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1 – 10 of 70Xiao Wang, Xuan Liang, Bo Wang, Chang-qing Guo, Shan-gui Zhang, Kai Yang, Shi-ya Shao, Yan Sun, Zheng Guo, Xue-yan Yu, Donghai Zhang, Tai-jiang Gui, Wei Lu, Ming-liang Sun and Rui Ding
The purpose of this study is to evaluate the effect of graphene, basalt flakes and their synergy on the corrosion resistance of zinc-rich coatings. As the important heavy-duty…
Abstract
Purpose
The purpose of this study is to evaluate the effect of graphene, basalt flakes and their synergy on the corrosion resistance of zinc-rich coatings. As the important heavy-duty anticorrosion coatings, zinc-rich coatings provided cathodic protection for the substrate. However, to ensure cathodic protection, a large number of zinc powder made the penetration resistance known as the weakness of zinc-rich coatings. Therefore, graphene and basalt flakes were introduced into zinc-rich coatings to coordinate its cathodic protection and shielding performance.
Design/methodology/approach
Three kinds of coatings were prepared; they were graphene modified zinc-rich coatings, basalt flakes modified zinc-rich coatings and graphene-basalt flakes modified zinc-rich coatings. The anticorrosion behavior of painted steel was studied by using the electrochemical impedance spectroscopy (EIS) technique in chloride solutions. The equivalent circuit methods were used for EIS analysis to obtain the electrode process structure of the coated steel system. Simultaneously, the corrosion resistance of the three coatings was evaluated by water resistance test, salt water resistance test and salt spray test.
Findings
The study found that the addition of a small amount of graphene and basalt flakes significantly improved the anticorrosion performance of coatings by enhancing their shielding ability against corrosive media and increasing the resistance of the electrochemical reaction. The modified coatings exhibited higher water resistance, salt water resistance and salt spray resistance. The graphene-basalt flakes modified zinc-rich coatings demonstrated the best anticorrosion effect. The presence of basalt scales and graphene oxide in the coatings significantly reduced the water content and slowed down the water penetration rate in the coatings, thus prolonging the coating life and improving anticorrosion effects. The modification of zinc-rich coatings with graphene and basalt flakes improved the utilization rate of zinc powder and the shielding property of coatings against corrosive media, thus strengthening the protective effect on steel structures and prolonging the service life of anticorrosion coatings.
Originality/value
The significance of developing graphene-basalt flakes modified zinc-rich coatings lies in their potential to offer superior performance in corrosive environments, leading to prolonged service life of metallic structures, reduced maintenance costs and a safer working environment. Furthermore, such coatings can be used in various industrial applications, including bridges, pipelines and offshore structures, among others.
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Vahid Ahmadi, Seyed Mohammad Ali Hosseini, Effat Jamalizadeh and Razie Naghizade
This paper aims to investigate the corrosion resistance of two types of coatings – one is ceria sol coating and the other is ceria sol coating modified by ZnO nanoparticles on…
Abstract
Purpose
This paper aims to investigate the corrosion resistance of two types of coatings – one is ceria sol coating and the other is ceria sol coating modified by ZnO nanoparticles on 7075 aluminum alloy in 3.5% NaCl solution.
Design/methodology/approach
Aluminum alloys were dipped into ceria sol and ceria sol modified by ZnO nanoparticles separately and removed after 10 min from the solutions and dried at 110°C for 30 min and heated at 500 °C for 30 min to form the coatings. The coatings have been characterized by using field emission scanning electron microscopy (FE-SEM), electrochemical impedance spectroscopy (EIS), X-ray diffraction (XRD) and energy dispersive spectroscopy (EDS). The EIS tests were performed in a corrosive solution of 3.5% NaCl.
Findings
The results showed that the coating of ceria sol modified by ZnO nanoparticles has higher corrosion resistance than the ceria sol coating and the bare sample. Also, the best efficiency is related to aluminum sample immersion after 1 h in NaCl corrosive solution for coating modified by ZnO nanoparticles.
Originality/value
In this research, the modification of ceria sol coating by ZnO nanoparticles had an effect on improving the corrosion behavior of aluminum alloy. It is also understood that modification of coatings is an effective parameter on corrosion resistance.
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Bataa Sayed Mohamed Mazen, Badawi Mohamed Ismail, Rushdya Rabee Ali Hassan, Mahmoud Ali and Wael S. Mohamed
The purpose of this study is to detect the effect of some natural cellulosic polymers in their nano forms with the addition of zinc oxide nanoparticles on restoring the lost…
Abstract
Purpose
The purpose of this study is to detect the effect of some natural cellulosic polymers in their nano forms with the addition of zinc oxide nanoparticles on restoring the lost mechanical strength of degraded papyrus without any harmful effects on the inks.
Design/methodology/approach
In the current study, the USB digital microscopy, scanning electron microscope, measurement of mechanical properties (tensile and elongation), pH measurement, color change and infrared spectroscopy were undertaken for the samples before and after treatment and aging.
Findings
In the current study, the USB digital microscopy, scanning electron microscope, measurement of mechanical properties (tensile and elongation), pH measurement, color change and infrared spectroscopy were undertaken for the samples before and after treatment and aging.
Originality/value
The effect of strengthening materials was studied on cellulose and carbon ink, which makes this study closer to reality as the manuscript is the consistent structure of cellulose and inks, whereas most of the literature stated the impact of consolidation materials on the strengthening the cellulosic supports without attention to their impact on inks.
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Gözde Konuk Ege, Özge Akay and Hüseyin Yüce
This study aims to investigate the ammonia-sensing performance of polyaniline/polyethylene oxide (PANI/PEO) and polyaniline/polyethylene oxide/zinc oxide (PANI/PEO-ZnO) composite…
Abstract
Purpose
This study aims to investigate the ammonia-sensing performance of polyaniline/polyethylene oxide (PANI/PEO) and polyaniline/polyethylene oxide/zinc oxide (PANI/PEO-ZnO) composite nanofibers at room temperature.
Design/methodology/approach
Gas sensor structures were fabricated using microfabrication techniques. First, onto the SiO2 wafer, gold electrodes were fabricated via thermal evaporation. PANI/PEO nanofibers were produced by the electrospinning method, and the ZnO layer was deposited by using radio frequency (RF) magnetron sputtering on the electrospun nanofibers as a sensing layer. Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM) and X-ray diffraction were performed to characterize the analysis of nanofibers. After all, gas sensing analysis of PANI/PEO and PANI/PEO/ZnO nanofibers was conducted using an experimental setup at room temperature conditions. Furthermore, the impact of humidity (17%–90% RH) on the sensor resistance was actively investigated.
Findings
FTIR analysis confirms the presence of functional groups of PANI, PEO and ZnO in nanofiber structure. SEM micrographs demonstrate beads-free, thinner and smooth nanofibers with ZnO contribution to electrospun PANI/PEO nanofibers. Moreover, according to the gas sensing results, the PANI/PEO nanofibers exhibit 115 s and 457 s response time and recovery time, respectively. However, the PANI/PEO/ZnO nanofibers exhibit 245 s and 153 s response time and recovery time, respectively. PANI/PEO/MOx composite nanofibers ensure stability to the NH3 gas owing to the high surface/volume ratio and decrease in the humidity dependence of gas sensors, making gas sensors more stable to the environment.
Originality/value
In this study, ZnO was deposited via RF magnetron sputtering techniques on PANI/PEO nanofibers as a different approach instead of in situ polymerization to investigate and enhance the sensor response and recovery time of the PANI/PEO/ZnO and PANI/PEO composite nanofibers to ammonia. These results indicated that ZnO can enhance the sensing properties of conductive polymer-based resistive sensors.
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Agnishwar Girigoswami, Poornima Govindharaj, Mahashweta Mitra Ghosh and Koyeli Girigoswami
Abstract
Purpose
In addition to agriculture, energy production, and industries, potable water plays a significant role in many fields, further increasing the demand for potable water. Purification and desalination play a major role in meeting the need for clean drinking water. Clean water is necessary in different areas, such as agriculture, industry, food industries, energy generation and in everyday chores.
Design/methodology/approach
The authors have used the different search engines like Google Scholar, Web of Science, Scopus and PubMed to find the relevant articles and prepared this mini review.
Findings
The various stages of water purification include coagulation and flocculation, coagulation, sedimentation and disinfection, which have been discussed in this mini review. Using nanotechnology in wastewater purification plants can minimize the cost of wastewater treatment plants by combining several conventional procedures into a single package.
Social implications
In society, we need to avail clean water to meet our everyday, industrial and agricultural needs. Purification of grey water can meet the clean water scarcity and make the environment sustainable.
Originality/value
This mini review will encourage the researchers to find out ways in water remediation to meet the need of pure water in our planet and maintain sustainability.
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Dongwei Wang, Faqiang Li, Yang Zhao, Fanyu Wang and Wei Jiang
This paper aims to study the tribological characteristics of the electrical contact system under different displacement amplitudes.
Abstract
Purpose
This paper aims to study the tribological characteristics of the electrical contact system under different displacement amplitudes.
Design/methodology/approach
First, the risk frequency of real nuclear safety distributed control system (DCS) equipment is evaluated. Subsequently, a reciprocating friction test device which is characterized by a ball-on-flat configuration is established, and a series of current-carrying tribological tests are carried out at this risk frequency.
Findings
At risk frequency and larger displacement amplitude, the friction coefficient visibly rises. The reliability of the electrical contact system declines as amplitude increases. The wear morphology analysis shows that the wear rate increases significantly and the degree of interface wear intensifies at a larger amplitude. The wear area occupied by the third body layer increases sharply, and the appearance of plateaus on the surface leads to the increase of friction coefficient and contact resistance. EDS analysis suggests that oxygen elements progressively arise in the third layer as a result of increased air exposure brought on by larger displacement amplitude.
Originality/value
Results are significant for recognizing the tribological properties of electrical connectors in nuclear power control systems.
Peer review
The peer review history for this article is available at: https://publons.com/publon/10.1108/ILT-03-2024-0098/
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Ali Hassanzadeh, Ebrahim Ghorbani Kalhor, Khalil Farhadi and Jafar Abolhasani
This study aims to investigate the efficacy of Ag@GO/Na2SiO3 nanocomposite in eliminating As from aqueous solutions. Employing response surface methodology, the research…
Abstract
Purpose
This study aims to investigate the efficacy of Ag@GO/Na2SiO3 nanocomposite in eliminating As from aqueous solutions. Employing response surface methodology, the research systematically examines the adsorption process.
Design/methodology/approach
Various experimental parameters including sample pH, contact time, As concentration and adsorbent dosage are optimized to enhance the As removal process.
Findings
Under optimized conditions, the initial As concentration, contact time, pH and adsorbent dosage are determined to be 32 ppm, 50 mins, 6.5 and 0.4 grams, respectively. While the projected removal of As stands at 97.6% under these conditions, practical application achieves a 93% removal rate. Pareto analysis identifies the order of significance among factors as follows: adsorbent dosage > contact time > pH > As concentration.
Practical implications
This study highlights the potential Ag@GO/Na2SiO3 as a promising adsorbent for efficiently removing industrial As from aqueous solutions, and it is likely to have a good sufficiency in the filtration of water and wastewater treatment plans to remove some chemical pollution, including paints and heavy metals.
Originality/value
The simplicity of the nanocomposite preparation method without the need for advanced equipment and the cheapness of the raw materials and its potential ability to remove As are the prominent advantages of this research.
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Sirisha Deepthi Sornapudi, Meenu Srivastava, Srinivas Manchikatla, Samuel Thavaraj H. and Senthil Kumar B.
Natural extracts produced with Annona squamosa and Moringa oleifera leaves through the methanol-based solvent were coated on 100% cotton and 80%:20% polyester/cotton blends to…
Abstract
Purpose
Natural extracts produced with Annona squamosa and Moringa oleifera leaves through the methanol-based solvent were coated on 100% cotton and 80%:20% polyester/cotton blends to improve the functional properties such as antimicrobial activity, wicking, stiffness and crease recovery of the fabric using an eco-friendly 1,2,3,4-butane tetracarboxylic acid (BTCA) crosslinking agent.
Design/methodology/approach
In this study, 100% cotton and 80:20% Polyester/Cotton fabrics with surface densities of 113.5 g/m2 and 101 g/m2 were treated BTCA. Eight different samples were produced by padding through the natural extracts. The FTIR investigation was performed on all the fabric samples. These coated fabrics were studied for their antimicrobial activity, wicking, stiffness and crease recovery properties.
Findings
It was found that the BTCA cross-linked fabrics showed higher antimicrobial activity against gram-positive and gram-negative bacteria. Similarly, the percentage crease recovery angle was higher for the Annona squamosa coated sample than for Moringa Oleifera leaf extract in both cotton and polyester cotton blend samples. Furthermore, no significant variation in stiffness values was discovered between the control samples of cotton and polyester cotton blend and its treatment one. It was interesting to note that treating the fabrics with cross-linker showed improved vertical wicking properties, which were closer to control fabric values. The study confirms that crosslinking the fabrics with BTCA has improved the functional properties of the fabrics. The zone of inhibition values of BTCA cross-linked moringa methanolic leaves extract coated cotton and polyester cotton blend were 6 to 6.5 cm, which was more than 50% higher than non-BTCA cross-linked fabric, and BTCA cross-linker has improved the vertical wicking properties.
Research limitations/implications
The outcome of this study will help to gain a better understanding of BTCA cross-linkers for improving the functional coating on textile substrates.
Originality/value
This study was conducted to improve the natural extract coating on textile material with eco-friendly aspects, enhancing the commercial utility of these finished fabrics
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Amin Reihani, Fatemeh Shaki and Ala Azari
Acrylamide (AA) is predominantly used as a synthetic substance within various industries. However, AA is also recognized as a carcinogen. Zinc oxide nanoparticles (ZnO-NPs) are…
Abstract
Purpose
Acrylamide (AA) is predominantly used as a synthetic substance within various industries. However, AA is also recognized as a carcinogen. Zinc oxide nanoparticles (ZnO-NPs) are becoming increasingly attractive as medical agents. However, to the knowledge, the effects of ZnO-NPs on preventing cytotoxicity with AA have not been reported. Therefore, this study aims to determine the protective effects of ZnO-NPs against the cytotoxicity caused by AA.
Design/methodology/approach
MTT assay was used to determine the cytotoxicity. Reactive oxygen species (ROS) formation, carbonyl protein, malondialdehyde (MDA) and glutathione (GSH) were measured and analyzed statistically.
Findings
The findings observed that the presence of 200 µM AA led to a substantial reduction in cell viability (p < 0.001). However, ZnO-NPs restored cell viability at 50 and 100 µM concentrations (p = 0.0121 and p = 0.0011, respectively). The levels of ROS were significantly reduced (p = 0.001 and p = < 0.001) to 518 ± 47.57 and 364 ± 47.79, respectively, compared to the AA group. The levels of GSH were significantly increased (p = 0.004 and p = 0.002) to 16.9 ± 1.3 and 17.6 ± 0.5, respectively, compared to the AA group. The levels of MDA were significantly decreased (p = 0.005, p < 0.001 and p < 0.001) when compared to the AA group, as were the levels of carbonyl protein (p = 0.009 and p < 0.002) in comparison to the AA group.
Originality/value
In summary, the outcomes of this research indicate that ZnO-NPs played a role in inhibiting AA-induced oxidative stress and cytotoxicity.
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Sagar H. Mane, Tushar S. Wagh, Gotan H. Jain and Madhavrao K. Deore
The study aims to develop an inexpensive metal oxide semiconductor gas sensor with high sensitivity, excellent selectivity for a specific gas and rapid response time.
Abstract
Purpose
The study aims to develop an inexpensive metal oxide semiconductor gas sensor with high sensitivity, excellent selectivity for a specific gas and rapid response time.
Design/methodology/approach
This study synthesized Zn2SnO4 nanostructures using a hydrothermal method with a 1 M concentration of zinc chloride (ZnCl2) as the zinc source and a 0.7 M concentration of tin chloride (SnCl4) as the tin source. Thick films of nanostructured Zn2SnO4 were then produced using screen printing. The structural properties of Zn2SnO4 were confirmed using X-ray diffraction, and the formation of Zn2SnO4 nanoparticles was verified by transmission electron microscopy. Scanning electron microscopy was used to analyse the surface morphology of the fabricated material, while energy dispersive spectroscopy provided insight into the chemical composition of the thick film. These fabricated thick films underwent testing for various hazardous gases, including nitrogen dioxide, ammonia, hydrogen sulphide (H2S), ethanol and methanol.
Findings
The nanostructured Zn2SnO4 thick film sensor demonstrates a notable sensitivity to H2S gas at a concentration of 500 ppm when operated at 160°C. Its selectivity, response time and recovery time were assessed and documented.
Research limitations/implications
The primary limitations of this research on metal oxide semiconductor gas sensors include poor selectivity to specific gases, limited durability and challenges in achieving detection at room temperature.
Practical implications
The nanostructured Zn2SnO4 thick film sensor demonstrates a strong response to H2S gas, making it a promising candidate for commercial production. The detection of H2S is crucial in various sectors, including industries and sewage plants, where monitoring this gas is essential.
Social implications
Currently, heightened global apprehension about atmospheric pollution stems from the existence of perilous toxic and flammable gases. This underscores the imperative need for monitoring such gases. Toxic and flammable gases are frequently encountered in both residential and industrial environments, posing substantial hazards to human health. Noteworthy accidents involving flammable gases have occurred in recent years. It is crucial to comprehend the presence and composition of these gases in the surroundings for precise detection, measurement and control. Thus, there has been a significant push for extensive research and development in diverse sensor technologies using various materials and methodologies to monitor and regulate these gases effectively.
Originality/value
In this research, Zn2SnO4 nanostructures were synthesized using a hydrothermal method with ZnCl2 at a concentration of 1 M for zinc and SnCl4 at a concentration of 0.7 M for tin. Thick films of nanostructured Zn2SnO4 were then fabricated via screen printing technique. Following fabrication, all thick films were subjected to testing with various toxic gases, and the results were compared to previously published data. The analysis indicated that the nanostructured Zn2SnO4 thick film sensor demonstrated outstanding performance concerning gas response, gas concentration, selectivity and response time, particularly towards H2S gas.
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