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The relatively complex corrosion mechanism of aluminium has been studied by several authors. Corrosion of aluminium occurs only when the metal protective oxide layer is damaged and when the repair mechanism is prevented by chemical dissolution. Polarization methods have been extensively used to investigate the mechanism of localised corrosion and processes that lead to localised corrosion. The potential‐pH diagrams are shown in Fig. 1A. In using potentiostatic techniques, the potential is controlled and current is determined as the independent variable. Potentiostatic and potentiody‐namic techniques have been applied by several authors to study the corrosion of aluminium in different environment. Both anodic and cathodic polarization curves have been used to interpret the kinetics of pitting corrosion of aluminium in chloride containing environments. Both the anodic and cathodic process are complex and the interpretation of the anodic and cathodic polarization curves of aluminium is often tedious. The situation arises partly from the fact that the role of film formation on the kinetics of corrosion is not clearly understood. Previously there is not established mechanisms of initiation and propagation of pits in aluminium and its alloys. Several parameters such as pitting potential, breakdown potential, active passive transition potential, related to the pitting process of aluminium, are full of controversy. Numerous references on the above can be found in literature).

Cyclic voltametry and potentiodynamic single sweep techniques are used to study the electrochemical behaviour of lead in Na₂CO₃ solutions containing various concentrations of ClO₄^‐ as aggressive anion. The effects of different concentrations, in terms of destruction of passivity and initiation of pitting corrosion, were monitored with reference to the change in integrated anodic charge. It was found that Δq_a (taken as a measure of the extent of pitting) varies linearly with log C_ClO4‐. The pitting corrosion potential, E_pitting, varies with log C_ClO4‐ according to sigmoidal curves. These curves are explained on the basis of formation of passive, active and continuously propagating pits. Additions of aliphatic amines shift the pitting corrosion potential, E_pitting, into the noble (positive) direction, indicating the inhibition action of the added amines on the pitting attack. E_pitting varies with the logarithm of the inhibitor concentration according to: E_pitting = a + b log C_inh. The inhibition of pitting corrosion by the aliphatic amines is assumed to be due to either competitive adsorption between the CO₃^2– with ClO₄^‐ anions, and/or the chemisorption of the amine on the metal with the formation of a metal‐nitrogen coordination bond. The efficiency of these compounds as pitting corrosion inhibitors increases with the increase in the chain length of the alkyl group.

PITTING CORROSION generally takes the form of localised corrosive attack at closely defined points, whose area constitutes only a minute part of the total surface of the steel. The considerably higher rate at which the steel goes into solution at these points causes the cavities to grow in depth, and may ultimately result in perforation. Fig. 1. The rate of pitting corrosion is largely determined by the proportion of the total cathodic to the total anodic area. The anodic current and the cathodic current flowing in the corrosion cell are equal.

The SiC reinforced Al composite is perhaps the most successful class of metal matrix composites (MMCs) produced to date. They have found widespread application for aerospace, energy, and military purposes, as well as in other industries – for example, they have been used in electronic packaging, aerospace structures, aircraft and internal combustion engine components, and a variety of recreational products. In all these applications, welding plays a vital role. Little attention has been paid to SiC reinforced aluminium matrix composites joined by gas tungsten arc (GTA) welding. The purpose of this paper is to outline the manufacturing method for producing MMCs, GTA welding of MMCs and pitting corrosion analysis of welded MMCs.

This paper focuses upon production and welding of metal matrix composites. The welded composites have been treated at elevated and cryogenic temperatures for experimental studies. Pitting corrosion analysis of welded plates was carried out as per Box Benkehn Design.

From the results, it should be noted that maximum pitting resistance was observed with MMCs containing 10% SiC treated at cryogenic temperature. Corrosion resistance of welded composites treated at elevated temperature was found to be higher than that of as‐welded and at cryogenic temperature treated composites. The pitting potential increases with increase in % SiC to certain level and decreases with further increase in % SiC. Corrosion potential of composites treated at elevated temperature is high compared to other composites. Maximum pitting resistance is observed when the welding current was kept at 175 amps for 10% addition of SiC in LM25 matrix treated at cryogenic temperature.

The paper outlines the manufacturing method for producing MMCs, GTA welding of MMCs and pitting corrosion analysis of welded MMCs. The results obtained may be helpful for the automobile and aerospace industries.

The potentiodynamic anodic polarization curves for the lead electrode were obtained in 0.1 mol L‐1 KOH solution in the absence and presence of C103‐ or C104‐ as aggressive ions at different concentrations. Lower concentrations of these ions have no significant influence on the passive film, while higher concentrations raise the active dissolution current density, and cause destruction of passivity and initiation of pitting corrosion. The critical pitting corrosion potential varies with the concentration of the aggressive ions according to sigmoidal curves. These curves were explained on the basis of the formation of passivitable, active and continuously propagagting pits depending on the range of the aggressive ion concentration. Additions of increasing concentrations of chromate, phosphate, sulphate and carbonate ions cause a shift of the critical pitting potential in the noble direction accounting for increase resistance to pitting attack (inhibition). The pitting corrosion potential varies with the concentration of the inhibitive ions, in the presence of a constant concentration of the aggressive ions, according to curves of sigmoidal shape. From these curves one can determine the minimum concentration of the inhibitive ions necessary for inhibition of pitting corrosion to occur.

This paper aims to evaluate the corrosion behavior of Ti-6Al-4V parts produced with electron beam melting (EBM) machine and compare it with wrought Ti-6Al-4V alloy.

Potentiodynamic and potentiostatic tests were applied on EBM Ti-6Al-4V in 3.5 per cent mass NaCl solution to determine the pitting potential and critical pitting temperature (CPT). A relation between pitting potential and temperature was established for EBM Ti-6Al-4V alloy by conducting potentiodynamic testing under different temperatures. CPT was also measured for EBM Ti-6Al-4V alloy in 3.5 per cent mass NaCl solution at a standard potential of 800 mV vs saturated calomel electrode (SCE). The same tests were performed on wrought Ti-6Al-4V for comparison purposes. Moreover, CPT for EBM Ti-6Al-4V alloy was measured in 3.5 per cent mass NaCl solution of different pH of 2.0, 5.7 and 10.0 to examine the effect of aggressive conditions on the pitting corrosion of EBM alloy.

Potentiodynamic test resulted in a relatively high pitting potential of EBM alloy, which was close to the pitting potential of wrought alloy even at higher temperatures. In addition, EBM samples did not pit when potentiostatic test was performed at 800 mV vs SCE, even at high and low values of pH.

EBM Ti-6Al-4V alloy has been increasingly playing an important role in aerospace, automobile and industrial fields. The technique and conditions of manufacturing form voids and increase roughness of the exterior surface of EBM objects, which might increase the tendency to initiate pitting corrosion within its holes and surface folds. This article shows that, despite surface variations and porosity in EBM Ti-6Al-4V alloy, the material maintained its corrosion resistance. It was found that the corrosion behavior of EBM alloy was close to that of the conventionally made wrought Ti-6Al-4V alloy.

The purpose of this study was to investigate the pitting resistance and assess the critical pitting temperature (CPT) of a super martensitic stainless steel, 00Cr13Ni5Mo2, made in China, considering especially the difference in the pitting corrosion resistance between the domestic super martensitic stainless steel and an imported one.

Potentiodynamic sweep tests were applied to investigate the effects of four NaCl concentrations (weight per cent) of 1, 3.5, 9 and 17, and four testing temperatures of 30, 50, 75 and 90°C on the pitting resistance of the domestic super martensitic stainless steel in the presence of CO₂. Potentiostatic sweep tests were utilized to determine the CPT. Furthermore, chemical immersion exposures, implemented according to the appropriate standard were used to evaluate the difference in the pitting corrosion resistance between the domestic super martensitic stainless steel and an imported one. In addition, the morphology of pits was analyzed using a scanning electron microscope.

The pitting potential of the domestic super martensitic stainless steel decreased with an increase in NaCl concentration and temperature in the presence of CO₂. The CPT of the domestic super martensitic stainless steel measured by potentiostatic polarization was 41.16°C. Two types of typical corrosion pits, closed pits formed at 35°C and open pits formed at 50°C, were observed. Furthermore, compared to the super martensitic stainless steel made in Japan, the domestic one was better in terms of pitting potential, corrosion rate and the density of the pits, but worse in terms of the depth of the pits, which may result in a risk of corrosion perforation of tubing and casings.

The paper highlights that chloride ions, temperature and the presence of CO₂ play an important role on the pitting resistance of super martensitic stainless steel.

This paper aims to expand the application area of Inconel 718 alloy in marine environment, the sensitivity of pitting corrosion should be analyzed and discussed, especially the effect of block carbides.

Effect of carbides on the sensitivity of pitting corrosion for Inconel 718 alloy was carried out at 30°C in 3.5% NaCl solution using dynamic electrochemical impedance spectroscopy and anodic polarization techniques. In addition, the initiation of pitting corrosion was investigated by immersion test in 0.05 M HCl + 6% FeCl₃ solution.

As a result, the precipitation of carbides, as the initiation of pitting corrosion, increased pitting corrosion susceptibility, especially the block carbides could lead to deep-spalling. Within that process, temperature and potential acted as the main controlling factors, and the effect of the latter was more distinct.

The initiation of pitting corrosion was revealed by the immersion test. The mechanism of pitting corrosion was analyzed and discussed.

Aluminum tripolyphosphate was used as a corrosion inhibitor in a simulated concrete pore solution. For studies of the inhibition mechanism of aluminum tripolyphosphate on the carbon steel, its influence on the pitting initiation on the carbon steel in a Cl⁻ containing pore solution were investigated.

Potentiodynamic polarization curves, Mott–Schottky plots and potentiostatic polarization of the carbon steel in the pore solution with different content of aluminum tripolyphosphate were measured, as well as the optical micrographs of pitting on the carbon steel was observed.

The metastable pitting potential and the stable pitting potential increased, while the donor density and the flat band potential decreased with the concentration of aluminum tripolyphosphate in solution. Furthermore, the initiation of pitting was suppressed, as well as the transition from metastable to stable pitting was hindered by the aluminum tripolyphosphate. The scale parameter (a), in the extreme distribution of the maximum current peak, could be used to predict the transition from metastable to stable pitting.

The inhibition mechanism of aluminum tripolyphosphate on carbon steel in pore solution was revealed. It suppresses the initiation of pitting and hinders the transition from metastable to stable pitting. Furthermore, a parameter defined as the scale parameter (a) in the extreme distribution of the maximum current peak was introduced to predict the transition from metastable to stable pitting.

The purpose of this paper is to study the electrochemical behavior of Sn electrode in Na₂B₂O₇ solutions in the absence and presence of NaNO₃ as a pitting corrosion agent.

The electrochemical behavior of Sn electrode was studied by using cyclic voltammetry and potentiodynamic polarization measurements and complemented with scanning electron microscopy examinations.

This paper shows that in the absence of NO₃ − ions, the anodic polarization of Sn electrode exhibits active/passive transition. Addition of various concentrations of NO₃ − anions to the borate solution enhances active anodic dissolution and tends to break down the passive oxide film at a certain pitting potential. The pitting potential, and hence the pitting corrosion resistance, decreases with increasing NO₃-ion concentration and temperature but increases with scan rate and repetitive cycling. Addition of CrO₄²⁻, WO₄²⁻ or MoO₄²⁻ oxyanions to the borate nitrate solution inhibits the pitting corrosion of Sn.

This is the first study that shows the effect of NO₃ − ion as a pitting corrosion agent.