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This paper aims to design the nano-titanium dioxide (TiO₂) coating system which has superhydrophilic property, self-cleaning mechanism and antifog property as well as strong adhesion on glass substrate.

Two hydrophilic materials have been used such as TiO₂ nanoparticles as fillers and hydrophilic copolymer, Pluronic F-127 by using simple sol–gel approach. The prepared solution was applied onto glass through dip- and spray-coating techniques and then left for drying at ambient temperature.

The nano-TiO₂ superhydrophilic coating has achieved the water contact angle of 4.9° ± 0.5°. The superhydrophilic coating showed great self-cleaning effect against concentrated syrup and methylene blue where thin layer of water washes the dirt contaminants away. The nano-TiO₂ coating exhibits great antifog performance that maintains high transparency of around 89% when the coated glass is placed above hot-fog vapor for 10 min. The fog droplets were condensed into water film which allowed the transmission of light through the glass. The strong adhesion of coated glass shows no total failure at scratch profile when impacted with scratch load of 500, 800 and 1,200 mN.

Findings will be useful in the development of self-cleaning superhydrophilic coating that is applicable on building glass and photovoltaic panel.

The developed nano-TiO₂ coating is developed by the combination of hydrophilic organic copolymer–inorganic TiO₂ network to achieve great superhydrophilic property, optimum self-cleaning ability and supreme antifog performance.

The findings will be useful for residents in building glass window where the application will reduce dust accumulation and keep the glass clean for longer period.

The synthesis of nano-TiO₂ superhydrophilic coating which can be sprayed on large glass panel and cured at ambient temperature.

This paper introduced the simple synthesis process of self-cleaning coating with fog-resistance property using hydrophobic polydimethylsiloxane (PDMS) polymer and nano-calcium carbonate (nano-CaCO₃) and titanium dioxide (TiO₂).

The synthesis method of PDMS/nano-CaCO₃-TiO₂ is based on sol-gel process. The crosslinking between PDMS and nanoparticles is driven by the covalent bond at temperature of 50°C. The 3-Aminopropyltriethoxysilane is used as binder for nanoparticles attachment in polymer matrix. Two fabrication methods are used, which are dip- and spray-coating methods.

The prepared coated glass fulfilled the requirement of standard self-cleaning and fog-resistance performance. For the self-cleaning test BS EN 1096-5:2016, the coated glasses exhibited the dust haze value around 20%–25% at tilt angle of 10°. For the antifog test, the coated glasses showed the fog haze value were below 2% and the gloss value were above 85%. The obtained results completely achieved the standard antifog value ASTM F659-06 protocol.

Findings will provide an infrastructure support for the building glass to enhance building’s energy efficiency, cleaning performance and friendly environment.

This study proposed the simple synthesis method using hydrophobic polymer and nano-CaCO₃ and nano-TiO₂, which can achieve optimum self-cleaning property at low tilt angle and fog-resistance performance for building glass.

The research findings have high potential for building company, cleaning building company and government sector. The proposed project capable to reduces the energy consumption about 20% per annum due to labor cost, time-consuming and safety during manual cleaning.

The novel method to develop self-cleaning coating with fog-resistance using simple synthesis process and fabrication method for building glass application.

The purpose of this paper is to review the new trends in plastic additives, with special focus on developments in food packaging materials.

Phenomenological research has brought awareness and increased insight into the role of various plastic additives on the packaging of foods. The approach is based on the current trends and the industrial protocols for the additives used in plastic polymer processing for the development of food packaging materials.

Packaging of foodstuffs is a dynamic process which continually responds to the changes in supply and demand which are the result of adaptations to the varying demands of the consumer, changes in retail practices, technological innovations, new materials and developments in legislation, especially, with respect to environmental concerns. A wide range of additives is available for enhancing the performance and appearance of food packaging, as well as improving the processing of the compound. Polymer additives are important areas of innovation for packaging materials.

The paper reviews and summarizes the recent developments in the functionality of different additives, along with their advantages and disadvantages, currently being used to enhance the properties of food packaging materials that can positively influence the environment within the packaging for the increased demand for raw or processed foods.

The purpose of this paper is to develop the efficiency of styrene-acrylate (SA) emulsions for polymer cement waterproof coatings with improved bacteria resistance and mechanical properties.

For effective bacteria resistance and excellent mechanical properties, various concentrations of methacryloxyethylhexadecyl dimethylammonium bromide (MHDB) were synthesised and incorporated into SA emulsions. The properties of SA emulsions modified with MHDB were characterised and compared with those of unmodified ones according to the formulations of polymer cement waterproof coatings.

The SA emulsions modified with MHDB exhibited significant enhancement of bacteria resistance and mechanical properties over the unmodified ones. The positive quaternary nitrogen and long-chain alkyl groups of MHDB in SA emulsions could attract phospholipid head groups of bacterial and insert them into the cell wall, which results in biomass leak and bactericidal effect. Moreover, MHDB as a softened monomer was beneficial to the synthesis of SA copolymer with low glass-transition temperature (T_g), then the copolymer and cement would form a more compact film which was the main reason for the enhancement of mechanical properties.

The modifier MHDB was synthesised from diethylaminoethyl methacrylate (DEAM) and 1-bromohexadecane. Besides, the congeners of MHDB could be synthesised from DEAM and 1-bromododecane, 1-tetradecyl dromide, 1-octadecyl bromide, etc. In addition, the efficiency of other modifications into SA emulsions for antibacterial polymer cement waterproof coatings could be studied as well.

The method provided a practical solution for the improvement of water-based antibacterial acrylate polymer cement waterproof coatings.

The method for enhancing bacteria resistance and mechanical properties of the waterproof coating was novel and valuable.

The coatings industry is in large measure a function of the world around it. Advances in related disciplines are scrutinised carefully by coatings chemists because of the ramifications that these new discoveries and inventions may have if applied directly to the coatings area. This is certainly true relative to new resins and other raw materials. It applies also to the development of new energy forms which reflect themselves in new ways to cure coatings. Accordingly, some of these newer advances which could eventually have important ramifications in the coatings industry will be reviewed here.

The purpose of this paper is to study the effect of synthesis conditions on properties of TiO₂ nanoparticles to be used for photocatalysis and also producing TiO₂ using a low temperature method.

TiO₂ nanoparticles were synthesised via a sol‐gel method at low temperature and the effect of parameters such as: synthesis temperature, HNO₃ concentration, calcination temperature and synthesis time on properties of TiO₂ were studied. The effects of the physico‐chemical properties of TiO₂, its concentration and light intensity on photocatalytic properties of TiO₂ nanoparticles were investigated also.

The results showed that TiO₂ with Anatase phase were formed at 80‐100°C by using proper HNO₃ concentration, synthesis time and calcinations temperature. Calcinations programme and temperature and also the synthesis time affect the formation of TiO₂ crystalline phase (i.e. Rutile and Brookite), their surface area and crystallite size. To evaluate the photocatalytic properties of TiO₂ nanoparticles, fluorescein was used as a model molecule. Results showed that degradation of fluorescein could be described by pseudo‐first order kinetics. The effect of TiO₂ concentration and light intensity on photocatalytic activity showed that increasing concentration of TiO₂ and the light intensity would increase the degradation of fluorescein.

The method used in this work to prepare TiO₂ nanoparticles is an economic method for low temperature synthesis of TiO₂ nanoparticles with high photocatalytic activity, which could find numerous applications in coating technology.

No one particular fluid has cooling and lubrication properties suitable for every metalworking application. The purpose of this paper is first, to investigate the effect of anionic and nonionic mixed emulsifier system in stabilization of cutting fluid formulations and second, to study the interaction synergism of the fulfill additives of metalworking fluids to achieve low scar diameters, high stability, anti rusting and corrosion properties.

A lot of set mixtures in this work were formulated to get the demand needed for soluble oil metalworking fluids. It was based on a blend of emulsifier package (anionic‐non ionic), and in order to reach acceptable manufacturing conditions, coupling agent, stabilizer, biocide, base oil and anti‐rust additives were added to the formulation. Different percentages of these components were incorporated to optimize the stability of the emulsifier system. Standard tests were carried out to evaluate the performance of oil‐in‐water (O/W) emulsions as lubricating and cooling fluids in machining operations. The evaluation was drawn in five factors; oil stability, emulsion stability, pH, anti‐rust (corrosion inhibition), biological activity and extreme pressure performance tests.

All tests achieved excellent results according to the ASTM. From the obtained results, the formula (named EPRI 950) exhibited a good performance compared with the commercial cutting fluid.

This work investigates the effect of anionic and nonionic mixed emulsifier system in stabilization of cutting fluid formulations; and the interaction synergism of the fulfill additives of metalworking fluids to achieve low scar diameters, high stability, anti‐rusting and corrosion properties.

The fire safety of structures is an existing and important design aspect, which is assured by strict regulations. As a means to adhere to the strict requirements, fire protection has become a core problem. It is particularly difficult to comply with these regulations in the case of timber, which is a combustible material. These problems could be solved by enveloping the wood in fire retardant materials. MSZ EN 1995-1-2 currently does not take into consideration the fire-retardant materials charring rate under fire exposure.

However, currently these fire retardants are proving to be reliable and depending on their application can achieve better reaction-to-fire classifications. During the research, the authors used five different fire-retardant materials on three different types of wood and tested their behaviours in a laboratory. When selecting them, it was important to choose the species that are most commonly used in the building industry but which have significantly different densities. Our choice fell upon spruce (360 kg/m³), Scots pine (540 kg/m³) and oak (650 kg/m³). During the tests, we examined the weight reduction and the process of burning on the specimens treated with the fire retardant material. In addition, the authors also performed tests by derivatography on both untreated and treated specimen.

The question is whether the effects of the fire retardants should be taken into consideration when calculating the extent of the burn. The Eurocode (MSZ EN 1995-1-2) does not provide any opinions. On the market, there are manufacturers who are already discussing the possibilities of reducing the burn rate during the qualification of paints. In this paper, based on the results we received, we discuss the beneficial effects of the fire retardants which can be taken into account while measuring cross-sections.

By using fire retardants, a high proportion of cross-sectional area gain is only possible in case of small cross-sections; therefore, it is advisable to use them here as well. This can be effective for example in many smaller cross-sections, when there is a little space and therefore requires a small cross-section. Thus, if a larger cross-section without protection is not possible, it can be replaced by a smaller cross section, treated with a fire retardant.

The purpose of this paper is to develop different combinations of acrylic polyol and silicone resins with various weight ratios and to test the coating properties using electrochemical impedance spectroscopy (EIS).

The performance properties such as coating resistance, capacitance, dielectric constant, water uptake and diffusion coefficient were evaluated using EIS with exposure to 3.5 per cent NaCl solution for 60 days.

The binders developed in this study were coated on cold rolled steel plates. The dry film thickness was found to be in the range of 50 microns. From EIS results, it was found that Acrylic polyol sample with 30 weight per cent of silicone exhibits the best properties, as it has high coating resistance in the range of 109 Ohms for the full period of exposure, whereas all other samples showed poor performance with the exposure time. For these samples, the parameters measured such as the coating resistance of the samples decreased while the coating capacitance, percentage of water uptake and diffusion coefficient of the samples increased after being exposed to corrosive solution for 60 days. The coatings developed by 0, 10 and 60 weight per cent silicone showed high coating capacitance on the first day of exposure, and these systems failed early during the exposure. The water uptake percentage and diffusion coefficient of all samples were found to be less than 50 per cent and below 10-11 cm2 s−1, respectively. An optimum cross-linking between the resins is considered as the main contribution for the best performance shown by the sample that consists of 30 weight per cent of silicone in acrylic matrix that provides maximum barrier properties of the coating.

Developing coatings using hybrid binders (silicone resin and acrylic polyol resin) is new area of research. This will explore more research in the formulation of novel coatings.