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The purpose of this paper is to develop a computational model for the simulation of heterojunction organic photovoltaic devices with a specific application to a light harvesting capacitor (LHC) consisting of a double layer of organic materials connected in series with two insulating layers and an external resistive load.

The model is based on a coupled system of nonlinear partial and ordinary differential equations describing current flow throughout the external resistive load as the result of exciton generation in the bulk, exciton dissociation into bonded pairs at the acceptor-donor material interface, and electron/hole charge generation and drift-diffusion transport in the two device materials.

Numerical simulation results are shown to be in good agreement with measured on-off transient currents and allow for novel insight on the microscopical phenomena which affect the external LHC performance, in particular, the widely different time scales at which such phenomena occur and their relation to the overall device dynamics.

The LHC demonstrates the viability of a novel approach for converting light energy into an electric current without a steady state flow of free charge carriers through the semiconducting layers. The new insight about the microscopic working principles that determine the macroscopically observed behavior of the LHC obtained via the model proposed in this paper are expected to serve as a basis for studying techniques for exploiting the full potential of the LHC.

The purpose of this paper is to investigate the effect of [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) on improvement of physical and electrical properties of vanadyl phthalocyanine derivative. The correlation between the physical characteristics of the active layers, comprising vanadyl 2,9,16, 23-tetraphenoxy-29H,31H-phthalocyanine (VOPcPhO) and PCBM, and the electrical properties of metal/organic/metal devices have been studied. The use of soluble vanadyl phthalocyanine derivative makes it very attractive for a variety of applications due to its tunable properties and high solubility.

The sandwich type structures Al/VOPcPhO/Al and Al/VOPcPhO:PCBM/Al were fabricated by spin casting the active organic layers between the top and bottom (aluminum) electrodes. The stand-alone (VOPcPhO) and composite (VOPcPhO:PCBM) thin films were characterized by X-ray diffraction, atomic force microscopy, UV/Vis and Raman spectroscopy. The electronic properties of the metal/organic/metal devices were studied using current-voltage (I-V) characteristics in dark at room temperature.

The values of barrier height for Al/VOPcPhO/Al and Al/VOPcPhO:PCBM/Al devices were obtained from the forward bias I-V curves and were found to be 0.7 eV and 0.62 eV, respectively. The present study indicates that the device employing VOPcPhO:PCBM composite film as the active layer, with better structural and morphological characteristics, results in reduced barrier height at the metal-organic film interface as compared to the one fabricated with the stand-alone film.

It is shown that doping VOPcPhO with PCBM improves the crystallinity, morphology and junction properties.

The spin coating technique provides a simple, less expensive and effective approach for preparing thin films. The soluble VOPcPhO is conveniently dissolved in a number of organic solvents.

The physical properties of the VOPcPhO:PCBM composite thin film and the electrical properties of the composite thin-film-based metal/organic/metal devices have not been reported in the literature, as far as our knowledge is concerned.

This paper aims to provide a technical insight into recent developments in organic lasers and their applications to sensing.

Following a review of progress in organic lasers, this paper considers a number of recent sensor developments based on this technology. Finally, future prospects are briefly considered.

This shows that organic lasers are the tropic of a major research effort. The broad aims are to reduce the optical pumping power and ultimately to achieve purely electrical operation. Few sensors based on organic lasers have yet been reported but recent examples include explosive vapour detectors, lab‐on‐a‐chip devices and biosensors.

This paper provides a review of organic laser developments and sensors that exploit this technology.

The study aims to carry out the production of a bulk heterojunction organic solar cell in a laboratory scale using a blend of poly (3-hexylthiopene) (P3HT) and [6, 6]-phenyl (C61) butyric acid methyl ether (PCBM).

Four inverted geometry organic solar cells were prepared based on 1:1 ratio of P3HT to PCBM and subjected to post annealing at different temperatures of 32, 120, 130 and 140°C. Solar cells were fabricated with structure glass/ITO/P3HT:PCBM/PEDOT:PSS/Au and characterized using Keithley 2400 series sourcemeter and a multimeter interfaced to a computer system with a LabVIEW software, which showed both dark and illumination current–voltage characteristic curves. Four reference cells were also fabricated with structure soda lime glass/P3HT:PCBM and annealed at different temperatures of 32, 120, 130 and 140°C.

The third organic solar cell prepared, Sample CITO, had the best performance with power conversion efficiency (PCE) of 2.0281 per cent, fill factor (FF) of 0.392, short circuit current of −0.0133 A and open circuit voltage of 0.389 V. Annealing of active layer was found to improve cell morphology, FF and PCE. Annealing of the active layer at 140°C resulted in a decrease of the PCE to 2.01 per cent.

These findings are in good agreement with previous investigation in literature which reported that best annealing temperature for a 1:1 ratio blend of active material is 130°C. Ultraviolet–visible spectra on reference cells showed that sample CITO had wider absorption spectra with peak absorbance at a wavelength of 508 nm.

This research is purely original.

For decades, continuous research work is going on to maximize the power harvested from the sun; however, there is only a limited analysis on exploiting the microwatt output power from indoor lightings. Microelectronic system has power demand in the µW range, and therefore, indoor photovoltaics would be appropriate for micro-energy harvesting appliances. “Energy harvesting is defined as the transfer process by which energy source is acquired from the ambient energy, stored in energy storage element and powered to the target systems”. The theory of energy harvesting is: gathering energy from surroundings and offering technological solutions such as solar energy harvesting, wind energy collection and vibration energy harvesting. “The solar cell or photovoltaic cell (PV), is a device that converts light into electric current using the photoelectric effect”. Factors such as light source, temperature, circuit connection, light intensity, angle and height can manipulate the functions of PV cells. Among these, the most noticeable factor is the light intensity that has a major impact on the operations of solar panels.

This paper aims to design an enhanced prediction model on illuminance or irradiance by an optimized artificial neural network (ANN). The input attributes or the features considered here are temperatures, maxim, TSL, VI, short circuit current, open-circuit voltage, maximum power point (MPP) voltage, MPP current and MPP power, respectively. To enhance the performance of the prediction model, the weights of ANN are optimally tuned by a new self-improved brain storm optimization (SI-BSO) model.

The superiority of the implemented work is compared and proved over the conventional models in terms of error analysis and prediction analysis. Accordingly, the presented approach was analysed and its superiority was proved over other conventional schemes such as ANN, ANN-Levenberg–Marquardt (LM), adaptive-network-based fuzzy inference system (ANFIS) and brainstorm optimization (BSO). In addition, analysis was held with respect to error measures such as mean absolute relative error (MARE), mean square root error (MSRE), mean absolute error and mean absolute percentage error. Moreover, prediction analysis was also performed that revealed the betterment of the presented model. More particularly, the proposed ANN + SI-BSO model has attained minimal error for all measures when compared to the existing schemes. More particularly, on considering the MARE, the adopted model for data set 1 was 23.61%, 48.12%, 79.39% and 90.86% better than ANN, ANN-LM, ANFIS and BSO models, respectively. Similarly, on considering data set 2, the MSRE of the implemented model was 99.87%, 70.69%, 99.57% and 94.74% better than ANN, ANN-LM, ANFIS and BSO models, respectively. Thus, the enhancement of the presented ANN + SI-BSO scheme has been validated effectively.

This work has established an improved illuminance/irradiance prediction model using the optimization concept. Here, the attributes, namely, temperature, maxim, TSL, VI, Isc, Voc, Vmpp, Impp and Pmpp were given as input to ANN, in which the weights were chosen optimally. For the optimal selection of weights, a novel ANN + SI-BSO model was established, which was an improved version of the BSO model.

The purpose of this paper is to answer this question by discussing the practicality of implementing microreactor technology towards large-scale renewable energy generation, as well as provide an incentive for future researchers to utilize microreactors as a useful alternative tool for green energy production. However, can microreactors present a viable solution for the generation of renewable energy to tackle the on-going global energy crisis?

In this paper, the practicality of implementing microreactor technology toward large-scale renewable energy generation is discussed. Specific areas of interest that elucidate considerable returns of microreactors toward renewable energy production are biofuel synthesis, hydrogen conversion and solar energy harvesting.

It is believed that sustained research on microreactors can significantly accelerate the development of new energy production methods through renewable sources, which will undoubtedly aid in the quest for a greener future.

This work aims to provide a sound judgement on the importance of research on renewable energy production and alternative energy management methods through microreactor technology, and why future studies on this topic should be highly encouraged. The relevance of this opinion paper lies in the idea that microreactors are an innovative concept currently used in engineering to significantly accelerate chemical reactions on microscale volumes; with the feasibility of high throughput to convert energy at larger scales with much greater efficiency than existing energy production methods.

The purpose of this paper is to study the optical and electrical characteristics of a single-junction solar cell based on a green-colour dye vanadyl 2,9,16, 23-tetraphenoxy-29H, 31H-phthalocyanine (VOPcPhO). The use of soluble vanadyl phthalocyanine derivative makes it very attractive for photovoltaic applications due to its tunable properties and high solubility.

A photoactive layer of VOPcPhO has been sandwiched between indium tin oxide (ITO) and aluminium (Al) electrodes to produce a ITO/PEDOT:PSS/VOPcPhO/Al photovoltaic device. The VOPcPhO thin film is deposited by a simple spin coating technique. To obtain the optimal thickness for the solar cell device, different thicknesses of the photoactive layer, achieved by manipulating the spin rate, have been investigated.

The device exhibited photovoltaic effect with the values of Jsc, Voc and FF equal to 5.26 × 10-6 A/cm2, 0.621 V and 0.33, respectively. The electronic parameters of the cell have been obtained from the analysis of current-voltage characteristics measured in dark. The values of ideality factor and barrier height were found to be 2.69 and 0.416 eV, respectively. The optical examination showed that the material is sensitive to light in the UV region between 270 nm and 410 nm, as well as in the visible spectrum within the range of 630 nm and 750 nm.

The solar cell based on a single layer of vanadyl phthalocyanine derivative results in low efficiency, which can be enhanced by introducing a variety of donor materials to form bulk heterojunction solar cells.

The spin coating technique provides a simple, less expensive and effective approach for preparing thin films.

A novel thin-film, single-junction organic solar cell, fabricated by using VOPcPhO, has been investigated for the first time ever. The vanadyl phthalocyanine derivative together with a donor material will have potential application for improved efficiency of the solar cells.

The purpose of this paper is to introduce flexible dye-sensitized solar cells (FDSSCs).

In the third generation solar cells, glass was used as a substrate, which due to its high weight and fragility, was not possible to produce continuously. However, in flexible solar cells, flexible substrates are used as new technology. The most important thing may choose a suitable substrate to produce a photovoltaic (PV) device with optimal efficiency.

Conductive plastics or metallic foils are the two main candidates for glass replacement, each with its advantages and disadvantages. As some high-temperature methods are used to prepare solar cells, metal substrates can be used to prepare PV devices without any problems. In contrast to the advantage of high thermal resistance in metals, metal substrates are dark and do not transmit enough light. In other words, metal substrates have a high loss of photon energy. Like all technologies, PV devices with polymer substrates have technical disadvantages.

In this study, the development of FDSSCs offers improved photovoltaic properties.

The most important challenge is the poor thermal stability of polymers compared to glass and metal, which requires special methods to prepare polymer solar cells. The second important point is choosing the suitable components and materials for this purpose.

Dependence of efficiency and performance of the device on the angle of sunlight, high-cost preparation devices components, limitations of functional materials such as organic-mineral sensitizers, lack of close connection between practical achievements and theoretical results and complicated fabrication process and high weight.