagram calculation and molecular dynamics. Then the wear tests were carried out for coatings.

The results show that both prepared MEA coatings have good quality and contain a single face-centered cubic phase. The wear performance of MEA coatings is improved by the refinement of grain size and the increase of dislocation density. Due to the addition of Fe atoms, the lattice distortion of the CoCrFeNi system increased, resulting in a higher dislocation density of the coating. Cr atoms in the CoCrFeNi system are the largest, and the local lattice distortions induced by them are greater. Through this study, MEA coatings with high hardness can be expanded to drilling field applications.

CoCrFeNi and CoCrNi MEA coatings were successfully prepared on the surface of high-nitrogen steel for the first time without obvious defects. The micromorphology and grain orientation of the different kinds of coatings were discussed in detail. The hardness-strengthening mechanism and structure stability of the coatings were illustrated by experiments and molecular dynamics simulations.

The peer review history for this article is available at: https://publons.com/publon/10.1108/ILT-04-2024-0116/

The purpose of this paper is to investigate the effect of plasma electrolytic oxidation (PEO) coatings and sealed PEO coatings on the corrosion resistance and cytocompatibility of a novel Mg-1Zn-0.45Ca alloy in simulated body fluid (SBF).

The microstructure, corrosion resistance and cytocompatibility of PEO coatings and phosphate conversion-treated PEO coatings were investigated and was compared with the bare Mg alloy.

The hot-extruded Mg-Zn-Ca alloy exhibit inhomogeneous microstructure and suffered from localized corrosion in the SBF. The PEO coating after phosphate conversion treatment offers enhanced protectiveness to the Mg alloy within an immersion period of up to 60 days, which is significantly improved compared with the performance of the PEO-coated Mg alloy, but the cytocompatibility was slightly decreased.

This work offers new perspective in balancing the protectiveness and cytocompatibility of bio-materials.

This paper aims to explore how graphene can improve the mechanical and anti-corrosion properties of TiO₂-SiO₂ sol-gel coating. This sol-gel coating has been prepared on aluminum alloy substrate using graphene as both nano-filler and corrosion inhibitor.

To examine the effect of graphene on mechanical properties of sol-gel coating, the abrasion resistance, adhesion strength and scratch resistance of coating have been evaluated. To reveal the effect of graphene on the anti-corrosion property of coating for aluminum alloy, the electrochemical impedance spectroscopy (EIS) has been conducted in 3.5 Wt.% NaCl medium.

Scanning electron microscopy images indicate that graphene nanoplatelets (GNPs) have been homogeneously dispersed into the sol-gel coating matrices (at the contents from 0.1 to 0.5 Wt.%). Mechanical tests of coatings indicate that the graphene content of 0.5 Wt.% provides highest values of adhesion strength (1.48 MPa), scratch resistance (850 N) and abrasion strength (812 L./mil.) for the sol-gel coating. The EIS data show that the higher content of GNPs improve both R₁ (coating) and R₂ (coating/Al interface) resistances. In addition to enhancing the coating barrier performance (graphene acts as nanofiller/nano-reinforcer for coating matrix), other mechanism can be at work to account for the role of the graphene inhibitor in improving the anticorrosive performance at the coating/Al interface.

Application of graphene-based sol-gel coating for protection of aluminum and its alloy is very promising.

This study aims to report the development and experimental evaluation of two kinds of PANI@semiconductor based photocathodic anti-corrosion coating, for application on stainless steel substrates.

PANI was in situ chemical polymerized on TiO₂ and BiVO₄ particles, and FT-IR and SEM/EDS were used to understand the characteristics and elemental distribution of the composite particles. Composite coatings, which consisted of epoxy, PANI@TiO₂ or PANI@BiVO₄ and graphene, were prepared on the 304L stainless steel. Photoelectrochemical response measurement, electrochemical tests and immersion tests were used to assess the anti-corrosion performance of the prepared coatings in 45°C 3.5 wt.% NaCl solution. And the corrosion protection mechanism was further explained by combining with surface observation.

The photoelectrochemical response tests revealed the good photocathodic effect of the coatings, and the reversible oxidation-reduction properties of PANI (pseudocapacitive effect) leading to the repeated usage of the coatings. Consequently, the anti-corrosion mechanism of the composite coating is attributed to the physical barrier effect of the coating, the anodic protection effect of PANI and the photocathodic and energy store effect.

These kind coatings could prevent corrosion from day to night for stainless steel, which has great engineering application prospects on stainless steel corrosion protection.

This paper aims to control the deformation of a thin wall CrZrCu cylinder components (wall thickness 5 mm, diameter 400 mm) during thermal spray alumina-titania (AT13) coating by adjusting the spray parameters without deteriorating its quality evidently.

The deformation was controlled by lowering the temperature of the component in the way of adjusting the spray parameters. The main parameters adjust included extending the spraying distance, from normally 120 mm to 140 mm, decreasing plasma power from 50to 42 kW. An alumina-titanium (AT13) ceramic coating was chosen for protecting the substrate from corrosion. Microscopic morphology and phase analysis, insulation resistance testing, neutral salt test and electrochemical method were used to analyze the anti-corrosion and insulation performances of the coating.

The results indicate that, after adjusting the spraying parameters, the coating has a relatively high porosity, with an average value of 8.96 ± 0.77%. The bonding strength of the coating is relatively low, with an average value of 17.69 ± 0.85 MPa. However, after sealing, the polarization resistance of the coating in seawater can be maintained above 6.25 × 10⁶ Ω.cm² for an extended period. The coating has a high resistance (=1.1 M Ω), and there is no apparent galvanic corrosion when contacted with TC4 alloy. Additionally, analysis of corrosion products on the sample surface reveals that the samples with sprayed alumina-titanium ceramic show no copper corrosion products on the surface, and the coating remains intact, effectively isolating the corrosive medium.

By adjusting the spraying parameters, the deformation of the cylinder thin-walled component can be effectively controlled, making the φ 400 × 392 mm (thickness 5 mm) CrZrCu cylinder com-ponent with a maximum diameter deformation of only 0.14 mm. The satisfactory corrosion performances can be achieved under adjusting spraying parameters, which can guarantee the application of ceramic coating for weapon launching system of naval ships.

This paper aims to discuss how acrylic resin influences the smoke generation of intumescent flame retardant coatings.

Thermal decomposition kinetics is used in this study to simulate the burning process. The thermal decomposition of acrylic resin can be identified in the intumescent coatings through the multi-peak fitting of derivative thermogravimetric (DTG) curves. The dormant influence of acrylic resin, combined with the smoke density, is calculated.

Multiple peaks fitting method of DTG curves helps estimate the decomposition process of acrylic resin in flame retardant coating. Combining DTG data with the smoking curve, smoking generation of acrylic resin during the combustion could be evaluated. The decomposition conversion rate of acrylic resin is 21.13 per cent. Acrylic resin generates 34.64 per cent of the total amount of smoke produced during the combustion of intumescent flame retardant coatings.

All the other intumescent flame retardant coating systems could be studied using the same approach as that used in this work to achieve an improved understanding of the smoke generation process during combustion.

The method developed here provided a simple and practical solution to analyse the decomposition and smoking generation of acrylic resin in the coating mixtures. It also can be used to analyse any thermal decomposition process of any mixed compounds.

The analysis method to evaluate resin’s smoking generation of coating’s total generation is novel, and it could be applied in all kinds of coatings and mixtures to estimate the smoking generation of one composition.

The purpose of this work was to study the effect of different wood surface preparations on the wetting and adhesion of coating.

In this research, six different chemical preparations to evaluate the photostability and properties of wood coating. Also, the effect of the same wood treatments on the properties of the coating, i.e. wetting, adhesion and the permeability of two types of coatings, was investigated.

As a result, benzoyl chloride and chromic acid were found to be the most effective photostabilizing preparations. Solvent-based polyurethane was more compatible with the prepared wood surfaces compared with water-based alkyd coatings.

Chemical modifications of wood surfaces affected the wetting of various coatings.

Various surface properties could be changed using preparation that affects important coating properties.

Unfortunately, the properties of transparent wood coatings used outdoors disappear through the early years of use, essentially due to the wood substrate’s photodegradation.

Wood is a widespread substrate because of its comfortable handling, availability, proper cost of preparation and its good mechanical strength because of its density. Architects and designers tend to use wood in the construction of green buildings. However, this material is disposed to weathering while using outdoors and it should be solved.

Introduction It is well appreciated that the primary purpose of an external coating on a pipeline is of course to prevent corrosion and the coating system should possess appropriate physical and chemical properties which allow this function to be fulfilled. There are, however, additional mechanical requirements of a coating system if the material is to be effective during handling, construction, testing and operation and it is within the context of these latter requirements that current interest in external coatings has arisen.