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Due to herbs and plants’ therapeutic properties and simplicity of availability in nature, humans have used them to treat a variety of maladies and diseases since ancient times. Later, as technology advanced, these plants and herbs gained significant relevance in some industries due to their suitable chemical composition, abundant availability and ease of access. Aegle marmelos is a species of plant that may be found in nature. Yet, little or very little literature was located on the coloration behavior of this plant’s leaves. This study aims to focus on the effect of different parameters on the extraction of colorant from Aegle marmelos leaves.

Some factors that affected on the extraction processes were examined and found to have significant impacts on the textile dyeing such as the initial dye concentration, extracted temperature, extracted bath pH and extracted time were all changed to see how they affected color extraction. The authors report a direct comparison between three heating methods, namely, microwave irradiation (MWI), ultrasonic waves (USW) and conventional heating (CH). The two kinetic models have been designed (pseudo-first and pseudo-second orders) in the context of these experiments to investigate the mechanism of the dyeing processes for fabrics under study. Also, the experimental data were analyzed according to the Langmuir and Freundlich isotherms.

From the result, it was discovered these characteristics were found to have a substantial effect on extraction efficiency. Temperature 90°C and 80°C when using CH and USW, respectively, while at 90% watt when using MWI, period 120 min when using CH as well as USW waves, while 40 min when using MWI, and pH 4, 5 and 10 for polyamide, wool and cotton, respectively, were the optimal extraction conditions. Also, the authors can say that wool gives a higher absorption than the other fabric. Additionally, MWI provided the best color strength (K/S) value, and homogeneity, at low temperatures reducing the energy and time consumed. The coloring follows the order: MWI > USW > CH. The adsorption isotherm of wool could be well fitted by Freundlich isotherm when applying CH and USW as a heating source, while it is well fitted by the Langmuir equation in the case of MWI. In the study, it was observed that the pseudo-first-order kinetic model fits better the experimental results of CH with a constant rate K₁ = −0.000171417 mg/g.min, while the pseudo-second-order kinetic model fits better the experimental results of absorption of both MWI (K2 = 38.14022572 mg/g.min) and USW (K₂ = 12.45343554 mg/g.min).

There is no research limitation for this work. Dye was extracted from Aegle marmelos leaves by applying three different heating sources (MWI, ultrasonic waves [USWW] and CH).

This work has practical applications for the textile industry. It is concluded that using Aegle marmelose leaves can be a possible alternative to extract dye from natural resource by applying new technology to save energy and time and can make the process greener.

Socially, it has a good impact on the ecosystem and global community because the extracted dye does not contain any carcinogenic materials.

The work is original and contains value-added products for the textile industry and other confederate fields.

The present study assesses the impact resistance of the shear thickening fluids-filled (STFs-filled) foam through drop-hammer impact tests.

The maximum residual impact load and specific impact energy absorption rate of STF-filled foam are studied with varying thickness (4–14 mm), densities (0.35–0.6 g/cm3) and hardness (40–50 Rockwell Hardness C Scale (HRC)) under different ambient temperatures (−20−20 °C) and impact energies (25–75 J).

The following conclusions are obtained from this study: (1) the higher the impact energy, the greater the maximum residual impact force and energy absorption efficiency of the material; (2) the impact resistance of STF-filled foam can be improved with the decrease of ambient temperature, achieving the highest energy absorption rate at −10?. (3) STF-filled foam substrate has the highest impact resistance, the lowest maximum residual impact force and the highest energy absorption coefficient when the density is 0.35  g/cm3, the hardness is 45HC and the thickness is 10 mm.

This is the first paper to analyze the impact of both environmental factors and material properties on the impact resistance of STF-filled foam. The results show that the decrease in temperature and the increase in hardness can enhance the impact resistance of STF-filled foam.

This paper aims to find a suitable solution to degrade the C.I. Reactive Red 24 (RR24) dyeing wastewater by using sodium persulphate to recycle water and inorganic salts.

The effects of temperature, the concentration of inorganic salts and Na₂CO₃ and the initial pH value on the degradation of RR24 were studied. Furthermore, the relationship between free radicals and RR24 degradation effect was investigated. Microscopic routes and mechanisms of dye degradation were further confirmed by testing the degradation karyoplasmic ratio of the product. The feasibility of the one-bath cyclic dyeing in the recycled dyeing wastewater was confirmed through the properties of dye utilization and color parameters.

The appropriate conditions were 0.3 g/L of sodium persulphate and treatment at 95°C for 30 min, which resulted in a decolorization rate of 98.4% for the dyeing wastewater. Acidic conditions are conducive to rapid degradation of dyes, while ·OH or SO₄⁻· have a destructive effect on dyes under alkaline conditions. In the early stage of degradation, ·OH played a major role in the degradation of dyes. For sustainable cyclic dyeing of RR24, inorganic salts were reused in this dyeing process and dye uptake increased with the times of cycles. After the fixation, some Na₂CO₃ may be converted to other salts, thereby increasing the dye uptake in subsequent cyclic staining. However, it has little impact on the dye exhaustion rate and color parameters of dyed fabrics.

The recommended technology not only reduces the quantity of dyeing wastewater but also enables the recycling of inorganic salts and water, which meets the requirements of sustainable development and clean production.

Using coconut shell aggregates (CSA) in concrete benefits agricultural waste management and reduces the demand for mineral resources. Several studies have found that concrete containing CSA can achieve strengths that are comparable to regular concrete. The purpose of the present work is to evaluate the concrete’s durability-related properties to supplement these earlier findings.

Cylindrical specimens were prepared with a constant water–cement ratio of 0.50 and CSA content ranging from 0% to 50% (at 10% increment) by volume of the total coarse aggregates. The specimens were cured for 28 days and then tested for density, surface hardness, electrical resistivity and water sorptivity. The surface hardness was measured to describe the concrete resistance to surface wearing, while the resistivity and sorptivity were evaluated to describe the material’s resistance to fluid penetration.

The results showed that the surface hardness of concrete remained on average at 325 Leeb and did not change significantly with CSA addition. The distribution of surface hardness was also similar across all CSA groups, with the interquartile range averaging 59 Leeb. These results suggest that the cement paste and gravel stiffness had a more pronounced influence on the surface hardness than CSA. On the other hand, concrete became lighter by about 9%, had lower resistivity by 80% and had significantly higher initial sorptivity by up to 110%, when 50% of its natural gravel was replaced with CSA. Future work may be done to improve the durability of CSA when used as coarse aggregate.

The present study is the first to show the lack of correlation between CSA content and surface hardness. It would mean that the surface hardness test may not completely capture the porous nature of CSA-added concrete. The paper concludes that without additional treatment prior to mixing, CSA may be limited only to applications where concrete is not in constant contact with water or deleterious substances.

This study aims to observe the coloring efficacy of graphite (G) and nano bentonite clay (BCNPs) on the adsorption of Basic Blue 5 dye from residual dye bath solution.

Some factors that affected the adsorption processes were examined and found to have significant impacts on the adsorption capacity such as the initial concentration of G and/or BCNPs (Co: 40–2,320 mg/L), adsorbent bath pH (4–9), shaking time (30–150 min.) and initial dye concentration (40–200 mg/L). The adsorption mechanism of dye by using G and/or BCNPs was studied using two different models (first-pseudo order and second-pseudo order diffusion models). The equilibrium adsorption data for the dye understudy was analyzed by using four different models (Langmuir, Freundlich, Temkin modle and Dubinin–Radushkevich) models.

It has been found that the adsorption kinetics follow rather a pseudo-first-order kinetic model with a determination coefficient (R²) of 0.99117 for G and 0.98665 for BCNPs. The results indicate that the Freundlich model provides the best correlation for G with capacities q_max = 2.33116535 mg/g and R² = 0.99588, while the Langmuir model provides the best correlation for BCNPs with R² = 0.99074. The adsorbent elaborated from BCNPs was found to be efficient and suitable for removing basic dyes rather than G from aqueous solutions due to its availability, good adsorption capability, as well as low-cost preparation.

There is no research limitation for this work. Basic Blue 5 dye graphite (G) and nano bentonite clay (BCNPs) were used.

This work has practical applications for the textile industry. It is concluded that using graphite and nano bentonite clay can be a possible alternative to adsorb residual dye from dye bath solution and can make the process greener.

Socially, it has a good impact on the ecosystem and global community because the residual dye does not contain any carcinogenic materials.

The work is original and contains value-added products for the textile industry and other confederate fields.

This study contributes to the literature on eco-innovation (EI) and the circular economy (CE) by providing insights into the factors of external knowledge absorption that facilitate the adoption of a subset of EIss called proactive-EIs. Proactive-EIs involve collaborations among multiple stakeholders, the use of technical knowledge and a greater level of investment than other innovations. In this study, the environmental actions taken by small and medium-sized enterprises (SMEs) in resource-intensive sectors in the European Union (EU) were observed, and elements related to the national context were compared.

The national innovation system (NIS) perspective was adopted using a multilevel framework to assess the determinants of proactive-EIs among SMEs in the EU. The framework involves three levels: micro- (environmental awareness), meso- (external collaboration and intra-industry agglomeration) and macro- (economic complexity, trade openness and government research and development [R&D]). The survey data of 6,188 SMEs in resource-intensive sectors were analysed using a binary logistic regression.

The results showed that public awareness, economic complexity and public sector R&D positively influenced SMEs' adoption of proactive-EIs, whereas external collaboration and sectoral agglomeration negatively influenced adoption.

Among the existing empirical studies on EI, areas related to external knowledge-based innovations and systematic assessments of heterogeneity among EU member states remain underexplored. This study contributed to the literature by assessing the conditions surrounding external knowledge absorption. The findings contribute to the green entrepreneurship literature in the context of developed economies and offer insights for managers and policymakers seeking to promote EIs.

The purpose of this paper was to study the color change kinetics of lac dye in response to aldehydes, carbon dioxide and other food spoilage metabolites for its potential application in intelligent food packaging.

UV–Vis spectroscopy was used to study the color change of dye solution. Ratio of absorbance of dye solution at 528 nm (peak of ionized form) to absorbance at 488 nm (peak of unionized form) was used to study the color change. Color change kinetics was studied in terms of change in absorbance ratio (A₅₂₈/A₄₈₈) with time using zero and first-order reaction kinetics. Lac dye-based indicator was prepared to validate the result of study for monitoring quality of strawberries.

Lac dye was orange-red in acidic medium and purple in alkaline medium. Color change of dye in response to benzaldehyde followed zero-order reaction kinetics, whereas for carbon dioxide first-order model was found best. No color change of dye solution was observed for alcohols, ketones and sulfur compounds. In the validation part, the color of the indicator label changed from purple to orange when the strawberries spoiled.

The study expands application area for lac dye as sensing reagent in intelligent food packaging for spoilage or ripeness detection of fruits and vegetables.

This paper aims to report the effect of titanium oxide (TiO₂) particles on the physical, mechanical, tribological and water resistance properties of 5% NaOH-treated bamboo fiber–reinforced composites.

In this research, the epoxy/bamboo/TiO₂ hybrid composite filled with 0–8 Wt.% TiO₂ particles has been fabricated using simple hand layup techniques, and testing of the developed composite was done in accordance with the American Society for Testing and Materials (ASTM) standard.

The results of this study indicate that the addition of TiO₂ particles improved the mechanical properties of the developed epoxy/bamboo composites. Tensile properties were found to be maximum for 6 Wt.%, and impact strength was found to be maximum for 8 Wt.% TiO₂ particles-filled composite. The highest flexural properties were found at a lower TiO₂ fraction of 2 Wt.%. Adding TiO₂ filler helped to reduce the water absorption rate. The studies related to the wear and friction behavior of the composite under dry and abrasive wear conditions reveal that TiO₂ filler was beneficial in improving the wear performance of the composite.

This research paper attempts to include both TiO₂ filler and bamboo fibers to develop a novel composite material. TiO₂ micro and nanoparticles are promising filler materials; it helps to enhance the mechanical and tribological properties of the epoxy composites and in literature, there is not much work reported, where TiO₂ is used as a filler material with bamboo fiber–reinforced epoxy composites.

Polyethylene terephthalate (PET) as a fiber molding polymer is widely used in aerospace, electrical and electronic, clothing and other fields. The purpose of this study is to improve the thermal insulation performance of polyethylene terephthalate (PET), the SiO₂ aerogel/PET composites slices and fibers were prepared, and the effects of the SiO₂ aerogel on the morphology, structure, crystallization property and thermal conductivity of the SiO₂ aerogel/PET composites slices and their fibers were systematically investigated.

The mass ratio of purified terephthalic acid and ethylene glycol was selected as 1:1.5, which was premixed with Sb₂O₃ and the corresponding mass of SiO₂ aerogel, and SiO₂ aerogel/PET composites were prepared by direct esterification and in-situ polymerization. The SiO₂ aerogel/PET composite fibers were prepared by melt-spinning method.

The results showed that the SiO₂ aerogel was uniformly dispersed in the PET matrix. The thermal insulation coefficient of PET was significantly reduced by the addition of SiO₂ aerogel, and the thermal conductivity of the 1.0 Wt.% SiO₂ aerogel/PET composites was reduced by 75.74 mW/(m · K) compared to the pure PET. The thermal conductivity of the 0.8 Wt.% SiO₂ aerogel/PET composite fiber was reduced by 46.06% compared to the pure PET fiber. The crystallinity and flame-retardant coefficient of the SiO₂ aerogel/PET composite fibers showed an increasing trend with the addition of SiO₂ aerogel.

The SiO₂ aerogel/PET composite slices and their fibers have good thermal insulation properties and exhibit good potential for application in the field of thermal insulation, such as warm clothes. In today’s society where the energy crisis is becoming increasingly serious, improving the thermal insulation performance of PET to reduce energy loss will be of great significance to alleviate the energy crisis.

In this study, SiO₂ aerogel/PET composite slices and their fibers were prepared by an in situ polymerization process, which solved the problem of difficult dispersion of nanoparticles in the matrix and the thermal conductivity of PET significantly reduced.

Herein, this study aims to use our recently tailored and fully characterized poly acrylonitrile (AN)-starch nanoparticle graft copolymer having 60.1 graft yield percentage as a starting substrate for copper ions removal from wastewater effluent after chemical modification with hydroxyl amine via oximation reaction as a calorimetric sensor.

The calorimetric sensor batch technique was used to determine the resin's adsorption capacity, while atomic adsorption spectrometry was used to determine the residual copper ions concentration in the filtrate before and after adsorption. This was done to convert the copolymer's abundant nitrile groups into amidoxime groups, and the resulting poly (amidoxime) resin was used as a copper ion adsorbent. To validate the existence of amidoxime groups, the resin was qualitatively characterized using a rapid vanadium ion test and instrumentally using Fourier transform infrared spectroscopy spectra and scanning electron microscopy morphological analysis.

At pH 7, 400 ppm copper ions concentration and 0.25 g adsorbent at room temperature, the overall adsorption potential of poly (amidoxime) resin was found to be 115.2 mg/g. The process's adsorption, kinetics and isothermal analysis were examined using various variables such as pH, contact time, copper ion concentration and adsorbent dose. To pretend the adsorption kinetics, various kinetics models, including pseudo-first-order and pseudo-second-order, were applied to the experimental results. The kinetic analysis indicated that the pseudo-second-order rate equation promoted the development of the chemisorption phase better than the pseudo-first-order rate equation. In the case of isothermal investigations, a study of observed correlation coefficient (R²) values indicated that the Langmuir model outperformed the Freundlich model in terms of matching experimental data.

To the best of the author's information, there is no comprehensive study for copper ions removal from waste water effluent using the recently tailored and fully characterized poly (AN)-starch nanoparticle graft copolymer having 60.1 graft yield percentage as a starting substrate after chemical modification with hydroxyl amine via oximation reaction as a calorimetric sensor.