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The purpose of this study is to improve the anticorrosion performance of low nickel stainless steel (AISI 201) in 3.5% NaCl by electroactive polyimide/copper oxide (EPI/CuO) composites coating.

Electroactive polyimide/copper oxide (EPI/CuO) composites were prepared by oxidative coupling polymerization followed by thermal imidization method.

The functional and structural properties of composites were characterized by X-ray diffraction, Fourier transmission infra-red and ultra violet-visible spectroscopy and the surface topography was characterized by field emission scanning electron microscope analysis and anticorrosion performance in 3.5 Wt.% NaCl was evaluated by electrochemical techniques. The obtained results of electrochemical techniques measurement indicated that the composites coated samples give better corrosion protection against attacking electrolyte.

The ever-increasing price of nickel (Ni) is driving the industries to use low-Ni austenitic stainless steels (ASSs). However, it exhibits relatively poor corrosion resistance as compared with conventional Cr-Ni ASSs. Nonetheless, its corrosion resistance can be enhanced by polymeric (electroactive polyimide [EPI]) coating. CuO particles exhibit the hydrophobic properties and can be used as inorganic filler to incorporate in EPI to further enhance the corrosion protection. The present research paper is beneficial for industries to use low-cost AISI 201, enhance its corrosion resistance and replace the use of costly conventional Cr-Ni ASSs.

The stimulus of the successful semiconductor device miniaturisation programmes coupled to recent progress in synthetic chemistry and molecular engineering has led to the emergence of a new inter‐disciplinary activity—molecular electronics—which holds long‐term promise for a new range of electronic materials and devices. From very speculative origins the field has begun to generate important applications based on photoresists, Langmuir‐Blodgett films, electroactive polymers and photochromic materials. A selection of topics ranging from molecular switches, memories, sensors, and the biological interface to prospects for a molecular computer are discussed with special emphasis on features such as stability, self‐organisation and self‐assembly which are unique to molecular systems.

The purpose of this study is to investigate the intergranular corrosion (IGC) susceptibility of a nitrogen-containing austenitic stainless steel QN2109. The intergranular corrosion (IGC) susceptibility of a nitrogen-containing austenitic stainless steel QN2109 was investigated.

The double-loop electrochemical potentiodynamic reactivation (DL-EPR) tests were carried out. Scanning electron microscopy and atomic force microscopy were used to characterize the microstructure.

The optimized test condition for QN2109 was 1 M H₂SO₄ + 0.01 M NH₄SCN at 40°C. The nose temperature of the temperature–time–sensitization (TTS) curve of QN2109 plot was approximately 750°C. Moreover, the IGC susceptibility started to appear at approximately 120 min. The Cr-depletion zone of QN2109 was generated by the formation of M23C6 rather than by the addition of nitrogen. The depth–width ratio of the grain boundaries after the DL-EPR tests decreased as the aging temperature increased. The degree of Cr depletion and size of the Cr-depletion zone at the grain boundary were reflected by the degree of sensitization and depth–width ratio, respectively.

The optimized test condition for DL-EPR tests of a nitrogen-containing austenitic stainless steel QN2109 was investigated. The TTS curve of QN2109 was first plotted to avoid IGC failure. The morphology of the Cr-depletion zone was reflected by the depth–width ratio.

This study aims to synthesize a series of new anticorrosive pigments using a new technique called “core-shell”. This technique is based on depositing thin surface layer of expensive, efficient anticorrosive pigment on a cheap extender. This extender forms the bulk of the new pigments. The new pigments were constructed on cores of either waste silica fume or kaolin comprising 80-85 per cent of their chemical structure, and the ferrite shell was about of 20-15 per cent. Electrochemical studies were undertaken on two series of pigments for comparison between ferrites/silica fume and ferrites/kaolin pigment to show their performance, as the shells are different.

The different ferrites/silica fume and ferrites/kaolin pigments were characterized using different analytical and spectrophotometric techniques, such as X-ray fluorescence (XRF) and transmission electron microscopy (TEM). Immersion test and electrochemical impedance measurements were done in 3.5 per cent NaCl.

The tests revealed that paint films containing Sr ferrite/silica and Ca ferrite/kaolin were the most effective in corrosion prevention.

Silica fumes have a large array of uses. These pigments can be applied in various industries such as painting, wooding coating, anti-corruption coating, powder coating, architectural paint and waterproof paints. Treated kaolin can be applied in many industries besides pigment manufacture and paint formulations; it can be applied as a reinforcing filler in rubber, plastics and ceramic composites.

The new pigments are considered ecofriendly materials, because using them converts a waste product and a natural ore to useful marketable product, leading to reducing cost and saving the environment at the same time.

The paper aims to promote the development of intelligent materials and the 4D printing technology by introducing recent advances and applications of additive layered manufacturing (ALM) technology of intelligent materials and the development of the 4D printing technology. Also, an arm-type ALM technology of shape memory polymer (SMP) with thermosetting polyurethane is briefly introduced.

This paper begins with an overview of the development and applications of intelligent materials around the world and the 4D printing technology. Then, the authors provide a brief outline of their research on arm-type ALM technology of SMP with thermosetting polyurethane.

The paper provides the recent developments and applications of intelligent materials and 4D printing technology. Then, it is suggested that intelligent materials mixed with different functional materials will be developed, and these types of materials will be more suitable for 4D printing.

This paper overviews the current developments and applications of intelligent materials and its use in 4D printing technology, and briefly states the authors’ research on arm-type ALM technology of SMP with thermosetting polyurethane.

This paper aims to investigate the electrochromic (EC) properties of poly(triphenylamine alkyl ether) and poly(triphenylamine aryl ether) in two different electrolyte solution to study the resistive switching behaviour of acid-doped poly(triphenylamine alkyl ether).

By Buchwald–Hartwig coupling reaction, two novel poly[N-p-phenoxy-N-[4-[2-(2-methoxyethoxy)ethoxy]ethoxy]triphenylamineandpoly[N,N-bis(4-phenoxy)]triphenylamine were synthesized from 4-phenoxyaniline and two dibromo aromatic compounds, 1,2-bis[β,β′-(p-bromophenoxy)ethoxy]ethane and bis(4-bromophenyl) ether.

Poly(triphenylamine alkyl ether) displayed excellent EC characteristics, with a coloration change from a colourless neutral state to light blue and red oxidized states, while poly(triphenylamine aryl ether) showed coloration a change from a colourless neutral state to light blue oxidized state in tetrabutylammonium perchlorate electrolyte solution. Moreover, p-toluenesulfonic acid-doped poly(triphenylamine alkyl ether) exhibited a non-volatile bistable resistive switching behaviour with a high high-conductivity/low-conductivity ratio of up to 104, long retention time exceeding 2.5 × 10³ s and the switching threshold voltage was also lower than −2V.

In this paper, the non-volatile bistable resistive switching behaviour of acid-dopedpoly(triphenylamine alkyl ether) was in accordance with the molar ratio of 1:1. The effects of different molar ratios remained to be studied.

Poly(triphenylamine ether)s may find optoelectronic applications as new EC and resistive switching materials.

The effects of alkyl and aryl ether structures in the main chain on the EC and resistive switching behaviour of triphenylamine unit have not yet been reported.

This paper aims to provide details of recent research into robots capable of ascending vertical or near-vertical surfaces and to illustrate how the ability to climb is set to resolve a critical industrial need arising from the growth in renewable energy.

Following a short introduction, the first parts of this paper describe a selection of recent research activities that involve innovative concepts and designs. The second part discusses climbing robot developments aimed at the automated inspection, maintenance and repair of wind turbine blades. Brief concluding comments are drawn.

Robots that can ascend vertical or near-vertical surfaces are the topic of an extensive and technologically innovative research effort. Many developments take their inspiration from the climbing abilities of living creatures. Drones with the ability to adhere to and climb vertical surfaces are also being developed. Potential applications include inspection, surveillance and search and rescue. Climbing robots are poised to provide a solution to the need to de-man and reduce the cost of inspecting and maintaining composite wind turbine blades.

This provides an insight into recent innovations in climbing robot concepts and designs and shows how the ability to ascend vertical surfaces is being exploited in the robotic inspection, maintenance and repair of wind turbine blades.

Examines the seventeenth published year of the ITCRR. Runs the whole gamut of textile innovation, research and testing, some of which investigates hitherto untouched aspects. Subjects discussed include cotton fabric processing, asbestos substitutes, textile adjuncts to cardiovascular surgery, wet textile processes, hand evaluation, nanotechnology, thermoplastic composites, robotic ironing, protective clothing (agricultural and industrial), ecological aspects of fibre properties – to name but a few! There would appear to be no limit to the future potential for textile applications.

The purpose of this paper is to report a comparative study of conducting polymer (CP) dispersed oil polyurethane coatings derived from a sustainable resource, i.e. polyaniline (PANI)/coconut oil polyesteramide urethane (CPEAU) and poly(1‐naphthylamine) (PNA)/linseed oil polyurethane (LPUA) coatings.

The coatings were prepared chemically and were characterized for their physico‐chemical, physico‐mechanical, corrosion protective efficiency, and open circuit potential measurements. The morphological analysis of the corroded carbon steel (CS), coated uncorroded CS, and coated corroded CS specimens, was carried out by SEM analysis.

The study revealed that the presence of a CP enhanced the corrosion protective efficiency of the sustainable resource‐based organic coatings. The type of CP used also played a major role in defining the corrosion resistance behavior of the coating materials.

The comparative study of anticorrosive properties of CP with oil‐based polyurethane blends has been studied for the first time.