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1 – 10 of 219Saeed Bastani, Mojtaba Jalili, Mehdi Ghahari and Parand Banihashem
This study aims to investigate the effect of trisodium nitrilotriacetic acid (NTA) on the physical and luminescence emission properties of NaLuF4:Yb, Tm Upconversion (UC…
Abstract
Purpose
This study aims to investigate the effect of trisodium nitrilotriacetic acid (NTA) on the physical and luminescence emission properties of NaLuF4:Yb, Tm Upconversion (UC) particles and compared with trisodium citrate (CA). Upconversion materials have been remarkably considered in many applications in the past decades. However, the morphology of the UC particles affects their emission properties, depending on the synthesis situation.
Design/methodology/approach
The UC particles were synthesized by the hydrothermal method. Properties such as crystal phase, particle morphology, particle size, smoothness and uniformity of particle surface and their emission intensity in the UV–Vis region were studied.
Findings
Observations showed that pH is an essential factor in determining the crystalline phase. In addition, quality factors affect the morphology, particle size and surface smoothness of crystalline facets. It was also found that the UC particles synthesized in the presence of trisodium NTA have a much higher emission intensity than those synthesized in the presence of CA. The use of UC particles in security inks to maintain the brand was also investigated.
Originality/value
To the best of the authors’ knowledge, for the first time, the effect of trisodium NTA as a chelating agent was investigated on morphology and UC intensity of NaLuF4:Yb,Tm phosphor.
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Iresha Herath, Ishanie Perera and Champika Hettiarachchi
Use of highly dye doped nano composite for organic pollutant degradation.
Abstract
Purpose
Use of highly dye doped nano composite for organic pollutant degradation.
Design/methodology/approach
One-pot synthesis of titanium nano-particles were carried out in the presence of N719 dye.
Findings
High dye doping and exceptional dye degradation efficiency was observed. Within 25 min, 99 per cent of methylene blue was removed from waste water.
Originality/value
A novel one-pot synthesis of the composite was introduced.
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Syafiqah Ishak, Shazlina Johari, Muhammad Mahyiddin Ramli and Darminto Darminto
This review aims to give an overview about zinc oxide (ZnO) based gas sensors and the role of doping in enhancing the gas sensing properties. Gas sensors based on ZnO thin film…
Abstract
Purpose
This review aims to give an overview about zinc oxide (ZnO) based gas sensors and the role of doping in enhancing the gas sensing properties. Gas sensors based on ZnO thin film are preferred for sensing applications because of their modifiable surface morphology, very large surface-to-volume ratio and superior stability due to better crystallinity. The gas detection mechanism involves surface reaction, in which the adsorption of gas molecules on the ZnO thin film affects its conductivity and reduces its electrical properties. One way to enhance the gas sensing properties is by doping ZnO with other elements. A few of the common and previously used dopants include tin (Sn), nickel (Ni) and gallium (Ga).
Design/methodology/approach
In this brief review, previous works on doped-ZnO formaldehyde sensing devices are presented and discussed.
Findings
Most devices provided good sensing performance with low detection limits. The reported operating temperatures were within the range of 200̊C –400̊C. The performance of the gas sensors can be improved by modifying their nanostructures and/or adding dopants.
Originality/value
As of yet, a specific review on formaldehyde gas sensors based on ZnO metal semiconductors has not been done.
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Wenhai Tan, Yichen Zhang, Yuhao Song, Yanbo Ma, Chao Zhao and Youfeng Zhang
Aqueous zinc-ion battery has broad application prospects in smart grid energy storage, power tools and other fields. Co3O4 is one of the ideal cathode materials for water zinc-ion…
Abstract
Purpose
Aqueous zinc-ion battery has broad application prospects in smart grid energy storage, power tools and other fields. Co3O4 is one of the ideal cathode materials for water zinc-ion batteries due to their high theoretical capacity, simple synthesis, low cost and environmental friendliness. Many studies were concentrated on the synthesis, design and doping of cathodes, but the effect of process parameters on morphology and performance was rarely reported.
Design/methodology/approach
Herein, Co3O4 cathode material based on carbon cloth (Co3O4/CC) was prepared by different temperatures hydrothermal synthesis method. The temperatures of hydrothermal reaction are 100°C, 120°C, 130°C and 140°C, respectively. The influence of temperatures on the microstructures of the cathodes and electrochemical performance of zinc ion batteries were investigated by X-ray diffraction analysis, scanning electron microscopy, cyclic voltammetry curve, electrochemical charging and discharging behavior and electrochemical impedance spectroscopy test.
Findings
The results show that the Co3O4/CC material synthesized at 120°C has good performance. Co3O4/CC nanowire has a uniform distribution, regular surface and small size on carbon cloth. The zinc-ion battery has excellent rate performance and low reaction resistance. In the voltage range of 0.01–2.2 V, when the current density is 1 A/g, the specific capacity of the battery is 108.2 mAh/g for the first discharge and the specific capacity of the battery is 142.6 mAh/g after 60 charge and discharge cycles.
Originality/value
The study aims to investigate the effect of process parameters on the performance of zinc-ion batteries systematically and optimized applicable reaction temperature.
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Grazielle de Oliveira Setti, Marcelo Fernandes de Oliveira, Izaque Alves Maia, Jorge Vicente Lopes da Silva and Ednan Joanni
This paper aims to demonstrate the functionalization of polyamide parts made by selective laser sintering (SLS) for application as substrates for chemical analysis by…
Abstract
Purpose
This paper aims to demonstrate the functionalization of polyamide parts made by selective laser sintering (SLS) for application as substrates for chemical analysis by surface-enhanced Raman scattering (SERS).
Design/methodology/approach
Fabrication of Nylon 12 (Duraform PA®) samples using two laser power levels and deposition of a layer of gold-coated zinc oxide nanostructures. Performance of these substrates in the detection of a known compound was tested by Raman spectroscopy.
Findings
The hydrothermal synthesis proved to be a good method for functionalizing the surface of polyamide parts made by the SLS process. By varying the synthesis temperature, ZnO nanoparticles and nanorods attached to the sample surfaces could be obtained. The degree of sample sintering had an effect on the growth of the nanostructures. The gold-coated functionalized surfaces enhanced the Raman signal from crystal violet by more than three orders of magnitude. ZnO nanorods grown on well-sintered SLS parts showed the best performance from the set of samples tested in this work.
Originality/value
ZnO nanostructures were grown directly on untreated surfaces of SLS-made polyamide. These substrates were used for chemical analysis by SERS.
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Aminu Muhammad, Sabah M. Mohammad, Zainuriah Hassan, Suvindraj Rajamanickam, Shireen Mohammed Abed and M.G.B. Ashiq
The purpose of this study is to dope silver (Ag) and fluorine (F) in zinc oxide (ZnO) for the enhancement of electrical and optical properties of ZnO, as previous studies reported…
Abstract
Purpose
The purpose of this study is to dope silver (Ag) and fluorine (F) in zinc oxide (ZnO) for the enhancement of electrical and optical properties of ZnO, as previous studies reported the improvement of these properties using individual doping of F and Ag. In this paper, F and Ag co-doped ZnO nanorods were synthesized using a modified hydrothermal method.
Design/methodology/approach
The hydrothermal method was modified and used for the synthesis of the doped ZnO nanostructures, where stainless autoclave and oven were replaced with the Duran laboratory bottle and water boiler system in the process. The ultraviolet metal-semiconductor-metal photodetector (PD) was fabricated using DC sputtering method.
Findings
Vertically aligned nanorods images were captured from field emission scanning electron microscopy. XPS analysis confirmed greater spin-orbital interaction in the F and Ag co-doped ZnO sample and revealed the presence of F, Ag, Zn and O in the samples, indicating a successful doping process. X-ray diffraction revealed a hexagonal wurtzite structure with enhanced crystal quality upon co-doping. The bandgap decreased from 3.19 to 3.14 eV upon co-doping because of reduced defects density in the sample. Finally, an ultra-violet PD was fabricated with enhanced sensitivity and response times upon co-doping.
Originality/value
The low-cost, less energy-consuming Duran laboratory bottle and water boiler system were used as the substitute of expensive, more energy-consuming stainless autoclave and oven in a hydrothermal method for synthesis of F and Ag co-doped ZnO and subsequent fabrication of PD.
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Swapan K. Bhattacharya, P. Markondeya Raj, Devarajan Balaraman, Hitesh Windlass and Rao R. Tummala
This paper addresses materials and processes for printed wiring board compatible embedded capacitors using polymer/ceramic nanocomposites and hydrothermal barium titanate…
Abstract
This paper addresses materials and processes for printed wiring board compatible embedded capacitors using polymer/ceramic nanocomposites and hydrothermal barium titanate. Polymers allow low temperature fabrication appropriate to the board (MCM‐L) technology. The lower dielectric constants of the commercially available polymers can be greatly compensated by incorporating higher permittivity ceramic fillers. Materials requirements for higher capacitance density (>30 nF/cm2) have been addressed through implementation of a novel low‐temperature processable hydrothermal barium titanate film on a patterned titanium foil laminated to the PWB. Application of hydrothermal grown barium titanate is currently being evaluated using a multi‐layer system‐on‐package demonstration.
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Suparna Banerjee and Prosenjit Mukherjee
Nanotechnology is nowadays very much successful in producing specifically functionalized nano-sized particles. In this work, copper nanoparticles were prepared by reduction method…
Abstract
Nanotechnology is nowadays very much successful in producing specifically functionalized nano-sized particles. In this work, copper nanoparticles were prepared by reduction method which is greener and environmentally suitable, cheap and best as compared to other conventional methods, particularly in the context of COVID in globalized world. The formation and size of copper nanoparticles was evidenced by the X-ray diffraction and transmission electron microscopy. The very high surface area of 35–50 m2/gm and very small crystallite sizes of 5–15 nm of these metal nanoparticles is mainly responsible for their effective involvement in removal of carbon dioxide gas as one of major hazardous pollutants from the environment. This chapter, as its main objective, mainly focuses on utility of nano technology and its beneficiary in creating a sustainable environment in economic world. Apart from laboratory experimental procedure and characterizations for preparation of copper nanoparticles, appropriate research methods such as simple statistical, econometric tools and mathematical tools have been used for economic analysis. However, as major findings of the results, developed countries have been successful in maintaining a sustainable human development, in spite of having higher per capita income (PCI) growth as compared to the role of developing countries with lower PCI in this global world.
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Srinivas Rao Sriram, Saidireddy Parne, Venkata Satya Chidambara Swamy Vaddadi, Damodar Edla, Nagaraju P., Raji Reddy Avala, Vijayakumar Yelsani and Uday Bhasker Sontu
This paper aims to focus on the basic principle of WO3 gas sensors to achieve high gas-sensing performance with good stability and repeatability. Metal oxide-based gas sensors are…
Abstract
Purpose
This paper aims to focus on the basic principle of WO3 gas sensors to achieve high gas-sensing performance with good stability and repeatability. Metal oxide-based gas sensors are widely used for monitoring toxic gas leakages in the environment, industries and households. For better livelihood and a healthy environment, it is extremely helpful to have sensors with higher accuracy and improved sensing features.
Design/methodology/approach
In the present review, the authors focus on recent synthesis methods of WO3-based gas sensors to enhance sensing features towards toxic gases.
Findings
This work has proved that the synthesis method led to provide different morphologies of nanostructured WO3-based material in turn to improve gas sensing performance along with its sensing mechanism.
Originality/value
In this work, the authors reviewed challenges and possibilities associated with the nanostructured WO3-based gas sensors to trace toxic gases such as ammonia, H2S and NO2 for future research.
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Shireen Mohammed Abed, Sabah M. Mohammad, Zainuriah Hassan, Aminu Muhammad and Suvindraj Rajamanickam
The purpose of this study is to fabricate an ultraviolet (UV) metal-semiconductor-metal (MSM) photodetector based on zinc oxide nanorods (ZnO NRs) grown on seeded silicon (Si…
Abstract
Purpose
The purpose of this study is to fabricate an ultraviolet (UV) metal-semiconductor-metal (MSM) photodetector based on zinc oxide nanorods (ZnO NRs) grown on seeded silicon (Si) substrate that was prepared by a low-cost method (drop-casting technique).
Design/methodology/approach
The drop-casting method was used for the seed layer deposition, the hydrothermal method was used for the growth of ZnO NRs and subsequent fabrication of UV MSM photodetector was done using the direct current sputtering technique. The performance of the fabricated MSM devices was investigated by current–voltage (I–V) measurements. The photodetection mechanism of the fabricated device was discussed.
Findings
Semi-vertically high-density ZnO (NRs) were effectively produced with a preferential orientation along the (002) direction, and increased crystallinity is confirmed by X-ray diffraction analysis. Photoluminescence results show a high UV region. The fabricated MSM UV photodetector showed that the ZnO (NRs) MSM device has great stability over time, high photocurrent, good sensitivity and high responsivity under 365 nm wavelength illumination and 0 V, 1 V, 2 V and 3 V applied bias. The responsivity and sensitivity for the fabricated ZnO NRs UV photodetector are 0.015 A W-1, 0.383 A W-1, 1.290 A W-1 and 1.982 A W-1 and 15,030, 42.639, 100.173 and 334.029, respectively, under UV light (365 nm) illumination at (0 V, 1 V, 2 V and 3 V).
Originality/value
This paper uses the drop-casting technique and the hydrothermal method as simple and low-cost methods to fabricate and improve the ZnO NRs photodetector.
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