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To replicate and extend research on psychopathy and intrinsic interpersonal preferences under the broader umbrella of affiliation, intimacy and antagonism, this paper aims to examine motivational correlates of psychopathy in a nonclinical sample (N = 125).

We used a multimethod design, including self-reports, a behavioral task and a physiological assessment of motive dispositions (automatic affective reactions to stimuli of interpersonal transactions measured with facial electromyography).

Results showed that self-reported psychopathy was negatively associated with self-reported intimacy motive. In the same vein, via the social discounting task, this paper found a negative association between psychopathy and a tendency to share hypothetical monetary amounts with very close others. Finally, regarding fEMG findings, multilevel analyses revealed that although individuals with low levels of psychopathy reacted more positively to affiliative stimuli, individuals with high levels of psychopathy reacted equally positively to both affiliative and antagonistic stimuli, and these results were robust across psychopathy measures. Results remained mostly unchanged on the subscale level.

These findings highlight the contribution of multimethod assessments in capturing nuances of motivation. Implicit physiological measures might be particularly sensitive in capturing motive dispositions in relation to psychopathy. Identifying mechanisms that foster positive connections between psychopathic traits and nonprosocial tendencies may be theoretically and clinically informative, with implications for forensic and penal practices.

This study comprehensively examines entropy generation and thermosolutal performance of a ternary hybrid nanofluid in a partially active porous cabinet. The purpose of this study is to comprehend the intricate phenomena of double diffusion by investigating the dispersion behavior of Al₂O₃, CuO, and Ag nanoparticles in water.

The cabinet design consists of two horizontal walls and two curved walls with the lower border divided into a heated and concentrated region of length b and the remaining sections are adiabatic. The vertical borders are cold and low concentration, while the upper border is adiabatic. Two cavity configurations such as convex and concave are considered. A uniform porous medium is taken within the ternary hybrid nanofluid. This has been characterized by the Brinkman-extended Darcy model. Thermosolutal phenomena are governed by the Navier-Stokes equations and are solved by adopting a higher-order compact scheme.

The present study focuses on exploring the influence of several well-defined parameters, including Rayleigh number, Darcy number, Lewis number, Buoyancy ratio number, nanoparticle volume concentration and heater size. The results indicate that the ternary hybrid nanofluid outperforms both the mono and hybrid nanofluids in all considered aspects.

This study brings forth a significant contribution by uncovering novel flow features that have previously remained unexplored. By addressing a well-defined problem, the work provides valuable insights into the enhancement of thermal transport, with direct implications for diverse engineering devices such as solar collectors, heat exchangers and microelectronics.

This paper aims to prepare a new donor–π–acceptor (D–π–A) and acceptor–π– D–π–A (A–π–D–π–A) phenothiazine (PTZ) in conjugation with vinyl isophorone (PTZ-1 and PTZ-2) were designed and their molecular shape, electrical structures and characteristics have been explored using the density functional theory (DFT). The results satisfactorily explain that the higher conjugative effect resulted in a smaller high occupied molecular orbital–lowest unoccupied molecular orbital gap (Eg). Both compounds show intramolecular charge transfer (ICT) transitions in the ultraviolet (UV)–visible range, with a bathochromic shift and higher absorption oscillator strength, as determined by DFT calculations.

The produced PTZ-1 and PTZ-2 sensors were characterized using various spectroscopic methods, including Fourier-transform infrared spectroscopy and nuclear magnetic resonance spectroscopy (¹H/¹³CNMR). UV–visible absorbance spectra of the generated D–π–A PTZ-1 and A–π–D–π–A PTZ-2 dyes were explored in different solvents of changeable polarities to illustrate positive solvatochromism correlated to intramolecular charge transfer.

The emission spectra of PTZ-1 and PTZ-2 showed strong solvent-dependent band intensity and wavelength. Stokes shifts were monitored to increase with the increase of the solvent polarity up to 4122 cm⁻¹ for the most polar solvent. Linear energy-solvation relationship was applied to inspect solvent-dependent Stokes shifting. Quantum yield (ф) of PTZ-1 and PTZ-2 was also explored. The maximum UV–visible absorbance wavelengths were detected at 417 and 419 nm, whereas the fluorescence intensity was monitored at 586 and 588 nm.

The PTZ-1 and PTZ-2 dyes leading to colorimetric and emission spectral changes together with a color shift from yellow to red.

This study aims to investigate the dual solutions for axisymmetric flow and heat transfer due to a permeable radially shrinking disk in copper oxide (CuO) and silver (Ag) hybrid nanofluids with radiation effect.

The partial differential equations that governed the problem will undergo a transformation into a set of similarity equations. Following this transformation, a numerical solution will be obtained using the boundary value problem solver, bvp4c, built in the MATLAB software. Later, analysis and discussion are conducted to specifically examine how various physical parameters affect both the flow characteristics and the thermal properties of the hybrid nanofluid.

Dual solutions are discovered to occur for the case of shrinking disk (λ < 0). Stronger suction triggers the critical values’ expansion and delays the boundary layer separation. Through stability analysis, it is determined that one of the solutions is stable, whereas the other solution exhibits instability, over time. Moreover, volume fraction upsurge enhances skin friction and heat transfer in hybrid nanofluid. The hybrid nanofluid’s heat transfer also heightened with the influence of radiation.

Flow over a shrinking disk has received limited research focus, in contrast to the extensively studied axisymmetric flow problem over a diverse set of geometries such as flat surfaces, curved surfaces and cylinder. Hence, this study highlights the axisymmetric flow due to a shrinking disk under radiation influence, using hybrid nanofluids containing CuO and Ag. Upon additional analysis, it is evidently shows that only one of the solutions exhibits stability, making it a physically dependable choice in practical applications. The authors are very confident that the findings of this study are novel, with several practical uses of hybrid nanofluids in modern industry.

This paper aims to examine the thermal transmission and entropy generation of hybrid nanofluid filled containers with solid body inside. The solid body is seen as being both isothermal and capable of producing heat. A time-dependent non-linear partial differential equation is used to represent the transfer of heat through a solid body. The current study’s objective is to investigate the key properties of nanoparticles, external forces and particular attention paid to the impact of hybrid nanoparticles on entropy formation. This investigation is useful for researchers studying in the area of cavity flows to know features of the flow structures and nature of hybrid nanofluid characteristics. In addition, a detailed entropy generation analysis has been performed to highlight possible regimes with minimal entropy generation rates. Hybrid nanofluid has been proven to have useful qualities, making it an attractive coolant for an electrical device. The findings would help scientists and engineers better understand how to analyse convective heat transmission and how to forecast better heat transfer rates in cutting-edge technological systems used in industries such as heat transportation, power generation, chemical production and passive cooling systems for electronic devices.

Thermal transmission and entropy generation of hybrid nanofluid are analysed within the enclosure. The domain of interest is a square chamber of size L, including a square solid block. The solid body is considered to be isothermal and generating heat. The flow driven by temperature gradient in the cavity is two-dimensional. The governing equations, formulated in dimensionless primitive variables with corresponding initial and boundary conditions, are worked out by using the finite volume technique with the SIMPLE algorithm on a uniformly staggered mesh. QUICK and central difference schemes were used to handle convective and diffusive elements. In-house code is developed using FORTRAN programming to visualize the isotherms, streamlines, heatlines and entropy contours, which are handled by Tecplot software. The influence of nanoparticles volume fraction, heat generation factor, external magnetic forces and an irreversibility ratio on energy transport and flow patterns is examined.

The results show that the hybrid nanoparticles concentration augments the thermal transmission and the entropy production increases also while the augmentation of temperature difference results in a diminution of entropy production. Finally, magnetic force has the significant impact on heat transfer, isotherms, streamlines and entropy. It has been observed that the external magnetic force plays a good role in thermal regulations.

Hybrid nanofluid is a desirable coolant for an electrical device. Various nanoparticles and their combinations can be analysed. Ferro-copper hybrid nanofluid considered with the help of prevailing literature review. The research would benefit scientists and engineers by improving their comprehension of how to analyses convective heat transmission and forecast more accurate heat transfer rates in various fields.

Due to its helpful characteristics, ferrous-copper hybrid nanofluid is a desirable coolant for an electrical device. The research would benefit scientists and engineers by improving their comprehension of how to analyse convective heat transmission and forecast more accurate heat transfer rates in cutting-edge technological systems used in sectors like thermal transportation, cooling systems for electronic devices, etc.

Entropy generation is used for an evaluation of the system’s performance, which is an indicator of optimal design. Hence, in recent times, it does a good engineering sense to draw attention to irreversibility under magnetic force, and it has an indispensable impact on investigation of electronic devices.

An efficient numerical technique has been developed to solve this problem. The originality of this work is to analyse convective energy transport and entropy generation in a chamber with internal block, which is capable of maintaining heat and producing heat. Effects of irreversibility ratio are scrutinized for the first time. Analysis of convective heat transfer and entropy production in an enclosure with internal isothermal/heat generating blocks gives the way to predict enhanced heat transfer rate and avoid the failure of advanced technical systems in industrial sectors.

This paper aims to study the fluid flow and heat transfer within the Casson nanofluid confined between disk and cone both rotating with distinct velocities. For a comprehensive investigation, two distinct nano-size particles, namely, silicon dioxide and silicon carbide, are submerged in ethanol taken as the base fluid.

This paper explores the disk and cone contraption mostly encountered for viscosity measurement in various industrial applications such as lubrication industry, hydraulic brakes, pharmaceutical industry, petroleum and gas industry and chemical industry.

It is worth mentioning here that the radially varying temperature profile at the disk surface is taken into the account. The effect of prominent emerging parameters on velocity fields and temperature distribution are studied graphically, while bar graphs are drawn to examine the physical quantities of industrial interest such as surface drag force and heat transfer rate at disk and cone.

To the best of the authors’ knowledge, no study in literature exists that discusses the thermal enhancement of nano-fluidic transport confined between disk and cone both rotating with distinct angular velocities with heat transfer.

This paper aims to study a non-Newtonian micropolar fluid flow over a bidirectional flexible surface for multiple exact solutions of momentum boundary layer and thermal transport phenomenon subject to wall mass flux, second-order slip and thermal jump conditions.

The coupled equations are transformed into ordinary differential equations using similarity variables. Analytical and numerical techniques are used to solve the coupled equations for single, dual or multiple solutions.

The results show that the stretching flow, shrinking flow, the wall drag, thermal profile and temperature gradient manifest large changes when treated for special effects of the standard parameters. The role of critical numbers is definitive in locating the domains for the existence of exact solutions. The nondimensional parameters, such as mass transfer parameter, bidirectional moving parameter, plate deformation strength parameter, velocity slips, material parameter, thermal jump and Prandtl number, are considered, and their physical effects are presented graphically. The presence of governing parameters exhibits special effects on the flow, microrotation and temperature distributions, and various exact solutions are obtained for the special parametric cases.

The originality and value of this work lie in its exploration of non-Newtonian micropolar fluid flow over a bidirectional flexible surface, highlighting the multiple exact solutions for momentum boundary layers and thermal transport under various physical conditions. The study provides insights into the effects of key parameters on flow and thermal behavior, contributing to the understanding of complex fluid dynamics.

The entropy and thermal behavior analyses of non-Newtonian nanofluid double-diffusive natural convection inside complex domains may captivate a bunch of scholars’ attention because of the potential utilizations that they possess in modern industries, for example, heat exchangers, solar energy collectors and cooling of electronic apparatuses. This study aims to investigate the second law and thermal behavior of non-Newtonian double-diffusive natural convection (DDNC) of Al₂O₃-H₂O nanofluid within a C-shaped cavity emplacing two hot baffles and impacted by a magnetic field.

For the governing equations of the complicated and practical system with all considered parameters to be solved via a formidable numerical approach, the finite element method acts as an approach to achieving the desired solution. This method allows us to gain a detailed solution to the studied geometry.

This investigation has been executed for the considered parameters of range, such as power-law index, baffle length, Lewis number, buoyancy ratio, Hartmann number and Rayleigh number. The main results reveal that isothermal and concentration lines are significantly more distorted, indicating intensified concentration and temperature distributions because of the growth of baffle length (L). Nu_ave decreases by 8.4% and 0.8% while it enhances by 49.86% and 33.87%, respectively, because of growth in the L from 0.1 to 0.2 and 0.2 to 0.3.

Such a comprehensive study on the second law and thermal behavior of DDNC of Al₂O₃-H₂O nanofluid within a C-shaped cavity emplacing two hot baffles and impacted by magnetic field has not yet been carried out.

This paper aims to derive a reduced-order model for the heat transfer across the interface between a millimetric thermocapillary liquid bridge from silicone oil and the surrounding ambient gas.

Numerical solutions for the two-fluid model are computed covering a wide parametric space, making a total of 2,800 numerical flow simulations. Based on the computed data, a reduced single-fluid model for the liquid phase is devised, in which the heat transfer between the liquid and the gas is modeled by Newton’s heat transfer law, albeit with a space-dependent Biot function Bi(z), instead of a constant Biot number Bi.

An explicit robust fit of Bi(z) is obtained covering the whole range of parameters considered. The single-fluid model together with the Biot function derived yields very accurate results at much lesser computational cost than the corresponding two-phase fully-coupled simulation required for the two-fluid model.

Using this novel Biot function approach instead of a constant Biot number, the critical Reynolds number can be predicted much more accurately within single-phase linear stability solvers.

The Biot function for thermocapillary liquid bridges is derived from the full multiphase problem by a robust multi-stage fit procedure. The derived Biot function reproduces very well the theoretical boundary layer scalings.

The purpose of this study is to determine the impact of two-phase power law nanofluid on a curved arterial blood flow under the presence of ovelapped stenosis. Over the past couple of decades, the percentage of deaths associated with blood vessel diseases has risen sharply to nearly one third of all fatalities. For vascular disease to be stopped in its tracks, it is essential to understand the vascular geometry and blood flow within the artery. In recent scenarios, because of higher thermal properties and the ability to move across stenosis and tumor cells, nanoparticles are becoming a more common and effective approach in treating cardiovascular diseases and cancer cells.

The present mathematical study investigates the blood flow behavior in the overlapped stenosed curved artery with cylinder shape catheter. The induced magnetic field and entropy generation for blood flow in the presence of a heat source, magnetic field and nanoparticle (Fe₃O₄) have been analyzed numerically. Blood is considered in artery as two-phases: core and plasma region. Power-law fluid has been considered for core region fluid, whereas Newtonian fluid is considered in the plasma region. Strongly implicit Stone’s method has been considered to solve the system of nonlinear partial differential equations (PDE’s) with 10–6 tolerance error.

The influence of various parameters has been discussed graphically. This study concludes that arterial curvature increases the probability of atherosclerosis deposition, while using an external heating source flow temperature and entropy production. In addition, if the thermal treatment procedure is carried out inside a magnetic field, it will aid in controlling blood flow velocity.

The findings of this computational analysis hold great significance for clinical researchers and biologists, as they offer the ability to anticipate the occurrence of endothelial cell injury and plaque accumulation in curved arteries with specific wall shear stress patterns. Consequently, these insights may contribute to the potential alleviation of the severity of these illnesses. Furthermore, the application of nanoparticles and external heat sources in the discipline of blood circulation has potential in the medically healing of illness conditions such as stenosis, cancer cells and muscular discomfort through the usage of beneficial effects.