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The analysis of boundary layers is needed to reflect the behaviour of fluid flows in current industrial processes and to improve the efficacy of products. Hence, this study aims to analyse the flow and heat transfer performance of hybrid alumina-copper/water (Al₂O₃-Cu/H₂O) nanofluid with the inclusion of activation energy and binary chemical reaction effect towards a moving wedge.

The multivariable differential equations with partial derivatives are converted into a specific type of ordinary differential equations by using valid similarity transformations. The reduced mathematical model is elucidated in the MATLAB system by using the bvp4c procedure. This solution method is competent in delivering multiple solutions once appropriate assumptions are supplied.

The results of multiple control parameters have been studied, and the findings are verified to provide more than one solution. The coefficient of skin friction was discovered to be increased by adding nanoparticles volume fraction from 0% to 0.5% and 1%, by almost 1.6% and 3.2%. Besides, increasing the nanoparticles volume fraction improves heat transfer efficiency gradually. The inclusion of the activation energy factor displays a downward trend in the mass transfer rates, consequently reducing the concentration profile. In contrast, the increment of the binary reaction rate greatly facilitates the augmentation of mass transfer rates. There is a significant enhancement in the heat transfer rate, approximately 13.2%, when the suction effect dominates about 10% in the boundary layer flow. Additionally, the results revealed that as the activation energy rises, the temperature and concentration profiles rise as well. It is proved that the activation energy parameter boosts the concentration of chemical species in the boundary layer. A similar pattern emerges as the wedge angle parameter increases. The current effort aims to improve the thermal analysis process, particularly in real-world applications such as geothermal reservoirs, chemical engineering and food processing, which often encountered mass transfer phenomenon followed by chemical reactions with activation energy.

The present results are original and new for the study of flow and heat transfer over a permeable moving wedge in a hybrid nanofluid with activation energy and binary chemical reaction.

The magnetohydrodynamic (MHD) flow problems are important in the field of biomedical applications such as magnetic resonance imaging, inductive heat treatment of tumours, MHD-derived biomedical sensors, micropumps for drug delivery, MHD micromixers, magnetorelaxometry and actuators. Therefore, there is the impact of the magnetic field on the transport of non-Newtonian Carreau fluid in the presence of binary chemical reaction and activation energy over an extendable surface having a variable thickness. The significance of irregular heat source/sink and cross-diffusion effects is also explored.

The leading governing equations are constructed by retaining the effects of binary chemical reaction and activation energy. Suitable similarity transformations are used to transform the governing partial differential equations into ordinary differential equations. Subsequent nonlinear two-point boundary value problem is treated numerically by using the shooting method based on Runge–Kutta–Fehlberg. Graphical results are presented to analyze the behaviour of effective parameters involved in the problem. The numerical values of the mass transfer rate (Sherwood number) and heat transfer rate (Nusselt number) are also calculated. Furthermore, the slope of the linear regression line through the data points is determined in order to quantify the outcome.

It is established that the external magnetic field restricts the flow strongly and serves as a potential control mechanism. It can be concluded that an applied magnetic field will play a major role in applications like micropumps, actuators and biomedical sensors. The heat transfer rate is enhanced due to Arrhenius activation energy mechanism. The boundary layer thickness is suppressed by strengthening the thickness of the sheet, resulting in higher values of Nusselt and Sherwood numbers.

The effects of magnetic field, binary chemical reaction and activation energy on heat and mass transfer of non-Newtonian Carreau liquid over an extendable surface with variable thickness are investigated for the first time.

The purpose of this paper is to explore the effects of binary chemical reaction and activation energy on nano Casson liquid flow past a stretched plate with non-linear radiative heat, and also, the effect of a novel exponential space-dependent heat source (ESHS) aspect along with thermal-dependent heat source (THS) effect in the analysis of heat transfer in nanofluid. Comparative analysis is carried out between the flows with linear radiative heat process and non-linear radiative heat process.

A similarity transformation technique is utilised to access the ODEs from the governed PDEs. The manipulation of subsequent non-linear equations is carried out by a well-known numerical approach called Runge–Kutta–Fehlberg scheme. Obtained solutions are briefly discussed with the help of graphical and tabular illustrations.

The effects of various physical parameters on temperature, nanoparticles volume fraction and velocity fields within the boundary layer are discussed for two different flow situations, namely, flow with linear radiative heat and flow with non-linear radiative heat. It is found that an irregular heat source/sink (ESHS and THS) and non-linear solar radiation play a vital role in the enhancement of the temperature distributions.

The problem is relatively original to study the effects of activation energy and binary chemical reaction along with a novel exponential space-based heat source on laminar boundary flow past a stretched plate in the presence of non-linear Rosseland radiative heat.

The purpose of this paper is to explore the novel aspects of activation energy in the nonlinearly convective flow of Walter-B nanofluid in view of Cattaneo–Christov double-diffusion model over a permeable stretched sheet. Features of nonlinear thermal radiation, dual stratification, non-uniform heat generation/absorption, MHD and binary chemical reaction are also evaluated for present flow problem. Walter-B nanomaterial model is employed to describe the significant slip mechanism of Brownian and thermophoresis diffusions. Generalized Fourier’s and Fick’s laws are examined through Cattaneo–Christov double-diffusion model. Modified Arrhenius formula for activation energy is also implemented.

Several techniques are employed for solving nonlinear differential equations. The authors have used a homotopy technique (HAM) for our nonlinear problem to get convergent solutions. The homotopy analysis method (HAM) is a semi-analytical technique to solve nonlinear coupled ordinary/partial differential equations. The capability of the HAM to naturally display convergence of the series solution is unusual in analytical and semi-analytic approaches to nonlinear partial differential equations. This analytical method has the following great advantages over other techniques:

• It provides a series solution without depending upon small/large physical parameters and applicable for not only weakly but also strongly nonlinear problems.

• It guarantees the convergence of series solutions for nonlinear problems.

• It provides us a great choice to select the base function of the required solution and the corresponding auxiliary linear operator of the homotopy.

It provides a series solution without depending upon small/large physical parameters and applicable for not only weakly but also strongly nonlinear problems.

It guarantees the convergence of series solutions for nonlinear problems.

It provides us a great choice to select the base function of the required solution and the corresponding auxiliary linear operator of the homotopy.

Brief mathematical description of HAM technique (Liao, 2012; Mabood et al., 2016) is as follows. For a general nonlinear equation:

where N denotes a nonlinear operator, x the independent variables and u(x) is an unknown function, respectively. By means of generalizing the traditional homotopy method, Liao (1992) creates the so-called zero-order deformation equation:

here q∈[0, 1] is the embedding parameter, H(x) ≠ 0 is an auxiliary function, h(≠ 0) is a nonzero parameter, L is an auxiliary linear operator, u_o(x) is an initial guess of u(x) and u ˆ ( x ; q ) is an unknown function, respectively. It is significant that one has great freedom to choose auxiliary things in HAM. Noticeably, when q=0 and q=1, following holds:

Expanding u ˆ ( x ; q ) in Taylor series with respect to (q), we have:

If the initial guess, the auxiliary linear operator, the auxiliary h and the auxiliary function are selected properly, then the series (4) converges at q=1, then we have:

By defining a vector u → = ( u o ( x ) , u 1 ( x ) , u 2 ( x ) , … , u n ( x ) ) , and differentiating Equation (2) m-times with respect to (q) and then setting q=0, we obtain the mth-order deformation equation:

where:

Applying L⁻¹ on both sides of Equation (6), we get:

In this way, we obtain u_m for m ⩾ 1, at mth-order, we have:

It is evident from obtained results that the nanoparticle concentration field is directly proportional to the chemical reaction with activation energy. Additionally, both temperature and concentration distributions are declining functions of thermal and solutal stratification parameters (P₁) and (P₂), respectively. Moreover, temperature Θ(Ω₁) enhances for greater values of Brownian motion parameter (N_b), non-uniform heat source/sink parameter (B₁) and thermophoresis factor (N_t). Reverse behavior of concentration ϒ(Ω₁) field is remarked in view of (N_b) and (N_t). Graphs and tables are also constructed to analyze the effect of different flow parameters on skin friction coefficient, local Nusselt number, Sherwood numbers, velocity, temperature and concentration fields.

The novelty of the present problem is to inspect the Arrhenius activation energy phenomena for viscoelastic Walter-B nanofluid model with additional features of nonlinear thermal radiation, non-uniform heat generation/absorption, nonlinear mixed convection, thermal and solutal stratification. The novel aspect of binary chemical reaction is analyzed to characterize the impact of activation energy in the presence of Cattaneo–Christov double-diffusion model. The mathematical model of Buongiorno is employed to incorporate Brownian motion and thermophoresis effects due to nanoparticles.

The purpose of this article is to analyze the heat and mass transfer with entropy generation during magnetohydrodynamics (MHD) flow of non-Newtonian Sisko nanofluid over a linearly stretching cylinder under the influence of velocity slip, chemical reaction and thermal radiation. The Brownian motion, thermophoresis and activation energy are assimilated in this nanofluid model. Convective boundary conditions on heat and mass transfer are considered. The physical model may have diverse applications in several areas of technology underlying thermohydrodynamics including supercritical fluid extraction, refrigeration, ink-jet printing and so on.

The dimensional governing equations are nondimensionalized by using appropriate similarity variables. The resulting boundary value problem is converted into initial value problem using the method of superposition and numerically computed by employing well-known fourth-order Runge–Kutta–Fehlberg approach along with shooting technique (RKF4SM). The quantitative impacts of emerging physical parameters on the velocity, temperature, concentration, skin friction coefficient, Nusselt number, Sherwood number, entropy generation rate and Bejan number are presented graphically and in tabular form, and the salient features are comprehensively discussed.

From graphical outcomes, it is concluded that the slip parameters greatly influence the flow characteristics. Fluid temperature is elevated with rising radiation parameter and thermal Biot number. Nanoparticle concentration is reported in decreasing form with activation energy parameter. Entropy is found to be an increasing function of magnetic field, Brownian motion and material parameters. The entropy is less generated for shear-thinning fluid compared to shear-thickening as well as Newtonian fluids in the system.

Till now no study has been documented to explore the impact of binary chemical reaction with Arrhenius activation energy on entropy generation in an MHD boundary layer flow of non-Newtonian Sisko nanofluid over a linear stretching cylinder with velocity slip and convective boundary conditions.

This paper aims to peruse the influence of second law analysis for electrically conducting fluid of a Casson nanofluid over a wedge. For activation energy, a modified Arrhenius function is used.

The highly non-linear governing equations are developed using similarity transformations and then computed numerically via Keller–Box method.

The influences of emerging parameters on velocity, temperature distribution and concentration of nanoparticle are explained and presented via graphs and tables. Also, the behavior of fluid flow is investigated through the coefficient of skin friction, Nusselt and Sherwood numbers. Results reveal that the velocity profile enhances due to increasing Casson parameter and magnetic parameter, whereas the temperature distribution and concentration of nanoparticle decrease with larger vales of Casson parameter. It is inspected that the concentration boundary layer increases due to activation energy and decreases due to reaction rate and temperature differences.

The authors believe that all the numerical results are original and significant which are used in biomedicine, industrial, electronics and transportation. The results have not been considered elsewhere.

The purpose of this paper is to analyze the combined effects of thermal radiation and activation energy with a chemical reaction on the quadratic convective flow of a micropolar fluid over an inclined plate. Convective thermal boundary condition and suction/injection effects are considered at the surface of an inclined plate.

The convection along with nonlinear Boussinesq approximation (i.e. quadratic convection or nonlinear convection) and usual boundary layer assumptions is employed in the mathematical formulation. Highly coupled nonlinear governing equations are tackled by a combined local non-similarity and successive linearization techniques.

The behavior of various pertinent parameters on the fluid flow characteristics is conferred through graphs and it reveals that the qualitative behaviors of velocity, temperature, skin friction and heat transfer rates of a micropolar fluid are similar for Biot number and radiation parameters. The suction/injection and activation energy parameters increase the concentration of the micropolar fluid within the boundary layer, while the chemical reaction parameter reduces the concentration in the same region. Further, this quadratic convection shows a strong influence on the fluid flow characteristics and then the impact of pertinent parameters is more prominent on the physical quantities, compared therewith results of the linear convection.

This kind of investigation is useful in the mechanism of combustion, aerosol technology, high-temperature polymeric mixtures and solar collectors which are operated at moderate to very high temperatures.

This attempt is a unique contribution to the establishment of both micropolar fluid and activation energy. This kind of study even in the absence of quadratic convection is not yet noted.

In various kinds of materials processes, heat and mass transfer control in nuclear phenomena, constructing buildings, turbines and electronic circuits, etc., there are numerous problems that cannot be enlightened by uniform wall temperature. To explore such physical phenomena researchers incorporate non-uniform or ramped temperature conditions at the boundary, the purpose of this paper is to achieve the closed-form solution of a time-dependent magnetohydrodynamic (MHD) boundary layer flow with heat and mass transfer of an electrically conducting non-Newtonian Casson fluid toward an infinite vertical plate subject to the ramped temperature and concentration (RTC). The consequences of chemical reaction in the mass equation and thermal radiation in the energy equation are encompassed in this analysis. The flow regime manifests with pertinent physical impacts of the magnetic field, thermal radiation, chemical reaction and heat generation/absorption. A first-order chemical reaction that is proportional to the concentration itself directly is assumed. The Rosseland approximation is adopted to describe the radiative heat flux in the energy equation.

The problem is formulated in terms of partial differential equations with the appropriate physical initial and boundary conditions. To make the governing equations dimensionless, some suitable non-dimensional variables are introduced. The resulting non-dimensional equations are solved analytically by applying the Laplace transform method. The mathematical expressions for skin friction, Nusselt number and Sherwood number are calculated and expressed in closed form. Impacts of various associated physical parameters on the pertinent flow quantities, namely, velocity, temperature and concentration profiles, skin friction, Nusselt number and Sherwood number, are demonstrated and analyzed via graphs and tables.

Graphical analysis reveals that the boundary layer flow and heat and mass transfer attributes are significantly varied for the embedded physical parameters in the case of constant temperature and concentration (CTC) as compared to RTC. It is worthy to note that the fluid velocity is high with CTC and lower for RTC. Also, the fluid velocity declines with the augmentation of the magnetic parameter. Moreover, growth in thermal radiation leads to a declination in the temperature profile.

The proposed model has relevance in numerous engineering and technical procedures including industries related to polymers, area of chemical productions, nuclear energy, electronics and aerodynamics. Encouraged by such applications, the present work is undertaken.

Literature review unveils that sundry studies have been carried out in the presence of uniform wall temperature. Few studies have been conducted by considering non-uniform or ramped wall temperature and concentration. The authors are focused on an analytical investigation of an unsteady MHD boundary layer flow with heat and mass transfer of non-Newtonian Casson fluid past a moving plate subject to the RTC at the plate. Based on the authors’ knowledge, the present study has, so far, not appeared in scientific communications. Obtained analytical solutions are verified by considering particular cases of the published works.

The purpose of this paper is to examine outcome of activation energy in rotating flow of an Oldroyd-B nano liquid.

Flow is generated due to stretched surface. Binary chemical reaction is studied. Brownian and thermophoresis effects are considered. The system of nonlinear ordinary differential equations is derived. Convergent series solutions are obtained by homotopy analysis method. The resulting expressions for velocities, temperature and concentration are computed for different embedded parameters.

It is found that velocities f′ and g  have decreasing effect when rotation parameter is enhanced. Brownian and thermophoresis are increasing functions of temperature and concentration. The physical quantities are sketched and discussed numerically. Concentration and temperature fields show decreasing behavior via Brownian and thermophoresis parameters.

Authors investigate the Rotating flow of Oldroyd-B nano fluid with chemical reactions. This work is not done yet in literature.

The purpose of this study is to study flow caused by rotating frame. Effects of Darcy–Forchheimer and porous medium are considered to study velocity field. Concentration field is discussed in presence of activation energy. Darcy–Forchheimer in a rotating frame is examined. Flow because of stretched sheet fills the porous space. Binary chemical reaction is entertained. Resulting system is numerically solved. The plots are arranged for rotational parameter, porosity parameter, coefficients of inertia, Prandtl number and Schmidt number. It is revealed that rotation on velocity has opposite effects when compared with temperature and concentration distributions. Skin friction coefficients and local Nusselt and Sherwood numbers are numerically discussed.

Darcy–Forchheimer in a rotating frame is examined. Flow because of stretched sheet fills the porous space. Binary chemical reaction is entertained. Resulting system is numerically solved. The plots are arranged for rotational parameter, porosity parameter, coefficients of inertia, Prandtl number and Schmidt number. It is revealed that rotation on velocity has opposite effects when compared with temperature and concentration distributions. Skin friction coefficients and local Nusselt and Sherwood numbers are numerically discussed.

The major findings here are as follows: an addition in porosity λ causes decay in velocity f′(η) while there is opposite behavior for temperature θ(η) and concentration ϕ(η) fields. θ and ϕ via β have similar results qualitatively. There is an opposite behavior of Pr on temperature and concentration. Inverse behavior of λ on ϕ and wall mass flux is noted. Concentration ϕ is decreasing function of reaction rate constant σ. Skin friction coefficient has similar qualitative results for λ and β. Temperature gradient −θ^′(0) is decreased by λ and β.

Here, the authors are interested to investigate rotating flow in a porous space. Dissipation and radiation effects are neglected. Effects of activation energy are studied. This work is not done yet in literature.