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The purpose of this paper is to investigate the mechanical properties changing of geopolymer cement under different brine salinity.

Geopolymer Cement of Class F Fly Ash and Class G Cement slurries were prepared according to API RP 10B. The optimum alkaline activator/cement and water/cement ratio of 0.44 was used for geopolymer and Class G cement samples, respectively. The alkaline activator was prepared by mixing the proportion of Sodium Hydroxide (NaOH) solutions of 8 M and Sodium Silicate (Na2SiO3) using ratio of 1:2.5 by weight. The slurries were cured for 24 hours at 130^oC and 3,000 psi in HPHT Curing Chamber followed by coring process. Both cement sample were immersed in brine water salinity up to 28 days with different brine salinity up to 30 per cent of NaCl. The mechanical properties were investigated using OYO Sonic Viewer-SX and Uniaxial Compressive Strength. The surfaces of the cement samples were extracted for Scanning Electron Microscope (SEM) and EDS tests to evaluate the morphology and chemical compositions of the cured samples.

The paper shows that geopolymer samples experiences strength reduction in brine water but the reduction rate of geopolymer is about half of the Ordinary Portland cement based oil well cement. The finding was also verified by SEM and EDS result.

This paper investigates the mechanical property changes of emerging geopolymer cement due to different water salinity. The results provide potential application of geopolymer cement for oil well cementing.

The long‐term durability of cement becomes an important challenge in oil and gas wells due to the aggressive acid gas. H₂S has been found in more and more wells. The purpose of this research was to add polymer latex to the Class G cement in order to promote the H₂S corrosion resistance of oilwell cement.

The water loss and thickening time of cement slurry and compressive strength and gas permeability of bond cement were investigated to determine the cement formulation. The corrosion resistance of the polymer cement was compared to base Class G cement in solution with 1.8 MPa H₂S at 120°C.

The optimum concentration of polystyrene latex was determined as 5 percent. The permeability change, compressive strength loss and corrosion ratio of latex cement were all lower than for the base Class G cement. The electrochemical impedance spectroscopy results and microstructure details confirmed that the latex cement had stronger resistance to the aggressive medium. Thus, latex cement had excellent corrosion resistance to H₂S.

The findings of this study can further improve the sulfide resistance of Class G cement. Two roles of the polystyrene latex were observed in the cement, including interstitial in‐filling of the pore structure and packing around hydration products, which are proposed to properly explain the results.

The purpose of this paper is to investigate the resistivity of geopolymer cement with nano-silica additive toward acid exposure for oil well cement application.

An experimental study was conducted to assess the acid resistance of fly ash-based geopolymer cement with nano-silica additive at a concentration of 0 and 1 wt.% to understand its effect on the strength and microstructural development. Geopolymer cement of Class C fly ash and API Class G cement were used. The alkaline activator was prepared by mixing the proportion of sodium hydroxide (NaOH) solutions of 8 M and sodium silicate (Na₂SiO₃) using ratio of 1:2.5 by weight. After casting, the specimens were subjected to elevated curing condition at 3,500 psi and 130°C for 24 h. Durability of cement samples was assessed by immersing them in 15 wt.% of hydrochloric acid and 15 wt.% sulfuric acid for a period of 14 days. Evaluation of its resistance in terms of compressive strength and microstructural behavior were carried out by using ELE ADR 3000 and SEM, respectively.

The paper shows that geopolymer cement with 1 wt.% addition of nano-silica were highly resistant to sulfuric and hydrochloric acid. The strength increase was contributed by the densification of the microstructure with the addition of nano-silica.

This paper investigates the mechanical property and microstructure behavior of emerging geopolymer cement due to hydrochloric and sulfuric acids exposure. The results provide potential application of fly ash-based geopolymer cement as oil well cementing.

Wells’ cementing is an important and costly step in the engineering sector for oil and gas well. The purpose of this study was to investigate the use of Algerian natural pozzolan (NP) in order to evaluate the influence of partial substitution of class G cement on slurry properties.

NP was characterized by X-ray fluorescence (XRF), scanning electron microscopy/energy-dispersive X-ray (SEM/EDX) and Fourier-transform infra-red spectrometry (FTIR). Their pozzolanic activity was evaluated by measuring the electrical conductivity in aqueous suspensions of pozzolan/calcium hydroxide. The replacement ration cement/NP was 10, 20 and 30 per cent, and the rheological behaviour, compressive strength properties at different ages, elastic properties, X-ray diffraction analysis, rapid chloride penetration, porosity and permeability of all slurries were investigated and compared with a standard sample.

The obtained results indicated that the replacement with 20 per cent by weight of cement at 21 and 28 days had a higher compressive strength (+30.62 per cent) and lower chloride penetration.

The results show the potential of the use of locally available NP in well cementing.

In the carbon dioxide capture and storage (CCS) project, the integrity of CO₂ injection wells plays a vital role in the long‐term safety of CO₂ storage. The authors aim to practically investigate possible CO₂ leakage of a CO₂ injection well section during the injection operation and shut‐in by the thermomechanical FEM simulation. The application of numerical simulation to the CO₂ injection well deep underground is the first step that will help in the quantitative evaluation of the mechanical risks.

The injection of CO₂ at a temperature different from those of the well and the surrounding geological formation is likely to cause different thermal deformations of constitutive well materials. This could lead to cement cracking and microannuli openings at the interfaces of different materials such as casing/cement and cement/rock. In this paper, the possibility and order of magnitude of cement cracking and microannuli creation in the cross section of the well are assessed from a numerical case study within a classical thermomechanical finite element model framework.

The possibility of compressive failure and tensile cracking in the cement of the studied wells due to CO₂ injection is small unless a large casing eccentricity or an initial defect in the cement is present. Some microannuli openings are generated at interfaces cement/casing and/or cement/rock during the CO₂ injection because of different thermal shrinkage of each material. However, the width is not important enough to cause significant CO₂ leakage under the studied conditions. The use of “flexible” cement especially developed for oil well applications could mitigate the risk of cement cracking during CO₂ injection.

Numerous experimental studies on the chemical deterioration of the cement under severe conditions have been carried out. On the other hand, only a few investigations have focused on the mechanical behavior under thermal/pressure changes related to CO₂ injection. In this paper, the quantitative analysis to investigate cement cracking and microannuli formation is achieved to help in the identification of possible mechanical defects to cause CO₂ leakage. In addition, the discussion about the risk of the possible casing eccentricity and the application of flexible cement in the oil and gas field to CO₂ injection well could be practically useful.

This paper attempted to study the alkali-activated (AA) binder consisting of 94% of ground granulated blast furnace slag (GGBFS) and 6% of blended powder of alkali metal hydroxide and metal sulfate, which acted as an activator.

Several concrete specimens (cubes, cylinders and prisms), which were casted using AA binders, were further tested for mechanical properties after exposure to elevated temperatures of 200 °C, 400 °C, 600 °C and 800 °C. Additionally, to understand the structural behavior in uniaxial compressive load, reinforced concrete short columns were cast, cured and tested at ambient temperature as well as after exposure to 300 °C, 600 °C and 900 °C, to know the residual strength after exposure to elevated temperature.

The findings for the residual strength of alkali-activated slag binder concrete (AASBC) indicated a substantial agreement with the results obtained for the residual strength of Portland slag cement (PSC) concrete, thereby showing the effectiveness of binder when used as a replacement of cement.

The study clearly indicates that the binder developed is an effective approach for the 100% replacement of cement in the concrete.

Cement as one of the major components of construction activities, releases a tremendous amount of carbon dioxide (CO₂) into the atmosphere, resulting in adverse environmental impacts and high energy consumption. Increasing demand for CO₂ consumption has urged construction companies and decision-makers to consider ecological efficiency affected by CO₂ consumption. Therefore, this paper aims to develop a method capable of analyzing and assessing the eco-efficiency determining factor in Iran’s 22 local cement companies over 2015–2019.

This research uses two well-known artificial intelligence approaches, namely, optimization data envelopment analysis (DEA) and machine learning algorithms at the first and second steps, respectively, to fulfill the research aim. Meanwhile, to find the superior model, the CCR model, BBC model and additive DEA models to measure the efficiency of decision processes are used. A proportional decreasing or increasing of inputs/outputs is the main concern in measuring efficiency which neglect slacks, and hence, is a critical limitation of radial models. Thus, the additive model by considering desirable and undesirable outputs, as a well-known DEA non-proportional and non-radial model, is used to solve the problem. Additive models measure efficiency via slack variables. Considering both input-oriented and output-oriented is one of the main advantages of the additive model.

After applying the proposed model, the Malmquist productivity index is computed to evaluate the productivity of companies over 2015–2019. Although DEA is an appreciated method for evaluating, it fails to extract unknown information. Thus, machine learning algorithms play an important role in this step. Association rules are used to extract hidden rules and to introduce the three strongest rules. Finally, three data mining classification algorithms in three different tools have been applied to introduce the superior algorithm and tool. A new converting two-stage to single-stage model is proposed to obtain the eco-efficiency of the whole system. This model is proposed to fix the efficiency of a two-stage process and prevent the dependency on various weights. Converting undesirable outputs and desirable inputs to final desirable inputs in a single-stage model to minimize inputs, as well as turning desirable outputs to final desirable outputs in the single-stage model to maximize outputs to have a positive effect on the efficiency of the whole process.

The performance of the proposed approach provides us with a chance to recognize pattern recognition of the whole, combining DEA and data mining techniques during the selected period (five years from 2015 to 2019). Meanwhile, the cement industry is one of the foremost manufacturers of naturally harmful material using an undesirable by-product; specific stress is given to that pollution control investment or undesirable output while evaluating energy use efficiency. The significant concentration of the study is to respond to five preliminary questions.

Environmental issues caused by the production of Portland cement have led to it being replaced by waste materials such as fly ash, which is more economical and safer for the environment. Also, fly ash is a material with sustainable properties. Therefore, this paper aims to focus on the development of sustainable construction materials using 100% high-calcium fly ash and potassium hydroxide (KOH)-based alkaline solution and study the engineering properties of the resulting fly ash-based geopolymer concrete. Laboratory tests were conducted to determine the mechanical properties of the geopolymer concrete such as compressive strength, flexural strength, curing time and slump. In phase I of the study, carbon nanotubes (CNTs) were added to determine their effect on the strength of the geopolymer mortar. The results derived from the experiments indicate that mortar and concrete made with 100% fly ash C require an alkaline solution to produce similar (comparable) strength characteristics as Portland cement concrete. However, it was determined that increasing the amount of KOH generates a considerable amount of heat causing the concrete to cure too quickly; therefore, it is notable to forming a proper bond was unable to form a stronger bond. This study also determined that the addition of CNTs to the mix makes the geopolymer concrete tougher than the traditional concrete without CNT.

Tests were conducted to determine properties of the geopolymer concrete such as compressive strength, flexural strength, curing time and slump. In Phase I of the study, CNTs were studied to determine their effect on the strength of the geopolymer mortar.

The results derived from the experiments indicate that mortar and concrete made with 100% fly ash C require an alkaline solution to produce the same strength characteristics as Portland cement concrete. However, it was determined that increasing the amount of KOH generates too much heat causing the concrete to cure too quickly; therefore, it is notable to forming a proper bond. This study also determined that the addition of CNTs to the mix makes the concrete tougher than concrete without CNT.

This study was conducted at the construction engineering and management concrete laboratory at North Dakota State University in Fargo, North Dakota. All the experiments were conducted and analyzed by the authors.

Many jurisdictions fine illegal cartels using penalty guidelines that presume an arbitrary 10% overcharge. This article surveys more than 700 published economic studies and judicial decisions that contain 2,041 quantitative estimates of overcharges of hard-core cartels. The primary findings are: (1) the median average long-run overcharge for all types of cartels over all time periods is 23.0%; (2) the mean average is at least 49%; (3) overcharges reached their zenith in 1891–1945 and have trended downward ever since; (4) 6% of the cartel episodes are zero; (5) median overcharges of international-membership cartels are 38% higher than those of domestic cartels; (6) convicted cartels are on average 19% more effective at raising prices as unpunished cartels; (7) bid-rigging conduct displays 25% lower markups than price-fixing cartels; (8) contemporary cartels targeted by class actions have higher overcharges; and (9) when cartels operate at peak effectiveness, price changes are 60–80% higher than the whole episode. Historical penalty guidelines aimed at optimally deterring cartels are likely to be too low.

Important differentiating attributes in the procedures used, the characteristic mineral composition of the binders, and the implications these have on the final long term stability and physico-mechanical performance of the concretes produced are identified and discussed, with the intent to improve transparency and clarity in the field of geopolymer concrete technologies.

This state-of-the-art review covers the area of geopolymer concrete, a class of sustainable construction materials that use a variety of alternative powders in lieu of cement for composing concrete, most being a combination of industrial by-products and natural resources rich in specific required minerals. It explores extensively the available essential materials for geopolymer concrete and provides a deeper understanding of its underlying chemical mechanisms.

This is a state-of-the-art review introducing the essential characteristics of alternative powders used in geopolymer binders and the effectiveness these have on material performance.

With the increase of need for alternative cementitious materials, identifying and understanding the critical material components and the effect they may have on the performance of the resulting mixes in fresh as well as hardened state become a critical requirement to for short- and long-term quality control (e.g. flash setting, efflorescence, etc.).

The topic explored is significant in the field of sustainable concrete technologies where there are several parallel but distinct material technologies being developed, such as geopolymer concrete and alkali-activated concrete. Behavioral aspects and results are not directly transferable between the two fields of cementitious materials development, and these differences are explored and detailed in the present study.