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The purpose of this paper was to prepare a ternary hierarchical rough particle to accelerate the anti-corrosive design for coastal concrete infrastructures.

A kind of micro-nano hydrophobic ternary microparticles was fabricated from SiO₂/halloysite nanotubes (HNTs) and recycled concrete powders (RCPs), which was then mixed with sodium silicate and silane to form an inorganic slurry. The slurry was further sprayed on the concrete surface to construct a superhydrophobic coating (SHC). Transmission electron microscopy and energy-dispersive X-ray spectroscopy mappings demonstrate that the nano-sized SiO₂ has been grafted on the sub-micron HNTs and then further adhered to the surface of micro-sized RCP, forming a kind of superhydrophobic particles (SiO₂/HNTs@RCP) featured of abundant micro-nano hierarchical structures.

The SHC surface presents excellent superhydrophobicity with the water contact angle >156°. Electrochemical tests indicate that the corrosion rate of mild steel rebar in coated concrete reduces three-order magnitudes relative to the uncoated one in 3.5% NaCl solution. Water uptake and chloride ion (Cl^-) diffusion tests show that the SHC exhibits high H₂O and Cl^- ions barrier properties thanks to the pore-sealing and water-repellence properties of SiO₂/HNTs@RCP particles. Furthermore, the SHC possesses considerable mechanical durability and outstanding self-cleaning ability.

SHC inhibits water uptake, Cl^- diffusion and rebar corrosion of concrete, which will promote the sustainable application of concrete waste in anti-corrosive concrete projects.

The purpose of this study is to assess the incorporation of fiber reinforced polymer (FRP) bars in concrete as a reinforcement enhances the corrosion resistance in a concrete structure. However, FRP bars are not practically used due to a lack of standard codes. Various codes, including ACI-440-17 and CSA S806-12, have been established to provide guidelines for the incorporation of FRP bars in concrete as reinforcement. The application of these codes may result in over-reinforcement. Therefore, this research presents the use of a machine learning approach to predict the accurate flexural strength of the FRP beams with the use of 408 experimental results.

In this research, the input parameters are the width of the beam, effective depth of the beam, concrete compressive strength, FRP bar elastic modulus and FRP bar tensile strength. Three machine learning algorithms, namely, gene expression programming, multi-expression programming and artificial neural networks, are developed. The accuracy of the developed models was judged by R², root means squared and mean absolute error. Finally, the study conducts prismatic analysis by considering different parameters. including depth and percentage of bottom reinforcement.

The artificial neural networks model result is the most accurate prediction (99%), with the lowest root mean squared error (2.66) and lowest mean absolute error (1.38). In addition, the result of SHapley Additive exPlanation analysis depicts that the effective depth and percentage of bottom reinforcement are the most influential parameters of FRP bars reinforced concrete beam. Therefore, the findings recommend that special attention should be given to the effective depth and percentage of bottom reinforcement.

Previous studies revealed that the flexural strength of concrete beams reinforced with FRP bars is significantly influenced by factors such as beam width, effective depth, concrete compressive strength, FRP bars’ elastic modulus and FRP bar tensile strength. Therefore, a substantial database comprising 408 experimental results considered for these parameters was compiled, and a simple and reliable model was proposed. The model developed in this research was compared with traditional codes, and it can be noted that the model developed in this study is much more accurate than the traditional codes.

The purpose of this paper is to review cases of artificial reefs built through additive manufacturing (AM) technologies and analyse their ecological goals, fabrication process, materials, structural design features and implementation location to determine predominant parameters, environmental impacts, advantages, and limitations.

The review analysed 16 cases of artificial reefs from both temperate and tropical regions. These were categorised based on the AM process used, the mortar material used (crucial for biological applications), the structural design features and the location of implementation. These parameters are assessed to determine how effectively the designs meet the stipulated ecological goals, how AM technologies demonstrate their potential in comparison to conventional methods and the preference locations of these implementations.

The overview revealed that the dominant artificial reef implementation occurs in the Mediterranean and Atlantic Seas, both accounting for 24%. The remaining cases were in the Australian Sea (20%), the South Asia Sea (12%), the Persian Gulf and the Pacific Ocean, both with 8%, and the Indian Sea with 4% of all the cases studied. It was concluded that fused filament fabrication, binder jetting and material extrusion represent the main AM processes used to build artificial reefs. Cementitious materials, ceramics, polymers and geopolymer formulations were used, incorporating aggregates from mineral residues, biological wastes and pozzolan materials, to reduce environmental impacts, promote the circular economy and be more beneficial for marine ecosystems. The evaluation ranking assessed how well their design and materials align with their ecological goals, demonstrating that five cases were ranked with high effectiveness, ten projects with moderate effectiveness and one case with low effectiveness.

AM represents an innovative method for marine restoration and management. It offers a rapid prototyping technique for design validation and enables the creation of highly complex shapes for habitat diversification while incorporating a diverse range of materials to benefit environmental and marine species’ habitats.

The purpose of this paper is to solve the abrupt deterioration of lubricant performance in high-temperature conditions.

Three silver pyrazolyl methyl pyridine complexes with different morphologies were synthesized. A four-ball tribometer was used to assess the tribological characteristics as an additive for pentaerythritol oleate both independently and compound with 1-hexyl-3-methylimidazolium bis(trifluoromethane sulfonyl)imide.

The results showed that when silver complexes and ionic liquids (IL) act independently, sheet silver complex 1 and rod silver complex 2 exhibit good lubricating performance; the optimal antifriction concentration of the ILs is 0.25 Wt.%. The tribological results of the compounds additive of ILs and silver complexes indicate that the wear scar diameter of compound 1 decreased by 16.914%, the wear volume reduced by 7.44% and the lubrication effect surpassed that of the two substances individually; rod compound 2 exhibited an antagonistic effect, intensifying wear; compound 3’s lubrication effect fell between that of the two individual components.

The compound of sheet silver complexes and ILs effectively solves the agglomeration problem of micro/nano lubricant additives. When the interface fails, self-repair is completed, improving the stability and antiwear performance of the lubricating oil.

The peer review history for this article is available at: https://publons.com/publon/10.1108/ILT-04-2024-0128

The purpose of this paper is to clarify the influence of low earth orbit space environment on the wear mechanism of TC4 alloy material and crank rocker mechanism.

In this study, friction experiments were carried out on TC4 alloy friction discs and crank rocker mechanisms, both before and after exposure to atomic oxygen and proton irradiation. Nanoindentation, grazing incidence X-ray diffraction (GIXRD), and X-ray photoelectron spectroscopy were employed to systematically characterize alterations in mechanical properties, surface phase, and chemical composition.

The results show that the wear mechanism of TC4 alloy friction disc is mainly adhesive wear in vacuum environment, while the wear mechanism of crank rocker mechanism includes not only adhesive wear but also abrasive wear. Atomic oxygen exposure leads to the formation of more oxides on the surface of TC4 alloy, which form abrasive particles during the friction process. Proton irradiation will lead to a decrease in fatigue performance and an increase in hardness on the surface of TC4 alloy, thus causing fatigue wear on the surface of TC4 alloy, and more furrows appear on the crank rocker mechanism after proton irradiation. In the three environments, the characteristics of abrasive wear of the crank rocker mechanism are more obvious than those of the TC4 alloy friction disc.

These results highlight the importance of understanding the subtle effects of atomic oxygen and proton irradiation on the wear behavior of TC4 alloy and provide some insights for optimizing its performance in space applications.

The peer review history for this article is available at: https://publons.com/publon/10.1108/ILT-02-2024-0051/

The objective was to investigate the utility of cottonseed oil (CSO) as a raw material for the synthesis of CSO water-based alkyd resin. The synthesis involved the polymerization of CSO, trimethylolpropane, phthalic anhydride (PA) and trimellitic anhydride (TMA). The prepared resin coating material was subsequently applied to the surface of steel structure material.

This study aimed to synthesize water-based alkyd resins using CSO. Therefore, the alkyd resin was introduced with TMA containing carboxyl groups and neutralized with triethylamine (TEA) to form a water-soluble salt. Then, the esterification kinetics of CSO water-based alkyd resin were investigated, and finally, the basic properties of CSO water-based alkyd resin coating were evaluated.

It was demonstrated that CSO water-based alkyd resin exhibited excellent water solubility and that the esterification kinetic of the synthesis reaction could be described by a second-order reaction. The coating properties of the material were investigated and found to have good basic properties, with 40% resin addition having the best corrosion resistance. Consequently, it could be effectively applied to the surface of steel structural materials.

This study not only met the requirement of environmentally friendly development but also expanded the application of CSO through the synthesis of CSO water-based alkyd resin via alcoholysis. Compared to fatty acid process, the alcoholysis reduced the need for fatty acid pre-extraction, simplifying the alkyd resin synthesis process. Thus, economic costs are effectively reduced.

The purpose of this paper is to prepare a multifunctional nanocomposite that is slow-release and resistant to seawater corrosion and biofouling corrosion and to explore the synergistic effect between the two corrosion inhibitors.

The morphology, structure and release properties of CAP@HNTs, BTA@HNTs and CAP/BTA@HNTs were investigated by scanning electron microscopy, transmission electron microscopy, Fourier transform infrared spectroscopy, specific surface area analysis and UV spectrophotometry. The corrosion resistance and antimicrobial properties were investigated by electrochemical measurements and bioinhibition rate tests, and the synergistic effect between the two corrosion inhibitors was explored by X-ray photoelectron spectroscopy.

The CAP/BTA@HNTs are responsive to acidic environments and have significantly improved antibacterial and corrosion resistance compared with CAP@HNTs and BTA@HNTs. CAP and BTA have a positive synergistic effect on anticorrosion and antifouling.

Two types of inhibitors, anticorrosion and antifouling, were loaded into the same nanocontainer to prepare a slow-releasable and multifunctional nanocomposite with higher resistance to seawater corrosion and biocorrosion and to explore the synergistic effect of CAP and BTA on corrosion resistance.

This study aims to investigate the individual electrochemical transients arising from local anodic events on stainless steel, to uncover the potential mechanisms producing different types of transients and to derive appropriate parameters indicative of the corrosion severity of such transient events.

An equivalent circuit model was used for the transient analysis, which was performed using a local current allocation rule based on the relative instant cathodic resistance of the coupled electrodes, as well as the kinetic parameters derived from the electrochemical polarization measurement.

The shape and size of the electrochemical current transients arising from SS 316 L were influenced by the film stability, local anodic dissolution kinetics and the symmetry of the cathodic kinetics between the coupled electrodes, where the ultralong transient might correspond to the propagation of film damage with a slow anodic dissolution rate. The dynamic cathodic resistance during the final stage of transient current growth can serve as a characteristic parameter that reflects the loss of passive film protection.

Estimation of the local anodic current trace opens a new way for individual electrochemical transient analysis associated with the charges involved, local current densities and changes in film resistance throughout localized corrosion processes.

This study aims to explore the synthesis and tribological performances of di-n-octyl sebacate (DOS) synthesized with spherical nano-MoS₂/sericite (SMS) and carboxylated SMS (CSMS) as catalysts.

SMS and CSMS were used as esterification catalysts to synthesize DOS from sebacic acid and n-octanol. The two catalysts were in situ dispersed in the synthesized DOS after the reaction to form suspensions. The tribological performances of the two suspensions after 20 days of storage were studied.

CSMS was more stably dispersed in DOS than SMS, and they reduced friction by 55.6% and 22.2% and wear by 51.3% and 56.5%, respectively. Such results were mainly caused by the COOH on CSMS, which was more conducive to improving the dispersion and friction reduction of CSMS than wear resistance. Another possible reason was the difference between the dispersion amounts of CSMS and SMS in DOS. The sericite of SMS was converted into SiO₂ to enhance wear resistance, while that of CSMS only partially generated SiO₂, and the rest still remained on the surface to reduce friction.

This work provides a more effective SMS catalytical way for DOS synthesis than the traditional inorganic acid catalytical method. SMS does not need to be separated after reaction and can be dispersed directly in DOS as a lubricant additive. Replacing SMS with CSMS can produce a more stable suspension and reduce friction significantly. This work combined the advantages of surface carboxylation modification and in situ catalytic dispersion and provided alternatives for the synthesis of DOS and the dispersion of MoS₂-based lubricant additives.

The purpose of this study is to evaluate the efficiency of a Brazilian steelmaking company’s reheating process of the hot rolling mill.

The research method is a quantitative modeling. The main research techniques are data envelopment analysis, TOBIT regression and simulation supported by artificial neural networks. The model’s input and output variables consist of the average billet weight, number of billets processed in a batch, gas consumption, thermal efficiency, backlog and production yield within a specific period. The analysis spans 20 months.

The key findings include an average current efficiency of 81%, identification of influential variables (average billet weight, billet count and gas consumption) and simulated analysis. Among the simulated scenarios, the most promising achieved an average efficiency of 95% through increased equipment availability and billet size.

Additional favorable simulated scenarios entail the utilization of higher pre-reheating temperatures for cold billets, representing a large amount of savings in gas consumption and a reduction in CO2 emissions.

This study’s primary innovation lies in providing steelmaking practitioners with a systematic approach to evaluating and enhancing the efficiency of reheating processes.