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Damage of aluminium alloy under contact loading is detected in different cases independent of contact configuration and operating conditions. An investigation of two industrial cases is proposed to describe how it is possible to study the material degradation under friction. The experimental simulation of aluminium damage in laboratory conditions is carried out. Two contact configurations are studied in order to reproduce the industrial damage of aluminium alloys. Varying experimental conditions relative to a specific contact body for each test have demonstrated a realistic correlation between damage, test configuration and material properties. Independent of the tribological system, plastic deformation seems to be the major parameter controlling the wear of aluminium alloy under friction in the studied cases.

This paper aims to assess the adsorption behaviour and the adhesion strength of lubricant films formed by polypropylene oxide-polyethylene oxide-polypropylene oxide (PPO-PEO-PPO) with phosphate ester additive on Ti-coated surface and to identify the influence of molecular architecture and phosphate ester additive.

The thickness of the adsorbed PPO-PEO-PPO with phosphate ester lubricant films on Ti surfaces was measured by ellipsometry. The adhesion strength of the copolymer and the copolymer with phosphate ester lubricants was studied by the micro-scratch tests; the scratch tracks on the surfaces were observed by atomic force microscopy and scanning electronic microscopy.

The copolymer with a higher weight percentage of PPO not only formed a thicker film but also showed stronger adhesion and better lubrication performance. The added phosphate ester increased the film thickness and improved the tribological behaviour. The finding reveals that the adsorbed film thickness which depends on the PPO chain length and the presence of phosphate ester has a considerable effect on the scratch behaviour.

This paper fulfils the studies about adsorption behaviour and lubrication mechanism of this new lubricant which has not been adequately investigated on the metal surface.

The purpose of this paper is to find a new method to evaluate the hydrogen embrittlement performance of heterogeneous materials and thin film materials.

The changes of hydrogen embrittlement properties of steel were studied by electrochemical hydrogen charging test and scratch test. The microstructure and properties of the alloy were analyzed by hardness tester, scanning electron microscope and three-dimensional morphology. The fracture toughness before and after hydrogen charging was calculated based on the scratch method.

The results showed that the hydrogen-induced hardening phenomenon occurs in the material after hydrogen charging. The scratch depth and width increased after hydrogen charging. The fracture toughness obtained by the scratch method showed that hydrogen reduces the fracture toughness of the material. The comparison error of fracture toughness calculated by indentation method was less than 5%.

The results show that the scratch method can evaluate the hydrogen embrittlement performance of the material. This method provides a possibility to evaluate the hydrogen embrittlement of thin-film and heterogeneous materials.

The purpose of this study is to design and develop a new functional coating system for aerospace AL7075-T6 alloy that would evaluate the mechanical properties of the coating.

This paper outlines the scratch adhesion characterisation of Cr/CrAlN coating using a combination of radio frequency (RF) and direct current (DC) physical vapour deposition (PVD) magnetron sputtering. The surface morphology, microstructure and chemical composition of the Cr/CrAlN film were evaluated by optical microscopy (OM), field emission scanning electron microscopy (FESEM) integrated with energy-dispersive X-Ray spectroscopy (EDX) and atomic force microscopy (AFM). The film-to-substrate adhesion was measured by a scratch test machine manufactured with a detection system, motorized stages, penetration depth sensors, optical microscope and tangential frictional load sensors.

The AFM and ultra-micro hardness results showed an increase in surface roughness to about 20 per cent and hardness to about 74 per cent. Moreover, the film-to-substrate adhesion strength of 1,814 mN was obtained with PVD deposition process.

The main limitation of this work is caused by PVD deposition process. Besides, surface defects such as pinholes contribute to a decrease in adhesion strength.

The higher hardness of CrAlN coating is used to improve the properties of softer aluminium substrates. This hardness prevents ploughing-induced wear and provides greater adhesion strength by preventing coating delamination.

Until now, CrAlN is coated only on ferrous alloys. It has not yet been tried on aluminium alloys. Moreover, coating functionality depends on higher adhesion and failure mechanisms involved in the film-to-substrate system, which is significant in aerospace applications.

This paper aims to analyse the influence of the thickness of different layers [diamond-like-carbon (DLC) and chromium nitride (CrN)] on the sliding wear behaviour of a multifunctional coating on AISI 1020 substrates. When small and cheap components need to be manufactured in large scale, they are often produced using soft metals, such as unhardened low carbon steels and pure iron.

Two families, one with thicker films and the other with thinner films, were deposited onto a soft carbon steel substrate by plasma-enhanced chemical vapour deposition (PECVD). Reciprocating linear tests with incremental loading assessed the durability of the coatings. In addition, friction coefficient and wear rates of both specimens and counterbodies were measured at a constant load.

Thinner layers presented lower sliding wear rates (four-five times lower) for both specimens and counterbodies, less spalling and protective tribolayers on the wear tracks.

Although multilayered CrN–DLC coatings on relatively hard substrates such as HSS and cemented carbide tools are already a proven technology, much less is known about its deposition on a much softer substrate such as low carbon steel. In previous works, we have analysed the influence of layer thickness on hardness and scratch resistance of the same coatings. This paper presents results for their performance under wear sliding conditions using an original approach (three-dimensional triboscopic maps) for two distinct configurations (increasing load and constant load).

The paper's aim is to synthesise ultraviolet (UV) curable polyurethane acrylate based on polyester polyol and to study change in its mechanical, chemical, optical and weather resistance properties with varying amount of nanosilica. It also seeks to determine its optimum loading levels for property maximisation.

New UV curable polyurethane acrylate has been synthesised using polyester polyol, blend of isophorone diisocyanate and toluene diisocyanate and hydroxyl ethyl acrylate. This resin was incorporated with nanosilica (1‐3 per cent) on the basis of total solids. The newly synthesised material was characterised by fourier transform infrared spectroscopy, gel permeation chromatography, X‐ray diffraction and scanning electron microscopy. The mechanical, chemical and optical properties of the coating films were studied and compared.

The hardness, tensile strength and abrasion resistance show significant enhancement with increasing amount of nanosilica. It is also found that UV cured polyurethane acrylate nanocoating exhibited improved weather resistance. The optimum concentration of nanosilica for better performance is found to be 3 per cent of total solids. The improvement is the result of inherent nature of nanosilica.

Nanosilica used in present context is having 10 nm mean diameter and near about 600 m²/g surface area. Nanosilica having different particle size, surface area and surface modification can be used to improve more specific properties.

Addition of nanosilica particles to polyurethane acrylate coating is a simple and inexpensive method resulting in phenomenal increase in properties.

The new organic‐inorganic hybrid nanocoating with improved weather resistance was synthesised. These coatings could find applications in demanding fields such as automotive topcoats.

The objective of this work was to examine the anticorrosive behaviour of four different epoxy coatings, which were formulated with zinc pigments and were applied on pretreated steel panels exposed to deionised/deaerated water taken from the installations of the Greek Public Electricity Company, as well as to compare the results of this study with those of a relevant, previous work. The coating's performance was assessed by the measurement of the potentiodynamic polarisation resistance, by electrochemical impedance spectroscopy and the measurement of dielectric permittivity, during the deionised/deaerated water immersion tests. Additionally, accelerated salt spray tests were performed. All types of coatings tested exhibited a high protective performance. It was concluded that the epoxy system containing zinc dust was the most effective anticorrosion coating under the conditions relevant to this study.

The purpose of this paper is to formulate two component polyurethane coatings based on acrylic polyol, to study the effects of variable nanosilica loadings in these coatings on different morphological, optical, mechanical, corrosion resistance and weather resistance properties and to study the intercalation of acrylic polyol molecules into nanosilica crystals by XRD technique.

Two component polyurethane coatings were synthesised using acrylic polyol and isocyanate HDI. The nanosilica was incorporated in polyurethane formulation at the weight ratios of 1%, 3% and 5% based on total weight of polyol and isocyanate. The performance of nanocoatings was compared for variable loads of nanosilica for different properties such as morphological, optical, mechanical, corrosion resistance, weather resistance and were studied for intercalation of acrylic polyol into nanosilica crystals by XRD technique.

Improvement in the properties of polyurethane coatings is achieved with the incorporation of nanosilica. The improvement is the result of inherently high properties of inorganic nanosilica. Tensile strength, scratch hardness, abrasion resistance, corrosion and weathering resistance show significant improvement in performance with the incorporation of nanosilica. Properties are found to deteriorate beyond a certain loading of nanosilica; hence it is important to optimise loading level. The optimal range for high performance was found to be in the range of 1% to 3%. The improvement was a result of synergistic behaviour and good interfacial interaction between polyurethane and nanosilica at optimal levels.

The method used for incorporation of nanosilica into polyurethane was direct incorporation method. The other method of incorporation, i.e. in situ addition and its effect on properties can also be studied.

With the addition of optimal loading level of nanosilica to polyurethane coatings, properties can be enhanced up to the mark. The addition is relatively easy and cost effective.

The paper proves the significance of incorporation of nanosilica on original properties of polyurethane coatings and widens the area of applications of two component polyurethane coatings from acrylic polyol by strengthening them in their properties. The coatings can be applicable in high performance topcoats especially for automotive topcoats.

The lack of a reliable and valid measurement tool for coding achievement emerges as a major problem in Turkey. Therefore, the purpose of this study is to develop a Scratch-based coding achievement test.

Initially, an item pool with 31 items was created. The item pool was classified within the framework of Bayman and Mayer’s (1988) types of coding knowledge to support content validity of the test. Then the item pool was applied to 186 volunteer undergraduates at Hacettepe University during the spring semester of the 2017-2018 academic year. Subsequently, the item analysis was conducted for construct validity of the test.

In all, 13 items were discarded from the test, leaving a total of 18 items. Out of the 18-item version of the coding achievement test, 4, 5 and 9 items measured syntactic, conceptual and strategic knowledge, respectively, among the types of coding knowledge. Furthermore, average item discrimination index (0.531), average item difficulty index (0.541) and Cronbach Alpha reliability coefficient (0.801) of the test were calculated.

Scratch users, especially those who are taking introductory courses at Turkish universities, could benefit from a reliable and valid coding achievement test developed in this study.

This paper has theoretical and practical value, as it provides detailed developmental stages of a reliable and valid Scratch-based coding achievement test.

The purpose of this paper is to study the correlation between abrasive wear resistance, contact configuration and grain size of aluminium alloy.

Different aluminium alloy with different grain size has been tested using a scratch test. Comparison between scratch parameters, especially scratch depth and grain size aluminium alloy, has been made. Two indenters were used: conical and spherical indenter.

Correlation between grain size of aluminium alloy, configuration contact and abrasive wear resistance has been discussed. This study can be useful for choosing material which can provide better abrasive wear resistance.

This study can be a reference both practically and academically. A similar study has been made in order to investigate the effect of hardness in abrasive wear resistance. However, the importance of microstructure and especially the grain size of aluminium alloy have been taken into account.