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This paper seeks to summarise the results of available research on the use of high velocity oxy‐fuel (HVOF) thermal‐spray technique to provide protection against high temperature corrosion and erosion‐corrosion of materials.

This paper describes one of the recent thermal‐spray processes, namely HVOF thermal‐spray technology and presents a survey of the studies on the use of this technique to provide protection against corrosion and erosion‐corrosion of high temperature alloys, with a special emphasis on boiler steels.

High temperature corrosion and erosion‐corrosion are serious problems observed in steam‐powered electricity generation plants, gas turbines, internal combustion engines, fluidized bed combustors, industrial waste incinerators and recovery boilers in paper and pulp industries. These problems can be prevented by changing the material or altering the environment, or by separating the component surface from the environment. Corrosion prevention by the use of coatings for separating materials from the environment is gaining importance in surface engineering. Amongst various surface modifying techniques, thermal spraying has developed relatively rapidly due to the use of advanced coating formulations and improvements in coating application technology. One of the variants of thermal spraying, namely HVOF has gained popularity in recent times due to its flexibility for in‐situ applications and superior coating properties.

This review covers mainly information that has been reported previously in the open literature, international journals and some well‐known textbooks.

The paper presents a concise summary of information for scientists and academics, planning to start their research work in the area of surface engineering.

This paper fulfils an identified information/resources need and offers practical help to an individual starting out on a career in the area of surface engineering for erosion‐corrosion and wear.

The purpose of this paper is to investigate the corrosion resistance of high velocity oxy-fuel (HVOF)-sprayed Diamalloy 2002 coating on carbon steel. The coating microstructure is examined in line with the corrosion resistance.

HVOF spraying of coating is achieved, and the coating response to electrolytic solution is measured experimentally in terms of corrosion resistance.

HVOF coating improves the corrosion resistance of the substrate such that the corrosion rate of the substrate is 7.1 mpy and the coating results in 4.5 mpy. However, presence of deep pit sites at the surface suggests the occurrence of preferential corrosion around the splat boundaries. In addition, closely spaced surface texture peaks act as crevice corrosion centers at the surface while initiating the formation of deep pit sites.

This study is limited by experimental investigations. In future, it may be extended to include model studies.

The findings of this study are very useful for those working in the coating industry. However, HVOF coating is limited to high temperature protection in harsh environments.

It is useful for the power industry, particularly for gas turbines.

It is an original work and describes the corrosion resistance of the coating surface. It is found that the coating improved the corrosion resistance of the steel surface.

To examine the tensile properties of high velocity oxy‐fuel (HVOF) sprayed Inconel 625 coating of steel substrate before and after the aqueous corrosion.

Workpieces were cut from steel sheets. After chemical and ultrasonic cleaning, workpiece surfaces were sand blasted and HVOF sprayed Inconel 625 coated. The coated and un‐coated surfaces were subjected to the aqueous corrosion tests for one and three weeks. After the completion of the corrosion tests, tensile properties of the workpieces were examined.

The workpieces subjected to a three weeks static corrosion environment fail at a lower load than the untreated workpiece due to high stiffness. The defect sites in the coating and at the interface act as stress risers and contribute substantially crack initiation and propagation in the coating. Under increasing tensile load in the plastic region, the substrate material can no longer support the coating. This results in extended cracking and gradually spalling of the coat. When the local critical stress for crack propagation is reached, elongated cracks occur, which in turn initiates splitting separation between the adjacent zones in the coating. The shear deformation of the adjusted zones results in the total failures of the coating.

The tests can be extended to include the duplex treated workpieces such as the laser treatment of surface after HVOF sprayed coating. This enhances the bonding of the coating through thermal integration of the coating and the base substrate material.

The results can be used to assess the HVOF sprayed coatings.

This paper provides information on mechanical behavior of HVOF sprayed coating when subjected to the tensile force and offers practical help for the researchers and scientists working in the coating area.

This paper seeks to examine the fatigue properties of HVOF sprayed Inconel‐625 coating of steel substrate before and after the aqueous corrosion.

Workpieces were cut from steel sheets. After chemical and ultrasonic cleaning, workpiece surfaces were sand‐blasted and HVOF sprayed Inconel‐625 coated. The coated and un‐coated surfaces were subjected to the aqueous corrosion tests for one and three weeks. After the completion of the corrosion tests, fatigue properties of the workpieces were examined.

Stainless steel coated workpieces demonstrated excellent fatigue life resistance versus coated carbon steel workpieces. Stainless steel workpieces apparently have a high‐cycle fatigue represented by in excess of 1.50 million cycles without cracking, thereby assuring a high‐fatigue life. The carbon steel specimens have low‐cycle fatigue and consequently a short fatigue life. In addition, high velocity impacting of splats on to the workpiece enhances the hardness of the surface. This, in turn, improves fatigue properties at the interface, particularly for stainless steel workpieces.

The tests can be extended to include the duplex treated workpieces such as the laser treatment of surface after HVOF sprayed coating. This enhances the bonding of the coating through thermal integration of the coating and the base substrate material.

The results can be used to assess the HVOF sprayed coatings.

This paper provides information on the fatigue behavior of HVOF sprayed coatings when subjected to the cyclic load and offers practical help for the researchers and scientists working in the coatings area.

The purpose of this study is to prepare WC-10Co-4Cr coatings using two processes of plasma spraying and high-velocity oxygen fuel (HVOF) spraying. The decarburization behaviors of the different processes are analyzed individually. The microstructural characteristics of the as-sprayed coatings are presented and the wear mechanisms of the different WC–10Co–4Cr coatings are discussed in detail.

The WC–10Co–4Cr coatings were formed on the surface of Q235 steel by plasma and HVOF spraying.

Plasma spraying causes more decarburizing decomposition of the WC phase than HVOF spraying. In the plasma spraying process, η(Cr25Co25W8C2) phase appears and the C content decreases from the top surface of the coating to the substrate.

In this study, two WC–10Co–4Cr coatings on Q235 steel prepared by plasma and HVOF spraying were compared with respect to the sliding wear behavior.

The wear mechanisms of the plasma- and HVOF-sprayed coatings were abrasive and oxidation, respectively.

This paper aims to use the high-velocity oxy fuel (HVOF) spraying process for depositing 93(WC–Cr₃C₂)–7Ni, 75Cr₃C₂–25NiCr, 83WC–17C_O and 86WC–10C_O–4Cr coatings on ASME SA213 T91 to study the corrosion resistance of these coatings in an actual boiler environment.

The HVOF spraying process was used for depositing 93(WC–Cr₃C₂)–7Ni, 75Cr₃C₂–25NiCr, 83WC–17C_O and 86WC–10C_O–4Cr coatings on ASME SA213 T91. All the coatings obtained are found to be uniform, dense and having thickness between 200 and 250 μm. All the coatings were exposed in an actual boiler environment at 900°C temperature for 10 cycles. Each cycle consisted of 100 h heating followed by 1 h cooling at ambient conditions. X-ray diffraction, scanning electron microscopy and energy-dispersive spectroscopy techniques were used to analyse corrosion products.

All the coated samples were found to be having higher corrosion resistance than the uncoated samples. Among coated specimens, 93(WC–Cr₃C₂)–7Ni coating has shown maximum and 75Cr₃C₂–25NiCr coating has shown minimum resistance to corrosion.

This paper is original research.

This paper aims to compare the wear behavior, surface roughness, friction coefficient and volume loss of high-velocity oxy-fuel (HVOF) sprayed WC–Co and WC–Cr₃C₂–Ni coatings on AISI 1095 steel with spraying times of 10 and 15 s.

In this study, the pin-on-disc testing technique was used to evaluate the wear characteristics at a speed of 0.24 m/s, load of 40 N and test time of 60 min under dry conditions at room temperature. The wear characteristics were examined and analyzed by scanning electron microscopy and energy dispersive X-ray spectroscopy. The surface roughness of a coated surface was measured, and microhardness measurements were performed on the cross-sectioned and polished surfaces of the coating.

Spraying time and powder material affected the hardness of HVOF coatings due to differences in the porosity of the coated layers. The average hardness of the WC–Cr₃C₂–Ni coating with a spaying time of 15 s was approximately 14% higher than that of the WC–Cr₃C₂–Ni coating with a spraying time of 10 s. Under an applied load of 40 N, the WC–Co coating with a spraying time of 15 s had the lowest variation in the friction coefficient compared with the other coatings. The WC–Co coating with a spraying time of 10 s had the lowest average and variation in volume loss compared to the other coatings. The WC–Cr₃C₂–Ni coating with a spraying time of 10 s exhibited the highest average volume loss. The wear features changed slightly with the spraying time owing to variations in the hardness and friction coefficient.

This study investigated tribological performance of WC–Co; WC-Cr₃C₂-Ni coatings with spraying times of 10 and 15 s using pin-on-disc tribometer by rotating the relatively soft pin (C45 steel) against hard coated substrate (disc).

The purpose of this paper is to investigate the erosion performance of high velocity oxy fuel- (HVOF) sprayed Al₂O₃–Cr₂O₃ composite coatings under silt slurry conditions.

The requisite HVOF composite coatings has been deposited on the stainless steel substrate (SS-304). The slurry erosion pot tester of make Ducom was used for conducting the silt slurry erosion tests on the required substrates. The comprehensive experiments were conducted at different particle size of silt in the range 212–250, 150–212, 53–106 µm, and the concentration of the silt ranged from 10%–40% by weight. The rotational speed of the pot tester has been varied between 500 and 1,500 revolutions per minute, and the test duration has been kept to 4 h.

The erosion wear resistance of the uncoated SS-304 has been greatly enhanced by the application of HVOF-sprayed Al₂O₃–Cr₂O₃ composite coatings. The addition of CeO₂ has a significant impact in reducing the erosive wear caused by silt slurry. The composite coating powder composition of 65%Cr₂O₃ + 34.5%Al₂O₃ + 0.5%CeO₂ has shown the highest erosion resistance.

The developed coatings have the potential to be used for hydro turbines as subjected to silt slurry conditions.

The erosion wear experiments are conducted comprehensively for coated and uncoated samples and the scanning electron micrographs supports the findings.

This study/paper aims to investigate the erosion wear performance of Ni-based coatings [Ni-Cr-O and NiCrBSiFe-WC(Co)] under sand-water slurry conditions.

A high-velocity oxy-fuel (HVOF) process was used to deposit the Ni-based coatings [Ni-Cr-O and NiCrBSiFe-WC(Co)] on the surface of stainless steel (SS 316L) substrate. A Ducom TR-41 erosion tester was used to conduct the tribological experiments on bare/HVOF coated SS 316L. The erosion wear experiments were carried out for different time durations (1.30-3.00 h) at different impact angles (0-60°) by running the pot tester at different rotational speeds (600-1,500 rev/min). The solid concentration of sand slurry was taken in the range of 30-60 Wt.%. The surface roughness of Ni-based coated surfaces was also measured along the transverse length of the specimens.

Results show the arithmetic mean roughness (Ra) values of Ni-Cr-O and NiCrBSiFe-WC coated SS-316L were 7.04 and 6.67 µm, respectively. The erosion wear SS-316L was almost 3.5 ± 1.5 times greater than that of the NiCrBSiFe-WC coatings. NiBCrSi-WC(Co) sprayed SS-316L showed lower erosion wear than Ni-Cr-O sprayed SS-316L. Microscopically, the eroded Ni-Cr-O coating underwent plowing, microcutting and craters. Ni-Cr-O coating have shown the ductile nature of erosion wear mechanism. NiBCrSi-WC(Co) surface underwent craters, plowing, carbide/boride pullout, fractures and intact. Erosion wear mechanisms on the eroded surface of NiBCrSi-WC(Co) were neither purely ductile nor brittle.

It is a useful technique to estimate the erosion wear of hydraulic machinery coated with Ni-based coatings imposed under mining conditions.

The erosion wear performance of HVOF-sprayed Ni-Cr-O and NiCrBSiFe-WC(Co) powders was investigated through extensive experimentation, and the results are well supported by scanning electron micrographs and 3D topology.

This study aims to investigate the electrochemical corrosion performance of high velocity oxygen fuel (HVOF) sprayed WC–12Co coating in 3.5 Wt.% NaCl solution, which provided a guiding significance on the corrosion resistance of H13 hot work mould steel.

A WC–12Co coating was fabricated on H13 hot work mould steel using a HVOF, and the electrochemical corrosion behaviors of WC–12Co coating and substrate in 3.5 Wt.% NaCl solution was measured using open circuit potential (OCP), potentiodynamic polarization curve (PPC) and electrochemical impedance spectroscopy (EIS) tests.

The OCP and PPC of WC–12Co coating positively shift than those of substrate, its corrosion tendency and corrosion rate decrease to enhance its corrosion resistance. The curvature radius of capacitance curve on the WC–12Co coating is larger than that on the substrate, and the impedance and polarization resistance of WC–12Co coating increase faster than those of substrate, which reduces the corrosion process.

The electrochemical corrosion behaviors of WC–12Co coating and substrate in 3.5 Wt.% NaCl solution is first measured using OCP, PPC and EIS tests, which improve the electrochemical corrosion resistance of H13 hot work mould steel.