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The aim of this work was to propose a method to prepare composite phosphate conversion coating (CPCC), including ternary phosphate conversion coating (TPCC) and binary phosphate conversion coatings (BPCC), with one-step chemical conversion and to reveal and compare the corrosion resistance between TPCC and BPCC.

In this work, a calcium–manganese–zinc (Ca–Mn–Zn) TPCC was prepared on the surface of magnesium alloy (MA) AZ91D with one-step chemical conversion method; for Ca-Mn-Zn@TPCC, its microstructure was characterized with scanning electron microscope observation and scanning tunneling microscope detection, and its composition was characterized with energy dispersion spectroscopy and X-ray photoelectron spectroscopy analyses. Particularly, the corrosion resistance of Ca-Mn-Zn@TPCC and its comparison with Ca–Mn, Ca–Zn and Mn–Zn BPCCs were clarified with electrochemical and immersion measurements.

Ca-Mn-Zn@TPCC, which was composed of Ca, Mn, Zn, P and O, exhibited a mud-shaped with cracks microstructure, and the average crack width, terrain fluctuation and coating thickness were 0.61 µm, 23.78 nm and 2.47 µm, respectively. Ca-Mn-Zn@TPCC provided good corrosion resistance to MA AZ91D; in NaCl solution, the total degradation of Ca-Mn-Zn@TPCC consumed eight days; corrosion products with poor adhesion peeled out from Ca-Mn-Zn@TPCC-coated MA AZ91D spontaneously. Besides, the corrosion resistance of Ca-Mn-Zn@TPCC was better than that of Ca-Mn@BPCC, Ca-Zn@BPCC or Mn-Zn@BPCC.

The successful preparation of Ca-Mn-Zn@TPCC on MA AZ91D surface confirmed the proposed method to prepare CPCC with one-step chemical conversion was feasible; at the same time, it was further confirmed that for phosphate conversion coating, ternary coating had better corrosion resistance than binary coating did.

The purpose of this paper is to investigate a chromium‐free conversion coating treatment for magnesium with phytic acid solution.

Pure magnesium was selected for the tests. Phytic acid solution was used as the conversion solution of surface treatment. The samples of magnesium were immersed in the solution under certain conditions to form a conversion coating on the surface of magnesium. The formation process of phytic acid conversion coating was studied by detecting the open circuit potential (OCP) and weight change of the pure magnesium for different conversion treatment times. Scanning electron microscopy (SEM) and electron energy spectrum (EDS) were used to examine the morphologies and compositions of the coatings, respectively.

The experimental results showed that the conversion coating had a multideck structure with netlike morphology, which is similar in nature to chromate conversion coatings, and was composed mainly of Mg, P, O and C. The contents of C and P and the size of the cracks in different conversion layers decreased from the external layer to the inner layer. The thickness of the conversion coating varied from 1.0μm to 15μm according to the processing parameters. The hydroxyl groups and phosphate carboxyl groups in the coating, which have similar properties to an organic paint coat, are beneficial to the combination of substrate and organic paint coating. The formation mechanism and thickness variation of the conversion coatings also are discussed.

The paper shows that phytic acid conversion coating could improve the electrochemical properties of magnesium and provide effective protection, which can improve the corrosion resistance of magnesium.

Corrosion protection efficiency of any protective system depends not only on the nature and quality of the coating system used but also on the condition of the mrface on which it is to be applied. Various metal cleaning methods include (a) chemical cleaning — solvent degreasing, alkali cleaning and acid pickling (b) mechanical cleaning — shot blasting and (c) chemical conversion coatings — phosphating. Several of the recent advances in the field of prepaint treatment of steel have had as an objective the provision of an intrinsically fine, compact, well adhered zinc phosphate coating. Studies in this direction have been carried out in Central Building Research Institute, Roorkee and conditions for a suitable phosphating process have been optimised. Some work on the development of zinc rich paints based on both inorganic as well as organic binders have already been reported. The study has been extended by evaluating the performance of these zinc rich coatings on phosphated steel panels. In this report the performance of the above mentioned coatings when applied on the phosphated steel panels have been discussed. The studies reported include the preparation of the phosphated mild steel panels having three levels of coating wight ranging between 1.5–7.5 g/m2 (obtained by varying only the immersion time and keeping other parameters similar). A cost of zinc rich paint (75m?) based on either sodium silicate or chlorinated rubber binder was then applied on these panels along with the unphosphated ones. Comparison of the corrosion protection efficiency of the various systems thus obtained was carried out by using both laboratory and accelerated laboratory tests as well as by outdoor exposure studies. The performance of the coatings on phosphated panels has been remarkedly satisfactory as compared to the unphosphated panels. This is particularly so when the coating weight of the phosphate layer is between 4.5–7.5 g/m2; there is not any marked difference in the performance of paints applied on a phosphated layer with a coating weight of about 1.5 g/m2 as compared to the unphosphated panels.

The purpose of this paper is to investigate corrosion protection provided by a water‐soluble corrosion inhibitor as a non‐toxic alternative to the chromate and phosphate conversion coatings on galvanised steel.

Untreated galvanised steel samples were assessed simultaneously with galvanised steel samples treated with the chromate‐free organic inhibitor, a conventional chromate conversion coating or a zinc phosphate modified with nickel, by means of immersion – weigh loss and electrochemical tests, using a naturally aerated 0.5 M NaCl aqueous solution as corrosive medium. In addition, selected superficial conditions of galvanised steel were submitted to a salt fog test. The electrochemical tests used were: open circuit corrosion potential logging, linear polarization, potentiodynamic polarization and electrochemical impedance spectroscopy. Corrosion products formed on samples withdrawn from the solution at different intervals were characterized using X‐ray diffraction.

All tests gave concordant results, indicating that the chromate‐free inhibitor showed moderate protective properties in this electrolyte. Among the considered superficial conditions, the phosphate coating showed the most deficient performance. In all cases, it was observed that after moderately intense initial attack, the corrosion rate diminishes due to the formation and growth of insoluble corrosion product layers, which exhibit a passivating action.

The chromate‐free organic corrosion inhibitor protected galvanised steel in this environment but the degree of protection was less than that provided by the chromate conversion coating.

The paper presents an alternative to the toxic treatments with chromates, since the inhibitor works as an additional coating, sealing pores and other discontinuities found in the zinc coating.

This study aims to investigate a chromium-free sealing treatment process to replace the chromate sealing process in response to the environmental hazards caused by chromate in the Phosphate chemical conversion (PCC) coating post-treatment sealing process.

In this paper, chromium-free sealing technology was used to post-treat PCC coatings. Scanning electron microscopy was used to investigate the structure of the surface of the PCC coatings after the sealing treatment, and the corrosion resistance, hydrophobicity and bonding were tested using an electrochemical workstation, a copper sulfate spot-drop test, a lacquer bonding test, a contact angle meter and a neutral salt spray test.

Chromium-free closure makes the grain distribution on the surface of the PCC coating more uniform and dense, and forms an organic film on the surface of the coating, which significantly improves the corrosion resistance and hydrophobicity of the PCC coating, does not affect the coating film bonding force and has similar performance with potassium dichromate solution.

The results show that the corrosion resistance of PCC coatings after chromium-free sealing treatment is improved, and chromium-free sealing has the potential to replace chromium sealing.

The purpose of this paper is to investigate the effect of plasma electrolytic oxidation (PEO) coatings and sealed PEO coatings on the corrosion resistance and cytocompatibility of a novel Mg-1Zn-0.45Ca alloy in simulated body fluid (SBF).

The microstructure, corrosion resistance and cytocompatibility of PEO coatings and phosphate conversion-treated PEO coatings were investigated and was compared with the bare Mg alloy.

The hot-extruded Mg-Zn-Ca alloy exhibit inhomogeneous microstructure and suffered from localized corrosion in the SBF. The PEO coating after phosphate conversion treatment offers enhanced protectiveness to the Mg alloy within an immersion period of up to 60 days, which is significantly improved compared with the performance of the PEO-coated Mg alloy, but the cytocompatibility was slightly decreased.

This work offers new perspective in balancing the protectiveness and cytocompatibility of bio-materials.

This paper aims to report the influence of hexamethylenetetramine (HMTA) on phosphate coatings formed on AZ31 magnesium alloys.

These phosphate coatings were obtained by immersing magnesium alloys in phosphate baths with HMTA. The morphology and composition of the phosphate coatings were investigated via scanning electron microscopy, energy dispersive spectrometry and X-ray diffraction.

The phosphate coatings were mainly composed of CaHPO₄·2H₂O. The HMTA concentration in the phosphate bath influenced the crystallization and corrosion resistance of the phosphate coating.

The polarization curve shows that the anti-corrosion qualities of the phosphate coating were optimal when the HMTA concentration was 1.0 g/L in the phosphate bath. Electrochemical impedance spectroscopy (EIS) shows that the electrochemical impedances increased gradually when the HMTA concentration varied from 1.0 to 3.0 g/L.

The purpose of this paper is to study the effect of different concentrations of pretreatment solution of copper acetate (1, 5 and 10 g/L) on the deposition, growth and protection ability of zinc phosphate coating.

Zinc phosphate coatings were deposited on steel surface by immersion method. Scanning electron microscopy (SEM) and energy-dispersive spectroscopy (EDS) were used to study the morphological evolution and chemical analysis of formed coatings. The electrochemical performance of the coatings was evaluated via potentiodynamic polarization curves, electrochemical impedance spectroscopy (EIS) and immersion test in an aerated 3.5% NaCl solution.

The results showed that the activation treatment accelerated the deposition of the phosphate coating and improved its surface coverage. A higher phosphate coating weight (7.35 g/m²) and more compact structure was obtained with pretreatment solution of 1 g/L copper acetate. Electrochemical results revealed that the protection ability of the phosphated substrates was markedly enhanced after the pretreatment, and the best corrosion protection was obtained with a concentration of 1 g/L copper acetate solution. The corrosion current density of phosphated substrate was reduced by 64.9% after activation treatment with 1 g/L copper acetate solution.

In this investigation, dense, stable and compact zinc phosphate layers with improved corrosion resistance were formed on a carbon steel surface after activation pretreatment with copper acetate solution prior to a phosphating step.

The phosphatability of a steel surface and, hence, the corrosion protection achieved is related to the quality of that steel surface. It is the intent of this paper to determine what parameters of the steel surface influence phosphatability. This was done by examining the influence of steel surface roughness and contamination on zinc phosphate coating quality, and by determining the relationship of phosphate coating weight and density to the corrosion resistance of painted steel. A high correlation was found between the amount of corrosion creepback of phosphatized and painted steel substrates and the amount of organic carbon present on the surface of the steel. The carbon, analyzed by Auger Electron Spectroscopy, average approximately 50A in depth and is not removed by phosphate precleaning operations. The carbon inhibits the formation and development of phosphate coatings which are required to provide satisfactory corrosion resistance.

This paper aims to achieve phosphating via optimal features of Mg metal as a suitable base coating, which is considered for other properties such as barrier properties against the passage of several factors.

In this research, in the phosphate bath, immersion time, temperature and the content of sodium nitrite as an accelerator were changed.

As a result, increasing the immersion time of AZ31 Mg alloy samples in the phosphating bath as well as increasing the ratio of sodium dodecyl sulfate (SDS) concentration to sodium nitrite concentration in the phosphating bath formulation increase the mass of phosphating formed per unit area of the Mg alloy. The results of the scanning electron microscope test showed phosphating is not completely formed in short immersion times, which is a thin and uneven layer.

Mg and its alloys are sensitive to galvanic corrosion, which would lead to generating several holes in the metal. As such, it causes a decrease in mechanical stability as well as an unfavorable appearance.

Mg is used in several industries such as automobile and computer parts, mobile phones, astronaut compounds, sports goods and home appliances.

Nevertheless, Mg has high chemical reactivity, so an oxide-hydroxide layer is formed on its surface, which has a harmful effect on the adhesion and uniformity of the coating applied on Mg.

By increasing the ratio of SDS concentration to sodium nitrite concentration in the phosphating bath, the corrosion resistance of the phosphating increases.