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This paper used a novel technique, which is thermo-compression bonding, and Sn-1.0Ag-0.5Cu solder to form a full intermetallic compound (IMC) Cu₃Sn joints (Cu/Cu₃Sn/Cu joints). The purpose of the study is to form high-melting-point IMC joints for high-temperature power electronics applications. The study also investigated the effect of temperature gradient on the microstructure evolution and the growth behavior of IMCs.

In this paper, the thermo-compression bonding technique was used to form full Cu₃Sn joints.

Experimental results indicated that full Cu/Cu3Sn/Cu solder joints with the thickness of about 5-6 µm are formed in a short time of 9.9 s and under a low pressure of 0.016 MPa at 450°C by thermo-compression bonding technique. During the bonding process, Cu₆Sn₅ grew with common scallop-like shape at Cu/SAC105 interfaces, which was followed by the growth of Cu₃Sn with planar-like shape between Cu/Cu6Sn5 interfaces. Meanwhile, the morphology of Cu₃Sn transformed from a planar-like shape to wave-like shape until full IMCs solder joints were eventually formed during thermo-compression bonding process. Asymmetrical growth behavior of the interfacial IMCs was also clearly observed at both ends of the Cu/SAC105 (Sn-1.0Ag-0.5Cu)/Cu solder joints. Detailed reasons for the asymmetrical growth behavior of the interfacial IMCs during thermo-compression bonding process are given. The compound of Ag element causes a reduction in Cu dissolution rate from the IMC into the solder solution at the hot end, inhibiting the growth of IMCs at the cold end.

This study used the thermo-compression bonding technique and Sn-1.0Ag-0.5Cu to form full Cu₃Sn joints.

The purpose of this paper is to investigate growth kinetics of interfacial Cu-Sn intermetallic compound (IMC) at the solid Cu/liquid Sn interface.

The Sn/Cu solid–liquid interfacial IMCs are fabricated under various soldering temperatures (240°C-270°C) and soldering times (5-240 s) by dipping method. The thickness and morphology of IMC are observed and analyzed by the optical microscope and scanning electron microscope.

Holding at 260°C, Cu/Sn solid–liquid interface Cu₆Sn₅ growth index experience a change from 0.08 to 0.30 within 10-190 s. The growth index is 0.08 in 10-40 s; the growth index is 0.30 in 40-190 s. Cu₆Sn₅ grain coarsening index is constant within 10-190 s. It is 0.13. The result of the index of Cu₆Sn₅ grain coarsening is different from predecessors 27 results Cu₆Sn₅ grain coarsening index for 1/3. This is because Cu₆Sn₅ grain grows at the expense of its near small grain to reduce the surface Gibbs free energy, and its morphology changes from regular shape to irregular shape. It sets up the mathematical expression about the initial formation time and temperature of Cu₃Sn in 240°C-270°C.

It obtains a mathematical model to express the changes of solid–liquid interface frontier concentration which has an effect on the interfacial Cu₆Sn₅ layer growth index and the Cu₆Sn₅ grain coarsening index. Different indexes can be obtained by establishing relevance equations, which can be used to predict the growth of the interface IMC layer. This mathematical model is established to design the solder pads and the sizes of the solder joints.