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The purpose of this study is to develop resin composite materials composed of polycaprolactone (PCL) acrylates and hydroxyapatite (HA) nanoparticles for ultraviolet digital light projection (DLP) three-dimensional (3D) printing technique.

Two PCL-based triacrylates, namely, glycerol-3 caprolactone-triacrylate (Gly-3CL-TA) and glycerol-6 caprolactone-triacrylate (Gly-6CL-TA) were synthesized from ring-opening polymerization of ε-caprolacton monomer in the presence of glycerol and then acrylation was performed using acryloyl chloride. 3D printing resins made of Gly-3CL-TA or Gly-6CL-TA, 5% HA and 3% of photoinitiator 2,4,6-Trimethylbenzoyl-diphenyl-phosphineoxide were then formulated. The surface topography, surface element composition, flexural strength, flexural modulus, cytotoxicity and degradation of the PCL-based scaffolds were then characterized.

Resin composite composed of Gly-3CL-TA or Gly-6CL-TA and 5% (w/w) of HA can be printed by 405 nm DLP 3D printers. The former has lower viscosity and thus can form a more uniform layer-by-layer structure, while the latter exhibited a higher flexural strength and modulus after being printed. Both composite materials are non-cytotoxic and degradable.

This study provides a direction of the formulation of environment-friendly resin composite for DLP 3D printing. Both resin composites have huge potential in tissue engineering applications.

The aim of this paper is to examine the effects of light controlling system that combined high refractive particles (n-TiO₂ [titanium dioxide – TiO₂]) and tartrazine lake dye (TL dye) on thickness, flexural strength, flexural modulus and surface details of the 3D-printed resin.

Influences of different concentrations of n-TiO₂ and TL dye in light-cured resin formulations for 3D printing (3DP) application were evaluated, including curing thickness, flexural strength and surface details under scanning electron microscopy.

The polymerization thickness of samples containing both n-TiO₂ and TL dye was lower compared to samples with TL dye solely. Samples containing more n-TiO₂ and more TL dye exhibited lower flexural strength and modulus. Ramp models showed that for samples containing 1 per cent TL dye, when their n-TiO₂ content increased from 1 to 5 per cent, surface laminate structures became sharper. However, when the TL dye content doubled to 2 per cent, the surface laminate structures were indefinite compared to 1 per cent TL dye-containing counterparts.

In visible-light 3DP, light controlling system in cooperate dye with high refractive particles provides better energy distribution and scattering control. High refractive particles, dyes and light exposure time had influenced the surface resolution and mechanical properties of the 3DP products.

In public firms, the largest shareholder can make decisions on cash dividends in favor of its own interests at the expense of other investors. While the second largest shareholder can actively participate in corporate governance and protect the interests of investors, its impact has not been fully understood. This research investigates how shareholding ratio and ownership type of the second largest shareholder moderate the relationship between controlling shareholder's shareholding ratio and cash dividends.

The authors conducted econometrics analysis based on a panel data of China's A-share listed companies from 2007 to 2017.

The authors find that the controlling shareholder's shareholding ratio has a significant negative impact on cash dividends. However, this influence is conditional on the shareholding ratio of the second largest shareholder. The negative impact is weakened when the second largest shareholder holds a large proportion of shares or when the shareholding gap between the second largest and the controlling shareholder is small.

This research extends the existing literature by highlighting the nuanced moderating effect of the second largest shareholder on the relationship between the controlling shareholder and cash dividends, thus making a unique contribution to the understanding of corporate governances in the emerging financial market in China.

Distribution of long-haul goods could be managed via multimodal transportation networks where decision-maker has to consider these factors including the uncertainty of transportation time and cost, the timetable limitation of selected modes and the storage cost incurred in advance or delay arriving of the goods. Considering the above factors comprehensively, this paper establishes a multimodal multi-objective route optimization model which aims to minimize total transportation duration and cost. This study could be used as a reference for decision-maker to transportation plans.

Monte Carlo (MC) simulation is introduced to deal with transportation uncertainty and the NSGA-II algorithm with an external archival elite retention strategy is designed. An efficient transformation method based on data-drive to overcome the high time-consuming problem brought by MC simulation. Other contribution of this study is developed a scheme risk assessment method for the non-absolutely optimal Pareto frontier solution set obtained by the NSGA-II algorithm.

Numerical examples verify the effectiveness of the proposed algorithm as it is able to find a high-quality solution and the risk assessment method proposed in this paper can provide support for the route decision.

The impact of timetable on transportation duration is analyzed and making a detailed description in the mathematical model. The uncertain transportation duration and cost are represented by random number that obeys a certain distribution and designed NSGA-II with MC simulation to solve the proposed problem. The data-driven strategy is adopted to reduce the computational time caused by the combination of evolutionary algorithm and MC simulation. The elite retention strategy with external archiving is created to improve the quality of solutions. A risk assessment approach is proposed for the solution scheme and in the numerical simulation experiment.