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The purpose of this paper is to produce cobalt (Co)-based thin films by metalorganic chemical vapor deposition (CVD) technique and then to evaluate structural and mechanical integrity.

Co-based thin films were produced by metalorganic CVD technique. Boronizing, carburization and nitridation of the produced Co thin films were accomplished through a post-treatment stage of thermal diffusion into as-deposited Co thin films, in order to produce cobalt boride (Co₂B), cobalt carbide and cobalt nitride thin films in the surface layer of Co. The surface topography and the crystal structure of the produced thin films were evaluated through scanning electron microscopy and X-ray diffraction, respectively. The mechanical integrity of the produced thin films was evaluated through nanoindentation technique.

The obtained results indicate that Co₂B thin film exhibits the highest nanomechanical properties (i.e. H and E), while Co thin film has enhanced plasticity. The cobalt oxide thin film exhibits higher resistance to wear in comparison to the cobalt thin film, a fact that is confirmed by the nanoscratch analysis showing lower coefficient of friction for the oxide.

This work is original.

Nature provides a wide range of structures with different functions, which can serve as a source of research concepts. Based on the bionics principle, a bionic structure was applied to drill pipe specimens to compare the bond strength of paint coatings with and without a bionic ring groove pattern machined on the substrate.

Using the Revetest Xpress Plus scratch tester, the bond strengths of the coatings on the drill pipe with and without the bionic structure were measured and the difference in bond strength was observed.

The critical scratch loads of the surface coatings were 12.77 and 5.4 N. Furthermore, the scratch curve from the plain sample had a larger fluctuation compared to the curve of the samples with bionic ring grooves.

This indicated that the application of a bionic pattern to the surface of the substrate could enhance the bond strength and the degree of mechanical adhesion between the coating and the surface of the drill pipe, which is beneficial for the anti-corrosion performance of the drill pipe.

The wear of an abrasive single-crystal diamond (SCD) grit affects the machining quality of the sapphire wafer. This paper aims to investigate the influence of crystallographic orientation on the wear characteristics of SCD grit scratching on sapphire.

The wear characteristics of two SCD grits (SCD100 and SCD111) with different crystallographic orientations were systematically investigated. The wear mechanism involved in the scratching process was explored. The wear morphology, scratching forces and friction coefficient during the scratching process were measured and analyzed.

The experiment results show that the wear progress of the two SCD grits is obviously different. The wear resistance of SCD111 grit is greater than that of SCD100 grit in normal wear stage. However, the SCD100 grit could remove more sapphire material than SCD111 grit. The SCD grits mainly sustain extrusion stress and shear stress during scratching on sapphire. The crystallographic orientation of SCD grits plays a significant role in the wear progress during scratching on sapphire.

The results of the experimental studies could provide a theoretical foundation for improving the fabrication of abrasive diamond tools.

This paper aims to present a methodology, based on traditional approaches, to predict the fatigue life and non‐propagating cracks of shot peened components and the damaging effect of a scratch created over the treated surface.

The finite element method is used to determine the actual strain at surface and fracture mechanics parameters calculated from cracks at the surface. The model considers residual stress (in order to introduce the effect of shot peening) and the scratch geometry. The total fatigue life is obtained by adding initiation life, to early and long crack propagation life using appropriate criteria.

Numerical predictions were compared with previous experimental tests, showing that this method is quite reliable for predicting both fatigue life and non‐propagating cracks of shot peened components, including the effect of damage due to a scratch.

The proposed method provides good results and a clear understanding of the fatigue process, however it requires a considerable amount of both material and shot peening parameters.

The methodology presented in this paper allows the determination of fatigue life and the prediction of non‐propagating cracks for components, including the effects of shot peening and scratch damage. These results can be used to quantify the scratch damage limits of components improved by shot peening.

This paper provides a useful tool for prediction of the effects of shot peening and scratch damage on fatigue life, using traditional approaches.

In order to study whether far-infrared fabrics can be used as a garment for breast cancer patients, or as an adjuvant rehabilitation underwear for breast cancer patients after postoperative radiotherapy and chemotherapy, to eliminate tissue edema. To explore the effect of different far-infrared fabrics on the proliferation and invasion of breast cancer cells as a basic in vitro study.

Six kinds of fabrics of the same specification with different far-infrared nanoparticles were selected. MCF7 and Bcap37 breast cancer cells were used to study the effect of far-infrared fabrics on cell proliferation and invasion. Six kinds of far-infrared fabrics were used to culture breast cancer cells and explore their effects on breast cancer cell growth and the difference between different far-infrared fabrics.

It is found that the far-infrared emissivity of six kinds of fabrics are different, among which tea carbon fabric is the highest, followed by volcanic fabric, graphene fabric and biomass graphene fabric are the lowest. The results show that the far-infrared fabrics can significantly inhibit the proliferation and invasion of breast cancer cells, the higher the far-infrared emissivity is, and the longer the time of far-infrared radiation, the more significant the inhibition effect is.

Far-infrared fabrics can inhibit proliferation and invasion of breast cancer cells in vitro. Therefore, far-infrared fabrics can be used for adjuvant rehabilitation of breast cancer patients. This conclusion provides a basis for the application of far-infrared functional fabrics in the medical field. This conclusion provides a basis for the application of far-infrared functional fabrics in medical field.

The paper explores the pattern of early closure risks for worker cooperatives, whether this pattern involves a “liability of newness” or a “liability of adolescence” and whether it applies identically to coops created from scratch, to rescues of failing firms and to conversions from sound conventional businesses to the cooperative form. Non-parametric hazard curves are estimated using data on the 2,740 worker cooperatives created in France in 1977–1993, 1,660 of which exited during the period. Comparisons are drawn with conventional French firms whenever data for the same cohorts are available.

This paper aims to assess the adsorption behaviour and the adhesion strength of lubricant films formed by polypropylene oxide-polyethylene oxide-polypropylene oxide (PPO-PEO-PPO) with phosphate ester additive on Ti-coated surface and to identify the influence of molecular architecture and phosphate ester additive.

The thickness of the adsorbed PPO-PEO-PPO with phosphate ester lubricant films on Ti surfaces was measured by ellipsometry. The adhesion strength of the copolymer and the copolymer with phosphate ester lubricants was studied by the micro-scratch tests; the scratch tracks on the surfaces were observed by atomic force microscopy and scanning electronic microscopy.

The copolymer with a higher weight percentage of PPO not only formed a thicker film but also showed stronger adhesion and better lubrication performance. The added phosphate ester increased the film thickness and improved the tribological behaviour. The finding reveals that the adsorbed film thickness which depends on the PPO chain length and the presence of phosphate ester has a considerable effect on the scratch behaviour.

This paper fulfils the studies about adsorption behaviour and lubrication mechanism of this new lubricant which has not been adequately investigated on the metal surface.

To investigate the influence of an organic corrosion inhibitor on the enhanced dissolution of metal, initiated by AFM tip scratching in corrosive media.

The test solutions were 1.5 M NaCl and 0.01 M HCl. AFM tip scratching experiments were performed for Cu‐Ni alloys in solutions with or without 0.005 M dodecylamine. AFM frictional loop tests were also performed to investigate the effect of dodecylamine on the tip‐surface frictional interaction.

Enhanced dissolution of Cu‐Ni alloy was observed as a result of AFM tip scratching both in NaCl and HCl solutions, and in HCl the effect was more severe than was the case in NaCl. Enhanced dissolution was inhibited markedly by adding 0.005 M dodecylamine to the corrosive media. The results of frictional loop tests indicated that frictional interaction between the tip and the alloy surface was diminished by the adsorption of dodecylamine on the sample surface. The weakening of tip‐surface frictional interaction and the elevation of the ionization energy of metal atoms were responsible for the notable inhibition effect of dodecylamine on the accelerated dissolution.

In this paper, the influence of an organic corrosion inhibitor on the corrosion of metal induced by outside forces was investigated. This was carried out initially by AFM scratching skill and the inhibition mechanism of dodecylamine on the enhanced dissolution of Cu‐Ni alloy initiated by AFM tip scratching.

Mechanical wear is the main wear form of abrasive single crystal diamond (SCD) grit. The mechanical wear of SCD grit has a significant influence on the tool life and machining quality. This paper aims to investigate the influence of grit–workpiece contact form on the mechanical wear characteristics of SCD grit.

Three different grit–workpiece contact forms, which involved point/line/face contact forms, are investigated to reveal the wear mechanism of SCD grit scratching on Ta12W. The wear morphology, wear volume and scratching forces are measured, and the stress models of different contact forms are analyzed.

The results show that mechanical wear mainly occurs in the grit–workpiece contact area and increases gradually from contact area to entire SCD grit. The scratching forces vary with the mechanical wear progress of SCD grits. The SCD grit with point contact form is the most prone to produce wear. The SCD grit with face contact form can remove more material volume than the other two SCD grits, and it is the most wear resistant. The stress state is closely related with the mechanical wear of SCD grit. The contact form has a significant influence on the mechanical wear of SCD grit.

The results of this study can provide a theoretical basis for the fabrication of abrasive tools.

The purpose of this paper is to find a new method to evaluate the hydrogen embrittlement performance of heterogeneous materials and thin film materials.

The changes of hydrogen embrittlement properties of steel were studied by electrochemical hydrogen charging test and scratch test. The microstructure and properties of the alloy were analyzed by hardness tester, scanning electron microscope and three-dimensional morphology. The fracture toughness before and after hydrogen charging was calculated based on the scratch method.

The results showed that the hydrogen-induced hardening phenomenon occurs in the material after hydrogen charging. The scratch depth and width increased after hydrogen charging. The fracture toughness obtained by the scratch method showed that hydrogen reduces the fracture toughness of the material. The comparison error of fracture toughness calculated by indentation method was less than 5%.

The results show that the scratch method can evaluate the hydrogen embrittlement performance of the material. This method provides a possibility to evaluate the hydrogen embrittlement of thin-film and heterogeneous materials.