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Oil‐in‐water (O/W) emulsion has been used in industrial rolling mills for many decades, but its lubrication mechanism is still not adequately understood. There is a need to understand the role of chemical ingredients and emulsifier in lubrication and tribological characteristics of rolling oil. With this purpose, the authors selected three commercially available O/W emulsions of different generations and of known industrial performance. The aim is to understand the lubrication mechanism of these rolling oils and to correlate the laboratory findings with that of industrial rolling mills.

The lubrication mechanism has been studied with the help of an ultra thin film interferometry EHD test rig, an advanced experimental rolling mill and a Coulter LS 230 instrument. Film thickness, rolling parameters and droplet size were measured. The coefficient of friction was computed with the help of the measured values of rolling parameters. Emulsion stability and saponification value (SAP) of the selected emulsions were also determined. The results of film thickness, rolling parameters and droplet size have been presented. The lubrication mechanism of the emulsions has been explained on the basis of film thickness, droplet size, emulsion stability, SAP value and coefficient of friction.

Results of the present study reveal that chemistry of O/W emulsions plays an important role in their film forming and tribological behavior. Rolling emulsions of relatively low stability, higher droplet size and high SAP value are found to provide better lubrication and lower coefficient of friction. The results of the present study correlate well with the actual industrial experience except those obtained on EHD test rig.

Coulter LS 230 instrument was available with M/s LUBRIZOL CORP., USA. Only limited study on droplet size was carried. Although the study carried out has given good information but it would have been more practical if the emulsion samples taken from the experimental mill stand would have been studied for droplet size.

From understanding point of view of lubrication mechanism of O/W emulsion, it will be useful for oil technologists, tribologists and rolling mill users.

The study is original in nature and gives information on lubrication mechanism of O/W emulsions in steel cold rolling of steel strips.

Epoxy resin emulsions are used in water‐based coatings for surface protection of concrete and metal. An unfortunate drawback for most emulsions is their poor freeze‐thaw stability. Epoxy emulsions are indeed unstable below 0°C, ‐5°C or ‐10°C, depending on the type of resin. In this study, other factors capable of influencing the freeze‐thaw behaviour were investigated: e.g. solids content, amount and type of emulsifiers, solvents, protective colloids. Discusses methods for testing the quality of thawed emulsions as well as the physics involved in their destabilization. Freeze‐thaw performance can be improved by different means but mostly not without sacrificing resistance properties of the coating. Therefore, avoiding temperatures below 0°C is still the best advice.

The purpose of this paper is to prepare waterborne UV-curable pigment pastes for cotton fabric printing.

O/W (oligomer-in-water) emulsions of polyurethane acrylate (PUA) oligomer in sodium dodecyl benzene sulphonate (SDBS) aqueous solution were prepared by ultrasonic emulsification method.

The present work studies various factors affecting the stability and droplet size of the O/W emulsion stabilised by SDBS. The optimal emulsifier concentration was 2.5 per cent, under which condition the stability of the emulsion increased as the emulsifier content increased, with a subsequent decrease in the droplet size of the emulsion, while above which emulsion agglomeration occurred. Increasing the power and duration of ultrasonic dispersion resulted in increased emulsion stability and decreased droplet size, while increases in the oligomer content reduced the emulsion stability. Darocure 1173 mixed with PUA and then emulsified in the SDBS aqueous solution guaranteed uniform dispersion of the photoinitiator, resulting in faster curing speed.

This paper presents a new method for making waterborne externally emulsified oligomers for UV curing, and finds that it is easy to convert the existing oligomers into waterborne equivalents by this method. Cotton fabrics printed with the oligomer emulsion based pastes were found to have good colour strength and crockfastness.

The purpose of this paper is to develop a new oil‐in‐water (O/W) emulsion used for alpha phase brass, which can increase the antiwear and anti‐galling abilities of the rollers, and improve the surface quality of the rolled brass sheet. The aim is to evaluate the tribological performance of new kind of O/W emulsion for the hot rolling of alpha brass, which provides the fundamental information for the selecting of new chemical group, and to understand the lubrication mechanism of the used rolling emulsion and to correlate the laboratory findings with those of industrial rolling of alpha phase brass.

According to the hydrophile‐lipophile balance theory and the evaluation results of friction, wear and lubrication using a four‐ball tribometer, a novel O/W emulsion was developed for the hot rolling process of CuZn₃₂(ASTM C26200) and CuZn₃₀(ASTM C26000) alloys by controlling the composition of the emulsion, such as emulsifying, antiwear, extreme pressure, antirust and so on. By scanning electron microscope (SEM), energy‐dispersive X‐ray (EDX), and roughness profile the tribological mechanism were studied.

The production result proved that it was easy to control the accuracy and size of the brass sheet because of the emulsion‐jet to the roller surface directly and in succession. Polyol with hydroxyl group is found to provide better lubrication and lower coefficient of friction. The actual hot rolling results proved that it was easy to control the accuracy and size of the brass sheet with the emulsion jet. The morphologies and roughness profile of the copper sheet surface were observed and measured by SEM and topographic meter under different lubricant conditions. The in situ results supported the selection of compositions of O/W emulsion. The suitable temperature of feed emulsion is over 20°C.

The tribological mechanism of friction modified emulsion is not still clear. The thermal mechanical properties of rollers under this kind of emulsion are also worth studying in the future.

Understanding the tribological behaviour of O/W emulsion, will be useful for emulsion chemists, tribologists and rolling mill users.

The current study shows new compositions of O/W emulsion used for hot rolling of alpha phase brass.

Modifications of poly(vinyl alcohol) (PVA) can improve the properties and performance of poly(vinyl acetate) (PVAc) emulsions stabilized with these modified colloids. Water resistance and toughness of the emulsions as wood adhesives can be achieved through chemical reactions of the hydroxy groups of the colloid with various modifiers. The chemical changes can be carried out either in the preparation of PVA through hydrolysis of copolymers of vinyl acetate and other monomers, or by the reaction of modifiers with PVA aqueous solutions. The modified PVAc emulsions show better properties than those of the conventional emulsions in performance tests and applications. The modified colloids are becoming increasingly used in the manufacture of PVAc emulsions in the adhesive industry, because of their advantages over emulsions made using conventional (unmodified) PVA. The trend of current research is to introduce more functionality into the colloid, so that the traditional protective colloids can be modified to function as crosslinkers and chain transfer agents.

This paper aims to study the effects of plum powder and apple pomace powder additions on the quality properties of buffalo meat emulsion.

Buffalo meat emulsions were prepared using different levels (2%, 4% and 6%) of plum powder and apple pomace powder, respectively. The meat emulsions were analysed for the physico-chemical, sensory and textural properties of the meat emulsion.

The pH of meat emulsions decreased significantly (p < 0.05) with an increased level of plum powder and apple pomace powder. Water-holding capacity (43.1%–48.1%), emulsion stability (80.2%–92.2%) and cooking yield (85.4%–91.0%) were significantly (p < 0.05) higher in plum powder and apple pomace powder added than the water-holding capacity (42.1%), emulsion stability (79.7%) and cooking yield (85.0%) of control emulsion. The moisture content was decreased significantly (p < 0.05), and crude fibre content was increased significantly (p < 0.05) with the increase in plum powder and apple pomace powder additions in meat emulsions. The total phenolic content and colour values (a* and b*) were significantly higher in plum powder and apple pomace powder added to meat emulsions. The sensory scores of meat emulsions were affected by the addition of plum powder and apple pomace powder. The meat emulsion added with 6% plum powder and 6% apple pomace powder showed significantly lower values of sensory overall acceptability. The hardness of meat emulsions increased with the addition of plum powder and apple pomace powder.

The results indicated that meat emulsions with a good cooking yield, fibre content, sensory acceptability and textural properties can be prepared by using plum powder and apple pomace powder.

The purpose of this study is to reveal the underlying mechanism in film formation of oil-in-water (O/W) emulsion.

This study focuses on the film forming characteristics of O/W emulsion between the surface of a steel ball and a glass disc coated with chromium. The lubricant film thicknesses of O/W emulsion with various mechanical stirring strength were discussed, which were observed by technique of relative optical interference intensity.

The authors directly observed the oil pool in the contact area, finding the size of oil pool was closely related to the film-forming ability of emulsion. Enrichment phenomenon occurs in oil pool, which was caused by phase inversion. Further investigations revealed that the emulsion is stable with strong stirring strength, resulting in a smaller oil pool size and worse film forming ability.

With the wide usage of O/W emulsion in both biological and industrial systems, the ability of emulsion film formation is considered as an important factor to evaluate the lubrication effectiveness.

The peer review history for this article is available at: https://publons.com/publon/10.1108/ILT-12-2022-0354/

This paper aims to examine the effect of wax, calcites and clay on the stability of petroleum emulsions. It proposes a proxy model that takes into cognizance the presence of solids other than asphaltene and resin. This study aims to investigate the combined effects of these solids on the stability of emulsions and show their relevance or otherwise in the creation of petroleum emulsions.

This paper used synthetic emulsions based on a response surface methodology using different weight concentrations of wax, calcites and clay. A Box–Behnken design model was adopted and the effects of the different variables on emulsion stability were analyzed. The conventional visual observation (batch testing) was augmented with a more robust technique of studying emulsion stability (Turbiscan) based on light backscattering or transmission. Analysis of variance and other statistics were used to analyze the results.

The paper makes an available proxy model that can predict the stability of petroleum emulsions in the presence of wax, calcites and clays. The findings suggest that in the presence of significant amount of wax (0.3 Wt.%), the presence of relatively lower concentration of clay (0.1 Wt.%) produces very stable petroleum emulsions. The results show that the most stable emulsion is obtained when significant amount of wax exists in the continuous phase and that a concentration of calcites more than wax (in a ratio of at least 2:1) produces an emulsion that separates very fast, indicating low stability.

Due to the variations in the amount of asphaltene and resins in crude oils, the proxy model cannot generally predict the stability of every emulsion that forms in the presence of these solids. To have a more general model, it should include asphaltene/resin. This can be tested further.

This paper provides useful information to the oil industry, especially where formation of severely stable emulsion is a problem. It also establishes the relationship that exists between solids in emulsion stabilization.

This paper satisfies a demand on the effects of other surface-active materials in addition to asphaltene/resin in stabilizing petroleum emulsions.

Printing toners are polymer composites accountable for transmission of digital images onto target substrates. Bearing in mind the ever increasing demand for high quality digital printing, modification and/or integration of existing techniques for manufacturing toners with favourable morphological and colour characteristics appears of vital importance. The present study aims to uncover the significance of in-situ polymerisation method, i.e. suspension, emulsion and mini-emulsion to control the microstructure of toner particles (particle size, particle size distribution and sphereness) while keeping the energy required for polymerisation along with reaction conversion at a reasonable level.

Assessment of particle size, particle size distribution and reaction conversion visualised the potential of suspension, emulsion and mini-emulsion polymerisation techniques to control microstructure, and colour characteristics of synthesized toners as well.

The results provided support for the fact that either the emulsion or mini-emulsion polymerisation routes will result in toners having an acceptable particle size and particle size distribution in the presence of a redox precursor. The higher monomer conversion at low temperature, as compared to the suspension polymerisation, was noticeable.

Analysing the glass transition temperature and colour characteristics of the resulting toners elucidated the superiority of mini-emulsion with respect to the other two cases which ranks this method on account of application.

For the first time, mini-emulsion route was put into practice and toners with acceptable colour and microstructure features were synthesised. In spite of lower polymerisation temperature and higher conversion of mini-emulsion compared to suspension and emulsion polymerisation techniques, further investigations are required to fine-tuning the properties of toners produced through this method.

In this work, the authors used reversible addition-fragmentation transfer (RAFT) polymerization to develop a new cationic acrylate modified epoxy resin emulsion for water-borne inkjet which have the advantages of both polyacrylate and epoxy resin. The emulsion was successfully used in the canvas coating for inkjet printing. This paper aims to contribute to the development of novel cationic emulsions for inkjet printing industry.

In this work, the epoxy acrylate was synthesized from RAFT agent and epoxy resin firstly. Cationic macromolecular emulsifier was prepared by RAFT polymerization, using 2,2’-Azobisisobutyronitrile as initiator, 2-(dimethylamino)ethyl methacrylate and styrene as monomer, which was directly used to prepare the emulsion. The influences of the amount of 2-(dimethylamino)ethyl methacrylate on particle size, zeta potential and water contact angle were studied. Finally, the cationic emulsion was used to print images by inkjet printing.

The emulsion has the smallest particle size, the highest potential and the highest water contact angle when the DM content is 13 Wt.%. The transmission electron microscopy analysis reveals the latex particles is core-shell sphere with the diameters in the range 120–200 nm. The emulsion was successfully used in the canvas coating for inkjet printing. This work will contribute to the development of novel cationic emulsions for inkjet printing industry.

The emulsion was successfully used in the canvas coating for inkjet printing. This work will contribute to the development of novel cationic emulsions for inkjet printing industry.