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The purpose of this study is to reveal the effect of nano-Al₂O₃ particle addition on the nucleation/growth kinetics, microhardness, wear resistance and corrosion resistance of Co–P–xAl₂O₃ nanocomposite plating.

The kinetics and properties of Co–P–xAl₂O₃ nanocomposite plating prepared by electroplating were investigated by electrochemical measurements, scanning electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy, Vickers microhardness measurement, SRV5 friction and wear tester and atomic force microscopy.

A 12 g/L nano-Al₂O₃ addition in the plating solution can transform the nucleation/growth kinetics of the plating from the 3D progressive model to the 3D instantaneous model. The microhardness of the plating increased with the increase of nano-Al₂O₃ content in plating. The wear resistance of the plating did not adhere strictly to Archard’s law. An even and denser corrosion product film was generated due to the finer grains, with a high corrosion resistance.

The effect of different nano-Al₂O₃ addition on the nucleation/growth kinetics and properties of Co–P–xAl₂O₃ nanocomposite plating was investigated, and an anticorrosion mechanism of Co–P–xAl₂O₃ nanocomposite plating was proposed.

This paper aims to compare the wear behavior, surface roughness, friction coefficient and volume loss of high-velocity oxy-fuel (HVOF) sprayed WC–Co and WC–Cr₃C₂–Ni coatings on AISI 1095 steel with spraying times of 10 and 15 s.

In this study, the pin-on-disc testing technique was used to evaluate the wear characteristics at a speed of 0.24 m/s, load of 40 N and test time of 60 min under dry conditions at room temperature. The wear characteristics were examined and analyzed by scanning electron microscopy and energy dispersive X-ray spectroscopy. The surface roughness of a coated surface was measured, and microhardness measurements were performed on the cross-sectioned and polished surfaces of the coating.

Spraying time and powder material affected the hardness of HVOF coatings due to differences in the porosity of the coated layers. The average hardness of the WC–Cr₃C₂–Ni coating with a spaying time of 15 s was approximately 14% higher than that of the WC–Cr₃C₂–Ni coating with a spraying time of 10 s. Under an applied load of 40 N, the WC–Co coating with a spraying time of 15 s had the lowest variation in the friction coefficient compared with the other coatings. The WC–Co coating with a spraying time of 10 s had the lowest average and variation in volume loss compared to the other coatings. The WC–Cr₃C₂–Ni coating with a spraying time of 10 s exhibited the highest average volume loss. The wear features changed slightly with the spraying time owing to variations in the hardness and friction coefficient.

This study investigated tribological performance of WC–Co; WC-Cr₃C₂-Ni coatings with spraying times of 10 and 15 s using pin-on-disc tribometer by rotating the relatively soft pin (C45 steel) against hard coated substrate (disc).

This paper aims to investigate the effect of Ti₃SiC₂ on the high-temperature tribological behaviors of NiCr coating, which was beneficial to improve the friction-wear performance of hot work mold.

NiCr-Ti₃SiC₂ coatings were prepared on H13 steel substrate by laser cladding. The microstructure, phases and hardness of obtained coatings were analyzed using a super-depth of field microscope, X-ray diffraction and microhardness tester, respectively, and the tribological performance of obtained coatings at 500°C was investigated using a high-temperature tester.

The results show the NiCr-Ti₃SiC₂ coatings are comprised of γ-Ni solid, solution, Ti_xNi_y, TiC and Ti₃SiC₂ phases, and the coating hardness is increased with the increase of Ti₃SiC₂ mass fraction, which is contributed to the fine-grain and dispersion strengthening effect by the addition of Ti₃SiC₂. The NiCr-Ti₃SiC₂ coatings present excellent friction reduction and wear resistance by the synergetic action of Ti₃SiC₂ lubricant and hard phase, and the wear mechanism is predominated by abrasive wear and oxidation wear.

Ti₃SiC₂ phase was used to reinforce the tribological performance of H13 steel at high temperature, and the roles of friction reduction and wear resistance were discussed.

The peer review history for this article is available at: https://publons.com/publon/10.1108/ILT-01-2023-0004/

The purpose of this paper is to use a wear test to determine the effect of sand on the wear rates of materials typically used in aerospace applications. Once a repeatable wear test has been established, it can be used to test any combination of materials or coatings. The effectiveness of several different test methods will also be evaluated, including the sample height, surface roughness and mass difference. In addition, the current work will observe the differences between applying sand before the samples are brought into contact or after. The wear rates obtained from these tests could also be used to predict the wear of other components in similar abrasive particulate environments.

A modified block-on-flat wear test of anodized aluminum on hard coat anodized aluminum was used to study this. The experiments were performed with and without sand to study the effects of the sand. Two methods of adding sand were also evaluated. Weighing and profilometry were used to study the differences between the tests.

Wear rates have been calculated based on both the change in the masses of the samples and the change in the height between the upper and lower samples over the course of each test. The wear rates from the change in the masses are repeatable with and without sand, but the results for the change in height show no repeatability without sand. In addition, only in the presence of sand do the trends for the two methods agree. The wear rate was found to be non-linear as a function of load and therefore not in agreement with Archard’s Wear Law. The wear rate also increased significantly when sand was present in the contact for the duration of the test. The sand appears to change the wear mechanism from an adhesive to an abrasive mechanism. Black wear particles formed both when there was sand and when there was not sand. The source of these particles has been investigated but not determined.

This work has not been previously published and is the original work of the authors.

This study aims to investigate the surface modification on 20CrMnTi gear steel individually treated by diamond-like carbon films and nitride coatings.

For this purpose, the mechanical properties of a-C:H, ta-C and AlCrSiN coatings are characterized by nano-indentation and scratch tests. The friction and wear behaviors of these three coatings are evaluated by ball-on-disc tribological experiments under dry contact conditions.

The results show that the a-C:H coating has the highest coating-substrate adhesion strength (495 mN) and the smoothest surface (Ra is about 0.045 µm) compared with the other two coatings. The AlCrSiN coating shows the highest mean coefficient of friction (COF), whereas the ta-C coating exhibits the lowest one (steady at about 0.16). The carbon-based coatings possess excellent self-lubricating properties compared with nitride ceramic ones, which effectively reduce the COF by about 64%. The major failure mode of carbon-based coatings in dry contact is slight abrasive wear. The damage of AlCrSiN coating is mainly adhesive wear and abrasive wear.

It is suggested that the carbon-based film can effectively improve the friction-reducing and wear resistance performance of the gear steel surface, which has a promising application prospect in the mechanical transmission field.

The peer review history for this article is available at: https://publons.com/publon/10.1108/ILT-05-2023-0129/

The demand for titanium alloys has received massive attention in the aerospace and automotive industry owing to their magnificent electrochemically compatibility and corrosion resistance, high strength at elevated temperatures and high strength-to-weight ratio. Although titanium alloy has impressive mechanical properties, they are challenging to machine or metal form due to its poor heat conductivity, high chemical reactivity, low modulus of elasticity, high friction coefficient and difficult lubricant that limits its application field and increases wear. However, surface treatment coating with the strong metallurgical bond between the titanium alloy matrixes is novel technique to resolve these challenges. This research will illustrate the influence of laser scanning power on the microstructure and tribological behavior of Nickel (NI)-composite claddings fabricated on TC4 titanium alloy to realize the strong metallurgical bond between the titanium alloy and NI-composite coating.

In this research, TiC/TC4 alloy nanocomposites were fabricated based on different laser power and temperatures. TC4 has been selected as a base material instead of TiC for the strong metallurgical bond between the titanium alloy matrixes. Then Ni-composite coating was used as the surface treatment coating on TC4 by laser cladding (LC) technique. The Ni-based alloy coating material powder is good self-fluxing, has high-temperature resistance and is analytically pure with 200 mesh, which can easily overcome the various challenges of titanium alloy. The chemical properties of Ni composite coating include 31.2% Chromium, 8%Titenium and 3.6% Carbon. The prepared surface treatment coating characterization and microstructure behavior are analyzed using optical micrograph, X-ray diffraction, scanning electron microscopes, energy dispersive spectroscopy and electron probe micro analyzer methods.

It is evident that at the beginning of the experiment, if the laser power increased, the quality of the coating increased. An optimal quality of the coating is found when the laser scanning power about 12.55 kJ/cm². Further increased laser power diminished the quality of the coating because the material plasticity had deteriorated. The TiC ceramic particle reinforced phase is dispersed into a two-phase solid solution of β-Ti and γ-Ni. The micro-hardness of the used coating is greater than the base alloy.

This research has practical value in the modern aerospace and automobile industry to increase the application of titanium alloy.

This paper aims to investigate the high temperature corrosion behaviour of ZrO₂-reinforced Cr₂O₃ matrix-based composite coatings on ASTM-SA213-T-22 steel at 900°C in molten salt environment. The different coatings were deposited by high velocity oxy fuel (HVOF) method.

Hot corrosion studies were conducted in simulated boiler environment in silicon carbide tube furnace at 900°C for 50 cycles on bare and HVOF-coated boiler steel specimens. Each cycle consisted 50 h of heating in the simulated boiler environment followed by 20 min of cooling in air. The weight change measurements were performed after each cycle to establish the kinetics of corrosion using thermogravimetric technique. X-ray diffraction and scanning electron microscopy techniques were used to analyse the corroded specimens.

The addition of 20 Wt.% ZrO₂ in Cr₂O₃ helped reduce corrosion rate by 89.25% as compared to that of uncoated specimen. The phase analysis revealed the presence of Cr₂O₃ and ZrO₂ phases in composite coating matrix, which may have prevented the base metal from interacting with the corrosive elements present in the highly aggressive environment and thus had increased the resistance to hot corrosion.

It should be mentioned here that high temperature corrosion behaviour of thermally sprayed ZrO₂–Cr₂O₃ composite coatings has never been studied, and to the best of the authors’ knowledge, it is not available in the literature. Hence, present investigation can provide valuable information for application of ZrO₂-reinforced coatings in high temperature fuel combustion environments.

Here, diazo coupling reaction was imparted on chemically inert lignin isolated from natural resources. Activated lignin was coupled with the diazotised aniline, m-nitroaniline, p-nitroaniline-, and p-anisidine gives organic pigments.

The continuous increase in particle size of pigments confirms addition of diazotised salt to lignin by coupling reaction. Further, the dispersing ability of these coloured pigments were exploited in polymer matrix. Epoxy-polyamine cross linking system was doped with difference percentage of pigments and coated on mild steel metal surface. The morphology of these composites was understood by SEM, particle size, differential scanning calorimeter and thermo gravimetric analysis.

The synthesised organic pigments were characterised by FT-IR, ¹H NMR and UV-visible spectroscopy. It was observed that hiding power of aniline- and m-nitroaniline–based azo pigments was more than p-nitroaniline- and p-anisidine–based azo pigments. Thermal properties as well as water contact angles of coatings were improved with pigment concentration. The chemical resistivity of coating was observed to be improved with the increasing % of lignin-based azo pigment.

Lignin-based azo pigment has great potential to replace metal oxide pigment and provide strategy for utilisation of lingo-cellulosic biowaste material.

The purpose of this paper is to develop a high-performance composite emulsion cement waterproof coating. The coating has excellent durability and is effective in protecting cement mortar substrates from harmful ions.

The polymer cement waterproof coatings with different emulsion compounding ratios were tested for mechanical properties and water resistance after alkali immersion, water immersion, thermal aging and UV aging, and the coatings were analyzed by infrared spectroscopy after aging to evaluate its durability. Meanwhile, the coating that presents favorable durability was applied to cement mortar test blocks. The protective effect of the coating on the test blocks was tested by immersion method, and X-ray diffraction analysis was performed on the eroded test blocks.

The coating with neoprene latex/acrylate latex weight ratio of 90/10 presents favorable durability and has superior overall performance. Besides, when it is applied to cement mortar blocks, the coatings effectively reduced the erosive effect of harmful ions on cement mortar blocks, resulting in much lower mass change ratios and less internal structural damage of the blocks significantly.

The obtained coating will be of great application potential for use in building waterproofing construction. Moreover, the coating can practically prevent chloride ions and sulfate ions from penetrating cement-based materials.

The purpose is to explore the improvement mechanism of coating and laser micro-texture on the surface properties of cemented carbide, so as to give full play to the technical advantages of both and improve the overall surface properties of the material.

The surface hardness of the coating was measured by a microhardness tester, the surface element composition of the coating was tested by an energy spectrum analyzer and the phase was measured by an X-ray diffractometer to observe the surface morphology after the friction and wear experiment.

Laser will generate new oxide and nitride films on the surface of the coating, which will improve the hardness of the coating surface and the bonding strength between the coating and the substrate. The surface micro-texture can collect wear debris during the friction process, reduce abrasive wear and play a good role in inhibiting the expansion of the coating failure zone.

Most of the research on traditional laser coating is to process micro-texture first and then coating. This study is the opposite. In this paper, the modification effect of laser on the coating surface is explored, and the parameters of laser and coating are optimized, which paves the way for the subsequent milling experiments of textured coating tools.