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The purpose of this study is to improve the mechanical properties, thermal insulation properties and flame retardant properties of polyethylene terephthalate (PET), the organic montmorillonite (OMMT)/SiO₂ aerogel/PET composites and fibers were prepared, and the effects of the OMMT/SiO₂ aerogel on the structure, thermal conductivity and flame retardance of the OMMT/SiO₂ aerogel/PET composites and their fibers were systematically investigated.

The OMMT/SiO₂ aerogel/PET composites and fibers were prepared by in-situ polymerization and melt spinning using SiO₂ aerogel as thermal insulation filler and OMMT (DK2) as comodified filler.

The experimental results showed that OMMT improved the crystallization properties of PET. Compared with the crystallinity of SiO₂ aerogel/PET composites (34.8%), SiO₂ aerogel/PET composites and their fibers reached 45.1% and 49.2%, respectively. The breaking strength of the OMMT/SiO₂ aerogel/PET composite fibers were gradually increased with the OMMT content. When the content of OMMT was 0.8 wt.%, the fracture strength of the composite fibers reached 4.40 cN/dtex, which was 54% higher than that of the SiO₂ aerogel/PET fiber. In addition, the thermal insulation properties of the composites and their fibers were improved by addition of fillers, and at the same time reached the flame retardant level. The thermal conductivity of the 0.8 wt.% OMMT/SiO₂ aerogel/PET composites was 101.78 mW/(m·K), which was 49.3% and 58.8% lower than that of the SiO₂ aerogel/PET composites and the pure PET, respectively. The thermal conductivity of the fiber fabrics woven from the 0.8 wt.% OMMT/SiO₂ aerogel/PET composites was 28.18 mW/(m·K), which was 29.0% and 44.6% lower than that of the SiO₂ aerogel/PET composite fiber fabrics and PET fiber fabrics. The flame retardancy of the composites was improved, with an limiting oxygen index value of 29.2% for the 0.8 wt.% OMMT/SiO₂ aerogel/PET composites, which was 4.1% higher compared to the SiO₂ aerogel/PET composites, and achieved the flame retardant level.

The SiO₂ aerogel/PET composites and their fibers have good mechanical properties, flame retardant properties and thermal insulation properties, exhibited good potential for application in the field of thermal insulation, such as warm clothing. Nowadays, as the energy crisis is becoming more and more serious, it is very important to improve the thermal insulation properties of PET to reduce energy losses and mitigate the energy crisis.

In this study, PET based composites and their fibers with excellent mechanical properties, thermal insulation properties and flame retardant property were obtained by using three-dimensional network porous silica aerogel with low density and low thermal conductivity as the thermal insulation functional filler and two-dimensional layered OMMT as the synergetic modified filler.

This study aims to evaluate in situ oxidative polymerization of aniline (Ani) as a post-processing method to promote extrusion-based 3D printed parts, made from insulating polymers, to components with functional properties, including electrical conductivity and chemical sensitivity.

Extrusion-based 3D printed parts of polyethylene terephthalate modified with glycol (PETG) and polypropylene (PP) were coated in an aqueous acid solution via in situ oxidative polymerization of Ani. First, the feedstocks were characterized. Densely printed samples were then used to assess the adhesion of polyaniline (PAni) and electrical conductivity on printed parts. The best feedstock candidate for PAni coating was selected for further analysis. Last, a Taguchi methodology was used to evaluate the influence of printing parameters on the coating of porous samples. Analysis of variance and Tukey post hoc test were used to identify the best levels for each parameter.

Colorimetry measurements showed significant color shifts in PP samples and no shifts in PETG samples upon pullout testing. The incorporation of PAni content and electrical conductivity were, respectively, 41% and 571% higher for PETG in comparison to PP. Upon coating, the surface energy of both materials decreased. Additionally, the dynamic mechanical analysis test showed minimal influence of PAni over the dynamic mechanical properties of PETG. The parametric study indicated that only layer thickness and infill pattern had a significant influence on PAni incorporation and electrical conductivity of coated porous samples.

Current literature reports difficulties in incorporating PAni without affecting dimensional precision and feedstock stability. In situ, oxidative polymerization of Ani could overcome these limitations. However, its use as a functional post-processing of extrusion-based printed parts is a novelty.

This study aims to report the development and experimental evaluation of two kinds of PANI@semiconductor based photocathodic anti-corrosion coating, for application on stainless steel substrates.

PANI was in situ chemical polymerized on TiO₂ and BiVO₄ particles, and FT-IR and SEM/EDS were used to understand the characteristics and elemental distribution of the composite particles. Composite coatings, which consisted of epoxy, PANI@TiO₂ or PANI@BiVO₄ and graphene, were prepared on the 304L stainless steel. Photoelectrochemical response measurement, electrochemical tests and immersion tests were used to assess the anti-corrosion performance of the prepared coatings in 45°C 3.5 wt.% NaCl solution. And the corrosion protection mechanism was further explained by combining with surface observation.

The photoelectrochemical response tests revealed the good photocathodic effect of the coatings, and the reversible oxidation-reduction properties of PANI (pseudocapacitive effect) leading to the repeated usage of the coatings. Consequently, the anti-corrosion mechanism of the composite coating is attributed to the physical barrier effect of the coating, the anodic protection effect of PANI and the photocathodic and energy store effect.

These kind coatings could prevent corrosion from day to night for stainless steel, which has great engineering application prospects on stainless steel corrosion protection.

This study aims to explore entropy evaluation in the bi-directional flow of Casson hybrid nanofluids within a stagnated domain, a topic of significant importance for optimizing thermal systems. The aim is to investigate the behavior of unsteady, magnetized and laminar flow using a parametric model based on the thermo-physical properties of alumina and copper nanoparticles.

The research uses boundary layer approximations and the Keller-box method to solve the derived ordinary differential equations, ensuring numerical accuracy through convergence and stability analysis. A comparison benchmark has been used to authenticate the accuracy of the numerical outcomes.

Results indicate that increasing the Casson fluid parameter (ranging from 0.1 to 1.0) reduces velocity, the Bejan number decreases with higher bidirectional flow parameter (ranging from 0.1 to 0.9) and the Nusselt number increases with higher nanoparticle concentrations (ranging from 1% to 4%).

This study has limitations, including the assumption of laminar flow and the neglect of possible turbulent effects, which could be significant in practical applications.

The findings offer insights for optimizing thermal management systems, particularly in industries where precise control of heat transfer is crucial. The Keller-box simulation method proves to be effective in accurately predicting the behavior of such complex systems, and the entropy evaluation aids in assessing thermodynamic irreversibilities, which can enhance the efficiency of engineering designs.

These findings provide valuable insights into the thermal management of hybrid nanofluid systems, marking a novel contribution to the field.

This paper aims to explore the influence of a particular label surface texture, i.e. embossing, on consumer purchase intentions and willingness to pay. This paper further highlights the underlying mechanisms explaining this relationship by unveiling the mediating role of willingness to touch and perceived package uniqueness.

Based on the visual salience theory and the stimulus–organism–response (SOR) model, this paper tests mediations and serial mediations across two online experiments and evidence from a laboratory experiment.

Study 1 reveals perceived package uniqueness as the mediator, such that embossed elements on the label increase perceived uniqueness, hence leading to greater purchase intentions and willingness to pay. In addition, Study 2 replicates these results and goes further by demonstrating the positive effect of embossing on purchase intentions and willingness to pay through willingness to touch then perceived package uniqueness.

The findings provide insightful managerial implications by drawing attention to the importance of using embossed elements on packaging, particularly when companies seek to differentiate themselves from competitors by stimulating consumers to touch their product packaging and having them perceive their products as unique.

Using visual salience theory and the SOR model, this research is, to the best of the authors’ knowledge, the first to shed light on the effect of embossing as a visual element of the packaging design on willingness to touch the product (haptics) and perceived uniqueness, ultimately enhancing purchase intentions and willingness to pay.

This article explores the impacts of the changing land-use on urban heat island (UHI) in an urban transformation zone in Ankara (Türkiye). Identifying a characteristic rural landscape until the 1950s, the study area experienced a drastic land-use change by razing the fertile landscape of the city and replacing it with a sealed surface. Development of the squatter houses after the 1960s and, subsequently, the implementation of a new housing morphology have introduced new sceneries, scales and surface conditions that make the study area a noteworthy case to analyze.

Regarding the drastic spatio-temporal change of the study area, this research assesses the impacts of the changing land-use on UHI based on three periods. Using 1957, 1991 and 2021 aerial imaginaries and maps, it analyzes the temperature alteration caused by the changing land-use. To do so, different surface types, green patterns and built-up areas have been modeled using Ankara climatic data and transferred to ENVI-Met to calculate the Universal Thermal Climate Index (UTCI) values.

The calculation has been developed over a transect covering an area of 40 m × 170 m, which includes diversity in terms of architecture, landscape and open space elements. To encourage future design strategies, the research findings deliberate into three extents that discuss the lacking climate knowledge in the ongoing urban transformation projects: impervious surface ratio and regional albedo variation, changing aspect ratio and temperature variation at the pedestrian level.

Urban transformation projects, being countrywide operations in Türkiye, need to cover climate-informed design strategies. Herein, the article underlines the critical position of design decisions in forming a climate-informed urban environment. Dwelling on a typical model of housing transformation in Türkiye, the research could trigger climate-informed urban development strategies in the country.

Thermophoresis deposition of particles is a crucial stage in the spread of microparticles over temperature gradients and is significant for aerosol and electrical technologies. To track changes in mass deposition, the effect of particle thermophoresis is therefore seen in a mixed convective flow of Williamson hybrid nanofluids upon a stretching/shrinking sheet.

The PDEs are transformed into ordinary differential equations (ODEs) using the similarity technique and then the bvp4c solver is employed for the altered transformed equations. The main factors influencing the heat, mass and flow profiles are displayed graphically.

The findings imply that the larger effects of the thermophoretic parameter cause the mass transfer rate to drop for both solutions. In addition, the suggested hybrid nanoparticles significantly increase the heat transfer rate in both outcomes. Hybrid nanoparticles work well for producing the most energy possible. They are essential in causing the flow to accelerate at a high pace.

The consistent results of this analysis have the potential to boost the competence of thermal energy systems.

It has not yet been attempted to incorporate hybrid nanofluids and thermophoretic particle deposition impact across a vertical stretching/shrinking sheet subject to double-diffusive mixed convection flow in a Williamson model. The numerical method has been validated by comparing the generated numerical results with the published work.

This study compares the fatigue performance and biocompatibility of as-built and chemically etched Ti-6Al-4V alloys in TPMS-gyroid and stochastic structures fabricated via Powder Bed Fusion Laser Beam (PBF-LB). This study aims to understand how complex lattice structures and post-manufacturing treatment, particularly chemical etching, affect the mechanical properties, surface morphology, fatigue resistance and biocompatibility of these metamaterials for biomedical applications.

Selective Laser Melting (SLM) technology was used to fabricate TPMS-gyroid and Voronoi stochastic designs with three different relative densities (0.2, 0.3 and 0.4) in Ti-6Al-4V ELI alloy. The as-built samples underwent a chemical etching process to enhance surface quality. Mechanical characterization included static compression and dynamic fatigue testing, complemented by scanning electron microscopy (SEM) for surface and failure analysis. The biocompatibility of the samples was assessed through in-vitro cell viability assays using the Alamar Blue assay and cell proliferation studies.

Chemical etching significantly improves the surface morphology, mechanical properties and fatigue resistance of both TPMS-gyroid and stochastic structures. Gyroid structures demonstrated superior mechanical performance and fatigue resistance compared to stochastic structures, with etching providing more pronounced benefits in these aspects. In-vitro biocompatibility tests showed high cytocompatibility for both as-built and etched samples, with etched samples exhibiting notably improved cell viability. The study also highlights the importance of design and post-processing in optimizing the performance of Ti64 components for biomedical applications.

The comparative analysis between as-built and etched conditions, alongside considering different lattice designs, provides valuable information for developing advanced biomedical implants. The demonstration of enhanced fatigue resistance and biocompatibility through etching adds significant value to the field of additive manufacturing, suggesting new avenues for designing and post-processing implantable devices.

This study aims to explore the synthesis and tribological performances of di-n-octyl sebacate (DOS) synthesized with spherical nano-MoS₂/sericite (SMS) and carboxylated SMS (CSMS) as catalysts.

SMS and CSMS were used as esterification catalysts to synthesize DOS from sebacic acid and n-octanol. The two catalysts were in situ dispersed in the synthesized DOS after the reaction to form suspensions. The tribological performances of the two suspensions after 20 days of storage were studied.

CSMS was more stably dispersed in DOS than SMS, and they reduced friction by 55.6% and 22.2% and wear by 51.3% and 56.5%, respectively. Such results were mainly caused by the COOH on CSMS, which was more conducive to improving the dispersion and friction reduction of CSMS than wear resistance. Another possible reason was the difference between the dispersion amounts of CSMS and SMS in DOS. The sericite of SMS was converted into SiO₂ to enhance wear resistance, while that of CSMS only partially generated SiO₂, and the rest still remained on the surface to reduce friction.

This work provides a more effective SMS catalytical way for DOS synthesis than the traditional inorganic acid catalytical method. SMS does not need to be separated after reaction and can be dispersed directly in DOS as a lubricant additive. Replacing SMS with CSMS can produce a more stable suspension and reduce friction significantly. This work combined the advantages of surface carboxylation modification and in situ catalytic dispersion and provided alternatives for the synthesis of DOS and the dispersion of MoS₂-based lubricant additives.

To improve the corrosion resistance of magnesium alloys, the construction of protective coatings is necessary to extend the service life of Mg-based materials.

SiO₂ nanoparticles modified by dodecyltrimethoxysilane (DTMS) were added to the PP and a superhydrophobic Mg(OH)₂/PP-60mSiO₂ composite coating was fabricated on the surface of AZ31 magnesium alloy via the hydrothermal method and subsequently the immersion treatment.

Hydrophilic SiO₂ nanoparticles become hydrophobic after modified by DTMS, showing a higher dispersibility in xylene. By incorporating modified SiO₂ nanoparticles into the composite PP coating, the hydrophobicity of the layer was enhanced, resulting in a contact angle of 166.3° and a sliding angle of 3.4°. It also improved the water repellency and durability of the coating. Furthermore, the intermediate layer of Mg(OH)₂ significantly strengthened the bond between the PP layer and the substrate. The Mg(OH)₂/PP-60mSiO₂ composite coating significantly enhances the corrosion resistance of the magnesium alloy by effectively blocking the infiltration of the corrosion anions during corrosion. The corrosion current density of the Mg(OH)₂/PP-60mSiO₂ composite coating is approximately 8.23 × 10^–9 A·cm^-2, which can achieve a magnitude three times lower than its substrate, making it a promising surface modification for the Mg alloy.

The composite coating effectively and durably enhances the corrosion resistance of magnesium alloys.