Search results

This study aims to systematically compare the effect of increasing fiber–matrix interface adhesion and matrix toughness in layered composite materials.

Silane ((3-glycidyloxypropyl) trimethoxysilane) was applied to strengthen the fiber–matrix interface connection in e-glass/epoxy laminated composite material. Using a cationic surfactant, 0.1% multi-walled carbon nanotubes (CNTs) were added to the matrix in two different ways, by with and without chemical functionalization using the vacuum infusion method.

In the results obtained from the three-point bending test specimens, it was determined that the synergistic effect of silane application and non-functionalized CNT in the matrix was higher in terms of flexural modulus and strength values.

The functionalization of multi-walled CNT did not give the expected results because of reasons such as viscosity increase and agglomeration in the matrix.

In this study, a simple model for normalization and prediction purposes was developed, which allows the determination of the flexural modulus and un-notched flexural strength values from one test result of the notched specimen. A systematic comparison was performed by varying each parameter in the composite material.

The purpose of this research is to assess the removal of oil spills from the seawater surface as well as the antibacterial activity of ZnFe₂O₄-cetyltrimethylammonium bromide (CTAB, cationic surfactant) magnetic nanoparticles (ZFO-CTAB MNPs).

A CTAB-assisted sol–gel method was used to synthesize ZFO-CTAB MNPs. X-ray powder diffraction and Fourier transform infrared spectroscopy were used for ZFO-CTAB MNPs characterization. Also, the magnetic force and apparent density of ZFO-CTAB MNPs were determined. The oil spill cleanup was investigated by using the gravimetric oil removal (GOR) technique, which used ZFO-CTAB MNPs as oil absorbent material and four oil samples (crude, diesel, gasoline and used oil) as oil spill models. The antibacterial activity of ZFO-CTAB MNPs against Gram-negative bacteria (Pseudomonas aeruginosa, Escherichia coli and Salmonella typhi) was investigated by using the optical density method.

The results revealed that, when the amount of ZFO-CTAB was 0.01 g, gasoline oil had the highest GOR (51.80 ± 0.88 g/g) and crude oil had the lowest (11.29 ± 0.82 g/g). Furthermore, for Escherichia coli, Salmonella typhi and Pseudomonas aeruginosa, ZFO-CTAB MNPs inhibited bacterial growth with a higher percentage (94.24%–95.63%).

The applications of ZFO-CTAB MNPs in the cleanup of oil spills from aqueous solutions, as well as their antibacterial activity. The results showed that ZFO-CTAB MNPs are a promising material for removing oil spills from bodies of water as well as an antibacterial agent against Gram-negative bacterial strains.

The purpose of this study is to examine how well reinforced concrete structures can be shielded against concrete carbonation using anti-carbonation coatings based on synthetic polymer.

Applying free radical polymerization, an acrylate terpolymer emulsion that a surfactant had stabilized was created. A thermogravimetric analysis, minimum film-forming temperature, Fourier transform infrared spectroscopy and particle size distribution are used to characterize the prepared eco-friendly water base acrylate terpolymer emulsion. Using three different percentages of the acrylate terpolymer emulsion produced, 35%, 45% and 55%, the anti-carbonation coating was formed. Tensile strength, tensile strain, elongation, crack-bridging ability, carbon dioxide permeability, chloride ion diffusion, average pull-off adhesion strength, water vapor transmission, gloss, wet scrub resistance, QUV/weathering and storage stability are the characteristics of the anti-carbonation coating.

The formulated acrylate terpolymer emulsion enhances anti-carbonation coating performance in CO₂ permeability, Cl-diffusion, crack bridging, pull-off adhesion strength and water vapor transmission. The formed coating based on the formulated acrylate terpolymer emulsion performed better than its commercial counterpart.

To protect the steel embedded in concrete from corrosion and increase the life span of concrete, the surface of cement is treated with an anti-carbonation coating based on synthetic acrylate terpolymer emulsion.

In addition to saving lives from building collapse, it maintains the infrastructure for the long run.

The anti-carbonation coating, which is based on the synthetic acrylate terpolymer emulsion, is environmentally benign and stops the entry of carbon dioxide and chlorides, which are the main causes of steel corrosion in concrete.

This study aims to investigate the behavior of vegetable oil with two additives. Base oil’s tribological qualities can be improved with the help of several additions. In the present investigation, soybean oil is served as the foundational oil due to its eco-friendliness and status as a vegetable oil with two additives, named polytetrafluoroethylene (PTFE) and molybdenum disulfide (MoS₂).

As additives, PTFE and MoS₂ are used; PTFE is renowned for its anti-friction (AF) properties, while MoS₂ is a solid lubricant with anti-wear (AW) properties. This investigation examines the synergistic impact of AF and AW additions in vegetable oil. The lubricity of the base oil is measured by using a four-ball tester, and the wear properties of the oil at different additive amounts are determined by using a universal tribometer.

PTFE (at 5 Wt.%) and MoS₂ (at 1 Wt.%) were found to improve the tribological performance of the base oil. The weld load is significantly increased when 5 Wt.% of PTFE + MoS₂ is added to the base oil.

A better tribological characteristic can be achieved by combining additives that amount to less than 1% of the base oil. In experiments with highly concentrated MoS₂, the adequate pressure improved dramatically, but the lubricant’s tribological characteristics did not.

The peer review history for this article is available at: https://publons.com/publon/10.1108/ILT-11-2022-0321/

First, the effect of magnetic field intensity and nano-ferrofluid concentrations on surface roughness was evaluated in magnetic minimum quantity lubrication (MMQL). Then, the effect of lubricant flow rate and nozzle position on surface roughness was investigated in MQL, MMQL, electrostatic MQL (EMQL) and electromagnetic MQL (EMMQL).

This study examined the performance of MQL under magnetic and electric fields in turning AISI 304 stainless steel in terms of surface roughness and compared the results with those obtained from wet cutting and MQL turning operations. To prepare the nano-ferrofluid used in different states of MQL, Fe₃O₄ nanoparticles were added to the base fluid.

The results showed that the surface roughness under the EMMQL technique decreased by 36% and 49.4% on average compared with wet and MQL techniques, respectively. The lubrication technique affected the surface roughness by 90.2%, whereas it was 8.3% for the lubricant flow rate. EMQL and EMMQL techniques had no significant difference in their effects on surface roughness. In the innovative MMQL technique, the nano-ferrofluid concentration of 6% and magnetic field intensity of 93 G resulted in lower surface roughness of the workpiece relative to other counterparts.

Examining previously published studies showed that using nano-ferrofluids under a magnetic field for cooling purposes in machining processes have less considered by researchers. This study applies an innovative method of lubrication under the concurrent effect of magnetic and electric fields, called EMMQL, to improve the efficiency of MQL in machining hard-to-cut materials. For comprehensively inspecting the newly presented method, the effects of several parameters, including the nano-ferrofluid concentration, magnetic field intensity, lubricant flow rate and position of lubricant spray nozzle, on the surface roughness of workpiece in turning of AISI 304 stainless steel are investigated.

Petroleum hydrocarbons are naturally occurring flammable fossil fuels used as conventional energy sources. It has carcinogenic, mutagenic properties and is considered a hazardous pollutant. Soil contaminated with petroleum hydrocarbons adversely affects the properties of soil. This paper aim to remove pollutants from the environment is an urgent need of the hour to maintain the proper functioning of soil ecosystems.

The ability of micro-organisms to degrade petroleum hydrocarbons makes it possible to use these microorganisms to clean the environment from petroleum pollution. For preparing this review, research papers and review articles related to petroleum hydrocarbons degradation by micro-organisms were collected from journals and various search engines.

Various physical and chemical methods are used for remediation of petroleum hydrocarbons contaminants. However, these methods have several disadvantages. This paper will discuss a novel understanding of petroleum hydrocarbons degradation and how micro-organisms help in petroleum-contaminated soil restoration. Bioremediation is recognized as the most environment-friendly technique for remediation. The research studies demonstrated that bacterial consortium have high biodegradation rate of petroleum hydrocarbons ranging from 83% to 89%.

Proper management of petroleum hydrocarbons pollutants from the environment is necessary because of their toxicity effects on human and environmental health.

This paper discussed novel mechanisms adopted by bacteria for biodegradation of petroleum hydrocarbons, aerobic and anaerobic biodegradation pathways, genes and enzymes involved in petroleum hydrocarbons biodegradation.

The purpose of this study is to address consumer’s preference of natural pigments over synthetic ones and their use in various product developments rather than using synthetic colours. A budding interest of using natural pigments has made researchers to explore several techniques for their stabilization and application in different food products.

In this review, four major natural pigments with potential health benefits have been studied. Betalins, carotenoids, anthocyanins and chlorophylls, in spite of having excellent bio-functional and therapeutic profile, are found to be unstable. Therefore, various nanoencapsulation techniques are used to increase their stability along with their therapeutic properties.

Nanoencapsulation of natural pigments improves their stability, their effect on therapeutic properties and their application in different food products. These findings could be attributed to the encapsulating material as it acts as a barrier and ushers changes in the matrix of natural pigments. Also, nanoencapsulation not only increases stability but also provides several health benefits such as anti-inflammation, anti-cancer, anti-allergic and anti-thrombotic properties.

This paper highlights the openings for the use of nanoencapsulation of natural pigments to stabilize them and use them as a potential colourant and functional ingredient in different food products. Phenols, carotenoids and antioxidant activity are the major factors that are responsible for promoting several health benefits.

The purpose of this study is to reveal the underlying mechanism in film formation of oil-in-water (O/W) emulsion.

This study focuses on the film forming characteristics of O/W emulsion between the surface of a steel ball and a glass disc coated with chromium. The lubricant film thicknesses of O/W emulsion with various mechanical stirring strength were discussed, which were observed by technique of relative optical interference intensity.

The authors directly observed the oil pool in the contact area, finding the size of oil pool was closely related to the film-forming ability of emulsion. Enrichment phenomenon occurs in oil pool, which was caused by phase inversion. Further investigations revealed that the emulsion is stable with strong stirring strength, resulting in a smaller oil pool size and worse film forming ability.

With the wide usage of O/W emulsion in both biological and industrial systems, the ability of emulsion film formation is considered as an important factor to evaluate the lubrication effectiveness.

The peer review history for this article is available at: https://publons.com/publon/10.1108/ILT-12-2022-0354/

Self-crosslinked long fluorocarbon acrylate polymer latex has good hydrophobic and oleophobicity, weather resistance, aging resistance, stability and other excellent properties, which make the polymer be widely used in coatings, dyes, adhesives and other products. The purpose of this study is to prepare self-crosslinked long fluorocarbon acrylate polymer latex via semi-continuous seeded emulsion technology and carry out comparative study on two different cross-linked monomers.

Methyl methacrylate (MMA) and butyl acrylate (BA) were used as the main monomers, dodecafluoroheptyl methacrylate (DFMA) as the fluoromonomer, hydroxypropyl methacrylate (HPMA) and N-methylol acrylamide (NMA) as cross-linked monomers, and 1-allyloxy-3–(4-nonylphenol)-2-propanol polyoxyethylene (10) ether (ANPEO10) and 1-allyloxy-3–(4-nonylphenol)-2-propanol polyoxyethylene (10) ether ammonium sulfate (DNS-86) as compound emulsifiers via the semicontinuous-seeded emulsion polymerization.

The properties of the polymer emulsions, which are prepared with two different cross-linked monomers, are compared and discussed, and it is concluded that HPMA is more suitable for the preparation of self-crosslinked polymer emulsions. The formula of the polymer latex is ANPEO10: DNS-86 = 1:1, and the mass ratio of the monomers used in the polymer is MMA: BA: DFMA: HPMA = 14.40:14.40:0.60:0.60.

Self-crosslinked long fluorocarbon acrylate polymer latex can be used in many fields such as coatings, dyes, adhesives and other products.

The self-crosslinked long fluorocarbon acrylate polymer latex is prepared by mixing the nonionic emulsifier ANPEO10 and the anionic emulsifier DNS-86 when potassium persulfate is used as the thermal decomposition initiator and the semicontinuous-seeded emulsion technology is adopted and the comparative study on two different cross-linked monomer is carried out, which is not reported in the open literatures.

This paper aims to design the nano-titanium dioxide (TiO₂) coating system which has superhydrophilic property, self-cleaning mechanism and antifog property as well as strong adhesion on glass substrate.

Two hydrophilic materials have been used such as TiO₂ nanoparticles as fillers and hydrophilic copolymer, Pluronic F-127 by using simple sol–gel approach. The prepared solution was applied onto glass through dip- and spray-coating techniques and then left for drying at ambient temperature.

The nano-TiO₂ superhydrophilic coating has achieved the water contact angle of 4.9° ± 0.5°. The superhydrophilic coating showed great self-cleaning effect against concentrated syrup and methylene blue where thin layer of water washes the dirt contaminants away. The nano-TiO₂ coating exhibits great antifog performance that maintains high transparency of around 89% when the coated glass is placed above hot-fog vapor for 10 min. The fog droplets were condensed into water film which allowed the transmission of light through the glass. The strong adhesion of coated glass shows no total failure at scratch profile when impacted with scratch load of 500, 800 and 1,200 mN.

Findings will be useful in the development of self-cleaning superhydrophilic coating that is applicable on building glass and photovoltaic panel.

The developed nano-TiO₂ coating is developed by the combination of hydrophilic organic copolymer–inorganic TiO₂ network to achieve great superhydrophilic property, optimum self-cleaning ability and supreme antifog performance.

The findings will be useful for residents in building glass window where the application will reduce dust accumulation and keep the glass clean for longer period.

The synthesis of nano-TiO₂ superhydrophilic coating which can be sprayed on large glass panel and cured at ambient temperature.