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Article
Publication date: 30 September 2022

Amirul Syafiq, Vengadaesvaran Balakrishnan and Nasrudin Abd. Rahim

This paper aims to design the nano-titanium dioxide (TiO2) coating system which has superhydrophilic property, self-cleaning mechanism and antifog property as well as strong…

Abstract

Purpose

This paper aims to design the nano-titanium dioxide (TiO2) coating system which has superhydrophilic property, self-cleaning mechanism and antifog property as well as strong adhesion on glass substrate.

Design/methodology/approach

Two hydrophilic materials have been used such as TiO2 nanoparticles as fillers and hydrophilic copolymer, Pluronic F-127 by using simple sol–gel approach. The prepared solution was applied onto glass through dip- and spray-coating techniques and then left for drying at ambient temperature.

Findings

The nano-TiO2 superhydrophilic coating has achieved the water contact angle of 4.9° ± 0.5°. The superhydrophilic coating showed great self-cleaning effect against concentrated syrup and methylene blue where thin layer of water washes the dirt contaminants away. The nano-TiO2 coating exhibits great antifog performance that maintains high transparency of around 89% when the coated glass is placed above hot-fog vapor for 10 min. The fog droplets were condensed into water film which allowed the transmission of light through the glass. The strong adhesion of coated glass shows no total failure at scratch profile when impacted with scratch load of 500, 800 and 1,200 mN.

Research limitations/implications

Findings will be useful in the development of self-cleaning superhydrophilic coating that is applicable on building glass and photovoltaic panel.

Practical implications

The developed nano-TiO2 coating is developed by the combination of hydrophilic organic copolymer–inorganic TiO2 network to achieve great superhydrophilic property, optimum self-cleaning ability and supreme antifog performance.

Social implications

The findings will be useful for residents in building glass window where the application will reduce dust accumulation and keep the glass clean for longer period.

Originality/value

The synthesis of nano-TiO2 superhydrophilic coating which can be sprayed on large glass panel and cured at ambient temperature.

Article
Publication date: 13 September 2023

Amirul Syafiq, Lilik Jamilatul Awalin, Syukri Ali and Mohd Arif

The paper aims to design the optimum formulation of the nano-titanium dioxide (TiO2) hydrophilic coating system using the synthetic polypropylene glycol (PPG), which can create…

Abstract

Purpose

The paper aims to design the optimum formulation of the nano-titanium dioxide (TiO2) hydrophilic coating system using the synthetic polypropylene glycol (PPG), which can create the reflection and absorption property.

Design/methodology/approach

TiO2 nanoparticles are used as fillers, and PPG has been blended at the proper ratio of 1PPG: 0.2TiO2. The prepared resin has been applied onto the glass substrate at different numbers of glass immersions during the dip-coating fabrication process. One-time glass immersion is labeled as T1 coating, two-time glass immersion is labeled as T2 coating and three-time glass immersion is labeled as T3 coating. All the prepared coating systems were left dry at ambient temperature.

Findings

T3 coating showed the lowest reading of WCA value at 40.50°, due to higher surface energy at 61.73 mN/m. The T3 coating also shows the greatest absorbance property among the prepared coating systems among the prepared coating. In terms of reflectance property, the T2 coating system has great reflectance in UV region and near-infrared region, which is 16.47% and 2.77 and 2.73%, respectively. The T2 coating also has great optical transmission about 75.00% at the visible region.

Research limitations/implications

The development of thermal insulation coating by studying the relationship between convection heat and reflectance at different wavelengths of incident light.

Practical implications

The developed coating shows high potential for glass window application.

Originality/value

The application of the hydrophilic coating on light absorption, reflectance and transmission at different wavelengths.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 11 October 2021

Vikram Singh Kashyap, Gaurav Sancheti and Jitendra Singh Yadav

The purpose of this study is to perform comprehensive investigation to assess the mechanical properties of nano-modified ternary cement concrete blend. Nano silica (NS) (1%, 2…

Abstract

Purpose

The purpose of this study is to perform comprehensive investigation to assess the mechanical properties of nano-modified ternary cement concrete blend. Nano silica (NS) (1%, 2% and 3%) and waste marble dust powder (MD) (5%, 10% and 15%) was incorporated as a fractional substitution of cement in the concrete matrix.

Design/methodology/approach

In this experimental study, 10 cementitious blends were prepared and tested for compressive strength, flexural strength, splitting tensile strength and static modulus of elasticity. The microstructural characteristics of these blends were also explored using a scanning electron microscope along with energy dispersive spectroscopy and X-ray reflection.

Findings

The results indicate an enhancement in mechanical properties and refinement in pore structure due to improved pozzolanic activities of NS and the filling effect of MD.

Originality/value

To the best of the authors’ knowledge, no study has reported the mechanical and microstructural behavior of concrete containing marble and NS.

Details

Journal of Engineering, Design and Technology , vol. 21 no. 5
Type: Research Article
ISSN: 1726-0531

Keywords

Article
Publication date: 12 January 2024

Qing Jiang, Yuhang Wan, Xiaoqian Li, Xueru Qu, Shengnan Ouyang, Yi Qin, Zhenyu Zhu, Yushu Wang, Hualing He and Zhicai Yu

This study aims to evaluate the thermal performance of sodium alginate (SA) aerogel attached to nano SiO2 and its radiative cooling effect on firefighting clothing without…

Abstract

Purpose

This study aims to evaluate the thermal performance of sodium alginate (SA) aerogel attached to nano SiO2 and its radiative cooling effect on firefighting clothing without environmental pollution.

Design/methodology/approach

SA/SiO2 aerogel with refractory heat insulation and enhanced radiative cooling performance was fabricated by freeze-drying method, which can be used in firefighting clothing. The microstructure, chemical composition, thermal stability, and thermal emissivity were analyzed using Fourier transform infrared spectroscopy, scanning electron microscopy, thermogravimetric analyzer and infrared emissivity measurement instrument. The radiative cooling effect of aerogel was studied using thermal infrared imager and thermocouple.

Findings

When the addition of SiO2 is 25% of SA, the prepared aerogel has excellent heat insulation and a high radiative cooling effect. Under a clear sky, the temperature of SA/SiO2 aerogel is 9.4°C lower than that of pure SA aerogel and 22.1°C lower than that of the simulated environment. In addition, aerogel has more exceptional heat insulation effect than other common fabrics in the heat insulation performance test.

Research limitations/implications

SA/SiO2 aerogel has passive radiative cooling function, which can efficaciously economize global energy, and it is paramount to environment-friendly cooling.

Practical implications

This method could pave the way for high-performance cooling materials designed for firefighting clothing to keep maintain the wearing comfort of firefighters.

Originality/value

SA/SiO2 aerogel used in firefighting clothing can release heat to the low-temperature outer space in the form of thermal radiation to achieve its own cooling purpose, without additional energy supply.

Graphical abstract

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 2 May 2024

Song Tang, Xiaowen Chen, Defen Zhang, Wanlin Xie, Qingzheng Ran, Bin Luo, Han Luo and Junwei Yang

The purpose of this study is to investigate the influence of varying concentrations of nano-SiO2 particle doping on the structure and properties of the micro-arc oxidation (MAO…

Abstract

Purpose

The purpose of this study is to investigate the influence of varying concentrations of nano-SiO2 particle doping on the structure and properties of the micro-arc oxidation (MAO) coating of 7075 aluminum alloy. This research aims to provide novel insights and methodologies for the surface treatment and protection of 7075 aluminum alloy.

Design/methodology/approach

The surface morphology of the MAO coating was characterized using scanning electron microscope. Energy spectrometer was used to characterize the elemental content and distribution on the surface and cross section of the MAO coating. The phase composition of the MAO coating was characterized using X-ray diffractometer. The corrosion resistance of the MAO coating was characterized using an electrochemical workstation.

Findings

The results showed that when the addition of nano-SiO2 particles is 3 g/L, the corrosion resistance is optimal.

Originality/value

This study investigated the influence of different concentrations of nano-SiO2 particles on the structure and properties of the MAO coating of 7075 aluminum alloy.

Details

Anti-Corrosion Methods and Materials, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 11 January 2024

Qiang Sun, Quantong Jiang, Siwei Wu, Chang Liu, Heng Tang, L. Song, Hao Shi, Jizhou Duan and BaoRong Hou

The purpose of this paper is to explore the effect of ZnO on the structure and properties of micro-arc oxidation (MAO) coating on rare earth magnesium alloy under large…

Abstract

Purpose

The purpose of this paper is to explore the effect of ZnO on the structure and properties of micro-arc oxidation (MAO) coating on rare earth magnesium alloy under large concentration gradient.

Design/methodology/approach

The macroscopic and microscopic morphology, thickness, surface roughness, chemical composition and structure of the coating were characterized by different characterization methods. The corrosion resistance of the film was studied by electrochemical and scanning Kelvin probe force microscopy. The results show that the addition of ZnO can significantly improve the compactness and corrosion resistance of the MAO coating, but the high concentration of ZnO will cause microcracks, which will reduce the corrosion resistance to a certain extent.

Findings

When the concentration of zinc oxide is 8 g/L, the compactness and corrosion resistance of the coating are the best, and the thickness of the coating is positively correlated with the concentration of ZnO.

Research limitations/implications

Too high concentration of ZnO reduces the performance of MAO coating.

Practical implications

The MAO coating prepared by adding ZnO has good corrosion resistance. Combined with organic coatings, it can be applied in corrosive marine environments, such as ship parts and hulls. To a certain extent, it can reduce the economic loss caused by corrosion.

Originality/value

The effect of ZnO on the corrosion resistance of MAO coating in electrolyte solution was studied systematically, and the conclusion was new to the common knowledge.

Details

Anti-Corrosion Methods and Materials, vol. 71 no. 2
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 12 April 2024

Yanwei Dai, Libo Zhao, Fei Qin and Si Chen

This study aims to characterize the mechanical properties of sintered nano-silver under various sintering processes by nano-indentation tests.

Abstract

Purpose

This study aims to characterize the mechanical properties of sintered nano-silver under various sintering processes by nano-indentation tests.

Design/methodology/approach

Through microstructure observations and characterization, the influences of sintering process on the microstructure evolutions of sintered nano-silver were presented. And, the indentation load, indentation displacement curves of sintered silver under various sintering processes were measured by using nano-indentation test. Based on the nano-indentation test, a reverse analysis of the finite element calculation was used to determine the yielding stress and hardening exponent.

Findings

The porosity decreases with the increase of the sintering temperature, while the average particle size of sintered nano-silver increases with the increase of sintering temperature and sintering time. In addition, the porosity reduced from 34.88%, 30.52%, to 25.04% if the ramp rate was decreased from 25°C/min, 15°C/min, to 5°C/min, respectively. The particle size appears more frequently within 1 µm and 2 µm under the lower ramp rate. With reverse analysis, the strain hardening exponent gradually heightened with the increase of temperature, while the yielding stress value decreased significantly with the increase of temperature. When the sintering time increased, the strain hardening exponent increased slightly.

Practical implications

The mechanical properties of sintered nano-silver under different sintering processes are clearly understood.

Originality/value

This paper could provide a novel perspective on understanding the sintering process effects on the mechanical properties of sintered nano-silver.

Details

Soldering & Surface Mount Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0954-0911

Keywords

Article
Publication date: 22 November 2018

A. Syafiq, A.K. Pandey, Vengadaesvaran Balakrishnan, Syed Shahabuddin and Nasrudin Abd Rahim

This paper aims to investigate the thermal stability and hydrophobicity of difference alkyl chain of silanes with silicon (Si) micro- and nanoparticles.

Abstract

Purpose

This paper aims to investigate the thermal stability and hydrophobicity of difference alkyl chain of silanes with silicon (Si) micro- and nanoparticles.

Design/methodology/approach

Sol-gel methods have been used to design superhydrophobic glass substrates through surface modification by using low-surface-energy Isooctyl trimethoxysilane (ITMS) and Ethyl trimethoxysilane (ETMS) solution. Hierarchical double-rough scale solid surface was built by Si micro- and nanoparticles to enhance the surface roughness. The prepared sol was applied onto glass substrate using dip-coating method and was dried at control temperature of 400°C inside the tube furnace.

Findings

The glass substrate achieved the water contact angle as high as 154 ± 2° and 150.4 ± 2° for Si/ITMS and Si/ETMS films, respectively. The Si/ITMS and Si/ETMS also were equipped with low sliding angle as low as 3° and 5°, respectively. The Si micro- and nanoparticles in the coating system have created nanopillars between them, which will suspend the water droplets. Both superhydrophobic coatings have showed good stability against high temperature up to 200°C as there are no changes in WCA shown by both coatings. Si/ITMS film sustains its superhydrophobicity after impacting with further temperature up to 400°C and turns hydrophobic state at 450°C.

Research limitations/implications

Findings will be useful to develop superhydrophobic coatings with high thermal stability.

Practical implications

Sol method provides a suitable medium for the combination of organic-inorganic network to achieve high hydrophobicity with optimum surface roughness.

Originality/value

Application of different alkyl chain groups of silane resin blending with micro- and nanoparticles of Si pigments develops superhydrophobic coatings with high thermal stability.

Details

Pigment & Resin Technology, vol. 53 no. 1
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 11 January 2024

Liangbin Chen, Lihong Zhao, Keren Ding, Kaibo Xu and Xianzhe Tang

This study aims to optimize the preparation conditions and modify the nanofiltration (NF) membranes to prepare high-performance polysulfone/sulfonated polysulfone composite…

Abstract

Purpose

This study aims to optimize the preparation conditions and modify the nanofiltration (NF) membranes to prepare high-performance polysulfone/sulfonated polysulfone composite nanofiltration (PSF/SPSF-NF) membranes through interfacial polymerization.

Design/methodology/approach

Investigating the impacts of anhydrous piperazine (PIP) concentration, trimesoyl chloride (TMC) concentration and basement membrane type on NF membrane performance, the optimal membrane was prepared. In addition, nano-SiO2 was added to the active separation layer to modify the NF membranes.

Findings

The comprehensive performance of PSF/SPSF-NF membranes was optimized when the concentration of PIP was 0.75 Wt.% and the concentration of TMC was 0.15 Wt.%, at which time the water flux was 66.1 L·m−2·h−1 and the retention rate of Na2SO4 was 98.1%. The comprehensive performance of polysulfone/sulfonated polysulfone-SiO2 nanofiltration (PSF/SPSF-SiO2-NF) membranes was optimized when the blending ratio of nano-SiO2 to PIP was 2:3, with a pure water flux of 81.9 L·m−2·h−1 and a Na2SO4 retention rate of 95.9%. Compared to polysulfone nanofiltration (PSF-NF) membranes and PSF/SPSF-NF membranes, NF membranes with nano-SiO2 increased the flux recovery rate by 22.9% and 8.7%.

Practical implications

PSF/SPSF-SiO2-NF membrane exhibits excellent antifouling properties.

Originality/value

There is currently no literature available on the preparation of NF membranes using polysulfone/sulfonated polysulfone (PSF/SPFS) as a substrate. This provides a method for modifying NF membranes, starting with the modification of the basement membrane and then modifying the active separation layer.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 2 March 2023

Bahareh Nikmehr, Bidur Kafle and Riyadh Al-Ameri

This study aimed to review various existing methods for improving the quality of recycled concrete aggregates (RCAs) as a possible substitution for natural aggregates (NAs) in…

Abstract

Purpose

This study aimed to review various existing methods for improving the quality of recycled concrete aggregates (RCAs) as a possible substitution for natural aggregates (NAs) in concrete. It is vital as the old paste attached to the RCA weakens its structure. It is due to the porous structure of the RCA with cracks, weakening the interfacial transition zone (ITZ) between the RCA and binding material, negatively impacting the concrete's properties. To this end, various methods for reinforcement of the RCA, cleaning the RCA's old paste and enhancing the quality of the RCA-based concrete without RCA modification are studied in terms of environmental effects, cost and technical matters. Furthermore, this research sought to identify gaps in knowledge and future research directions.

Design/methodology/approach

The review of the relevant journal papers revealed that various methods exist for improving the properties of RCAs and RCA-based concrete. A decision matrix was developed and implemented for ranking these techniques based on environmental, economic and technical criteria.

Findings

The identified methods for reinforcement of the RCA include accelerated carbonation, bio deposition, soaking in polymer emulsions, soaking in waterproofing admixture, soaking in sodium silicate, soaking in nanoparticles and coating with geopolymer slurry. Moreover, cleaning the RCA's old paste is possible using acid, water, heating, thermal and mechanical treatment, thermo-mechanical and electro-dynamic treatment. Added to these treatment techniques, using RCA in saturated surface dry (SSD) mixing approaches and adding fibres or pozzolana enhance the quality of the RCA-based concrete without RCA modification. The study ranked these techniques based on environmental, economic and technical criteria. Ultimately, adding fibres, pozzolana and coating RCA with geopolymer slurry were introduced as the best techniques based on the nominated criteria.

Practical implications

The study supported the need for better knowledge regarding the existing treatment techniques for RCA improvement. The outcomes of this research offer an understanding of each RCA enrichment technique's importance in environmental, economic and technical criteria.

Originality/value

The practicality of the RCA treatment techniques is based on economic, environmental and technical specifications for rating the existing treatment techniques.

Details

Smart and Sustainable Built Environment, vol. 13 no. 3
Type: Research Article
ISSN: 2046-6099

Keywords

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