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This study/paper aims to the authors applied low “Si” ions dose over cp-Ti-2, and the potent dose level was optimized for adequate corrosion resistance and effective proliferation of stem cells.

The cp-Ti surface was modified by silicon (Si) ions beam at 0.5 MeV in a Pelletron accelerator. Three different ion doses were applied to the polished samples, and the surface was characterized by XRD and AFM analysis.

At moderate “Si” ion dose (6.54 × 10¹² ions-cm⁻²), the potential shifted to a noble value. The small “i_corr” (1.22 µA.cm⁻²) and relatively large charge transfer resistance (43.548 kΩ-cm²) in the ringer‘s lactate solution was confirmed through Potentiodynamic polarization and impedance spectroscopy analysis. Compared to cp-Ti and other doses, this dose level also provided the effective proliferation of mesenchymal stem cells.

The dosage levels used were different to previous work and provided the effective proliferation of mesenchymal stem cells.

The purpose of this paper is to study the electrochemical, mechanical and thermal characteristics of polyester – epoxy coating systems using electrochemical impedance spectroscopy (EIS), pull-off test and differential scanning calorimetry (DSC). These are very important properties to evaluate the performance of a coating system. Proper measurement and analysis techniques are needed for a proper evaluation of these properties to ensure the coating performance.

Different ratios of polyester and epoxy resins have been blended to formulate good anticorrosive, mechanically strong and thermally stable binder coating system. EIS, pull-off test and DSC were used to evaluate these properties.

The sample containing 90 wt.% polyester exhibited the best corrosion resistance from the beginning until the end of exposure time. The value of corrosion resistance (R_c) obtained on the 30th day of exposure was found to be 2.89 × 108 ohm cm⁻². The glass transition temperature (T_g) was found to be increasing with the incorporation of epoxy to the binder system. The result from pull-off test showed the best adhesion with the sample containing 90 wt.% polyester which also has the lowest T_g promoted better adhesion properties.

The curing time must be reduced for practical applications.

Hybrid coatings systems have been formulated. This paper discusses on the highest coating resistance obtained polymer-substrate mechanical properties and thermal characteristic of the polyester/epoxy binder resin using DSC.

This study aims to investigate NiTi alloys’ characterization and corrosion behaviour produced by two different powder metallurgy (PM) methods.

It was pre-formed under a protective atmosphere at 900 °C under a force of 45 MPa and sintered for 1 h under 10–6 Mbar in an atmosphere-controlled heat treatment furnace at 1,100 °C. The relationship between microstructural properties, SEM, XRD, density, microhardness and corrosion behaviour of pre-alloyed NiTi alloys produced by two different methods with the production method was investigated.

As a result of the studies, TiO, NiTi, NiTi2 and Ni3Ti intermetallics were determined in XRD examinations. The best surface roughness was observed in the mechanically milled (MM’ed) pre-alloyed NiTi alloy compared to the pre-alloyed NiTi alloy mixed with turbula. The corrosion tests performed in 3.5% NaCl solution determined that the MM’ed pre-alloyed NiTi alloy had better corrosion resistance than the pre-alloyed NiTi alloy mixed with turbula. Pitting corrosion was visualized in the SEM images taken from the corrosion surfaces.

Two different PM methods produced pre-alloyed NiTi powders, and the effects of these methods on the mechanical and corrosion resistance of NiTi alloys were systematically investigated for the first time.

This study aims to investigate the electrochemical corrosion performance of high velocity oxygen fuel (HVOF) sprayed WC–12Co coating in 3.5 Wt.% NaCl solution, which provided a guiding significance on the corrosion resistance of H13 hot work mould steel.

A WC–12Co coating was fabricated on H13 hot work mould steel using a HVOF, and the electrochemical corrosion behaviors of WC–12Co coating and substrate in 3.5 Wt.% NaCl solution was measured using open circuit potential (OCP), potentiodynamic polarization curve (PPC) and electrochemical impedance spectroscopy (EIS) tests.

The OCP and PPC of WC–12Co coating positively shift than those of substrate, its corrosion tendency and corrosion rate decrease to enhance its corrosion resistance. The curvature radius of capacitance curve on the WC–12Co coating is larger than that on the substrate, and the impedance and polarization resistance of WC–12Co coating increase faster than those of substrate, which reduces the corrosion process.

The electrochemical corrosion behaviors of WC–12Co coating and substrate in 3.5 Wt.% NaCl solution is first measured using OCP, PPC and EIS tests, which improve the electrochemical corrosion resistance of H13 hot work mould steel.

The Internet of Things (IoT), as one of the new digital technologies, has created wide applications in various industries, and one of the most influential industries of this technology is the transportation industry. By integrating the IoT with the transportation industry, there will be dramatic changes in the industry, and it will provide many entrepreneurial opportunities for entrepreneurs to develop new businesses. Opportunity identification is at the heart of the entrepreneurial process, and entrepreneurs identify innovative goods or services to enter a new market by identifying, evaluating, and exploiting opportunities. Despite the desire of transportation managers to invest in the IoT and the increase in research in this area, limited research has focused on IoT-based entrepreneurial opportunities in the transportation industry. Therefore, the present study aims to identify IoT-based entrepreneurial opportunities in the transportation industry and examine their importance.

To achieve the research objective, the authors applied a mixed approach. First, adapting the lens of the industry value chain theory, a comprehensive literature review, besides a qualitative approach including semi-structured interviews with experts and thematic analysis, was conducted to identify the entrepreneurial opportunities. The identified opportunities were confirmed in the second stage using a quantitative survey method, including the Student t-test and factor analysis. Finally, the identified opportunities were weighted and ranked using the best worst method (BWM).

Entrepreneurial opportunities are classified into five main categories, including “smart vehicles”, “business partners/smart transportation supply side”, “supporting services”, “infrastructures”, and “smart transport management and control”. The infrastructures group of opportunities ranked the highest amongst the identified groups.

This study adds to the digital entrepreneurship opportunity recognition literature by addressing opportunities in a smart industry propelled by digital technologies, including developing new products or new applications of the available technologies. Additionally, inspired by the industry value chain theory, this article develops a framework including various digital entrepreneurial opportunity networks which are necessary to add value to any industry and, thus, could be applied by entrepreneurs to recognize opportunities for new intermediaries to enter other digital-based industries. Finally, the present study identifies the IoT-based entrepreneurial opportunities in the smart transportation industry and prioritizes them, providing practical insights regarding the creation of entrepreneurial ecosystems in the field of smart transportation for entrepreneurs and policymakers.

The purpose of this paper is to establish a methodology for the design and development of patient-specific elbow implant with an elastic modulus close to that of the human bone. One of the most preferred implant material is titanium alloy which is about 8 to 9 times higher in strength than that of the human bone and is the closest than other metallic biomedical materials.

The methodology begins with the design of the implant from patient-specific computed tomography information and incorporates the manufacturing of the implant via a novel rapid prototyping assisted microwave sintering process.

The elastic modulus and the flexural strength of the implant were observed to be comparable to that of human elbow bones. The fatigue test depicts that the implant survives the one million cycles under physiological loading conditions. Other mechanical properties such as impact energy absorption, hardness and life cycle tests were also evaluated. The implant surface promotes human cell growth and adhesion and does not cause any adverse or undesired effects i.e. no cytotoxicity.

Stress shielding, and therefore, aseptic loosening of the implant shall be avoided. In the event of any trauma post-implantation, the implant would not hurt the patient.

The present study describes a methodology for the first time to be able to obtain the strength required for the medical implant without sacrificing the fatigue life requirement.

This study aims to examine if relational attachment could be considered as a mediator in the relationship between social support and career regret. The theoretical framework is based on Kahn’s (2007) work on meaningful connections.

The authors used a three-part survey for data collection, spread over two months from 368 employees for co-worker social support and 324 employees for supervisor social support working in different sectors in India.

The results indicate that for co-workers, relational attachment acts as a mediator between instrumental support and career regret; but for personal support, the mediation effect is absent. However, instrumental support is not directly related to career regret. Notably, in case of social support from the supervisor, there does not seem to be any mediation effect for personal or instrumental support. But social support is related to career regret for both categories of support.

The authors contribute to literature that examines the mechanism, driving social support and career regret. By understanding how these factors interact and impact one another, researchers can develop interventions and strategies to help individuals navigate career decisions, improve their personal relationships and increase their access to social support. Ultimately, this research can lead to improved well-being and career satisfaction for individuals. As the sample is generalized, there is scope to examine if the relationships differ based on the work structures and idiosyncrasies of the industries.

This study examines the unmapped mechanism that mediates the social support and career regret relationship, and in the process, provides new directions for research.

This paper aims to present the way of modifying surfaces of 316L stainless steel elements that were manufactured in the selected laser melting (SLM) technology and then subjected to mechanical and electrolytic processing (electropolishing [EP]). The surface of the as-generated and commercial produced parts was modified by grinding and EP, and the results were compared. The authors also present an example of the application of EP for the final processing of a sample technological model – an initial prototype of a 316L steel implant manufactured in the SLM technology.

The analyzed properties included surface topography, roughness, resistance to corrosion, microhardness and the chemical composition of the surface before and after EP. The roughness described with the Ra, Rt and Rz was determined before and after EP of samples manufactured from 316L steel with use of traditional methods and additive technologies.

EP provides us with the opportunity to process elements with a complex structure, which would not be possible with use of other methods (such as milling or grinding). Depending on the expected final surface of elements after the SLM process, it is possible to reduce the surface roughness with the use of EP (for t = 20 min, Ra = 3.53 ± 0.37 µm and for t = 40 min, Ra = 3.23 ± 0.22 µm) or mechanical processing and EP (for t = 4 min, Ra = 0.13 ± 0.02 µm). The application of the EP method to elements made from 316L steel, in a bath consisting of sulfuric acid (VI), H2SO4 (35 Vol.%), phosphoric acid (V), H3PO4 (60.5 Vol.%) and triethanolamine 99 per cent (4.5 Vol.%), allows us to improve the surface smoothness and to obtain a value of the Ra parameter ranging from 0.11 to 0.15 µm. The application of a current density of 20 A/dm2 and a bath temperature of 55ºC results in an adequate smoothing of the surface (Ra < 0.16 µm) for both cold rolled and SLM elements after grinding. The application of EP, to both cold rolled elements and those after SLM, considerably improves the resistance to corrosion. The results of potentiodynamic corrosion resistance tests (jkor, EKA and Vp) of the 316L stainless steel samples demonstrate that the values of Vp for elements subjected to EP (commercial material: 1.3·10-4 mm/year, SLM material: 3.5·10-4 mm/year) are lower than for samples that were only ground (commercial material: 4.0·10-4 mm/year, SLM material: 9.6·10-4 mm/year). The microhardness was found to be significantly higher in elements manufactured using SLM technology than in those cold rolled and ground. The ground 316L steel samples were characterized by a microhardness of 318 HV (cold rolled) and 411 HV (SLM material), whereas the microhardness of samples subjected to EP was 230 HV (commercial material) and 375 HV (SLM material).

The 316L samples were built by SLM method. The surface of the SLM samples was modified by EP. Surface morphological changes after EP were studied using optical methods. Potentiodynamic tests enabled to notice changes in the corrosion resistance of 316L. Microhardness results after electropolished 316L stainless steel were shown. The chemical composition of 316L surface samples was presented. The smoothening of the surface amounted to Ra = 0.16 µm.

Drawing on Kahn’s model of meaningful connections, this study aims to examine relational attachment as a mediating mechanism linking social support in terms of instrumental support and personal support to employees’ subjective career success.

Data were collected in 2 waves from 247 employees working in Poland. Hypotheses were tested using structural equation modeling in AMOS.

The findings indicated that employees are more attached to and satisfied with their careers when they have a stronger relational attachment to others at work. Furthermore, relational attachment was found to be driven by tangible or intangible instrumental support received at work rather than the personal support received at work.

Managers should recognize the importance of workplace relationships and social support, which can lead to higher career commitment and career satisfaction. However, managers should keep in mind that too much interference in individuals’ privacy and providing too much personal support may lead to adverse outcomes.

The present study expands the scant literature on the mediating role of relational attachment at work between social support received at work and subjective career success.