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A newly developed polyvinyl acetate (PVA) emulsion latex for adhesive has been prepared by the semicontinuous process using a newly developed octyl aldehyde sodium bisulphite‐potassium persulphate redox pair initiation system. In this work the amount of polyvinyl alcohol (PVA) as a protective colloid has been changed and it was found that only a little amount of (PVA) together with the newly developed adduct could cause a stable latex with excellent mechanical properties for bonding wood which favours this redox system in large industrial applictions. Also monodisperse latex particles with low polydispersity index can be prepared by using 1% PVA coupled with the newly developed redox system. Finally the developed latex has been incorporated and the corresponding shear strength were measured.

This study aims to manufacture alternative window shutters using waste cotton fabrics by stiffening using polyvinyl acetate (PVA) with vinyl acrylic binder solutions.

The manufactured fabrics were evaluated for their tensile strength, drapeability, bending length by weight and color fastness to light. And finally, an analysis of variance was done for each parameter.

As the percent of PVA with a vinyl acrylic solution and the number of layers increased, the tensile strength, drape coefficient (percent), bending length (cm), and color fastness to light increased in both directions. The percent of PVA with a vinyl acrylic solution and the number of layers are statistically significant for each response such as tensile strength, drape coefficient (percent), bending length (cm), color fastness to light and water repellency at a 95% confidence interval. Tensile strength, drape coefficient (%) and bending length (cm) are always greater in the warp direction than in the weft direction. The tensile strength, drape coefficient (percent), bending length (cm) and color fastness to light of treated fabrics samples are greater than those of the untreated fabrics.

The factory waste fabrics can be recycled into window shutters which will provide the cheaper raw material for window shutter manufacturers.

The purpose of this paper is to investigate the effects of the components of whey‐protein based aqueous polymer‐isocyanate (API) adhesives on the bond strength.

The bond test (according to the JIS K6806‐2003 standard), Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM) were used to characterise the whey‐protein based API adhesives with various formulations and processing technologies.

The good bond strength of the optimised whey‐protein based API adhesive was attributed to the formation of strong chemical bonds in the bondline and to the additions of polyisocyanate, polyvinyl alcohol (PVA) and nano‐CaCO₃ powder that improved adhesive cohesive strength by either chemical crosslinks or mechanical interlocking. The blending procedures of whey protein, PVA, polyvinyl acetate (PVAc) and p‐p‐MDI had great impacts on the performances of the whey‐protein based API adhesives.

SEM micrographs showed that the effects of blending processes on the bond strength, pot life and colour might be attributed to the particle size of hydrophobic p‐MDI droplet and p‐MDI distribution in the protein‐PVA matrix.

The study lays the foundations of the formulation design and the processing technology for preparing whey‐protein based API adhesives.

The effects of the components of whey‐protein based API adhesives and the effects of blending processes on the bond strength were investigated by means bond strength evaluation, FTIR and SEM analyses; whey protein is utilised successfully to prepare novel API adhesives for structural uses.

The purpose of this paper is to develop an environmentally safe aqueous polymer‐isocyanate (API) wood adhesive for structural uses with whey protein isolate (WPI) that is a by‐product of cheese making.

The API formulations with whey proteins denatured at different heating temperatures and times, WPI/polyvinyl alcohol (PVA) denaturing processes, PVA contents and nano‐CaCO₃ (as filler) contents were investigated and optimised according to the JIS K6806‐2003 standard.

A whey‐protein based API adhesive was developed which had 28 h boiling‐dry‐boiling wet compression shear strength 6.81 MPa and dry compression shear strength 13.38 MPa beyond the required values (5.88 and 9.81 MPa, respectively) for structural use of commercial standards. The study also indicated that the thermal denaturation of 40 per cent WPI solution at 60‐63°C could unfold the globular structure of whey protein to some extent and therefore improve the bond strength and bond durability of whey‐protein based API adhesive; the additions of PVA and nano‐CaCO₃ as filler had a significant effect on the bond strength and bond durability of whey‐protein based API adhesive.

The thermally denatured WPI solutions (40 wt%) incline towards being decayed by moulds if not properly formulated.

Owing to the good bond strength and durability and environmental safety, the optimised whey‐protein based API adhesives have greater potential for commercial applications, especially for the structural wood bonds.

A novel API wood adhesive for structural use was developed using whey proteins that are often regarded as a waste due to their relatively small molecules and compact globular structures.

ALL ‘plastics’ are generally divided into two groups: the ‘thermoplastics’, which are formed by heating, can be re‐heated after forming, and re‐formed almost ad lib, such as celluloid, xylonite, rhodoid, cellophane, and perspex; and the ‘thermosetting plastics’, which are also formed by heating but cannot yet be re‐formed by the application of heat or any other means, probably the best‐known example of which is the thermosetting variety of bakelite.

Developments in acrylic polymer technology over the past few years have led to the possibility today of formulating total paint systems for wood using water based all‐acrylic coatings.

The paper's aim is to show the development of materials and methods which allow freeform fabrication of macroscopic Zn‐air electrochemical batteries. Freedom of geometric design may allow for new possibilities in performance optimization.

The authors have formulated battery materials which are compatible with solid freeform fabrication (SFF) while retaining electrochemical functionality. Using SFF processes, they have fabricated six Zn‐air cylindrical batteries and quantitatively characterized them and comparable commercial batteries. They analyze their performance in light of models from the literature and they also present SFF of a flexible two‐cell battery of unusual geometry.

Under continuous discharge to 0.25 V/cell with a 100 Ω load, the cylindrical cells have a specific energy and power density in the range of 40‐70 J/g and 0.4‐1 mW/cm², respectively, with a mass range of 8‐18 g. The commercial Zn‐air button cells tested produce 30‐750 J/g and 7‐9 mW/cm² under the same conditions, and have a mass range of 0.2‐2 g. The two‐cell, flexible Zn‐air battery produces a nominal 2.8 V, open‐circuit.

The freeform‐fabricated batteries have ∼10 percent of the normalized performance of the commercial batteries. High‐internal contact resistance, loss of electrolyte through evaporation, and inferior catalyst reagent quality are possible causes of inferior performance. Complicated material preparation and battery fabrication processes have limited the number of batteries fabricated and characterized, limiting the statistical significance of the results.

Performance enhancement will be necessary before the packaging efficiency and design freedom provided by freeform‐fabricated batteries will be of practical value.

The paper demonstrates a multi‐material SFF system, material formulations, and fabrication methods which together allow the fabrication of complete functional Zn‐air batteries. It provides the first quantitative characterization of completely freeform‐fabricated Zn‐air batteries and comparison to objective standards, and shows that highly unusual, functional battery designs incorporating flexibility, multiple cells, and unusual geometry may be freeform fabricated.

Defines what varnish is, and traces its history. Outlines the various types of varnish and their main uses – alkyds, cellulose, melamine, epoxy, polyurethanes, phenolic, thermoplastic, and natural varnishes. Reviews 15 properties and terminologies associated with varnishes. Supplies two brief examples of proper use of varnish. Concludes with ten ′general rules′ of varnishing.

There was a time when these compositions could command only a limited interest, but the range of applications is now so wide, that demand has expanded as an ever increasing clientele is using them.

The consumption of adhesives in Germany, France and the UK is forecast to grow at an aggregate rate of 2.7% p.a. giving a total market for the three countries of some 840,000 tonnes in 1996. Most of this growth is forecast to occur in Germany as a result of the need for reconstruction following reunification. These are some of the principal conclusions from a new detailed report on the European adhesives market published by IAL Consultants Limited. The report covers the UK, France and Germany in three separate volumes. Each volume costs £1,250 and the three volume set can be purchased for £3,000 from: IAL Consultants Ltd., 14 Buckingham Palace Road, London SW1W OQP; Tel: 071‐828 5036; fax:071‐828 9318.