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The purpose of this paper is to investigate the frictional behavior of polytetrafluoroethylene (PTFE) composites under oil‐free sliding conditions.

The friction force and power consumption of pressure packing seals, which were, respectively, made of common filled PTFE, 30 wt% CF (carbon fiber) + PTFE and C/C (carbon/carbon) + PTFE, are studied in a reciprocating oil‐free compressor arrangement. Their coefficient of friction is tested on a block‐on‐ring type tribometer.

The results indicate that influence of mean sliding velocity on filled PTFE composites is apparently more predominant than the others. The friction force curvilinear path of 30 wt% CF+PTFE is hardly influenced by changing crankshaft turn angle. For C/C+PTFE, the effect of mean piston velocity on friction force is not evident. The results also indicate that the friction coefficient of C/C+PTFE is lower than that of 30 wt% CF+PTFE if their applied normal force exceeds 9.8 N. Furthermore, their variation curve of friction force is little different and the power consumption of C/C+PTFE is slightly higher than that of 30 wt% CF+PTFE.

Neither the effect of real contact area on friction coefficient measured in a tribometer nor the influence of the temperature on friction force and power tested in a compressor is not taken into consideration here.

Owing to its good mechanical performances and frictional behaviors, C/C+PTFE is an optimum and promising material under conditions with sealing pressure up to 10 MPa and sliding velocity exceeding 4.0 m/s.

A novel material called C/C+PTFE is considered to make packing rings for oil‐free reciprocating compressors and its friction behaviour is tested on a refitted compressor.

The purpose of this paper is to elucidate the tribology behavior of polytetrafluoroethylene (PTFE) incorporated with three types of nickel–phosphorus (Ni-P) particles (i.e. low phosphorus [LP], medium phosphorus [MP] and high phosphorus [HP]) under dry sliding condition.

Ni-HP, Ni-MP and Ni-LP particles fabricated via an electroless plating process were incorporated into PTFE matrix with different additions to prepare Ni-P/PTFE composites (Ni-LP/PTFE, Ni-MP/PTFE and Ni-HP/PTFE). The tribology tests for these samples were carried out on a reciprocating ball-on-disc tribometer. The thermal stabilities, mechanical and tribological properties, morphologies and components of aforesaid Ni-P/PTFE composites were analyzed.

The marvelous effect of Ni-P incorporation on the simultaneous reduction in friction and wear of PTFE was corroborated.

Compared with that of pristine PTFE sample, the reduction on friction with a value of 27% and the reduction in wear about 94% for Ni-HP/PTFE composite is validated, which is probably related to the increased crystallinity and hardness due to the presence of Ni-P particles.

The purpose of this paper is to find a reason of a very high lubrication effectivity of a lithium grease filled with PTFE and copper powders when used as a lubricant between contacting steel surfaces under mixed friction conditions.

The paper presents the results of the differential thermal analysis (DTA) of a lithium grease lubricant filled with 6 wt% PTFE and 6 wt% Cu and of a 1:1 mass mixture of PTFE and copper powders alone. The chemical composition analysis of post‐DTA residual substances was carried out using the x‐ray microanalysis. The same method was employed for the examination of the chemical composition of the post‐test friction area in the balls of a four‐ball apparatus. The balls were lubricated with three greases: without any fillers (the base 1S lithium grease), with one filler (6 wt% Cu), and with two fillers (6 wt% PTFE and 6 wt% Cu). For the latter compound, the load was 500 daN, for the remaining compositions, the load was 126 daN.

The results of the analyses done confirmed a thesis that the synergism of PTFE and Cu in the tested grease under mixed friction conditions is possible due to the thermal decomposition of PTFE and creation – as a result of a reaction of this decomposition products with an earlier formed platering layer – of new layers that are (to a high probability) complexes containing copper, fluorine, and sulphur.

PTFE and copper powders when used as fillers for a lithium grease form a very effective lubrication compound for steel sliding pairs. The application of this compound results in an overall reduction of friction and wear that is greater than a simple summation of gains obtained when using these two additives separately.

It was proved that a dominant factor contributing to the synergistic effect of PTFE and copper in a lithium grease when used for the lubrication of steel surfaces is the fluorine that originate from the thermal disintegration of PTFE and not sulphur from the base grease.

This paper aims to investigate the tribological properties of polytetrafluoroethylene (PTFE) composites modified by nano-serpentine and nano-lanthanum oxide in a seawater environment.

In this paper, seven PTFE composites were prepared by unified design method and vacuum thermoforming method, and their hardness, water absorption and tribological properties were measured under seawater environment. The modification effects and thermal stability of the materials were analyzed by Fourier transform infrared spectroscopy, thermal gravimetry and differential scanning calorimetry. This paper analyzed the wear mechanism of PTFE composites by scanning electron microscopy and energy spectroscopy.

The results showed that the hardness of the PTFE composites were all improved, but the water absorption was increased with the increase of additives. The modification of nano-serpentine was successful and the thermal stability of PTFE composites was better. The lowest coefficient and minimum wear rate are 0.0267 and 8.67 × 10⁻⁵ · mm³ · (N · m)⁻¹ respectively, which is 34.9% and 76% less than the pure PTFE.

The analysis showed that the wear mechanism of PTFE composites was abrasive wear and a small amount of adhesive wear, and when the additive content was appropriate, it easily formed a transfer film on the surface mating parts.

The purpose of this paper is to investigate the effect of hexagonal boron nitride (h-BN) and poly (phenyl p-hydroxybenzoate) (PHBA) on improving the torsional tribological behavior of polytetrafluoroethylene (PTFE).

This paper investigates the torsional tribological behavior of PTFE composites filled with h-BN and PHBA under different angular displacements with a plane-on-plane torsional friction tester. The worn surface of PTFE composites was investigated by using a scanning electron microscope.

The shape of T–Θ curves of PTFE composites was influenced by both content fillers and torsional angule. The material with a higher coefficient of sliding friction exhibited the larger torsional angle under which the torsional regime transited from a partial slip to a gross slip. PTFE composites filled with 20 weight per cent PHBA and 10 weight per cent h-BN showed the best anti-wear properties. The specific wear rate of composites exhibits a negative correlation with material hardness. The wear volume loss presents a positive correlation with friction dissipation energy. The specific wear rate of all composites decreased with increasing torsional angle. The dominant wear mechanism of pure PTFE was adhesive wear. The slight plastic flow and plowing occurred on the worn surfaces of PTFE composites because of the higher hardness of composites and the lubrication of h-BN particles with layer crystal structure.

This paper put forward a kind of PTFE composite with low torsional wear rate, which can be used in the sliding slewing bearing or the center plate of a bogie.

The purpose of this paper is to explore the geometric parameter difference of the terrace-like structural transfer film under different working parameters [pressure and velocity (PV) values] and filled particle types (three fillers: SiO₂, TiO₂ and ZnO), and find the geometric parameter related to the wear of polytetrafluoroethylene (PTFE)-based composites.

PTFE composites were filled with SiO₂, TiO₂ and ZnO particles, and the morphology parameter of the PTFE composite transfer film under different PV values obtained from the rotary reciprocating pin-on-disk frictional tester was quantified by using a three-dimensional laser scanning microscope.

The results showed that the effective layer coverage rate and effective thickness of the transfer film had a good relationship with the wear of the three PTFE composites. On the whole, increasing the speed or load was helpful to increase the effective thickness of the three PTFE composite transfer films, but reduced the effective layer coverage rate. The greater the effective layer coverage rate and effective thickness of the transfer film, the better the wear resistance of the PTFE composites in the entire speed and load range.

This work will promote further understanding of the transfer film and lay a foundation for realizing its morphology regulation and improving the wear of the PTFE composites.

The purpose of this paper is to investigate the effect of SiO₂ on the tribological properties of polytetrafluoroethylene (PTFE) composites from an atomic level.

Effect of SiO₂ on the tribological properties of PTFE sliding against Cu was studied by molecular dynamics (MD) simulations to explore the inherent mechanisms from an atomic level.

SiO₂ had a higher interaction energy with PTFE than copper, which contributed to an increase of interfacial temperature and velocity with severe adhesive wear on the PTFE molecules.

This study reveals the mechanism of SiO₂ on the friction and wear behavior of PTFE by MD simulation.

The purpose of this paper was to construct lubrication model closer to the fact of thrust bearings and to calculate the bearings characteristics of lubrication for understanding how structures influence bearings performances and, importantly, what can be the most beneficial. Large-scale composite thrust bearings with Polytetrafluoroethylene (PTFE)-faced sector pad backed by steel base are used increasingly in equipment. But there are plenty of puzzled problems in design and application.

The authors established a 3D thermal elastohydrodynamic lubrication (TEHL) model. Oil film was formulated by Reynolds equation for pressure, and by energy equation for temperature varying through oil film thickness. Meanwhile, pad temperature was formulated by solid heat transfer equation. Elastic and thermal deformations of pad surface were calculated. Viscosity and density of oil were valued separately under different pressure and temperature. Load balance was considered as well as overturning moment balance. Finite difference method was applied to discrete these equations.

PTFE layer and steel base have either helpful or detrimental impact on contact strength and full film lubrication of thrust bearing depending on their relationship in thickness. Temperature lag between middle layer of steel base and pad surface depends on PTFE layer, but not on the steel base. PTFE layer thickness should be considered when alarming threshold value of the bearings temperature is chosen.

Three-dimensional TEHL model of large-scale composite thrust bearings was established, which included more factors close to the actual. Conclusions were drawn. These proposals are helpful to design the bearings.

The purpose of this paper is to formulate heavy-duty lithium complex grease using low molecular weight poly tetra fluoro ethylene (PTFE) micro-particles as extreme pressure (EP) additive manufactured by E-beam scissoring and ultra-high speed grinding process of pre-sintered PTFE scrap.

Lithium complex grease is formulated with PTFE micro-particles, and optimum treat rate was studied by standard bench tests by ASTM D 2266 and IP-239 for tribological properties and compared with commercially available Molybdenum Di sulphide (Moly)-based lithium complex grease. The performance of the grease was further evaluated by a cyclic load test at varying speeds and loads to simulate the operational field conditions.

The lithium complex PTFE grease was manufactured using PTFE micro-particles as EP additive. The PTFE micro-particles dispersed in the lithium complex grease significantly improve the anti-wear performance and load bearing properties. Further, when the product was tested under a cyclic load conditions on standard tribological bench test against commercially available Moly lithium complex grease, shows stable anti-wear properties and reduced coefficient of friction.

The low molecular weight PTFE micro-particles, manufactured in the in-house electron beam (E-beam) and ultra-high speed micronizer facility from a pre-sintered PTFE scrap has been used as EP additive for grease applications for the first time. The results on the cyclic load tests indicate significant performance improvement in retaining the anti-wear and friction properties. Thus, value addition is done in formulating superior performance grease and evaluating under cyclic load conditions similar to field operating conditions and also in creating value added additives by converting the pre-sintered PTFE scarp which is environmental hazard due to poor biodegradability, creating a cyclic economy and a sustainable concept.

This paper aims to explore the possibility of converting the nitrile butadiene rubber (NBR) water-lubricated bearing material into a self-lubricating bearing material by the action of polytetrafluoroethylene (PTFE) particles and water lubrication.

A group of experimental studies was carried out on a ring-on-block friction test. The physical properties, tribological properties and interface structure of PTFE-NBR self-lubricating composites filled with different percentages of PTFE particles were investigated.

The experimental results indicated that the reduction in friction and wear is a result of the formation of the lubricating film on the surface of the composites. The lubricating film was formed of a large amount of PTFE particles continuously supplied under water lubrication conditions and the PTFE particles here can greatly enhance the load capacity and lubrication performance.

In this study, the tribological properties of PTFE particles added to the NBR water-lubricated bearing materials under water lubrication were investigated experimentally, and the research was carried out by a ring-on-block friction test. It is believed that this study can provide some guidance for the application of PTFE-NBR self-lubricating.

The peer review history for this article is available at: https://publons.com/publon/10.1108/ILT-05-2020-0187/